Claims
- 1. A method of preparing a saturated hydrofluorocarbon represented by the following general formula (1), the method comprising the step of:
- reducing a chlorofluorocarbon or hydrochlorofluorocarbon represented by the following general formula (2), by hydrogen in a gas phase in the presence of a catalyst comprising elemental palladium and elemental bismuth, said catalyst being carried on a carrier,
- C.sub.n H.sub.p F.sub.z ( 1)
- C.sub.n H.sub.x Cl.sub.y F.sub.z ( 2)
- wherein "n" is an integer within a range from 3 to 6, "x" is an integer within a range from 0 to 2n, each of "y" and "z" is an integer within a range from 1 to 2n+1, x+y+z=2n+2 or 2n, p=x+y when x+y+z=2n+2, and p=x+y+2 when x+y+z=2n,
- wherein, before said step, said palladium and said bismuth are reduced at a temperature within a range from 200.degree. to 500.degree. C., in an atmosphere of hydrogen gas or in the presence of a reducing agent, and
- wherein said chlorofluorocarbon or hydrochlorofluorocarbon and said hydrogen are respectively in the form of gas, and wherein said catalyst is in the form of solid.
- 2. A method according to claim 1, wherein said chlorofluorocarbon or hydrochlorofluorocarbon is one compound selected from the group consisting of 1,3-dichloro-1,1,2,2,3-pentafluoropropane, 3,3-dichloro-1,1,1,2,2-pentafluoropropane, 1,3-dichloro-1,1,2,2,3,3-hexafluoropropane, 1,1,3-trichloro-1,2,2,3,3-pentafluoropropane and 2,3-dichloro-1,1,1,4,4,4-hexafluorobutene-2.
- 3. A method according to claim 1, wherein said carrier is activated carbon.
- 4. A method according to claim 1, wherein the amount of said palladium carried on said carrier is within a range from 0.01 to 20 wt % based on the total weight of said carrier.
- 5. A method according to claim 1, wherein the weight ratio of said bismuth to said palladium is within a range from 0.5:100 to 200:100.
- 6. A method according to claim 1, wherein the number of fluorine atoms of said hydrofluorocarbon is larger than the number of carbon atoms of said hydrofluorocarbon.
- 7. A method according to claim 6, wherein said hydrofluorocarbon is one member selected from the group consisting of 1,1,2,2,3-pentafluoropropane, 1,1,1,2,2-pentafluoropropane, 1,1,2,2,3,3-hexafluoropropane, 1,1,2,2,3-pentafluoropropane, and 1,1,1,4,4,4-hexafluorobutane.
- 8. A method according to claim 6, wherein said hydrofluorocarbon and said hydrochlorofluorocarbon are 1,1,2,2,3-pentafluoropropane and 1,3-dichloro-1,1,2,2,3-pentafluoropropane, respectively.
- 9. A method according to claim 6, wherein said hydrofluorocarbon and said hydrochlorofluorocarbon are 1,1,1,2,2-pentafluoropropane and 3,3-dichloro-1,1,1,2,2-pentafluoropropane, respectively.
- 10. A method according to claim 6, wherein said hydrofluorocarbon and said chlorofluorocarbon are 1,1,2,2,3,3-hexafluoropropane and 1,3-dichloro-1,1,2,2,3,3-hexafluoropropane, respectively.
- 11. A method according to claim 6, wherein said hydrofluorocarbon and said chlorofluorocarbon are 1,1,2,2,3-pentafluoropropane and 1,1,3-trichloro-1,2,2,3,3-pentafluoropropane, respectively.
- 12. A method according to claim 6, wherein said hydrofluorocarbon and said chlorofluorocarbon are 1,1,1,4,4,4-hexafluorobutane and 2,3-dichloro-1,1,1,4,4,4-hexafluorobutene-2, respectively.
- 13. A method according to claim 1, wherein said catalyst further comprises at least one element selected from the group consisting of W, Re, Ta, Os, Mo, Ir, Ru, Nb, Hf, Tl, Sn, Cu, In, Cd, Ag, Pb, Hg, Hf, Zr, Mg, La, and Ce.
- 14. A method according to claim 13, wherein the weight ratio of said at least one element to said palladium is within a range from 0.5:100 to 200:100.
- 15. A method according to claim 1, wherein, when said chlorofluorocarbon or hydrochlorofluorocarbon in the form of gas is reduced in said step and said chlorofluorocarbon or hydrochlorofluorocarbon has a boiling point not higher than 70.degree. C., said step is conducted at a temperature within a range from 70.degree. to 400.degree. C.
Parent Case Info
This is a continuation application of Ser. No. 08/434,363, filed on May 5, 1995, now abandoned.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
5326914 |
Baker |
Jul 1994 |
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Foreign Referenced Citations (4)
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0580181 |
Jan 1994 |
EPX |
2-207038 |
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Continuations (1)
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Number |
Date |
Country |
Parent |
434363 |
May 1995 |
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