Claims
- 1. A process for treating a deactivated monofunctional, non-acidic reforming catalyst comprising L zeolite, a catalyst metal comprising at least one Group VIII noble metal, an inorganic binder, and carbon deposits, said process comprising:
- a) subjecting the non-acidic L zeolite catalyst to a gas stream comprising less than about 10 vol. % water, inert gas, and about 0.1 vol. % to about 25 vol. % oxygen under oxidation conditions comprising a temperature within the range of about 380.degree. C. to about 540.degree. C. effective for removing a substantial portion of the coke from the zeolite catalyst;
- b) subjecting the zeolite catalyst from which coke has been removed to a gaseous stream comprising inert gas, 0.1 vol. % to 25 vol. % hydrogen, less than about 10 vol. % water, and about 0.005 vol. % to about 10 vol. % of a source of chlorine wherein said gas stream contains essentially no oxygen under conditions comprising a temperature within the range of about 400.degree. C. to about 530.degree. C. to result in a chlorinated catalyst;
- c) exposing said chlorinated catalyst to another gas stream comprising inert gas, about 0.1 vol. % to about 25 vol. % oxygen, less than 10 vol. % water at a gas flow rate below about 20 cc/g catalyst/min. and under conditions comprising a temperature within the range of about 400.degree. C. to about 540.degree. C. effective for removing excess chlorine from said chlorinated catalyst, stabilizing the Group VIII noble metal, and resulting in said Group VIII noble metal being well dispersed as particles over said surface of said zeolite catalyst upon subsequent reduction; and
- d) contacting the catalyst from which excess chlorine has been removed with another gaseous stream comprising less than about 10 vol. % water, inert gas, and about 1 vol. % to about 25 vol. % hydrogen, at a temperature within the range of about 400.degree. C. to about 530.degree. C. for up to about 10 hours to effect a reduction of said Group VIII noble metal particles of the zeolite catalyst.
- 2. The process of claim 1, wherein at least about 90% of said particles have a diameter of less than about 7 Angstrom as measured with bright field imaging on a transmission electron microscope with 4 Angstrom point-to-point resolution.
- 3. The process of claim 1, wherein said gas stream in step a) contains essentially no water.
- 4. The process of claim 1, wherein said oxidation conditions in step a) comprise a time less than about 10 hours.
- 5. The process of claim 1, wherein said amount of oxygen in said gas stream in step a) is within the range of about 0.5 vol. % to about 12 vol. %.
- 6. The process of claim 1, wherein the source of chlorine in said gaseous stream in step b) is a member selected from the group consisting of Cl.sub.2, HCl, chlorinated hydrocarbons and mixtures thereof.
- 7. The process of claim 6, wherein said source of chlorine in said gaseous stream in step b) is a member selected from the group consisting of HCl and Cl.sub.2.
- 8. The process of claim 1, wherein said gas flow rate in step c) is below about 10 cc/g catalyst/min.
- 9. The process of claim 1, wherein said amount of oxygen in said gas in step c) is within the range of about 0.5 vol. % to about 12 vol. %.
- 10. The process of claim 1, wherein said amount of water in said gas in step c) is within the range of about 1.0 vol. % to 3.0 vol. %.
- 11. The process of claim 1, wherein said gas in step c) contains essentially no water.
- 12. The process of claim 1, wherein said step c) is continued for a time less than about 7 hours.
- 13. The process of claim 1, wherein said another gaseous stream in step d) contains essentially no water.
- 14. The process of claim 1, wherein said another gaseous stream in step d) comprises about 0.5 vol. % to about 5 vol. % water.
- 15. The process of claim 1, wherein said inert gas is nitrogen.
- 16. The process of claim 1, wherein said inorganic binder material is selected from the group consisting of kaolin, alumina and silica.
- 17. The process of claim 1, wherein said L zeolite comprises exchangeable cations at least a portion of which are selected from the group of exchangeable cations consisting of lithium, sodium, potassium, rubidium, cesium, calcium, and barium, and mixtures of lithium, sodium, potassium, rubidium, cesium, calcium, and barium.
- 18. The process of claim 17, wherein said exchangeable cations are selected from the group consisting of potassium, and barium.
- 19. The process of claim 18, wherein said Group VIII noble metal is platinum.
- 20. The process of claim 19, wherein said catalyst metal comprises rhenium.
- 21. The process of claim 1, wherein the amount of said Group VIII noble metal present is within the range of about 0.2 wt. % to about 6 wt. %.
Parent Case Info
This application is a continuation of application Ser. No. 08/104,255, filed Aug. 10, 1993, now abandoned, which is a continuation of application Ser. No. 07/709,154, filed Jun. 3, 1991, now abandoned, which is a continuation of application Ser. No. 07/432,221, filed Nov. 6, 1989, now abandoned, which is a continuation of application Ser. No. 07/205,567, filed Jun. 15, 1988, now U.S. Pat. No. 4,925,819, which is a continuation of application Ser. No. 07/814,027, filed Dec. 23, 1985, now abandoned, which is a continuation of application Ser. No. 08/550,951, filed Nov. 10, 1983, now abandoned.
US Referenced Citations (6)
Continuations (6)
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Number |
Date |
Country |
Parent |
104255 |
Aug 1993 |
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Parent |
709154 |
Jun 1991 |
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Parent |
432221 |
Nov 1989 |
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Parent |
205567 |
Jun 1988 |
|
Parent |
814027 |
Dec 1985 |
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Parent |
550951 |
Nov 1983 |
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