This disclosure relates to a method of manufacturing a fiber-reinforced resin (FRP: Fiber-Reinforced Plastic) and, specifically, to improvement of a method of manufacturing a fiber-reinforced resin wherein resin is injected from an injection port opened in a direction facing a surface of a reinforcing-fiber substrate, and the resin is then impregnated into the reinforcing-fiber substrate.
When a matrix resin for molding of an FRP is impregnated into a reinforcing-fiber substrate placed in a cavity part of a molding die comprising a plurality of dies, in particular, into a reinforcing-fiber substrate having a large surface area, to shorten the molding time, reduce the cost of manufacture, improve the productivity and the like, an RTM (Resin Transfer Molding) employing a so-called “multi-point” injection method is known wherein resin is injected almost simultaneously from a plurality of injection ports opened in a direction facing the surface of the reinforcing-fiber substrate, and the resin is then impregnated into the reinforcing-fiber substrate, in particular, in the thickness direction thereof (for example, JP-A-2005-246902). Further, to improve the surface quality of a molded article, although an RTM method wherein a surface layer having a resin distribution medium is provided on at least one surface of a reinforcing-fiber substrate placed in a molding die and resin can be quickly distributed in the plane direction of the surface of the reinforcing-fiber substrate (for example, JP-A-2007-269015), and an RTM method wherein a random mat layer is interposed in at least one surface layer part of a reinforcing-fiber substrate so that voids or pinholes are not generated on, in particular, the design surface side to improve the surface quality (for example, JP-A-2005-232601), are also known, in JP '015 and JP '601, an example that injecting resin from an injection port opened in a direction facing the surface of the reinforcing-fiber substrate is not mentioned at all.
As described above, although there are advantages capable of shortening the molding time, reducing the cost of manufacture, maintaining excellent productivity and the like in the method of injecting resin from an injection port opened in a direction facing the surface of the reinforcing-fiber substrate, in particular, in the multi-point injection method, there are possibilities in the conventional methods that the following problems may occur.
Namely, for example, as shown in
Further, as another source causing the design property at the position directly below the injection port to be deteriorated, raised is a matter that in the region of a section located directly below the injection port, released from the injection port, or a downstream section thereof, the resin after injection is desired to be cured for a molded article, but in the interior of the injection port, for the purpose of suppressing the curing of the resin and maintaining a smooth flow of the resin to be injected, the resin is controlled at a relatively low temperature and, consequently, the resin temperature at the part directly below the injection port is liable to become low, and therefore, the curing shrinkage is likely to be gathered to this part.
Paying attention to the above-described problems in the conventional methods, it could be helpful to provide a method of manufacturing a fiber-reinforced resin wherein, in a method of injecting resin from an injection port opened in a direction facing a surface of a reinforcing-fiber substrate, in particular, in the multi-point injection method, by adding an improvement to the reinforcing-fiber substrate side, pressing down of the surface of the reinforcing-fiber substrate due to the injected resin can be suppressed, and the resin layer of the surface can be reduced, thereby improving the design property of the surface of a molded article while maintaining the excellent productivity.
We provide a method of manufacturing a fiber-reinforced resin in which resin is injected into a reinforcing-fiber substrate placed in a molding die from an injection port opened in a direction facing a surface of the reinforcing-fiber substrate, and the resin is then impregnated into the reinforcing-fiber substrate, including forming a space for injected-resin transit passage in the reinforcing-fiber substrate in the molding die by at least partially removing in advance a section of the reinforcing-fiber substrate located directly below the injection port in a thickness direction of the reinforcing-fiber substrate, and impregnating the resin injected from the injection port into the reinforcing-fiber substrate through the space for injected-resin transit passage.
We also provide the method according to the first step, wherein the space for injected-resin transit passage is formed to pass through the reinforcing-fiber substrate in the thickness direction of the reinforcing-fiber substrate.
We further provide the method according to the first step, wherein an area of the space for injected-resin transit passage in a surface direction of the reinforcing-fiber substrate is an opening area of the injection port toward an interior of the molding die or more.
We further provide the method according to the first step, wherein an area of the space for injected-resin transit passage in a surface direction of the reinforcing-fiber substrate is less than an opening area of the injection port toward an interior of the molding die.
We further provide the method according to the first step, wherein a plurality of injection ports are opened, and the space for injected-resin transit passage is formed relative to at least one injection port.
We further provide the method according to the first step, wherein the space for injected-resin transmit passage is formed relative to a plurality of stacked reinforcing-fiber substrates.
We further provide the method according to the first step, wherein the space for injected-resin transmit passage is formed relative to a plurality of stacked reinforcing-fiber substrates, further including disposing an intermediate layer having a resin flowability higher than that of each reinforcing-fiber substrate relative to the plurality of reinforcing-fiber substrates such that a part of the intermediate layer faces the space for injected-resin transit passage.
We further provide the method according to the first step, wherein the molding die includes a double-sided die, and a thickness of a cavity is set at a predetermined thickness decided in advance.
We further provide the method according to the first step, wherein the space for injected-resin transit passage is formed at a position within a product area of an article to be molded.
We further provide the method according to the first step, wherein a method of impregnating resin into the reinforcing-fiber substrate is a constant discharge method.
We further provide the method according to the first step, wherein the space for injected-resin transit passage is formed to pass through the reinforcing-fiber substrate in the thickness direction of the reinforcing-fiber substrate, and wherein an area of the space for injected-resin transit passage in a surface direction of the reinforcing-fiber substrate is an opening area of the injection port toward an interior of the molding die or more.
We further provide the method according to the first step, wherein the space for injected-resin transit passage is formed to pass through the reinforcing-fiber substrate in the thickness direction of the reinforcing-fiber substrate, and wherein an area of the space for injected-resin transit passage in a surface direction of the reinforcing-fiber substrate is less than an opening area of the injection port toward an interior of the molding die.
We further provide the method according to the first step, wherein the space for injected-resin transit passage is formed to pass through the reinforcing-fiber substrate in the thickness direction of the reinforcing-fiber substrate, and wherein a plurality of injection ports are opened, and the space for injected-resin transit passage is formed relative to at least one injection port.
We further provide the method according to the first step, wherein an area of the space for injected-resin transit passage in a surface direction of the reinforcing-fiber substrate is an opening area of the injection port toward an interior of the molding die or more, and wherein a plurality of injection ports are opened, and the space for injected-resin transit passage is formed relative to at least one injection port.
We further provide the method according to the first step, wherein an area of the space for injected-resin transit passage in a surface direction of the reinforcing-fiber substrate is less than an opening area of the injection port toward an interior of the molding die, and wherein a plurality of injection ports are opened, and the space for injected-resin transit passage is formed relative to at least one injection port.
We also provide the method according to the first step, wherein the space for injected-resin transit passage is formed to pass through the reinforcing-fiber substrate in the thickness direction of the reinforcing-fiber substrate, and wherein the space for injected-resin transit passage is formed relative to a plurality of stacked reinforcing-fiber substrates.
We further provide the method according to the first step, wherein an area of the space for injected-resin transit passage in a surface direction of the reinforcing-fiber substrate is an opening area of the injection port toward an interior of the molding die or more, and wherein the space for injected-resin transit passage is formed relative to a plurality of stacked reinforcing-fiber substrates.
We further provide the method according to the first step, wherein an area of the space for injected-resin transit passage in a surface direction of the reinforcing-fiber substrate is less than an opening area of the injection port toward an interior of the molding die, and wherein the space for injected-resin transit passage is formed relative to a plurality of stacked reinforcing-fiber substrates.
We further provide the method according to the first step, wherein a plurality of injection ports are opened, and the space for injected-resin transit passage is formed relative to at least one injection port, and wherein the space for injected-resin transit passage is formed relative to a plurality of stacked reinforcing-fiber substrates.
We provide methods of manufacturing a fiber-reinforced resin in which resin is injected into a reinforcing-fiber substrate placed in a molding die from an injection port opened in a direction facing a surface of the reinforcing-fiber substrate, and the resin is then impregnated into the reinforcing-fiber substrate, is characterized in that a space for injected-resin transit passage is formed in the reinforcing-fiber substrate in the molding die by at least partially removing in advance a section of the reinforcing-fiber substrate located directly below the injection port in a thickness direction of the reinforcing-fiber substrate, and the resin injected from the injection port is impregnated into the reinforcing-fiber substrate through the space for injected-resin transit passage. Further, the space part also has the advantage of suppressing a sharp pressure elevation immediately after the resin injection and further to adapt the temperature of the resin immediately after being introduced into the molding die to the temperature of the die.
In such a method of manufacturing a fiber-reinforced resin, when the resin is injected from the injection port opened in the direction facing the surface of the reinforcing-fiber substrate, the space for injected-resin transit passage having a form of a hole or the like is formed by at least partially removing in advance a section of the reinforcing-fiber substrate located directly below the injection port, and the injected resin is impregnated into the reinforcing-fiber substrate through the space for injected-resin transit passage. By the presence of the space for injected-resin transit passage, because the resin having been injected from the injection port is first injected into the space for injected-resin transit passage, and therefrom impregnated into the reinforcing-fiber substrate, the initial collision of the resin immediately after being injected from the injection port against the surface of the reinforcing-fiber substrate disappears, or is relieved, the pressing down of the surface of the reinforcing-fiber substrate which had been caused by the collision, is suppressed, depression of the surface is suppressed, and the resin layer of the surface at this part is relieved. By this relief of the resin layer, the curing shrinkage of the resin can be suppressed. Further, because depression of the surface is suppressed, the distortion of the arrangement of reinforcing fibers in the surface layer section of the reinforcing-fiber substrate is also suppressed. Furthermore, after the resin is completely charged into the die, because the space for injected-resin transit passage is filled with only the resin material, it becomes a resin supply source when the resin impregnated into peripheral sections of the reinforcing-fiber substrate is cured and shrunk. As a result, the surface quality of an article to be molded can be greatly improved, and the design property can be improved.
Further, although the above-described space for injected-resin transit passage may be formed at least partially in the thickness direction of the reinforcing-fiber substrate, namely, although it may be formed to some extent in depth from the surface of the reinforcing-fiber substrate at the injection port side, it is preferred that it is formed to pass through the reinforcing-fiber substrate in the thickness direction. In such a structure with respect to the resin injected from the injection port, the resin of initial flow during acceleration does not collide directly with the reinforcing-fiber substrate, and the resin passes through the interior of the space for injected-resin transit passage formed to pass through the reinforcing-fiber substrate, and collides with the inner surface of a die provided at a side opposite to a side of a die provided with the injection port. The power of the injected resin is reduced by the collision to the inner surface of the die and, thereafter, the resin is impregnated into the reinforcing-fiber substrate. Therefore, pressing down of the surface of the reinforcing-fiber substrate, which had been caused by the initial collision, is further suppressed, depression of the surface is further suppressed, the resin layer of the surface at this part is further relieved, and the curing shrinkage of the resin can be further suppressed. Further, because the depression of the surface is further suppressed, distortion of the arrangement of reinforcing fibers in the surface layer section of the reinforcing-fiber substrate is also further suppressed. As a result, the surface quality of an article to be molded can be more greatly improved, and the design property can be more improved.
As the area of the space for injected-resin transit passage in the surface direction of the reinforcing-fiber substrate, both of an example wherein it is equal to the opening area of the injection port toward the interior of the molding die, or more, and an example wherein it is less than the opening area of the injection port toward the interior of the molding, can be employed. It may be appropriately selected in consideration of injection speed of resin from the injection port, degree of influence to each other between adjacent injection port sections in case of multi-point injection and the like.
Further, in our methods of manufacturing a fiber-reinforced resin, in particular, when employing multi-point injection, a great effect can be expected to improve the design property of a molded article. Namely, our methods are particularly effective in a case opened with a plurality of injection ports, and in that case, relative to at least one injection port which is considered to be particularly effective, desirably, relative to a plurality of injection ports, the above-described space for injected-resin transit passage may be formed.
Further, the method of manufacturing a fiber-reinforced resin can also be applied when the above-described reinforcing-fiber substrate comprises a plurality of stacked reinforcing-fiber substrates, and the above-described space for injected-resin transit passage may be formed relative to the plurality of stacked reinforcing-fiber substrates.
In the plurality of stacked reinforcing-fiber substrates, it is preferred that an intermediate layer having a resin flowability higher than that of each reinforcing-fiber substrate is disposed relative to the plurality of reinforcing-fiber substrates, and a part of the intermediate layer faces the above-described space for injected-resin transit passage. Namely, it is a structure disposing a material with a better resin flowability than a surface layer side, for the intermediate layer. This flowability is generally defined as a permeability using Darcy's law, and it can be determined by examination. In this structure wherein a material with good flowability is disposed for the intermediate layer, since the resin flowed into the intermediate layer from the space for injected-resin transit passage flows in the layer more quickly than in the reinforcing-fiber substrates stacked on both sides thereof, a part of the resin flowing in the intermediate layer flows from the intermediate layer to the surface layer sides in the thickness direction of the substrate, and resin flows from the intermediate layer to the surface layer sides are formed. This resin flow toward the substrate surface side is likely to press the surface layer side of the stacked body of the plurality of reinforcing-fiber substrates toward the inner surface of the molding die, and by this pressing, the resin-rich part at the substrate surface layer side is further reduced and, therefore, it becomes possible to expect a more excellent design property of the surface of a molded article.
Further, when the above-described molding die comprises a double-sided die, it is preferred that the thickness of a cavity is set at a predetermined thickness decided in advance. The “predetermined thickness decided in advance” substantially means a target thickness of molded article. In the method, as described above, because a depression is hardly generated at a section directly below the injection port, even in the state of the reinforcing-fiber substrate immediately before the resin impregnation and even in the state after the resin impregnation, a target shape with no depression on the surface can be easily maintained, and if the thickness of the cavity is simply set at a target predetermined thickness of a molded article, both the state of the reinforcing-fiber substrate during the resin injection and the state of the molded article after the injection and curing of the resin can be maintained at desirable states.
Further, because the structure is employed wherein the injected resin is impregnated into the reinforcing-fiber substrate through the above-described space for injected-resin transit passage, the resin sent into the space for injected-resin transit passage is left even after the curing and molding. However, in particular, in a molded article having a large area and a relatively complicated shape, in a position within a product area of an article to be molded, there frequently exists a part such as a hole which is required to be cut off after molding. In such a case, the above-described space for injected-resin transit passage can be easily formed at a position within a product area of an article to be molded, for example, at a position within a product area of an article to be molded and at a portion to be cut off after molding, the space for injected-resin transit passage after molding, which is left with cured resin, and the periphery thereof, may be removed as needed, and when there is no problem even if it is left as it is, it can be left as it is.
Further, because an effect can also be expected to reduce a resin viscosity at a position directly below the injection port and accompanying therewith to reduce the injection pressure, it is preferred to employ an injection molding using a constant discharge pump rather than a constant pressure pump. The constant discharge pump means a pump which discharges by adjusting the flow rate by the rotational speed and the displacement of the pump such as a gear pump, an axial piston pump or a plunger pump mounted with a servo motor. Such pumps are excellent in discharge ability at a constant flow rate, on the other hand, have a possibility that when flowing in the interior having a great flow resistance such as in the reinforcing-fiber substrate, the standing up of the back pressure becomes sharp and, therefore, the effect capable of reducing the injection pressure can be exhibited greatly and preferably.
Furthermore, our methods can be suitably employed for a manufacturing method having a plurality of injection ports. For example, in a die having a plurality of parts directly below injection ports, it is difficult to equalize the thicknesses of a cavity and the fiber volume contents of a reinforcing-fiber stacked body at the parts directly below injection ports, and if there is an injection port relatively easy to be flowed therein, the flow pattern is disturbed, and accompanying therewith, an inconvenience occurs. To improve the inconvenience disturbing the flow pattern, although a method of processing and adjusting the die itself can be exemplified, it is not easy when the size of the die is large. On the other hand, it can be easily processed in the actual spot.
Thus, in the method of manufacturing a fiber-reinforced resin, by forming in advance the space for injected-resin transit passage at a section of the reinforcing-fiber substrate located directly below the injection port, pressing down of the surface of the reinforcing-fiber substrate due to the injected resin can be suppressed, the resin layer of the surface is relieved, and it becomes possible to improve the design property of the surface of a molded article while maintaining the excellent productivity.
Hereinafter, the examples of our methods will be explained referring to the figures.
In the above-described method, since the space for injected-resin transit passage 6 having a through hole form is formed at a section of the reinforcing-fiber substrate 4 directly below the injection port 5, the resin 7 having been injected from the injection port 5 is first injected into the space for injected-resin transit passage 6, and therefrom impregnated into the reinforcing-fiber substrate 4, the initial collision of the resin immediately after being injected from the injection port 5 against the surface of the reinforcing-fiber substrate 4 disappears, pressing down of the surface of the reinforcing-fiber substrate 4, which had been caused by the collision, is suppressed, and depression of the surface is suppressed. Further, because the space for injected-resin transit passage 6 is formed as a through hole form, as described above, the injected resin 7 collides with the inner surface of lower die 2, and the power thereof is reduced. Also from this point of view, pressing down of the surface of the reinforcing-fiber substrate 4 is further suppressed, and the depression of the surface is further suppressed. Accordingly, a resin-rich layer or a resin-only layer substantially is not formed on the surface at this section. Therefore, the curing shrinkage of resin in the conventional methods, in which a resin layer had been formed at this section, is suppressed. Further, because depression of the surface is suppressed, distortion of the arrangement of reinforcing fibers in the surface layer section of the reinforcing-fiber substrate 4 such as one shown in
As aforementioned, the above-described method is effective, in particular, for a case of multi-point injection.
Further, in the example shown in
The reinforcing fibers of the used reinforcing-fiber substrate are not particularly restricted. Carbon fibers, glass fibers, aramide fibers, and a combination of these reinforcing fibers, can be used for the substrate. Further, also with respect to the form of the substrate, an arbitrary form such as a woven fabric, a form arranging reinforcing fibers in one direction, a stacked body thereof, can be employed. Furthermore, the matrix resin of the fiber-reinforced resin also is not particularly restricted, and although a thermosetting resin and a thermoplastic rein can be both employed, our methods are particularly effective when curing shrinkage of resin is liable to occur and, further, when a multi-point injection method is used.
Our methods can be applied to manufacture of substantially any fiber-reinforced resin and, in particular, it is suitable for when a good design property is required for a surface of a molded article.
Number | Date | Country | Kind |
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2012-030436 | Feb 2012 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2013/053698 | 2/15/2013 | WO | 00 |