Patent Application
20050147853
This application claims priority to German Application No. 10204124.5, filed Feb. 1, 2002, which priority application is incorporated herein by reference in its entirety.
The present methods relate to the humidification of hydrogen gas to be used in a fuel cell, and in particular, a solid polymer (PEM) fuel cell.
The operation of fuel cells with pure hydrogen, including the recirculation of hydrogen are known. For example, U.S. Pat. No. 6,117,577 describes a design in which hydrogen supplied to the anode of a fuel cell is recirculated. In this case, the recirculation apparatus includes a water separator, which in turn feeds a humidification and cooling system, and further includes a compressor to compensate for pressure drops occurring in the fuel cell itself and the anode of the fuel cell.
Also known in the prior art are designs in which a jet pump or similar device takes the place of the compressor, which requires a very high hydrogen inlet pressure, but if hydrogen pressure tanks are used, then a high inlet pressure is already available.
In addition, U.S. Pat. No. 5,200,278 describes a design in which hydrogen is recirculated in a similar manner and is supplied to the intake for the anode. This design also uses a compressor or similar device and includes the separation of liquid constituents that are present in the hydrogen.
A further design of the above-mentioned type is described in WO 00/63993, which shows an auxiliary power unit (APU) with a solid polymer fuel cell, in which the hydrogen is recirculated in order to make it possible to consume all of the available hydrogen.
According to the above-mentioned publications, liquid water is fed into the membrane areas for the purpose of humidifying and cooling the fuel cells and the membranes of the fuel cells. Subsequently, this water is discharged via the exhaust gases of the cathode and the anode, together with product water.
However, this design is complicated, since it requires special humidifying systems. There remains a need for a method that does not require a separate humidification step or apparatus.
In the present methods, the fuel is preferably supplied at a higher than normal stoichiometry. This makes a comparatively large amount of gas available for recirculation, due to the larger (excess) quantity of hydrogen that is supplied to the anode. This comparatively large amount of gas is able to absorb and transport moisture, which reaches the anode area due to the difference in partial pressures. This fuel exhaust gas that is present downstream of the anode, together with the moisture contained in the gas, is recirculated to the hydrogen feed stream to the anode by means of a recirculation device, such as a hydrogen recirculation fan or pump. The mixing of the dry hydrogen gas with the recirculated moist hydrogen gas results in a dew point of for example 70° C., in one embodiment in the range of 40° C.-70° C., which ensures adequate humidification of the anode side of the fuel cell membrane.
In one aspect, the present methods may enable operation so that no additional water is required for membrane humidification, such that the need for related apparatus, such as for example humidifiers and similar devices, is eliminated.
These and other aspects will be evident upon reference to the attached Figures and following detailed description.
The hydrogen originates from a hydrogen source 5, shown in the figure with dotted lines. Hydrogen source 5 may for example be a hydrogen tank. For example, pressure tanks or metal hydride storage can be used as hydrogen source 5. It is also possible for the hydrogen to originate from a gas generation system or fuel processing system, which produces a hydrogen-rich gas through reforming. In such a case, suitable purification devices are required to remove from the hydrogen stream substances that cannot be converted in fuel cell 1, i.e. CO2, residues of the reformer source material, inert gases, etc. The nature of hydrogen source 5 is not material to the present methods. All that is required is that hydrogen is made available to fuel cell 1, where, together with oxygen, it is converted to water and electrical energy.
Hydrogen at a pressure p1 and a temperature T1 is provided to anode 3, where it is partially converted to electric current and water together with the oxygen originating in cathode 2. Subsequently, the residual unreacted hydrogen is discharged from anode 3 at a temperature T2 and a pressure p2. Pressure p2 is slightly lower than pressure p1 due to the pressure drop across anode 3.
One aspect of the present methods is that the volumetric flow rate of hydrogen reaching anode 3 is larger than the amount of hydrogen converted in anode 3. The ratio of hydrogen supplied to the anode to hydrogen converted at anode 3 is referred to as the stoichiometric ratio, λ. In accordance with the present methods, this stoichiometric ratio is significantly larger than 1, making it possible to recirculate the hydrogen gas. For this purpose, the hydrogen gas is returned to the anode inlet pipe via a liquid separator 6 and a recirculation device 7, such as a fan. Recirculation device 7 increases the pressure of the recirculated hydrogen exhaust stream to compensate for the pressure drop across anode 3, the subsequent line elements, and liquid separator 6.
The typical pressure levels in the illustrated embodiment are very low. For example, the hydrogen supply pressure p1 may be approximately 5 bar absolute, preferably between 1.5 to 5 bar of absolute pressure, in which case recirculation device 7 depending on the fuel cell would typically have to compensate for pressure drops on the order of several hundred mbar. For high-pressure applications, i.e. where pressure p1 is significantly higher than 5 bar, e.g. 10 or 15 bar, the present methods may be employed, however the energetic benefits may not be as significant as in a low-pressure system or a system that operates at a pressure that is only several hundred mbar higher than ambient pressure.
Hydrogen supplied to anode 3 is typically humidified. The illustrated embodiment does not require any separate humidification component, such as a humidifier, in which water and hydrogen are brought into direct or indirect contact with each other. During the operation of fuel cell 1, a certain amount of product water accumulates in the hydrogen gas flowing through anode 3. Subsequently, the hydrogen gas can return this moisture to the anode through the recirculation system and make it available to the hydrogen gas entering anode 3. After a start-up phase is complete, a saturation state is reached, so that the hydrogen gas will be at its dew point. Consequently, when the hydrogen gas leaves anode 3, it will carry a comparably large quantity of water vapor and possibly liquid water, due to the fact that the outlet temperature T2 is typically higher than the inlet temperature T1.
As the hydrogen gas passes through liquid separator 6, liquid water present in is the hydrogen gas is removed from the stream. The remaining hydrogen gas—containing water vapour—is then mixed with the hydrogen from hydrogen source 5. The humidity of the hydrogen gas entering anode 3 will depend on the set the stoichiometric ratio, λ, and the operating temperature T1.
If, for example, temperature T1 is approximately 60° to 80° C. and temperature T2 is 5 to 15 K higher, then λ can be set so that a particular dew point is reached at pressure p1 and temperature T1, so that water does not need to be added for humidification.
The purpose of
The three curves show that as the temperature difference increases, reaching the point where no additional water is needed requires a smaller and smaller λ. In the described embodiments, λ is between approximately 1.5 and 5. A ΔT of 5 K or 10 K may be considered for practical applications, since the λ required for such a temperature difference will be on the order of 1.5 to 3.5 which can be realized without difficulty in a system of the type illustrated.
Using the present methods, if for example the system is operated according to the solid line for ΔT=15 K, it can be ensured—given a sufficiently high λ—that the anode side of membrane 4 can be humidified without having to resort to humidification of the hydrogen using water supplied from external sources, which would require a corresponding humidification system.
Moreover, it is clearly also possible to manage without a system for recovering as much water as possible from the anode exhaust gas in order to keep the system self-sufficient with respect to its water supply, e.g. a condenser or similar device. The water condensing at the respective dew points is carried in liquid form in the recirculation system and can easily be removed by liquid separator 6, which represents a minimal expense and offers little complexity with respect to hardware and space requirements.
From the foregoing it will be appreciated that, although specific embodiments of the invention have been described herein for purposes of illustration, various modifications may be made without deviating from the spirit and scope of the invention. Accordingly, the invention is not limited except as by the appended claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10204124.5 | Feb 2002 | DE | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP03/00969 | 1/31/2003 | WO |
