The invention concerns a method of producing bristles for applying media through extrusion of a filament which can be cut into bristles and provided with cavities for receiving the medium and from which the medium is discharged during proper use of the bristles, as well as a bristle and brushes comprising such bristles produced in accordance with this method.
Brushes comprising bristles for applying liquid, viscous or powdery media are used mainly for body, hair and mouth care but also in the household and for technical applications. The invention is described below mainly in connection with tooth brushes, one of the main fields of application.
Tooth brushes are known which highlight film on the teeth through application of a suitable indicating color to allow the user of the tooth brush to increase brushing of such indicated tooth locations (DE 195 45 644). Towards this end, the brushes are coated with the indicating color or with microcapsules containing the color and the coating is optionally sealed. A hollow brush with inserted indicating medium is also described in this connection. This document does not explain in detail how these hollow brushes are filled. It is further known (CA 549 168) to jacket the brushes of a single-use tooth brush with a tooth care medium. Bristles are also known (U.S. Pat. No. 5,678,275) whose circumference is provided with irregularly shaped grooves. They do not accommodate media but are supposed to accept soilage particles to remove them from the mouth during brushing of the teeth.
It is furthermore known (WO 98/24341) to accommodate therapeutically effective or other media having dental medical effects in a hollow brush which are released at the free open end of the brush during use. The hollow brush is optionally reinforced by radial walls such that it comprises three or four chambers with parallel axes. The desired media are introduced in liquid form. Towards this end, filaments having the cross-sectional shape of the finished bristles are extruded and several filaments are combined into multi-veined strands having a diameter up to 5.5 cm and a length up to 1.2 m. One end of the strand is dipped into the liquid medium and suction is applied to the opposite open ends of the filaments. Since a high suction pressure is required due to the capillary cavities and the large strand length and since collapsing of the walls due to the elasticity of a suitable plastic must be prevented, the wall must be quite thick and complete filling of the hollow bristles is not possible. Viscous or dispersed media cannot be introduced into the capillary cavities due to the high pressure drop. During use of the bristle, the medium is only discharged via the open end of the bristles and is therefore fully undefined and incomplete.
U.S. Pat. No. 4,775,585 describes a polymer article e.g. in the form of a fiber having a solid cross section. A medium is introduced into portions of the cross section which should be dispensed when the fiber is in use. The portions of the fiber containing the medium can be circular sectors distributed about the periphery or could form an outer ring of the cross section. This configuration does not lead to defined release of the medium.
U.S. Pat. No. 4,010,308 discloses a fiber having a porous coating, hollow portions of which accommodate a medium. The hollow cavities result in relatively rapid and undefined release of the medium. An electrically conducting fiber can be created by using of an electrolyte as the medium and the outer surface of the fiber can be provided with an insulating, impermeable shellac coating. No medium release is therefore envisioned.
It is the underlying purpose of the invention to propose a method for economical introduction of media of arbitrary consistency and effect into a bristle and for discharge thereof in a desired dosage during the useful life of the bristle.
This object is achieved in accordance with the invention by a method according to the independent method claims. In a first embodiment of the invention, the filament is extruded having a core which also determines the mechanical properties of the bristle, with cavities being formed at a separation from the center of the core which open towards the circumference of the filament via a gap formed at the circumference, wherein the cavities are filled with medium from the outside, the gaps being formed such that they are closed in an unloaded state of the bristle and first open in response to pressure generated during proper use of the bristle to release the medium.
In the inventive method, the media is externally introduced into the cavities which are open to the outside, i.e. they must not be suctioned via a pressure drop over a relatively large distance, which would entail corresponding pressure losses. The cavities may therefore be advantageously filled at constant medium density. The consistency of the medium is not important for introduction. It can be liquid, viscous or disperse. Discharge occurs directly through the circumferential openings during use: they are sufficiently narrow to retain the medium and are discharged only during use, e.g. via the forces applied during brushing or through media present at the location of use which interact with the medium in the brush and rinse or dissolve same, i.e. saliva or a tooth care medium for tooth brushes and, in the simplest case, water or moisture for cleaning brushes.
A further advantageous embodiment of the method proposes extrusion of the filament with a core which also determines the mechanical properties of the bristle, with formation of the cavities at a separation from the center of the core, the cavities opening towards the circumference of the filament and being filled with the medium from the outside, wherein the filament is subsequently provided, at least in parts, with a layer which at least partially covers the openings and controls discharge of the medium under normal conditions of brush use. In this method, the shape of the circumferential opening and the opening width are less decisive. The selection of the material of the layer, its thickness and the extent to which the cavities containing the medium are covered can control discharge of the medium over time and in dependence on how long brushes having such bristles are used.
If the cavities are preferably closed by a jacket, the medium can be discharged via the open bristle end or through the openings in the cavities exposed during slow wear of the jacket or also by diffusion through the jacket, wherein the jacket may have a thinner wall than the bristle in accordance with WO 98/24341, since it is not subjected to pressure during filling.
It is particularly economical when the cavities are formed during extrusion of the filament. Therein, the cavities are preferably formed with substantially parallel axes, optionally at a separation from one another.
Another variant consists in that the cavities are formed after extrusion of the filament which would permit a substantially radial formation of cavities having arbitrary contour and arrangement.
Both above-mentioned method variants may provide that the cavities are formed as capillary gaps extending from the center of the core towards the outside or that the cavities are formed as channels with openings which narrow into a gap at the circumference. The capillary gaps produce a retaining effect for the medium and same is discharged only under conditions of use, e.g. bristle pressure, added external media, or the like.
The shape and/or width of the gaps is preferably adjusted to the consistency of the medium. It is furthermore advantageous to form the gaps such that they are completely closed in the unloaded state and open only under pressure.
In a particularly economic fashion, the cavities which open to the outside can be filled in continuous operation on an endless filament, wherein the filament is guided through an optionally pressurized medium bath or through a cross-section, tapering like a nozzle, with the medium being supplied about the circumference. If the opening width of the cavities is large enough and the consistency of the medium sufficiently viscous, filling may also be effected without pressure during continuous operation. In this case, it is advisable to subsequently close the cavities with a jacket disposed on the filament.
The jacket preferably consists of a synthetic thermoplastic material which is extruded onto the filament, filled with the medium. It is preferably extruded with excess size and shrunk onto the filament through cooling to thereby particularly protect temperature sensitive media. Liquid components can not evaporate and temperature reactant components do not decompose. If a jacket made from a plastic material permitting diffusion of the medium is applied, it may optionally be covered in parts by a diffusion-tight material to control diffusion locally and/or the diffusion rate.
If the jacket is made from transparent plastic, medium consumption can be visually monitored, e.g. through corresponding coloration of the medium. The type of media may thereby also be observed.
In addition or instead of displaying the medium and/or its consumption it is possible to provide an effectivity display for the bristle function to guarantee that the bristle is used only as long as it has the properties required for its intended use. The bristle may also be technically designed such that it is used only as long as it is effective, by applying a jacket to the filaments which is made from a thermoplastic material comprising filling agents which determine its wear factor, wherein the plastic and the added filling agents are adjusted to the admissible degree of wear of the bristle during appropriate use. This method can be used to provide any type of bristle, optionally consisting of only a core and a jacket, with an effectivity display. Filling agents which determine the wear factor can, in particular, be solids which reduce the intermolecular bonding in the polymer of the jacket and control the wear factor through their type, size and amount. The solids of an application bristle can be selected such that they simultaneously fulfill a function during application, e.g. calcium carbonate or chloride as mineral agents in tooth brushes. The addition of waxes, in particular ionomer wax, has also proved favorable since they are distributed more uniformly in the polymer matrix and thus provide a uniform wear factor. The sliding behavior of the bristle is also improved. This also permits fine adjustment of an effectivity display.
In accordance with a further method variant, for application, different media having different functions may be disposed in layers or with localized separation and can be discharged at separate locations. In the same fashion, it is possible to locally separate components of an agent, having an affinity to one another, which should be effective only at the location of use. An example thereof is the desired formation or regeneration of calcium fluoride layers on teeth which can be effected in ionising media with Ca(+) and F(−) ions which can be produced from locally separated Ca and F compounds in the moist atmosphere of the mouth and throat area.
The media or active components can also be separately disposed through layered accommodation in the cavities and combined only when dispensed. The diffusion rate of the media or active components can be controlled through the formation of layers.
Furthermore, active components and/or filling agents can be accommodated in the core or in the jacket or in both. Finally, the core may be extruded as a monofilament or multifilament. The core and/or jacket may optionally be foamed during extrusion or afterwards.
The invention finally concerns a bristle which is obtained from the filament produced in accordance with the invention through cutting to the desired length and a brush having a bristle support for mounting bristles of the above-mentioned type thereby forming a bristle field or part thereof.
In some applications, it is recommended to close the bristles at least at their useful end e.g. using thermal methods such as welding, friction welding, laser welding or the like.
The inventive method and bristles produced in accordance with the method are described below by means of some embodiments shown in the drawing.
a shows a first phase of the production of a filament in cross section;
b shows a second phase of the production of a filament in cross section;
c shows a third phase of the production of a filament in cross section;
d shows a fourth phase of the production of a filament in cross section;
e shows a fifth phase of the production of a filament in cross section;
f shows a sixth phase of the production of a filament in cross section;
The filament 1 with cavities 4, extruded and pre-treated in this fashion, is subsequently filled with the medium 6. The filament 1 is drawn through a channel (indicated in
In the embodiment of
In the embodiment in accordance with
The filament of the embodiment in accordance with
In the embodiment of
The embodiment of
In the embodiment of
In the embodiment in accordance with
The filament 1 in accordance with
Number | Date | Country | Kind |
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100 17 306 | Apr 2000 | DE | national |
This is a Continuation of PCT/EP01/03466 filed Mar. 27, 2001 and claims Paris Convention priority of DE 100 17 306.3 filed Apr. 9, 2000 the entire disclosure of which are hereby incorporated by reference.
Number | Name | Date | Kind |
---|---|---|---|
3785919 | Hickman | Jan 1974 | A |
4010308 | Wiczer | Mar 1977 | A |
4775585 | Hagiwara et al. | Oct 1988 | A |
5313909 | Tseng et al. | May 1994 | A |
5678275 | Derfner | Oct 1997 | A |
5836769 | Spencer | Nov 1998 | A |
Number | Date | Country |
---|---|---|
34 00 941 | Oct 1984 | DE |
195 08 539 | Sep 1996 | DE |
195 25 808 | Jan 1997 | DE |
195 33 815 | Mar 1997 | DE |
195 45 644 | Apr 1997 | DE |
197 48 733 | May 1999 | DE |
692 27 777 | May 1999 | DE |
198 18 345 | Oct 1999 | DE |
198 29 943 | Jan 2000 | DE |
0 450 210 | Oct 1991 | EP |
2 323 026 | Sep 1998 | GB |
WO 97 25 902 | Jul 1997 | WO |
WO 98 24 341 | Jun 1998 | WO |
Number | Date | Country | |
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20030044604 A1 | Mar 2003 | US |
Number | Date | Country | |
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Parent | PCT/EP01/03466 | Mar 2001 | US |
Child | 10260961 | US |