Information
-
Patent Grant
-
6484392
-
Patent Number
6,484,392
-
Date Filed
Monday, February 28, 200024 years ago
-
Date Issued
Tuesday, November 26, 200222 years ago
-
Inventors
-
Original Assignees
-
Examiners
- Arbes; Carl J.
- Trinh; Minh
Agents
-
CPC
-
US Classifications
Field of Search
US
- 029 828
- 029 868
- 029 863
- 029 33 F
- 029 825
- 174 102 R
- 174 28
- 174 29
- 174 102 P
- 174 728
- 219 549
- 439 578
- 439 584
-
International Classifications
-
Abstract
A process of weaaving metal conductor wires to form a metal woven shielding conductor layer over the outer surface of an insulated cable. The insulated cable is accompanied with at least one solder or tin wire. When the at least one solder or tin wire is immersed in a molten metal plating solution, it melts down hence generating a spatial margin between the insulated cable and the metal woven shielding conductor layer. This prevents the insulated cable from biting with its outer surface into the metal woven shielding conductor layer when it is thermally expanded in the molten metal plating solution. As the metal woven shielding conductor layer is impregnated deeply with the molten metal, there are hardly any generated gaps and undulation on the surface of the metal plating layer. Accordingly the suppression of reflection and attenuation of a transmission signal will be improved.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a coaxial cable producing method and a coaxial cable and particularly, to a method of producing a coaxial cable of which the metal plating layer formed by impregnating a metal woven shielding conductor layer with a molten metal is improved at its inner surface in the smoothness and thus its adhesivity to an insulated cable is increased and to such a coaxial cable.
2. Description of the Prior Art
As high frequency coaxial cables enhanced in the electric characteristics including the suppression of reflection and attenuation in a high frequency range, semi-rigid type coaxial cables are known in which an insulated cable produced by coating a center conductor with an insulator layer is coaxially covered at its outer surface with a metal pipe made of, for example, copper or aluminum.
The semi-rigid type coaxial cables using the metal pipe are however high in the production cost and poor in the flexibility, hence making the wiring operation difficult.
Alternatively, modified coaxial cables which are decreased in the production cost and improved in the flexibility although their electric characteristics including the suppression of reflection and attenuation are lower than those of the semi-rigid type coaxial cables using the metal pipe have been proposed comprising an insulated cable produced by coating the outer surface of a center conductor with an insulator layer and covered with a metal woven shielding conductor layer and a metal plating layer produced by passing the insulated cable through a molten metal plating solution to impregnate the metal woven shielding conductor layer with a molten metal.
FIG. 10
is an explanatory view showing a process of forming the metal woven shielding layer in a modified coaxial cable producing method using the molten metal plating.
An insulated cable W formed by coating the outer surface of a center conductor (
102
in
FIG. 11
) with an insulator layer (
103
in
FIG. 11
) with the use of a common means at the previous step is released from a supply reel
20
, passed on a guide roll
21
, and directed into a dice
24
.
Also, a group of metal conductor wires
14
are woven with reels
25
, on which the metal conductor wires
14
are wound, spinning about the insulated cable W at the entrance of the dice
24
to form a metal woven shielding conductor layer (
104
in
FIG. 11
) over the outer surface of the insulated cable W.
A resultant intermediate cable
111
having the metal woven shielding conductor layer (
104
in
FIG. 11
) covered over the outer surface of the insulated cable W is drawn by the action of a drawing capstan
22
and taken up on a take-up reel
23
.
FIG. 11
is a cross sectional view of the intermediate cable
111
.
The metal woven shielding conductor layer
104
of the intermediate cable
111
is closely bonded to the outer surface of the insulated cable W.
FIG. 12
is an explanatory view showing a process of forming a metal plating layer in the method of producing a coaxial cable using the molten metal plating.
The intermediate cable
111
is released from a supply reel
51
, coated with a flux by a flux coating apparatus
52
, guided by a guide roller
53
A, and directed into a molten metal plating solution
55
in a molten metal plating tub
54
. Then, the cable is guided by a guide roller
53
B in the molten metal plating tub
54
, moved out from the molten metal plating solution
55
, passed through a plating solution squeezing dice
56
disposed above the molten metal plating solution
55
for adjusting to a desired thickness of the plating, cooled down by a cooling apparatus
57
to complete a coaxial cable
101
, guided by a guide roller
53
C, and taken up on a take-up reel
58
.
FIG. 13
is a cross sectional view of the coaxial cable
101
produced by the coaxial cable producing method using the molten metal plating.
The coaxial cable
101
comprises the insulated cable W formed by coating the center conductor
102
with the insulator layer
103
and the metal plating layer
105
formed on the insulated cable W by impregnating the metal woven shielding conductor layer
104
with the molten metal.
FIG. 14
is an exemplary diagram of the attenuation and reflection characteristics of a transmission signal on the coaxial cable
101
.
A one-meter length of the coaxial cable
101
was prepared and its reflection and attenuation characteristics at a high frequency range from 0.045 GHz to 18 GHz were measured with a network analyzer.
Peaks of the reflection and the attenuation which may result from the effect of a winding pitch of the metal woven shielding conductor layer
104
are shown at about 10 GHz of a transmission frequency.
Also, the standing wave ratio of a reflected voltage at a high frequency range from 0.045 GHz to 18 GHz is 1.4.
SUMMARY OF THE INVENTION
In the conventional method of producing a coaxial cable using the molten metal plating, the metal woven shielding conductor layer
104
is adhered closely to the outer surface of the insulated cable W during the step of forming the intermediate cable
111
as shown in FIG.
11
. When the intermediate cable
111
is immersed in the molten metal plating solution
55
, for example, at 260° C., the insulator layer
103
made of a resin material is thermally expanded hence biting into the metal woven shielding conductor layer
104
. This causes the metal woven shielding conductor layer
104
to be hardly impregnated with the molten metal. Accordingly, when the insulator layer
103
is cooled down and returns to its original size, portions of the metal woven shielding conductor layer
104
are exposed from the inner surface of the metal plating layer
105
thus generating gaps and undulations of the surface.
If there are generated gaps and undulations of the inner surface of the metal plating layer in which a high frequency current runs, the high frequency characteristic may be declined. More particularly, peaks of the reflection and attenuation which may result from the effect of a winding pitch of the metal woven shielding conductor layer
104
appear about at 10 GHz of the transmission frequency, hardly ensuring the effectiveness within a frequency range including 10 GHz.
In addition, the adhesivity between the insulated cable W and the metal plating layer
105
is poor, causing the metal plating layer
105
to be easily slipped out.
It is an object of the present invention to provide a coaxial cable producing method and a coaxial cable of which the metal plating layer formed by impregnating a metal woven shielding conductor layer with a molten metal is improved at its inner surface in the smoothness and its adhesivity to the insulated cable is increased.
As a first aspect of the present invention, a method of producing a coaxial cable is provided comprising the steps of covering with a metal woven shielding conductor layer an insulated cable formed by coating the outer surface of a center conductor with an insulator layer, and passing the cable through a molten metal plating solution to impregnate the metal woven shielding conductor layer with a molten metal to have a metal plating layer, said step of covering with the metal woven shielding conductor layer being arranged in which the insulated cable is accompanied with one or more solder or tin wires while the metal woven shielding conductor layer is being woven.
In the method of producing a coaxial cable as the first aspect, when the intermediate cable having the insulated cable associated with one or more solder or tin wires is immersed in the molten metal plating solution, the solder or tin wires are dissolved into the molten metal plating solution thus generating a spatial margin between the insulated cable and the metal woven shielding conductor layer. This prevents the insulator layer from biting into the metal woven shielding conductor layer when it is thermally expanded. Accordingly, as the metal woven shielding conductor layer is impregnated deeply with the molten metal, there are generated no gaps or undulations on the inner surface of the metal plating layer. Hence, the coaxial cable will be improved in the suppression of reflection and attenuation of a transmission signal. Also, the metal plating layer will hardly be slipped out.
As a second aspect of the present invention, a method of producing a coaxial cable is provided comprising the steps of covering with a metal woven shielding conductor layer an insulated cable formed by coating the outer surface of a center conductor with an insulator layer, and passing the cable through a molten metal plating solution to impregnate the metal woven shielding conductor layer with a molten metal to have a metal plating layer, said step of covering with the metal woven shielding conductor layer being arranged in which one or more spacer wires are provided between the insulated cable and the metal woven shielding conductor layer during the weaving action and removed out when the weaving action is completed.
In the method of producing a coaxial cable as the second aspect, one or more of the spacer wires are removed from the insulated cable when the weaving action has been finished, thus generating a spatial margin between the insulated cable and the metal woven shielding conductor layer in the intermediate cable. This prevents the insulator layer from biting into the metal woven shielding conductor layer when it is thermally expanded as the intermediate cable is immersed in the molten metal plating solution. Accordingly, since the metal woven shielding conductor layer is impregnated deeply with the molten metal, there are generated no gaps or undulations on the inner surface of the metal plating layer. Hence, the coaxial cable will be improved in the suppression of reflection and attenuation of a transmission signal. Also, the metal plating layer will hardly be slipped out.
As a third aspect of the present invention, a method of producing a coaxial cable is provided comprising the steps of covering with a metal woven shielding conductor layer an insulated cable formed by coating the outer surface of a center conductor with an insulator layer, and passing the cable through a molten metal plating solution to impregnate the metal woven shielding conductor layer with a molten metal to have a metal plating layer, said step of covering with the metal woven shielding conductor layer being arranged in which the metal woven shielding conductor layer is woven while the insulated cable is being heated to thermally expand the insulator layer.
In the method of producing a coaxial cable as the third aspect, the metal woven shielding conductor layer is woven while the insulator layer is being thermally expanded. The resultant intermediate cable is thus obtained with the metal woven shielding conductor layer fitted closely to the insulator layer thermally expanded. This prevents the insulator layer from biting into the metal woven shielding conductor layer when it is thermally expanded as the intermediate cable is immersed in the molten metal plating solution. Accordingly, since the metal woven shielding conductor layer is impregnated deeply with the molten metal, there are generated no gaps or undulations on the inner surface of the metal plating layer. Hence, the coaxial cable will be improved in the suppression of reflection and attenuation of a transmission signal. Also, the metal plating layer will hardly be slipped out.
As a fourth aspect of the present invention, a method of producing a coaxial cable is provided in that the coaxial cable produced according to the method of producing a coaxial cable as any of the first to third aspects is reduced in the diameter with the use of a dice or a swaging machine to eliminate the space and thus increase the adhesivity between the insulator layer and the metal plating layer.
In the method of producing a coaxial cable as the fourth aspect, the coaxial cable is reduced in the diameter using a dice or a swaging machine, thus eliminating the space and improving the adhesivity between the insulator layer and the metal plating layer. Accordingly, the coaxial cable will be improved in the suppression of reflection and attenuation of a transmission signal. Also, the metal plating layer will hardly be slipped out.
As a fifth aspect of the present invention, a coaxial cable is provided having an insulated cable produced by coating the outer surface of a center conductor with an insulator layer and covered with a metal plating layer formed by impregnating a metal woven shielding conductor layer with a molten metal and particularly characterized in that the metal plating layer is arranged smooth at its inner surface and adhered closely to the outer surface of the insulated cable.
The coaxial cable as the fifth aspect allows the metal plating layer to be smooth at its inner surface and adhered closely to the outer surface of the insulated cable. Accordingly, the coaxial cable will be improved in the suppression of reflection and attenuation of a transmission signal. Also, the metal plating layer will hardly be slipped out.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1
is an explanatory view showing a process of forming a metal woven shielding conductor in a method of producing a coaxial cable according to a first embodiment of the present invention;
FIG. 2
is a cross sectional view of an intermediate cable of the first embodiment of the present invention;
FIG. 3
is an explanatory view showing a process of molten metal plating in the method of producing a coaxial cable according to the first embodiment of the present invention;
FIG. 4
is a cross sectional view of the coaxial cable of the first embodiment of the present invention;
FIG. 5
is a chart showing the attenuation characteristic and the standing wave ratio of a reflected voltage on the coaxial cable according to the first embodiment of the present invention;
FIG. 6
is an explanatory view showing a process of forming a metal woven shielding conductor in a method of producing a coaxial cable according to a second embodiment of the present invention;
FIG. 7
is a cross sectional view of an intermediate cable of the second embodiment of the present invention;
FIG. 8
is an explanatory view showing a process of forming a metal woven shielding conductor in a method of producing a coaxial cable according to a third embodiment of the present invention;
FIG. 9
is a cross sectional view of an intermediate cable of the third embodiment of the present invention;
FIG. 10
is an explanatory view showing a process of forming a metal woven shielding conductor in a conventional method of producing a coaxial cable;
FIG. 11
is a cross sectional view of an intermediate cable of the conventional method;
FIG. 12
is an explanatory view showing a process of molten metal plating in the conventional method of producing a coaxial cable;
FIG. 13
is a cross sectional view of a conventional coaxial cable; and
FIG. 14
is a chart showing the attenuation characteristic and the standing wave ratio of a reflected voltage on the conventional coaxial cable.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Embodiments of the present invention will be described referring to the drawings. The present invention is not limited to the embodiments.
First Embodiment
FIG. 1
is an explanatory view showing a process of forming a metal woven shielding conductor layer in the method of producing a coaxial cable according to a first embodiment of the present invention.
An insulated cable W produced by coating the outer surface of a center conductor (
102
in
FIG. 2
) with an insulator layer (
103
in
FIG. 2
) using a common means at the preceding step is released out from a supply reel
20
, passed through a guide roll
21
, and directed into a dice
24
.
Also, at least one of a solder or tin wire
6
is released out from a solder or tin supply reel
26
and guided into the dice
24
so as to run directly on the insulated cable W.
Simultaneously, a group of metal conductor wires
14
are woven with their corresponding reels
25
, on which the metal conductor wires
14
are wound, spinning about the insulated cable W and the solder or tin wire
6
at the entrance of the dice
24
to fabricate a metal woven shielding conductor layer (
104
in
FIG. 2
) over the outer surfaces of the insulated cable W and the solder or tin wire
6
.
A resultant intermediate cable
11
having the metal woven shielding conductor layer (
104
in
FIG. 2
) formed on the outer surfaces of the insulated cable W and the solder or tin wire
6
is then taken up on a take-up reel
23
by the drawing action of a drawing capstan
22
.
FIG. 2
is a cross sectional view of the intermediate cable
11
.
The intermediate cable
11
is provided in which the insulated cable W and the solder or tin wire
6
are covered at their outer surfaces with the metal woven shielding conductor layer
104
.
FIG. 3
is an explanatory view showing a process of forming a metal plated layer in the method of producing a coaxial cable according to the first embodiment of the present invention.
The intermediate cable
11
is released out from a supply reel
51
and coated with a flux by a flux coating apparatus
52
.
Then, the intermediate cable
11
coated with the flux is passed on a guide roll
53
A, directed into a molten metal plating solution
55
in a molten metal plating tub
54
, guided by a guide roller
53
B in the molten metal plating tub
54
, and moved out from the molten metal plating solution
55
. During the movement, the metal woven shielding conductor layer
104
of the intermediate cable
11
is impregnated with the molten metal. At the time, the solder or tin wire
6
is dissolved into the molten metal plating solution
55
, hence leaving a spatial margin under the metal woven shielding conductor layer
104
. This prevents the insulator layer
103
of a resin material from biting into the metal woven shielding conductor layer
104
when it is i- thermally expanded. Accordingly, the metal woven shielding conductor layer
104
is impregnated deeply with the molten metal so that a resultant metal plating layer (
105
in
FIG. 4
) has no gaps and undulations on the inner surface thereof.
The cable is then passed through a plating solution squeezing dice
56
disposed above the molten metal plating solution
55
to determine a desired thickness of the plating layer, cooled down by a cooling apparatus
57
, and reduced in the diameter by a diameter reducing dice
60
to complete a coaxial cable
1
. The coaxial cable
1
is guided by a guide roll
53
C and taken up on a take-up reel
58
.
FIG. 4
is a cross sectional view of the coaxial cable
1
produced by the method of producing a coaxial cable according to the first embodiment of the present invention.
The coaxial cable
1
has a structure comprising the metal plating layer
105
which is formed on the outer surface of the insulated cable W, which is produced by coating the outer surface of a center conductor
102
with an insulator layer
103
, by impregnating the metal woven shielding conductor layer
104
with the molten metal. Since the molten metal fills the metal woven shielding conductor layer
104
, there are generated no gaps and undulations on the inner surface of the metal plating layer
105
and thus the coaxial cable
1
is improved in the suppression of reflection and attenuation of a transmission signal. In addition, the metal plating layer
105
will hardly be slipped out from the cable.
In a desired example, the center conductor
102
is a silver plated copper coated steel wire having an outer diameter of 0.91 mm, the insulator layer
103
is a coating of a ethylene tetrafluoride resin extruded to a thickness of 0.99 mm, the solder or tin wire
6
is 0.3 mm in the outer diameter, and the metal woven shielding conductor layer
104
comprises 16 strands, each consisting of 7 tin plated soft copper wires of 0.1 mm in outer diameter. The intermediate cable
11
has an outer diameter of 3.5 mm.
The molten metal plating solution
55
is a molten tin plating solution having a temperature of 260° C. The time required for passing through the molten metal plating solution
55
is about 6 seconds.
The squeezing dice
56
has an inner diameter of 3.55 mm such that the diameter of a finished plated cable is 3.55 mm in the outer diameter.
The cooling apparatus
57
operates an air-cooling action at an atmosphere temperature of 10° C.
The diameter reducing dice
60
has an inner diameter of 3.47 mm.
FIG. 5
is an exemplary diagram showing the signal attenuation characteristic and the signal reflection characteristic on the coaxial cable
1
.
A one-meter length of the coaxial cable
1
was prepared and its attenuation and reflection characteristics at a high frequency range from 0.045 GHz to 18 GHz were measured using a network analyzer.
As apparent, peaks of the attenuation and reflection characteristics which may result from the effect of a winding pitch of the metal woven shielding conductor layer
104
is not shown.
Also, the standing wave ratio of a reflected voltage at the high frequency range from 0.045 GHz to 18 GHz is 1.1 or smaller.
The solder or tin wire
6
has preferably a round shape in cross section but may be an oval, rectangular, or square shape in cross section depending on the application. The solder or tin wire
6
could be made of a tin-lead alloy having a melting point of 350° C. or less, or any other suitable metal or alloy.
It was found from a series of experiments that the cross section of the solder or tin wire
6
was preferably 0.0008 to 0.070 times greater than that of the insulated cable W.
Second Embodiment
FIG. 6
is an explanatory view showing a process of forming a metal woven shielding conductor layer in a method of producing a coaxial cable according to a second embodiment of the present invention.
An insulated cable W having a center conductor (
102
in
FIG. 7
) coated at its outer surface with an insulator layer (
103
in
FIG. 7
) by a common means at the preceding step is released out from a supply reel
20
, passed on a guide roll
21
, and directed into a dice
24
.
A spacer wire
27
is provided stationary close to the entrance of the dice
24
to come directly on the insulated cable W.
A group of metal conductor wires
14
are woven to form a metal woven shielding conductor layer (
104
in
FIG. 7
) over the outer surfaces of the insulated cable W and the spacer wire
27
while reels
25
on which the metal conductor wires
14
are wound are spinning about the insulated cable W and the spacer wire
27
at the entrance of the dice
24
. Because the spacer wire
27
is provided stationary at a location close to the entrance of the dice
24
, it stays behind and leaves a space when the insulated cable W has run away from the entrance of the dice
24
.
A resultant intermediate cable
12
formed by covering the outer surface of the insulated cable W with the metal woven shielding conductor layer (
104
in
FIG. 7
) and having the space made by the spacer wire
27
in-between is then drawn by a drawing capstan
22
and taken up on a take-up reel
23
.
FIG. 7
is a cross sectional view of the intermediate cable
12
.
The intermediate cable
12
has a space provided by the spacer wire
27
on the outer surface of the insulated cable W and covered with the metal woven shielding conductor layer
104
.
The process of forming a metal plating layer in the method of producing a coaxial cable according to the second embodiment of the present invention is identical to that shown in FIG.
3
.
Since the space under the metal woven shielding conductor layer
104
is provided by the spacer wire
27
, the insulator layer
103
of the resin material is prevented from biting into the metal woven shielding conductor layer
104
when it is thermally expanded. This allows the metal woven shielding conductor layer
104
to be impregnated deeply with the molten metal and will generate no gaps or undulations on the inner surface of the metal plating layer (
105
in FIG.
4
).
A resultant coaxial cable is equal in the quality to the coaxial cable
1
shown in FIG.
4
.
In a desired example, the spacer wire
27
is a stainless steel wire having an outer diameter of 0.4 mm. The other components are identical to those described in the previous example.
The spacer wire
27
is preferably round in the cross section and may have an oval or rectangular or square cross section depending on the application. The material of the spacer wire
27
may be other than stainless steel, for example, tungsten.
It was found from a series of experiments that the cross section of the spacer wire
27
was preferably 0.0008 to 0.070 times greater than that of the insulated cable W.
Third Embodiment
FIG. 8
is an explanatory view showing a process of forming a metal woven shielding conductor layer in a method of producing a coaxial cable according to a third embodiment of the present invention.
An insulated cable W having a center conductor (
102
in
FIG. 9
) coated at its outer surface with an insulator layer (
103
in
FIG. 9
) by a common means at the preceding step is released out from a supply reel
20
and passed via a guide roll
21
to a heater
28
. A thermally expanded insulated cable W′ heated by the heater
28
is then directed into a dice
24
.
Also, a group of metal conductor wires
14
are woven to form a metal woven shielding conductor layer (
104
in
FIG. 9
) over the outer surface of the thermally expanded insulated cable W′ while reels
25
on which the metal conductor wires
14
are wound are spinning about the thermally expanded insulated cable W′ at the entrance of the dice
24
. When the thermally expanded insulated cable W′ has been cooled down and returned back to the insulated cable W, a spatial margin is generated between the insulated cable W and the metal woven shielding conductor layer (
104
in FIG.
9
).
A resultant intermediate cable
13
having the spatial margin between the insulated cable W and the metal woven shielding conductor layer (
104
in
FIG. 9
) is drawn by the action of a drawing capstan
22
and taken up on a take-up reel
23
.
FIG. 9
is a cross sectional view of the intermediate cable
13
.
The intermediate cable
13
has on the outer surface of the insulated cable W the spatial margin for accepting a thermal expansion of the insulated cable W covered with the metal woven shielding conductor layer
104
.
The process of forming a metal plating layer in the method of producing a coaxial cable according to the third embodiment of the present invention is identical to that shown in FIG.
3
.
Since the spatial margin for accepting a thermal expansion of the insulated cable W is provided under the metal woven shielding conductor layer
104
, the insulator layer
103
of a resin material is prevented from biting into the metal woven shielding conductor layer
104
when it is thermally expanded. Accordingly, because the metal woven shielding conductor layer
104
is impregnated deeply with the molten metal, there will be generated no gaps or undulations on the inner surface of the metal plating layer (
105
in FIG.
4
).
The quality of a resultant coaxial cable is equal to that of the coaxial cable
1
shown in FIG.
4
.
In a preferred example, the heater
28
is an electric heater capable of heating the insulated cable W at 260° C. for 20 seconds. The other components are identical to those described in the previous example.
ADVANTAGE OF THE INVENTION
The coaxial cable producing method and the coaxial cable according to the present invention allow the metal woven shielding conductor layer to be impregnated deeply with the molten metal, thus causing the metal plating layer to be improved in the smoothness at the inner surface and its adhesivity to the outer surface of the insulated cable to be increased. Accordingly, the suppression of reflection and attenuation of high frequency signals will highly be enhanced while undesired removal of the metal plating layer is hardly caused.
Claims
- 1. A method of producing a coaxial cable comprising the steps of: providing an insulated cable formed by coating an outer surface of a center conductor with an insulator layer:providing at least one of a solder wire and a tin wire adjacent an outer surface of the insulated cable; providing a metal shielding conductor layer around the outer surface of the insulated cable and the at least one of the solder wire and the tin wire; and passing the insulated cable with the metal shielding conductor layer surrounding the outer surface of the insulated cable and the at least one of the solder wire and the tin wire through a molten metal plating solution to impregnate the metal shielding conductor layer with the molten metal thereby forming a metal plating layer, whereby the at least one of the solder wire and the tin wire melts into the molten metal plating solution.
- 2. The method of producing a coaxial cable according to claim 1, wherein the metal shielding conductor layer is woven.
Priority Claims (1)
Number |
Date |
Country |
Kind |
11-308863 |
Oct 1999 |
JP |
|
US Referenced Citations (12)
Foreign Referenced Citations (3)
Number |
Date |
Country |
0385549 |
Sep 1990 |
EP |
2001250441 |
Sep 2001 |
JP |
WO9813835 |
Apr 1998 |
WO |