The present disclosure relates to solar modules, and more particularly, to solar modules formed of shingled cells or strips of cells, which deliver a higher module efficiency than conventional ribbon interconnected solar modules.
Over the past few years, the use of fossil fuels as an energy source has been trending downward. Many factors have contributed to this trend. For example, it has long been recognized that the use of fossil fuel-based energy options, such as oil, coal, and natural gas, produces gases and pollution that may not be easily removed from the atmosphere. Additionally, as more fossil fuel-based energy is consumed, more pollution is discharged into the atmosphere causing harmful effects on life close by. Despite these effects, fossil-fuel based energy options are still being depleted at a rapid pace and, as a result, the costs of some of these fossil fuel resources, such as oil, have risen. Further, as many of the fossil fuel reserves are located in politically unstable areas, the supply and costs of fossil fuels have been unpredictable.
Due in part to the many challenges presented by these traditional energy sources, the demand for alternative, clean energy sources has increased dramatically. To further encourage solar energy and other clean energy usage, some governments have provided incentives, in the form of monetary rebates or tax relief, to consumers willing to switch from traditional energy sources to clean energy sources. In other instances, consumers have found that the long-term savings benefits of changing to clean energy sources have outweighed the relatively high upfront cost of implementing clean energy sources.
One form of clean energy, solar energy, has risen in popularity over the past few years. Advancements in semiconductor technology have allowed the designs of solar modules and solar panels to be more efficient and capable of greater output. Further, the materials for manufacturing solar modules and solar panels have become relatively inexpensive, which has contributed to the decrease in costs of solar energy. As solar energy has increasingly become an affordable clean energy option for individual consumers, solar module and panel manufacturers have made available products with aesthetic and utilitarian appeal for implementation on residential structures. As a result of these benefits, solar energy has gained widespread global popularity.
Further details and aspects of exemplary embodiments of the present disclosure are described in more detail below with reference to the appended figures.
The present disclosure is directed to a method including singulating a solar cell to form a plurality of strips, wherein the singulation exposes unpassivated portions of the solar cell, and re-passivating the plurality of strips, wherein the re-passivation eliminates active recombination centers. The method further includes aligning the re-passivated strips in an overlapping pattern, depositing electrically conductive adhesive (ECA) between the overlapped portions of the re-passivated strips, wherein the ECA adheres adjacent re-passivated strips to one another and electrically connects the re-passivated strips to form a string, and encapsulating the string.
The sorting may include sorting the strips to ensure that similar shaped strips are grouped together or placing the singulated strips in a stack with unpassivated portions aligned. Further the method may include covering at least the top and bottom surfaces of the stack or all passivated surfaces of the strips placed in the stack leaving only the unpassivated surfaces exposed. Still further the method may include applying pressure to the stack to limit ingress of passivation materials.
The method may include thermally treating the unpassivated portions of the strips or oxidizing the unpassivated portions of the strips in an ozone chamber, or chemically bathing the unpassivated portions of the strips, or depositing a passivating material on the unpassivated portions of the strips.
The method may include exposing the entire strip to re-passivation, where the re-passivation is undertaken by thermal treatment in a furnace, oxidation in an ozone chamber, or chemically bathing the strips.
The solar cells may be are square solar cells or pseudo-square solar cells. And the solar cells may include bus bars on at least one side and may further include fingers on at least one side.
A further aspect of the present disclosure is directed to method including singulating a solar cell to form two or more strips, wherein the singulation exposes unpassivated portions of the solar cell, re-passivating the plurality of strips, wherein the re-passivation eliminates active recombination centers, aligning the re-passivated strips into a string, electrically connecting the re-passivated strips of the string, and encapsulating the string.
Various aspects of the present disclosure are described hereinbelow with reference to the drawings, which are incorporated in and constitute a part of this specification, wherein:
The present disclosure is directed to a method of forming solar modules and particularly solar modules formed using shingling processes employing strips of solar cells that have undergone a re-passivation process.
The solar cells of the present disclosure are used as the building block of solar modules. A solar cell is made up of a substrate configured to be capable of producing energy by converting light energy into electricity. Examples of suitable photovoltaic material include, but are not limited to, those made from multicrystalline or monocrystalline silicon wafers. These wafers may be processed through the major solar cell processing steps, which include wet or dry texturization, junction diffusion, silicate glass layer removal and edge isolation, silicon nitride anti-reflection layer coating, front and back metallization including screen printing, and firing. The wafers may be further processed through advanced solar processing steps, including adding rear passivation coating and selective patterning to thereby obtain a passivated emitter rear contact (PERC) solar cell, which has a higher efficiency than solar cells formed using the standard process flow mentioned above. The solar cell may be a p-type monocrystalline cell or an n-type monocrystalline cell in other embodiments. Similar to the diffused junction solar cells described as above, other high efficiency solar cells, including heterojunction solar cells, can utilize the same metallization patterns in order to be used for the manufacture of a shingled array module. The solar cell may have a substantially square shape with chamfered corners (a pseudo-square) or a full square shape.
Once the solar cells 10 or 20 are manufactured with the finger 14 patterns either with or without the cut lines 22 as, the cells 10, 20 are ready to be singulated. Singulation is the cutting (often by etching) along the cut line 22. The etching removes material, for example in the cut line 22, to weaken the solar cell 20. Each etching has a depth of between about 10% and about 90% of wafer thickness. The etching may be formed using a laser, a dicing saw, or the like. In an embodiment, the etching extends across the solar cell 10, 20 from edge to edge. In another embodiment, the etching extends from one edge to just short of an opposite edge of the solar cell 10, 20. Once weakened, application of a force to the weakened areas results in the breaking of the solar cell 10, 20 along the etching to form strips 24 as depicted in
In order to singulate, the solar cell 10, 20 is placed on a vacuum chuck including a plurality of fixtures which are aligned adjacent each other to form a base. The vacuum chuck is selected so that the number of fixtures matches the number of discrete sections of the solar cell 10, 20 to be singulated into strips 24. Each fixture has apertures or slits, which provide openings communicating with a vacuum. The vacuum, when desired, may be applied to provide suction for temporarily mechanically coupling the solar cell 10, 20 to the top of the base. To singulate the solar cell 10, 20, the solar cell 10, 20 is placed on the base such that the each discrete section is positioned on top of a corresponding one of the fixtures. The vacuum is powered on and suction is provided to maintain the solar cell 10, 20 in position on the base. Next, all of the fixtures move relative to each other. In an embodiment, multiple ones of the fixtures move a certain distance away from neighboring fixtures thereby causing the discrete sections of the solar cell 10, 20 to likewise move from each other and form resulting strips 24. In another embodiment, multiple ones of the fixtures are rotated or twisted relative to their longitudinal axes thereby causing the discrete sections of the solar cell 10, 20 to likewise move and form resulting strips 24. The rotation or twisting of the fixtures may be effected in a predetermined sequence, in an embodiment, so that no strip 24 is twisted in two directions at once. In still another embodiment, mechanical pressure is applied to the back surface of the solar cell 10, 20 to substantially simultaneously break the solar cell 10, 20 into the strips 24. It will be appreciated that in other embodiments, other processes by which the solar cell 10, 20 is singulated may alternatively be implemented.
After the solar cell 10, 20 is singulated, the strips 24 may optionally be sorted. Though not shown in the figures, a common shape for a solar cell is a so-called pseudo-square, in which the four corners of the cell are chamfered. As a result when singulating pseudo-square cells the two end strips 24 of a pseudo-square solar cell will have a different shape (chamfered corners) than the center three strips 24 (rectangular). Like formed strips 24 are collected and sorted together. In an embodiment, sorting strips 24 is achieved using an auto-optical sorting process. In another embodiment, the strips 24 are sorted according to their position relative to the full solar cell 10, 20. After sorting, strips 24 having chamfered corners are segregated from those strips 24 having rectangular non-chamfered corners. For further processing, in accordance with one aspect of the present disclosure, only like strips 24 are used together (either chamfered or rectangular). Further, depending on which configuration of front and back surfaces (see FIGS. 4, 6, 7, etc.) is utilized, the segregation may require ensuring that the strips 24 are properly aligned with one another.
From these singulated strips 24, solar modules may be formed using shingling techniques as described in co-pending U.S. application Ser. No. 15/622,783 entitled SHINGLED ARRAY SOLAR CELLS AND METHOD OF MANUFACTURING SOLAR MODULES INCLUDING THE SAME, the entire contents of which are incorporated herein by reference.
However, as a result of the singulation process, namely etching and breaking of the solar cell 10, 20 along the cut line, the passivation of the cell 10, 20 is disrupted and native silicon surfaces are exposed, particularly on the side walls of the strips 24, these surfaces are un-passivated. Unpassivated surfaces such as the exposed native silicon surfaces of the strip 24 sidewalls are effective recombination centers and if left untreated result in efficiency losses in the strips 24 and a solar module formed of the strips 24. Active recombination centers permit recombination of photon generated electrons and holes reducing the efficiency of solar cells. Passivation is the process of protecting a solar cell's surfaces by depositing or forming a material which reduces or eliminates the recombination center, particularly at the surface of the solar cell, and therewith enhances solar cell and solar module efficiency. This process also protects the solar cell from unnecessary oxidation, contamination, and other perils of harsh environments. Two common techniques for passivation of surfaces are glassivation and oxide passivation.
Typically the solar cell 10, 20 can be passivated using a number of schemes depending on factors such as the thermal, UV, and long-term stability, the optical properties (e.g., parasitic absorption, refractive index), and the processing requirements (e.g., surface cleaning, available fabrication methods). Silicon nitride (a-SiNx:H) is an important material in Si photovoltaics as it is used in virtually all solar cells as an antireflective coating. a-SiNx:H also provides (some) surface passivation and, for multicrystalline Si, it provides bulk passivation by hydrogenation of bulk defects. Traditionally, thermally-grown SiO2 has been used as effective passivation scheme in high efficiency laboratory cells. Thermal-oxidation generally leads to excellent passivation properties irrespective of doping type and surface concentration. Another widely-investigated material is amorphous Si (a-Si:H). The combination of intrinsic and doped a-Si:H nanolayers (<10 nm) has also been successfully applied in (commercial) hetero junction solar cells.
However, not all of these methods will be appropriate or cost effective for large scale production of solar modules. In accordance with the present disclosure, the un-passivated surfaces could be individually re-passivated by exposing the strips 24 to an oxidizing environment. This exposure will result in the oxidation of the surface to eliminate the active recombination centers. This may be done using, for example, a furnace to heat treat the un-passivated surfaces, or an ozone chamber or chemical bath to chemically treat the un-passivated surface. This may be done in batches where the furnace, chamber, or bath is sized to receive several hundred or even thousands of strips 24 for treatment. After re-passivation, the strips 24 can then be assembled as solar modules and not suffer the reduced power output caused by the unpassivated surfaces.
In an alternative embodiment, rather than exposing the entire strip 24 to the furnace, chamber, or bath, the strips 24 can be collected and formed into a stack. The top and bottom surfaces of the stack are covered, as are the shorter sides of the strips 24 which have not been affected by the singulation process. This stacking may be done in connection with a jig or receptacle that provides the covering for the front and back and desired sides of the strips 24. After careful collection and alignment of all of the strips 24 pressure may be applied to limit the ability of any treatment material entering between any two strips 24. Once so assembled, the entire stack may be placed in the furnace, chamber, or bath for treatment. In this way, impact to the front and back surfaces of the strips 24, which have not been un-passivated and are of greater importance for the production of energy, are not affected in the re-passivation process.
As a further alternative, once assembled in a stack the strips 24 may be placed in a reaction chamber and a thin passivation layer deposited on the un-passivated surfaces. The passivation layer may be formed of amorphous silicon, silicon oxide, silicon nitride, or others. Again, the front and back surfaces of the strips 24, which are the primary surfaces for power generation, are not affected by this additional treatment step.
Once sorted and segregated, and re-passivated, the strips 24 are ready to be assembled into strings 30. To form strings 30, as shown in
Strings 30 formed of strips 24, ten of which are shown here, are disposed over the back sheet. Although not specifically depicted, it will be appreciated that a glass layer is disposed over the strips 24 and electrical connections associated therewith for protective purposes. Here, the strips 24 are rectangular. The strings 30 are disposed side-by-side lengthwise across the solar module 50.
The edges of any two adjacent strings 30 are spaced apart providing a small gap 54 there between. The gap 54 has a uniform width between the two adjacent strings 30 in a range of between about 1 mm and about 5 mm. In another embodiment, the edges of two or more of the strings 30 are immediately adjacent each other.
The strings 30 are grouped together, for example, in
In accordance with one embodiment, the series connection of the first string set 54 to the second string set 54 can be made by attaching the negative side of the first string set 54 and the positive side of the second string set 54 to a common bus bar. Alternatively, positive sides of both the first and second string sets 54 may be placed on the same side of the solar module and a cable, wire, or other connector may be used to electrically connect the negative side of the first string set 54 to the positive side of the second string set 54. This second configuration promotes efficiency in manufacturing by allowing all string sets 54 to be placed in the solar module 50 without reorientation of one of them, and reduces the size of the bus bars 54, 55, 58, 60, as well as making all bus bars 54, 55, 58, 60 of similar length rather than having one side be long and the other side formed of two short bus bars, thus reducing the number of components of the entire module 50.
The sets 54 of strings 30 are positioned over an EVA layer and glass in a configuration as described above with respect to the solar module 50. The sets 54 of strings 30 may be placed one at a time over the EVA layer, in an embodiment. Alternatively, the desired number of sets 54 of strings 30 may be substantially simultaneously placed over the EVA layer. Suitable machinery for automated laying up of the sets 54 of strings 30 commonly used in mass production of solar modules 50 may be employed.
To form connections between the sets 54 of strings 30, the strings 30 are interconnected at step 208. For example, bus bars (e.g., bus bars 55, 56, 58, 60) are electrically connected to corresponding portions of the sets 54 of strings 30 via conductive ribbon material. An isolation strip 62 including suitably positioned electrically conductive ribbons (not shown) adhered thereto, is positioned to extend between two adjacent sets 54 of strings 30 in the manner described above. Electrical wires to be hidden in a junction box (not shown) are either protected or otherwise isolated in order to permit the wires to be placed in the junction box at later stages of manufacture.
Next, another encapsulation layer is laid on top of the sets 54 of strings 30 at step 210. Then, a backsheet is positioned over the encapsulation layer at step 212 to form one or more lamination stacks. The backsheet material protects the solar module circuitry from environmental impact. In an embodiment, the back sheet is dimensioned slightly larger than the glass plate to improve the manufacturing yield. In another embodiment, the backsheet material can be replaced with glass to offer even better protection from environment.
After the backsheet layup, the lamination stacks are loaded into a vacuum lamination chamber in which the stacks are adhered to each other under a high temperature profile in vacuum. The particular details of the lamination process are dependent on the specific properties of the encapsulation material used.
After lamination, the module is framed at step 214. Framing is employed to provide mechanical strength that is sufficient to withstand wind and snow conditions after the solar module 50 is installed. In an embodiment, the framing is made up of anodized aluminum material. In another embodiment, the framing is disposed on an outer edge of the solar module 50. In still another embodiment, the framing extends over a portion of the glass and/or the back sheet. Additionally, silicone is used to seal the gap between glass and framing so that the edges of the solar module 50 are protected from unwanted materials that may unintentionally become trapped within the solar module 50 which can interfere with the operation of the solar module 50. As will be appreciated, solar modules 50 without frames may also be formed without departing from the scope of the present disclosure.
After framing, a junction box is installed on the backsheet, and the interconnect ribbons and bus bars (e.g., bus bars 55, 56, 58, 60) are soldered or clamped to contact pads in the junction box at step 216. Silicone potting material may be used to seal the edge of junction box to prevent moisture and or contaminants getting into the solar module 50. In addition, the junction box itself may be potted to prevent the component from corrosion.
The module is tested at step 218. Examples of tests include, but are not limited to flash testing to measure the module power output, electroluminescence testing for crack and micro-crack detection, grounding testing and high pot testing for safety, and the like.
As an alternative, where only the cut sides of the strips 24 are to be re-passivated or exposed to the passivation process, the method requires a step 312 of sorting the singulated strips 24 following singulation. Next the strips 24 are placed in a jig at step 314, which may result in covering the top most string 30, the bottom most string 30, and the sides which had not been previously un-passivated. This prevents the passivation processes from significantly impacting those sides and otherwise affecting the surfaces, their passivation, reflective coatings and metallization patterns. Once placed in the jig to form a stack, pressure is applied in step 316 to the stack to further limit the ability of passivation materials from impacting the front and back surfaces (and passivated sides) of the strips 24. With pressure applied, the stack is placed in the furnace, ozone chamber, or chemical bath at step 318 and passivation is performed in step 320. Alternatively, the stack may be placed in a deposition chamber where a deposition process may be undertaken. Finally, at step 320 the passivation is performed and the strips 24 may then be used to form strings 30 and modules 50 at step 310.
Though the preceding has been described in connection with the formation of strings of shingled strips 24, these same re-passivation techniques can also be undertaken with respect to traditional ribbon interconnected cells. A current trend in ribbon interconnected solar modules is to utilize a half cell, that is the standard 156 mm×156 mm cell is singulated to form two cells 156 mm×78 mm. As described above, these singulated half-cells have two exposed edges in need of re-passivation. The techniques described herein can be employed in the manufacture of modules utilizing these half cells. The main difference in this technique is that rather than shingle the half cells after re-passivation, the half cells are aligned and interconnected with ribbons which are typically soldered to the half cell and then its neighboring half cell, in series to form a string of half cells. Multiple half cell strings can then be connected in parallel across module bus bars to form a module following encapsulation and interconnection of the strings, essentially as described above with the shingled cells.
While several embodiments of the disclosure have been shown in the drawings, it is not intended that the disclosure be limited thereto, as it is intended that the disclosure be as broad in scope as the art will allow and that the specification be read likewise. Any combination of the above embodiments is also envisioned and is within the scope of the appended claims. Therefore, the above description should not be construed as limiting, but merely as exemplifications of particular embodiments. Those skilled in the art will envision other modifications within the scope of the claims appended hereto.
Filing Document | Filing Date | Country | Kind |
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PCT/CN2018/073256 | 1/18/2018 | WO | 00 |