Method of producing calcium, sodium or magnesium soaps from fatty acids or oleins from animal or vegetable fats and use thereof as nutrients in monogastric animal feed

Abstract

Procedure for producing calcium, sodium or magnesium fatty acid soaps or vegetable or animal soapstocks and their use as nutrients in monogastric animal feeds. This procedure makes it possible to add glycerol, glycerol plus emulsifier or emulsifier to soaps, and simplifying the process by making the addition in the same production process. The use of these soaps in monogastric animals, such as pigs and fowl, decreases feeding costs compared to the use of whole fats (triglycerides) commonly used in the nutrition of monogastrics. The soaps are obtained in powder or granular form which is an advantage as regards currently giving it in liquid form.

Description

TECHNICAL FIELD

The present invention refers to animal feed, specifically to the preparation of fodder with fats and their use in animal feeds. More specifically, the present invention describes a procedure for the production of calcium, sodium or magnesium fatty acid soaps or vegetable or animal soapstocks to be used as nutrients in monogastric animal feeds.

BACKGROUND OF THE INVENTION

Fats have several nutritional and not strictly nutritional advantages, which makes them suitable for use in fodder. Among the not strictly nutritional uses, are: they control powder formation and improve palatability, consumption, the structure and form of the fodder and moreover, lubricates machinery which improves its performance and useful life. From a nutritional point of view, fats have advantages, such as: they increase the energy content of the fodder, reduce calorie stress and, due to its lower heat increment, improve the energy efficiency per kcal of metabolisable energy.

The key criterion to evaluate a fat is its net energy content. This value basically depends on its gross energy and its intestinal digestibility, which basically depends on its solubilisation capacity and micelle formation in the intestine. Due to the particular digestive characteristics of ruminants (supplementary fat affects the microorganisms in their rumen, and hydrogenates and saturates free fatty acids in the rumen by hydrolysing triglycerides), fat absorption is different to that of monogastric animals, therefore the assessment of the same fat for animal feed will be different depending on whether it is going be used for ruminant or monogastric feeds.

As well as the net energy content, other important criteria when considering the inclusion of a fat in fodder are its availability and price compared to other energy sources. Bearing these criteria in mind, there is growing interest in animal fats,

obtained by processing fats from natural sources for use in feeds. Due to their lower price, among those of note are the by-products of different industries where the raw material is fat and in particular, soapstocks (residues of refined edible fats), lecithins, fried fats, distillates from glycerol production, and others.

In the context of using fats derived from their natural forms, the use of so-called soaps, molecules without glycerol where the fatty acids are saponified, usually by calcium, sodium or magnesium cations, has been extended to animal feeds. Their use has been extended to ruminant feeds in particular. When they are used in monogastric feeds, for economic reasons or ease of use, the results are worse than those obtained with the use of triglycerides, mostly in whole fats, on lacking glycerol, which is considered vital for the formation of micelles, which are only required for good digestibility of the fats by these monogastric animals.

Taking this background into account, the main objective of this invention consists of modifying the process for obtaining these soaps in a way that they can be used in animal feeds in proportions that might improve the production costs of monogastric animal species. This objective is achieved by means of the addition of glycerol and/or emulsifiers, accepted for use in animal feeds by European or international legislation, in the production process of the aforementioned soaps, in proportions that make the use of triglycerides in monogastric animals cheaper and effective.

Thus the use of glycerol, in a variable range that can and must be lower than that contained in triglycerides, added or not to other emulsifiers, will make digestibility easier and improve animal production costs.

SUMMARY OF THE INVENTION

The invention describes a procedure for producing calcium, sodium, or magnesium fatty acid soaps present in vegetable or animal soapstocks or in other fats and their use as nutrients in animal feeds. It consists of incorporating into the aforementioned soaps, glycerol, glycerol plus emulsifier or emulsifier only, already widely used in ruminant feeds, with the aim of extending the use of the described soaps to other, monogastric farm animals, for example pigs and fowl. One advantage is

that the aforementioned incorporation is carried out in the same soap production process and most importantly is that the results of the products obtained rival, energy-wise, whole fats (triglycerides), commonly employed in monogastric nutrition, which leads to improved costs in nutrition, at the same time provided in an easily supplied powder or granular form, which has clear advantages over adding fats in the liquid form known in the state of the technique.

DETAILED DESCRIPTION OF THE INVENTION

The present invention describes a procedure for producing calcium, sodium, or magnesium fatty acid soaps or vegetable or animal soapstocks to which is added a component, glycerol, alone or with emulsifiers in proportions that make them cheaper due to the cost and efficiency of the use of triglycerides in monogastric animals. This compound, glycerol, is bound to fatty acids in molecules, the majority of which are generally in fats of natural origin, triglycerides, while it is lower in the proportion of starting fats used here, the proportion of free fatty acids being much higher that they can give rise to the production of soaps.

The use of glycerol, in a variable range that can and must be less than that contained in triglycerides, adding or not adding emulsifiers, will lead to better digestibility and improve farm animal costs.

One advantage of the present invention is that the addition of glycerol, alone or with authorised emulsifiers, is carried out in the production process of the aforementioned soaps, without added cost or expense to the known procedure.

Another advantage of the present invention is that the products obtained can be competitive, due to their nutritional efficiency, with whole fats commonly used in the nutrition of monogastric animals, which leads to improved costs in nutrition as their use lowers costs.

An additional advantage of the invention is that the products obtained can be supplied in powder or granular form, which is an easier supply form compared to the currently used liquid forms.

In a first aspect, the invention refers to a discontinuous procedure, which can be automated, improved by preparing mixtures that contain glycerol and/or emulsifiers and alkaline or alkaline earth salts elements and saturated or unsaturated fatty acids, which includes the following steps:

(1) heat a fat or a source rich in fatty acids acceptable for animal feed to a temperature that is at least slightly higher than the solidifying temperature of the aforementioned fat;

(2) proceed to add glycerol or an emulsifying agent or combination of the same;

(3) add, or simultaneously with the addition of the glycerol and/or other emulsifying agent, or after that addition, a source of alkaline or alkaline earth ions, which can be an oxide, hydroxide or a salt of the same or one of their mixtures;

(4) homogenise the mixture;

(5) add water;

(6) allow to stand for sufficient time for the fatty acids to saponify;

(7) evaporate the water until almost dry.

In a preferred realisation of the invention, the evaporation of the water is produced either in a container different from the reaction container or over another surface or on a conveyor belt, preferably in a tray, over which the contents of the reaction container are unloaded before there is complete saponification. The aforementioned tray or chosen support, are preferably at ambient (room) temperature and the reaction mixture remains in it until the reaction is completed and when the water has evaporated, until there is a residual content between 2% and 5%.

In this way, a dry and powdery product is obtained, which is cooled and is eventually milled in case there are lumps. Once this product is obtained, it can easily be used for animal feeds as it is, or mixed with any fodder.

An advantage of this discontinuous application option of the invention procedure is that the loading and unloading from the reaction container itself, as well as from the tray where the reaction batch is unloaded so that it continues reacting, can be automated, thus achieving an easy to control, very low cost automated production.

The reaction container is preferably provided with a stirrer and open to the atmosphere. The stirring speed is in the range of 1000 to 5000 rpm.

The amount of water to add will differ according to conditions, depending on factors such as the amount of free fatty acids or the cation source used, but to be able to guarantee the reaction, it will normally vary between 11.5% and 23.5%.

The temperature to which the fat or fatty acid source is heated will be at least higher than the solidifying temperature of the aforementioned fat, in such a way that it may saponify, so that the normal working range is between 45° C. and 100° C. The temperature will, preferably, be such that the fat is in viscous liquid form, capable of being pumped and stirred, without having required an excessive energy cost to heat it up, therefore temperatures in the range of 60° C. to 85° C. are preferred.

The glycerol and/or other emulsifier can be added simultaneously along with the alkaline or alkaline earth ion source compound or before the addition of this compound. It is preferred that the addition of glycerol and/or emulsifying agent is simultaneous with the alkaline or alkaline earth ion source compound as the process may be faster. In any case, the glycerol and/or other emulsifier must be added before adding water, so that the glycerol is already present at the time of saponification and remains homogeneously distributed and incorporated. In this way, a perfect mixture with the oily fraction is obtained in the shortest time.

Glycerol is a by-product obtained from triglyceride refining, which may or may not be subjected to further refining to produce glycerine. In the procedure of this invention the use of unrefined glycerol is preferred. The glycerol proportion will vary depending on the amount of free fatty acids present in the source fat and whether there is an optional emulsifier present, but will vary between 4% and 12%.

The emulsifier may be any of these present in Table 1, which shows a list approved by the European Union for use in animal feed. The proportion to add in each case will vary according to criteria, which includes their emulsifying ability and cost.

TABLE 1
Emulsifying, stabilising, thickening and gelling agents authorised by the
European Union
		Chemical
		formula,	Animal species or animal	Maximum
CE No.	Additive	description	category	age
E-322	Lecithins	—	All animal species or	—
			animal categories
E-400	Alginic acid	—	All animal species or	—
			animal categories
E-401	Sodium alginate	—	All animal species or	—
			animal categories
E-402	Potassium alginate	—	All animal species or	—
			animal categories
E-403	Ammonium alginate	—	All animal species or	—
			animal categories except
			aquarium fish
E-404	Calcium Alginate	—	All animal species or	—
			animal categories
E-405	1,2-propanodiol	—	All animal species or	—
	alginate (propylene		animal categories
	glycol alginate)
E-406	Agar	—	All animal species or	—
			animal categories
E-407	Carrageenan	—	All animal species or	—
			animal categories
E-410	Garrofin gum (carob	—	All animal species or	—
	gum)		animal categories
E-411	Tamarind seed flour	—	All animal species or	—
			animal categories
E-412	Guar gum	—	All animal species or	—
			animal categories
E-413	Traganth	—	All animal species or	—
			animal categories
E-414	Acacia (gum arabic)	—	All animal species or	—
			animal categories
E-415	Xanthan gum	—	All animal species or	—
			animal categories
E-418	Gellan gum	Polytetrasaccharide	Dogs	—
		that contains	Cats
		glucose, glucoronic
		acid, rhamnose
		(2:1:1) produced by
		Pseudomonas
		elodea
		(ATCC31466)
E-420	Sorbitol	—	All animal species or	—
			animal categories
			except aquarium fish
E-421	Mannitol	—	All animal species or	—
			animal categories
E-422	Glycerol	—	All animal species or	—
			animal categories
E-432	Polyoxyethylene	—	All animal species or	—
	sorbitan monolaurate		animal categories
	(polysorbate 20)
E-433	Polyoxyethylene	—	All animal species or	—
	sorbitan monooleate		animal categories
	(polysorbate 80)
E-434	Polyoxyethylene	—	All animal species or	—
	sorbitan		animal categories
	monopalmitate
	(polysorbate 40)
E-435	Polyoxyethylene	—	All animal species or	—
	sorbitan monostearate		animal categories
	(polysorbate 60
E-436	Polyoxyethylene (20)	—	All animal species or	—
	sorbitan tristearate		animal categories
E-440	Pectins	—	All animal species or	—
			animal categories
E-450b(i)	Pentasodium	—	Dogs	—
	triphosphate		Cats
E-460	Microcrystalline	—	All animal species or	—
	cellulose		animal categories
			except aquarium fish
E-460 (ii)	Powdered cellulose	—	All animal species or	—
			animal categories
E-461	Methyl cellulose	—	All animal species or	—
			animal categories
E-462	Ethyl cellulose	—	All animal species or	—
			animal categories
E-463	Hydroxypropyl	—	All animal species or	—
	cellulose		animal categories
E-464	Hydroxypropyl methyl	—	All animal species or	—
	cellulose		animal categories
E-465	Ethyl methyl cellulose	—	All animal species or	—
			animal categories
E-466	Carboxy methyl	—	All animal species or	—
	cellulose (Sodium		animal categories
	carboxy methyl
	cellulose)
E-470	Sodium, potassium	—	All animal species or	—
	and calcium salts of		animal categories
	fatty acids, alone or
	mixed, obtained from
	edible fats or distilled
	nutrient fatty acids
E-471	Mono- and	—		—
	diglycerides of fatty
	acids
E-472	Mono- and	—	—	—
	diglycerides of
	nutrient fatty acids
	esterified with the
	following acids:
	a) acetic
	b) lactic
	c) citric
	d) tartaric
	e) Mono- and diacetyl
	tartaric
E-473	Sucrose esters of fatty	—	All animal species or	—
	acids (saccharose and		animal categories
	nutrient fatty acid
	esters)
E-474	Sucroglycerides	—	All animal species or	—
	(mixture of		animal categories
	saccharose and
	mono- and diglyceride
	of nutrient fatty acids)
E-475	Polyglycerol esters of	—	All animal species or	—
	non-polymerised		animal categories
	nutrient fatty acids
E-477	Propane-1,2-diol	—	All animal species or	—
	esters of fatty acids		animal categories
	(propylene glycol) and
	nutrient fatty acids,
	alone or mixed with
	diesters
E-480	Stearoyl-2-lactylate	—	All animal species or	—
	acid		animal categories
E-481	Sodium stearoyl-2-	—	All animal species or	—
	lactylate		animal categories
E-482	Calcium stearoyl-2-	—	All animal species or	—
	lactylate		animal categories
E-483	Stearyl tartrate	—	All animal species or	—
			animal categories
E-484	polyethylene glycol	—	All animal species or	—
	ricinoleate		animal categories
E-486	Dextrans	—		—
E-487	Polyethlene glycol	—	Calves	—
	ester of soya oil fatty
	acidd
E-488	Suet fatty acid	—	Calves	—
	polyethylated
	glycerides
E-489	Polyglycerol ether and	—	Calves	—
	alcohols obtained by
	oleic and palmitic acid
	reduction.
E-490	1,2-propanodiol	—	Weaning calves	—
			Fattening cattle
			Calves
			Lambs
			Goat kids
			Pigs
			Free range fowl
E-491	Sorbitan	—	All animal species or	—
	monostearate		animal categories
E-492	Sorbitan tristearate	—	All animal species or	—
			animal categories
E-493	Sorbitan monolaurate	—	All animal species or	—
			animal categories
E-494	Sorbitan monooleate	—	All animal species or	—
			animal categories
E-495	Sorbitan monopalmitate	—	All animal species or	—
			animal categories
E-496	Polyethylene Glycol	—	All animal species or	—
	6000		animal categories
E-497	Polyoxypropylene-	—	All animal species or	—
	polyoxyethylene		animal categories
	polymers (PM 6800-9000)
E-498	polyglycerol esters of	—	Dogs	—
	polycondensed ricin
	fatty acids
E-499	Cassia gum	—	Dogs	—
			Cats
			Maximum
		Minimum content	content		End of
		mg/kg of whole	mg/kg of whole	Other	authorisation
	CE No.	fodder	fodder	stipulations	period
	E-322	—	—	All feeds	No time limit
	E-400	—	—	All feeds	No time limit
	E-401	—	—	All feeds	No time limit
	E-402	—	—	All feeds	No time limit
	E-403	—	—	All feeds	No time limit
	E-404	—	—	All feeds	No time limit
	E-405	—	—	All feeds	No time limit
	E-406	—	—	All feeds	No time limit
	E-407	—	—	All feeds	No time limit
	E-410	—	—	All feeds	No time limit
	E-411	—	—	All feeds	No time limit
	E-412	—	—	All feeds	No time limit
	E-413	—	—	All feeds	No time limit
	E-414	—	—	All feeds	No time limit
	E-415	—	—	All feeds	No time limit
	E-418	—	—	Feeds with a	No time limit
				moisture content
				greater than 20%
	E-420	—	—	All feeds	No time limit
	E-421	—	—	All feeds	No time limit
	E-422	—	—	All feeds	No time limit
	E-432	—	5000 (alone or	Only in milk	No time limit
			jointly with other	substitutes
			polysorbates)
	E-433	—	5000 (alone or	Only in milk	No time limit
			jointly with other	substitutes
			polysorbates)
	E-434	—	5000 (alone or	Only in milk	No time limit
			jointly with other	substitutes
			polysorbates)
	E-435	—	5000 (alone or	Only in milk	No time limit
			jointly with other	substitutes
			polysorbates
	E-436	—	5000 (alone or	Only in milk	No time limit
			jointly with other	substitutes
			polysorbates
	E-440	—	—	All feeds	No time limit
	E-450b(i)	—	5000	All feeds	No time limit
			5000
	E-460	—	—	All feeds	No time limit
	E-460 (ii)	—	—	All feeds	No time limit
	E-461	—	—	All feeds	No time limit
	E-462	—	—	All feeds	No time limit
	E-463	—	—	All feeds	No time limit
	E-464	—	—	All feeds	No time limit
	E-465	—	—	All feeds	No time limit
	E-466	—	—	All feeds	No time limit
	E-470	—	—	All feeds	No time limit
	E-471	—	—	All feeds	No time limit
	E-472	—	—	All feeds	No time limit
	E-473	—	—	All feeds	No time limit
	E-474	—	—	All feeds	No time limit
	E-475	—	—	All feeds	No time limit
	E-477	—	—	All feeds	No time limit
	E-480	—	—	All feeds	No time limit
	E-481	—	—	All feeds	No time limit
	E-482	—	—	All feeds	No time limit
	E-483	—	—	All feeds	No time limit
	E-484	—	—	All feeds	No time limit
	E-486	—	—	All feeds	No time limit
	E-487	—	—	All feeds	No time limit
	E-488	—	—	All feeds	No time limit
	E-489	—	5000	Only in milk	No time limit
				substitutes
	E-490	—	12000	All feeds	No time limit
			36000	All feeds	No time limit
			36000	All feeds	No time limit
			36000	All feeds	No time limit
			36000	All feeds	No time limit
			36000	All feeds	No time limit
			36000	All feeds	No time limit
	E-491	—	—	All feeds	No time limit
	E-492	—	—	All feeds	No time limit
	E-493	—	—	All feeds	No time limit
	E-494	—	—	All feeds	No time limit
	E-495	—	—	All feeds	No time limit
	E-496	—	300	All feeds	No time limit
	E-497	—	50	All feeds	No time limit
	E-498	—	—	All feeds	No time limit
	E-499	—	17600	Feeds with a	No time limit
				moisture content
				greater than 20%
			17600	Feeds with a	No time limit
				moisture content
				greater than 20%

The soaps obtained will preferably be calcium, sodium or magnesium soaps. To obtain them, the compounds preferred as a cation source are CaO, NaOH and MgO or combinations of the same. These compounds are added in a stoichiometric or slightly higher quantity to that required, so that all, or almost all, of the free fatty acids present in the fat used form salts.

Calcium oxide (lime) is a basic oxide that is preferentially used as it costs less than magnesium oxide and caustic soda. The source of calcium oxide is mainly burnt limestone which contains around 96% in weight of CaO and around 4% of other oxides. Similarly, the source of MgO is calcined magnesite and the source of caustic soda is NaOH. It is within the scope of the invention to use a mixture of calcium oxide and magnesium oxide in any proportion. The preferable size of the CaO and/or MgO particles is from 30 to 120 micrometres.

Raw Materials

The starting fat that can be used in the invention procedure will be any suitable for animal feed that contains mainly free saturated and/or unsaturated fatty acids with 14 to 20 carbon atoms. The fatty acids commonly found in the domestic animal diet are shown in Table 2:

TABLE 2
Fatty acids commonly found in the domestic animal diet.
(Unsaturated)
Linoleic	CH3—(CH2)4—CH═CH—CH2—CH═CH—(CH2)7—COOH	(C18:2)	−5
Linolenic	CH3—CH2—CH═CH—CH2—CH═CH—CH2—CH═CH—(CH2)7—COOH	(C18:3)	−11
* The first number indicates the total number of carbon atoms and the second one the number of double bonds in the molecule.

In general, the most important fatty acids found in fats of natural origin are those shown in Table 3:

TABLE 3
The most important fatty acids in fats of natural origin
	Saturated
No of C	Acid	Unsaturated Acid	Unsaturated acid formula
4	Butyric		—
6	Capronic		—
8	Caprylic		—
10	Caprinic	Caproleic	CH2═CH—(CH2)7—COOH
12	Lauric	Laurenic	CH3—CH2—CH═CH—(CH2)7—COOH
14	Myristic	Myristoleic	CH3—(CH2)3—CH═CH—(CH2)7—COOH
16	Palmitic	Palmitoleic	CH3—(CH2)5—CH═CH—(CH2)7—COOH
18	Stearic	Oleic	CH3—(CH2)7—CH═CH—(CH2)7—COOH
18	—	Linoleic	CH3—(CH2)4—(CH═CH—CH2)2(CH2)6—COOH
18	—	Linolenic	CH3—(CH2—CH═CH)3—(CH2)7—COOH
18	—	Eleostearic	CH3—(CH2)3—(CH═CH)3—(CH2)7—COOH
20	Arachic	Arachidonic	CH3—(CH2)4—(CH═CH—CH2)4—(CH2)2—COOH
22	Behenic	Erucic	CH3—(CH2)7—CH═CH—(CH2)11—COOH

Among the fats of vegetable origin that can be used, cottonseed, soya, sunflower, rapeseed, corn, olive, palm, coconut, palm kernel, linseed and peanut oil, soya lecithins refined from residues or any of these or their mixtures used in the industry, can be mentioned. These fats contain from around 5% by weight to around 42.5% by weight of palmitic acid; from trace amounts to less than 1% by weight of palmitoleic acid; from around 2% by weight to around 5% by weight of stearic acid; from around 7% by weight to 80% by weight of oleic acid; from around 1% by weight to 62% by weight of linoleic acid, and from trace amounts to around 51% (in linseed oil) of linoleic acid.

Among the fats of animal origin that could be used in the procedure of the invention are suet and lard, which contain around 25% of palmitic acid and 40% oleic acid by weight. As regards stearic acid in these two sources, the percentages are around 20% for suet and around 15% for lard.

In a preferred realisation of the invention the raw material used as a source of fatty acids is a soapstock derived from palm oil refining known as “palm fatty acid distillate” internationally know by its acronym PFAD. This commercial product is obtained industrially by vacuum distilling the fatty acids present in natural palm oil. This soapstock is preferred as it is cheap and accessible and for its good ability to be adapted to the procedure of the invention, among other reasons, as it generally contains a higher percentage of free fatty acids than other soapstocks, 90-95% PFAD compared to the usual 50-60%. Tables 4 and 5 give details of its usual composition, as well as the different physicochemical parameters it exhibits.

	TABLE 4
	CONSTITUENT	CONTENTS
	Free fatty acids	65-95%	by weight
	Triglycerides	5-35%	by weight
	Water	<5%	by weight
	Unsaponifiable	<3%	by weight
	Palmitic Acid	37-46.5%	by weight
	Oleic Acid	36-43%	by weight
	Linoleic Acid	7.5-10.5%	by weight
	Stearic Acid	2.5-5.5	by weight
	Lauric, myristic, linoleic	Trace amounts
	Acids

TABLE 5
PARAMETER           VALUE
Iodine Index        51-55
Melting Point, ° C. 45-47
Peroxide content    <10-12 meq O2/Kg

The melting point of this soapstock is between 40° C.-41° C., therefore, to work with it, the correct temperature would be at least above 45° C., approximately 70° C. being preferable to work with.

Calcium soaps of fatty acids mixed with glycerol are prepared from this soapstock according to the procedure of the invention to include them in fodder. Productive yield tests will be carried out with these fodders on monogastric animals where these fodders have been included in their diet, against control monogastric animals. The comparison tests described below in the corresponding examples show that the products of the invention not only can be used as a substitute for other sources without a loss in yield, but also, in some cases, an increase in growth in the animals can even be observed.

Comparitive Productive Yield Tests

Example 1

Effect on the Productive Yields and Quality of the Carcass of Broiler Chickens by Including Soap with Fatty Acids Distilled from Palm Oil (SCa) and Soap with Fatty Acids Distilled from Palm Oil with Glycerol (SCa+G) in Fowl Fodder

Objective

To determine the effect of including PFAD with glycerol calcium soaps in the diet compared with including PFAD calcium soaps on the productive parameters (average daily consumption, daily weight and conversion index) and the carcass quality of broiler chickens.

Material and Methods

Experimental Animals

A total of 390 Ross male chickens were used, housed according to the experimental treatment.

Experiment Design

Designed to randomise 2 treatments based on 2 feeding schedules according to the fat source (Table 6). In the 0 to 21 day diet (0-21 d) 2 fat sources were used: PFAD calcium soap and PFAD calcium soap+glycerol. Each treatment was replicated 5 times and each replicate was made up of 39 chickens housed in the same pen.

TABLE 6
Experimental treatments.
		AME*	AME*
Treatment	Fat Source	kcal/kg	kcal/kg
1	SCa	2.975	3.050
2	SCa + glycerol	2.975	3.050
*AME: Apparent Metabolisable Energy
Number of treatments:	2
Replicates per treatment:	5
Total replicates:	10
Broilers per replicate:	39
Broilers per treatment:	195
Total broilers:	390

Experimental Diets

The experimental diets were formulated according to the FEDNA raw materials composition tables (1999). All the diets covered or exceeded the USA National Research Council (NRC, 1994) requirements for broilers of this age. All the animals were kept on an ad libitum experimental diet, that is, with free access to food at all times, so they ate as much as they wanted. The diets were in granular form. The quantitative composition and calculated analysis of the experimental diets are shown in Table 7, where, besides the apparent metabolisable energy (AME), the ether extract values (EE), crude protein (CP), available lysine (AL), the available joint methionine-cysteine value (Meth+Cys availability), total phosphorous (P) and available phosphorous (available P), can be observed. The experimental feeds were analysed to determine, moisture, ash content, crude protein (CP), ether extract (after acid hydrolysis) (CF) and crude fibre (CFi), which gave the results presented in Table 8.

TABLE 7
Experimental diet.
	0-21 d		21-42 d
	Raw Material	T1	T2	T1	T2
	Corn	10.5	10.5	22.6	22.6
	Barley	16.0	16.0	6.8	6.8
	Wheat	30.0	30.0	30.0	30.0
	Soya flour 47.5	34.6	34.6	31.6	31.6
	Soya oil	1.0	1.0	1.0	1.0
	Calcium Soap	5.1	—	5.4	—
	Mod. Calcium Soap	—	5.1	—	5.4
	Salt	0.37	0.37	0.38	0.38
	Phosphate	1.50	1.50	1.46	1.46
	DL-Methionine	0.27	0.27	0.25	0.25
	L-Lysine	0.10	0.10	0.05	0.05
	Corrector	0.50	0.50	0.50	0.50
	Nutrients	T7	T8	T7	T8
	AME	2975	2975	3050	3050
	EE	7.0	7.0	7.4	7.4
	CP	22.6	22.6	21.0	21.0
	Avail. lysine	1.16	1.16	1.03	1.03
	Avail. Meth + Cys	0.88	0.88	0.82	0.82
	Ash	5.5	5.5	5.3	5.3
	Ca	0.95	0.95	0.95	0.95
	P	0.68	0.68	0.66	0.66
	Avail. P	0.42	0.42	0.40	0.40
	Na	0.16	0.16	0.16	0.16
	1Analysis calculated according to the FEDNA raw materials composition tables (1999).

TABLE 8
Chemical analysis of the experimental diets
	Moisture	CP	CF	CFi	Ash	Finos	Durability
Trtmnt.	(%)	(%)	(%)	(%)	(%)	(%)	(%)
1 Prestart	10.10	22.00	7.30	3.65	5.15	1.6	99.1
2 Start	10.25	22.45	6.75	3.85	5.25	3.0	98.6
1	11.10	21.35	8.05	3.25	5.15	0.4	98.8
Fattening
2	11.15	21.45	6.95	3.00	5.10	0.5	98.8
Fattening

The analysis of the feed, did not show any differences that might affect the results.

Controls:

Productive parameters and death per replicate (mean daily gain, mean daily consumption and conversion index) at 21 and 42 days.

Statistical Analysis of the Data

The data were analysed using the SAS GLM procedure version 6.12 (SAS Institute, 1990) for random designs. The initial weight as covariable and the diet were included in the model for analysing the productive parameters.

Results

Significant differences and trends were observed between 0 and 21 days of life. The animals that consumed SCa+ glycerol, grew more than those who only consumed SCa as a fat source. This higher growth was associated with a significant increase in consumption, which led to a slight drop in the conversion index.

No significant differences were seen for any of the productive parameters during the fattening phase, from 21 to 42 days. A general numerical improvement, in weight gain, consumption and conversion index was observed when they consumed the SCa+glycerol diet.

There were no differences between treatments, over the total period, but the higher growth and consumption was maintained.

The results are presented in Tables 9, 10, 11, and show the live weight on days 0 (LW0), 21 (LW21), and 42 (LW42), the mean daily consumption (MDC), mean daily gain (MDG), the conversion index (CI) and the coefficient of variation, and pointing out the probability where there are differences using Pr>F values. Significant differences (P<0.05) between pairs of values are indicated by letters (a, b) next to these values, while “x” and “e” next to a pair of values indicates a trend (P<0.1).

TABLE 9
Productive results: Period 0-21 d.
		LW0
Trtmnt	Males	(g)	LW21 (g)	MDC (g)	MDG (g)	CI
1	SCa	42.34	841.3 y	52.68 b	38.03	1.385
2	SCa +	42.95	878.6 x	54.95 a	39.81	1.380
	glycerol
Pr > F	CV	1.64	2.67	2.50	2.80	2.07
	LW at	—	0.0281	0.0061	0.0323	0.3130
	0 d
	Trtmnt	0.2038	0.0539	0.0472	0.0538	0.8036

TABLE 10
Productive results: Period 21-42 d.
					MDG
Trtmnt	Males	LW0 (g)	LW21 (g)	MDC (g)	(g)	CI
1	SCa	841.3 y	2901	183.0	97.21	1.883
2	SCa +	878.6 x	2952	185.5	99.63	1.862
	glycerol
Pr > F	CV		2.42	2.02	3.43	1.70
	LW at	0.0281	0.0885	0.0728	0.6111	0.1991
	21 d
	Trtmnt	0.0539	0.4688	0.4869	0.4687	0.4947

TABLE 11
Productive results: Period 0-42 d
Trtmnt	Males	LW0 (g)	LW21 (g)	MDC (g)	MDG (g)
1	SCa	42.34	117.6 y	67.93	1.731
2	SCa + glycerol	42.95	120.2 x	69.41	1.731
Pr > F	CV	1.03	1.54	2.30	1.11
	LW at 0 d	—	0.0078	0.0780	0.4274
	Trtmnt	0.2038	0.0807	0.2259	0.9767

Example 2

Effect of Including Soap with Fatty Acids Distilled from Palm Oil (SCa)+Glycerol on the Productivity of Recently Weaned Piglets

Objective

To determine the effect of including SCa+glycerol as a replacement for soya oil on the productive parameters (mean daily gain, mean daily consumption and conversion index) of recently weaned piglets.

Materials and Methods

Experimental Animals

A total of 84 weaned 28 day old piglets (Duroc x Landrace*Large White), with an initial mean weight of 8.4±1.0 kg, were used. The piglets were grouped taking into account the initial live weight. At the beginning all the animals were individually crimped.

Experimental Design

The design randomised 2 treatments (Table 12), based including two fat sources (soya oil and SCa+glycerol). For the analysis of the productive parameters and faecal digestibility, each treatment was replicates 6 times and each experimental unit was made up of 7 piglets (50% males and 50% females) housed together. The study was divided into two periods: prestarter: from 28 to 41 days old, and starter: from 41 to 61 days old.

Start of the study: 11^th Mar. 2004End of the study: 13^th Apr. 2004

TABLE 12
Experimental treatments.
	T1	Soya oil	—
	T2	—	PFAD calcium soap + Glycerol
			(SCa + Glycerol)
Number of treatments:	2
Replicates per treatment:	6
Total number of replicates:	12
Piglets per replicate:	7
Piglets per treatment:	42
Total number of piglets:	84

Experimental Diets

The experimental diets (Table 13) were designed according to the FEDNA raw materials composition tables (2003). The diets contained 0.5% diatomaceous earth as an indigestible marker for calculating the faecal digestibility of the ether extract. The diets were formulated to be isonutritive, according to NRC requirements (1998) for piglets of this age. The diets were presented in granules and provided ad libitum throughout the experiment.

TABLE 13
Calculated composition and analysis of the experimental diets.
	Prestarter:
	28-41	Starter: 41-61
	T1	T2	T1	T2
Nutrients, %
Barley	5.50	5.50	19.27	20.50
Corn	29.00	29.00	28.19	27.00
Soft wheat	25.00	25.00	25.00	25.00
Potato protein	11.70	11.70	8.50	8.50
Soya flour, 47%	9.00	9.20	11.00	11.00
Sweet whey powder (cattle)	12.80	12.80	—	—
Soya oil	2.30	—	3.00	—
PFAD calcium soap + glycerol	—	3.00	—	4.00
L-lysine 50%	0.47	0.47	0.69	0.71
L-threonine	0.05	0.05	0.14	0.14
OH-methionine	0.18	0.18	0.18	0.18
Calcium carbonate	0.80	0.00	1.09	0.00
Di-calcium Phosphate	1.27	1.29	1.39	1.42
Sodium chloride	0.21	0.21	0.45	0.45
Choline-75	0.08	0.10	0.10	0.10
Vitamin-mineral adjuster1	0.40	0.40	0.40	0.40
Acidifier	0.60	0.60	0.60	0.60
Diatomaceous earth	0.50	0.50	—	—
Calculated analysis2
Energy, Kcal/kg	2390	2390	2410	2410
Crude protein, %	21.0	21.0	19.6	19.5
Ether extract, %	4.4	4.4	5.0	5.2
Crude Fibre (CFi) %	2.3	2.1	3.1	2.8
Neutral Detergent Fibre (NDF) %	7.8	7.4	10.4	10
Starch, %	35.9	36.2	42.1	42.5
Lactose, %	9.0	9.0	—	—
Calcium, %	0.78	0.80	0.83	0.85
Total phosphorous, %	0.59	0.59	0.58	0.58
Avail, phosphorous %	0.42	0.42	0.37	0.37
Sodium %	0.18	0.18	0.18	0.18
Avail. lysine %	1.30	1.30	1.24	1.24
Avail. Meth + Cyst %	0.78	0.78	0.72	0.72
Avail. Threonine %	0.81	0.81	0.77	0.77
Avail. Tryptophan %	0.20	0.20	0.18	0.18
1Provided per kilogram of diet: 12,500 UI vit A; 1,800 UI vit D3; 40.0 mg vit E; 1.5 mg vit K3, 5.0 mg vit B2; 2.5 mg vit B6; 25.0 μg vit B12; 30 mg nicotinic acid; 15.0 mg pantothenic acid; 0.5 mg folic acid; 1.3 mg de vit B1; 1.0 mg iodine; 100 mg iron; 45 mg manganese; 0.3 mg selenium; 120 mg zinc; 0.1 mg cobalt; 160 mg copper.
2Based on FEDNA values (2003).

The calculated fatty acid composition in the different diets is shown in Table 14.

TABLE 14
1Calculated fatty acid composition of the experimental diets.
	Age
	28-41 d		Age 41-61 d
	Fatty acids, %	T1	T2	T1	T2
	C<14	0.02	0.07	0.00	0.07
	C16:0	0.51	1.81	0.57	2.32
	C18:0	0.13	0.21	0.14	0.25
	C18:1	0.85	1.35	0.96	1.67
	C18:2	2.07	1.12	2.42	1.24
	C18:3	0.24	0.07	0.29	0.07
	C>20	0.09	>0.01	0.11	0.00
	1Based on FEDNA values (2003).

Before preparing the diets representative samples were taken of the calcium soaps used in the trial and the fatty acid profile was analysed¹ following the method used by Soares and López-Bote (2002). The results are shown in Table 15. ¹Norel, S. A. Ctra. Pla Santa Maria, km 2,5. Poligono Industrial de Valls. 43800 Valls. Tarragona

TABLE 15
Chemical analysis of the fat sources.
%                   PFAD calcium soap + glycerol
                    QUANTITATIVE ANALYSIS
Crude fats          73.8
Calcium             10.9
Dry material        92.7
Ash                 11.5
Glycerol            6.1
                    FATTY ACID PROFILE
Lauric acid C12:0   1.7
Myristic acid C14:0 2.0
Palmitic acid C16:0 51.3
Stearic acid C18:0  5.4
Oleic acid C18:1    32.9
Linoleic acid C18:2 6.8

Before starting the study the following were analysed²: moisture, ash, crude protein (Kjeldahl), ether extract (Soxhlet after acid hydrolysis), crude fibre (Weende), starch and calcium content in the experimental feeds. The chemical analysis is shown in Table 16. ²Laboratorio de Mouriscade: 36515 Vilanova-Lalin, Pontevedra. Responsable: Maria Hermida.

TABLE 16
Chemical analysis of the experimental diets.
	Prestarter		Starter
	(Age		(Age
	28-41 d)		41-61 d)
	Nutrients	T1	T2	T1	T2
	Dry material	89.0	88.5	88.0	88.2
	Crude protein	20.8	20.0	19.1	19.2
	Crude fibre	2.6	2.3	4.0	3.4
	Ether extract	4.2	3.2	4.4	2.9
	Starch	39.3	41.1	43.9	41.0
	Ash	5.3	4.6	4.4	4.4
	Calcium	0.88	0.78	0.66	0.75

Analysis and Measurements

Before starting the study:

• • Chemical analysis of the feeds (dry material, protein, ether extract, starch, calcium and fatty acid profile).The following parameters were recorded during the study:
  • Animal weights and feed consumption of the same at days 28, 41, and 61 to calculate yields (growth, consumption and conversion index) for each period and overall.
  • At the end of the prestarter period (41 d old), samples of faeces were taken from different piglets from each replicate which were later mixed to obtain a uniform and homogeneous sample and then to carry out faecal digestibility analysis. The samples were packed in a labelled container which was hermetically sealed. The faecal digestibility calculations are detailed below.

Faecal Digestibility of the Ether Extract

The faecal digestibility of the fatty acids to 41 days old was calculated by the insoluble in acid ash method described by Vogtmann et al. (1975). Given that the marker (diatomaceous earth) is indigestible, it is taken that, for the marker:

Ingested=excreted

• • Marker ingestion: [M]_p×I
  • Marker excretion: [M]_e×E

Where:

• • [M]_p: concentration of the marker in the feed
  • I: ingested
  • [M]_e: concentration of the marker in the faeces
  • E: excreted

$\begin{array}{cc}{\left[M\right]}_p\times I={\left[M\right]}_e\times EE=\frac{{\left[M\right]}_p}{{\left[M\right]}_e}\times I& \left[\mathrm{Formula}1\right]\end{array}$

The digestibility of the nutrient X will be:

$\begin{array}{cc}X\mathrm{Digestibility}=\frac{I\times {\left[X\right]}_p-E\times {\left[X\right]}_e}{I\times {\left[X\right]}_p}& \left[\mathrm{Formula}2\right]\end{array}$

• • With:
    • [X]_p: concentration of nutrient X ingested in the feed
    • I: ingested
    • [X]_e: concentration of nutrient X in the faeces
    • E: excretedOn substituting the value of E (Formula 1) in Formula 2:

$X\mathrm{Digestibility}=\frac{I\times {\left[X\right]}_f-\frac{{\left[M\right]}_p}{{\left[M\right]}_e}\times I\times {\left[X\right]}_e}{I\times {\left[X\right]}_p}$ $X\mathrm{Digestibility}=\frac{{\left[X\right]}_f-\frac{{\left[M\right]}_p}{{\left[M\right]}_e}\times {\left[X\right]}_e}{{\left[X\right]}_p}=1-\frac{{\left[M\right]}_p\times {\left[X\right]}_e}{{\left[M\right]}_e\times {\left[X\right]}_p}$ $X\mathrm{Digestibility}=1-\frac{{\left[X\right]}_e/{\left[M\right]}_e}{{\left[X\right]}_p/{\left[M\right]}_p}$

The fatty acids were analysed according to the methods used by Soares and López-Bote (2002).

Statistical Analysis of the Data

The data were analysed using the SAS GLM version 6.12. (SAS Institute) procedure, for designs with random clusters. The data are presented as corrected least squares means. The model included the percentage of males per replicate, the cluster (pen) and treatment as main variables, and the initial weight was included as a covariable. The mortality was analysed by the SAS CATMOD procedure.

Results

The weights of the animals at the beginning of the study (28 days old) and at the end of the prestarter period (41 days old) and starter period (61 days old) are shown in Table 18. The animal weights progressed similarly but there were no significant differences between treatments throughout the experimental period. But there was a tendency for the live weight at 42 days of life to be higher in animals who consumed SCa+glycerol.

TABLE 18
Effect of using vegetable fats on live weight (28-61 days old).
	Age in days
	Treatment	28	41	61
	T-1	8.4	11.6y	19.6
	T-2	8.3	12x	19.6
	SEM1	—	0.1	0.3
	P2	—	0.0869	0.9245
	1Standard Error of the Mean (N = 6).
	2Significance: different letters in the same column indicate tendency (P < .1).

The effects of vegetable fat soaps on the productive parameters are shown in Table 19. There were significant differences between treatments for the consumption and a numeric improvement in weight gain in the prestarter period. No differences were seen in the starter period. The animals with SCa with glycerol had the same result as those who consumed soya oil.

TABLE 19
Effect of fat sources on the mean daily gain (MDG), mean daily
consumption (MDC) and the conversion index (CI) in the prestarter
and starter period.
	Prestarter	Starter
	28-41 d old	41-61 d old
	MDG	MDC	CI	MDG	MDC	CI
Treatment	(g/d)	(g/d)	(g/g)	(g/d)	(g/d)	(g/g)
T-1	253	274b	1.09	398	604	1.52
T-2	276	312a	1.14	388	609	1.57
SEM1	11	8	0.04	13	18	0.03
P2	0.17	0.0055	0.42	0.64	0.87	0.30
1Standard Error of the Mean (N = 6).
2Significance: different letters in the same column indicate significant differences (P < 0.05).

The effects of the different treatments on the productive parameters of the animals for the whole period of the study (28-61 days old) are shown in Table 20. No significant differences were seen in weight gain, mean daily consumption or the conversion index in the total study period. However, the use of SCa+glycerol in piglet diets, is an alternative to the consumption of soya oil.

TABLE 20
Effects of vegetable fat sources on the mean daily gain (MDG),
mean daily consumption (MDC) and conversion index (CI) for the
overall period (28-61 d).
	28-61 d old
		MDG	MDC	CI
	Treatment	(g/d)	(g/d)	(g/g)
	T-1	346	474	1.37
	T-2	345	492	1.43
	SEM1	10	12	0.03
	P	0.94	0.32	0.21
	1SEM = Standard Error of the Mean (N = 6).

The effects of treatment on the faecal digestibility (%) of the fatty acids are shown in Table 21.

TABLE 21
Effects of the fatty acids on the apparent faecal digestibility (%).
Treatment	C10:0, %	C12:0, %	C14:0, %	C16:0, %	C18:0, %	C18:1, %	C18:2, %	C18:3, %	C20:0, %
T-1	18.9b	1.2b	76.5b	74.4b	−21.1b	95.1b	97.2b	94.9b	21.1b
T-2	78.9a	82.4a	87.3a	78.4a	28.7a	97.7a	98.9a	97.8a	55.0a
EEM1	10.6	5.4	1.1	1.1	6.5	0.5	0.5	0.8	3.6
P2	0.0032	0.0001	0.0001	0.0269	0.0001	0.0066	0.0513	0.0215	0.0001
1SEM = Standard Error of the Mean (N = 6).
2Significance level: different letters in the same column indicate significant differences (P < .05).

A significant improvement, in absolute values, was observed in the digestibility of all the fatty acids in animals that ate the diet with PFAD calcium soap+Glycerol. This effect can be partly explained by the capacity of the glycerol molecule to re-esterify free fatty acids and, therefore, it helps in the formation of easily absorbable micelles in the intestine.

Conclusions

Taking into account the results and experimental conditions in which the study was carried out, we can conclude that:

• • a) In the overall period of the study (28 to 61 days old) there were no significant differences between treatments for weight gain and consumption. This indicates that the use of palm fatty acid distillate calcium soap with glycerol (SCa+glycerol) can replace soya oil as a fat contribution in the piglet diet, without affecting productive yields.
  • b) The animals that ate the diet with SCa+glycerol had a higher apparent faecal digestibility of all the fatty acids than soya oil. Therefore, the energy efficiency of PFAD Soap+Glycerol could be higher than that of soya oil, from a nutritional point of view.
  • c) The use of PFAD calcium soap+glycerol as a vegetable fat source in diets of recently weaned piglets is a good alternative to using soya oil, as it does not adversely affect the productive parameters and improves the fatty acid digestibility of the diet, as well as reducing feeding costs.

REFERENCES

• AOAC., 2000. Official Methods of Analysis (17^th Ed.). Association of Official Analytical Chemists. Arlington, Va., EE.UU.
• FEDNA, 2003. Tablas FEDNA de composición y valor nutritivo de alimentos para la fabricación de piensos compuestos (2^a ed.). C. de Blas, P. Garcia, and G. G. Mateos. Ed. Fundación Española para el Desarrollo de la Nutrición Animal. Universidad Politécnica de Madrid. España.
• GCP, 2000. Good Clinical Practice for the Conduct of Clinical Trials or Veterinary Medicinal Products. VICH GL9, June 2000. International Cooperation on Harmonisation of Technical Requirements for Registration of Veterinary Medicinal Products. Brussels, Belgium. http://vich.eudra.org/pdf/2000/GI09_st7.pdf
• NRC, 1194. Nutrient Requirements of Poultry. 9^th ed. National Academy Press, Washington D.C., EE.UU.
• NRC, 1998. Nutrient Requirements of Swine. 10^th rev. Ed. National Academy Press, Washington D.C., EE.UU.
• SAS Institute, 1990. SAS® User's Guide: Statistics. SAS Institute, Cary, N.C., EE.UU.
• SCAN “Guidelines for the assessment of additives in feeding stuffs” Part II: Enzymes and Micro-organisms, http://europa.eu.int/comm/food/fs/sc/scan/out68_en.pdf)
• Soares, M, López-Bote, 2002. Effects of dietary lecithin and fat unsaturation on nutrient utilisation in weaned piglets. Anim. Feed Sci. Technol. 95: 169-177.
• Vogtmann, H., Pfirter, H. P., Prabucki, A. L. (1975). A new method of determining metabolisability of energy and digestibility of fatty acids in broiler diets. British Poultry Science, 16 (5): 531-534.

Claims

1. A procedure for preparing mixtures that contain glycerol and/or an emulsifying agent along with saturated or unsaturated fatty acid salts and elements from the alkaline or alkaline earth group that includes the following steps: a) heat a fat or source rich in fatty acids acceptable for animal feeding to a temperature that is at least slightly higher than its melting temperature;b) then add glycerol, or optionally an emulsifying agent or combinations of the same;c) add a source of alkaline or alkaline earth ions selected between an oxide, hydroxide or a salt of the same, or their combinations;d) homogenise the mixture;e) add water;f) allow to stand for sufficient time so that saponification of the fatty acids occurs;g) evaporate the water until almost dry.

2. A procedure according to claim 1, where the fat or source rich in fatty acids acceptable for animal feeding is heated to a temperature in the range of 45° C. to 100° C.

3. A procedure according to claim 1, where the process of mixing the components is made at a speed between 1000 and 3000 rpm.

4. A procedure according to claim 1, where the quantity of water added varies between 11.5% and 23.5%.

5. A procedure according to claim 1, where the quantity of glycerol added varies between 4% and 12%.

6. A procedure according to claim 1, where the emulsifying agent that is optionally added is one among any of those permitted by European Legislation for animal feeding.

7. A procedure according to claim 1, where the glycerol and/or emulsifying agent is added at the same time as the alkaline or alkaline earth ion source.

8. A procedure according to claim 1, where the glycerol and/or emulsifying agent is added after the addition of the alkaline or alkaline earth ion source.

9. A procedure according to claim 1, where the evaporation of the water is carried out in a container with a large surface area, different from the mixing container.

10. A procedure according to claim 1, where the product obtained is subjected to an additional grinding process.

11. A procedure according to claim 1, where the alkaline or alkaline earth ion source is added in stoichiometric or slightly higher quantities than that required for the formation of salts of the fatty acids present in the mixture.

12. A procedure according to claim 11, where the alkaline or alkaline earth ion source is calcium oxide, magnesium oxide, sodium hydroxide or combinations of the same.

13. A procedure according to claim 1, where the starting fat is selected from cotton oil, sunflower oil, rapeseed oil, linseed oil, peanut oil, suet, lard, a soapstock derived from processing any edible fat, soya lecithin, and mixtures of the same.

14. A procedure according to claim 13, where the starting fat is a soapstock derived from palm oil, obtained by vacuum distillation, known as “palm fatty acids distillate”.

15. A procedure according to claim 12, where the alkaline or alkaline earth ion source is calcium oxide and the starting fat is “palm fatty acids distillate”.

16. A fodder for animal feeding characterised by having a composition that contains fatty acid salts and alkaline or alkaline earth elements together with an emulsifying agent selected from glycerol and/or any of those permitted by European Legislation for animal feeds.

17. A fodder for animal feeding according to claim 16, characterised because the only emulsifying agent present is glycerol.

18. A fodder for animal feeding according to claim 17, characterised because the emulsifying agent present is a combination of glycerol and another emulsifying agent selected from any one of those permitted by European Legislation for animal feeds.

19. A fodder for animal feeding according to claim 16, characterised by containing a mixture of fatty acid salts and alkaline or alkaline earth elements selected from calcium, magnesium, sodium or mixtures of the same, together with an emulsifying agent.

20. A fodder for animal feeding according to claim 16, characterised by containing salts of alkaline or alkaline earth elements and fatty acids from a starting fat selected from cotton oil, sunflower oil, rapeseed oil, corn oil, olive oil, palm oil, coconut oil, palm kernel oil, linseed oil, peanut oil, suet, lard, a soapstock derived from processing any edible fat, soya lecithin, and mixtures of the same, together with an emulsifying agent.