Claims
- 1. A process for preferentially removing hdyrogen sulfide from a gas mixture comprising hydrogen sulfide and carbon dioxide and converting the hydrogen sulfide to elemental sulfur comprising
- treating said gas mixture at atmospheric pressure with an aqueous solution consisting of inert salts, dissolved bicarbonate ions in sufficient concentration to establish an equilibrium imbalance to prevent substantial dissolution of carbon dioxide, a catalytic quantity of ions of a transition metal and dissolved oxygen in an amount sufficient to stoichiometrically convert all of the hydrogen sulfide to elemental sulfur.
- 2. A process as in claim 1 wherein the bicarbonate ions result from the dissolution of a soluble alkali metal bicarbonate and the transition metal ions result from the dissolution of nickel chloride.
- 3. A process as in claim 1 wherein the bicarbonate ions result from the dissolution of from about 1 to about 20 gram moles per liter of a soluble alkali metal bicarbonate and the transition metal ions result from the dissolution of from about one part by weight of a soluble transition metal salt per 50 parts by weight of hydrogen sulfide to about 1 part by weight of a soluble transition metal salt to about 200 parts by weight of hydrogen sulfide.
- 4. A process as in claim 3 wherein the soluble alkali metal bicarbonate is sodium bicarbonate and the soluble transition metal salt is nickel chloride.
- 5. A process as in claim 1 wherein the bicarbonate ions result from the reaction of carbonate ions and carbon dioxide in an aqueous medium.
- 6. A process for converting hydrogen sulfide to elemental sulfur wherein the hydrogen sulfide is originally present in a gas mixture consisting of hydrogen sulfide and carbon dioxide said process comprising
- treating the gas mixture comprising hydrogen sulfide and carbon dioxide at atmospheric pressure with an aqueous solution consisting of inert salts, dissolved bicarbonate ions in sufficient concentration to establish an equilibrium imbalance to prevent substantial dissolution of carbon dioxide, a catalytic quantity of ions of a transition metal and dissolved oxygen.
- 7. A process for preferentially removing hydrogen sulfide from a gas mixture comprising hydrogen sulfide and carbon dioxide and converting the hydrogen sulfide to elemental sulfur comprising
- treating the gas mixture at atmospheric pressure with an aqueous solution consisting of inert salts, dissolved bicarbonate ions in sufficient concentration to establish an equilibrium imbalance to prevent substantial dissolution of carbon dioxide and
- treating the said aqueous solution containing hydrogen sulfide with oxygen and a catalytic quantity of transition metal ions dissolved in an aqueous medium to convert the hydrogen sulfide to elemental sulfur.
- 8. A process for preferentially removing hydrogen sulfide from a gas mixture consisting of hydrogen sulfide and carbon dioxide and converting the hydrogen sulfide to elemental sulfur comprising
- treating said gas mixture at atmospheric pressure with an aqueous solution consisting of inert salts, dissolved bicarbonate ions in sufficient concentration to establish an equilibrium imbalance to prevent substantial dissolution of carbon dioxide, a catalytic quantity of ions of a transition metal and dissolved oxygen.
- 9. A process for preferentially removing hydrogen sulfide from a gas mixture comprising hydrogen sulfide and carbon dioxide and converting the hydrogen sulfide to elemental sulfur comprising
- treating said gas mixture at atmospheric pressure with an aqueous solution consisting of dissolved bicarbonate ions in sufficient concentration to establish an equilibrium imbalance to prevent substantial dissolution of carbon dioxide, a catalytic quantity of ions of a transition metal and dissolved oxygen in an amount sufficient to stoichiometrically convert all of the hydrogen sulfide to elemental sulfur.
- 10. A process as in claim 9 wherein the bicarbonate ions result from the dissolution of a soluble alkali metal bicarbonate and the transition metal ions result from the dissolution of nickel chloride.
- 11. A process as in claim 9 wherein the bicarbonate ions result from the dissolution of about 1 to about 20 gram moles per liter of a soluble alkali metal bicarbonate and the transition metal ions result from the dissolution of from about 1 part by wieght of a soluble transition metal salt per 50 parts by weight of hydrogen sulfide to about 1 part by weight of a soluble transition metal salt to about 200 parts by weight of hydrogen sulfide.
- 12. A process as in claim 11 wherein the soluble alkali metal bicarbonate is sodium bicarbonate and the soluble transition metal salt is nickel chloride.
- 13. A process as in claim 9 wherein the bicarbonate ions result from the reaction of carbonate ions and carbon dioxide in an aqueous medium.
- 14. A process for converting hydrogen sulfide to elemental sulfur wherein the hydrogen sulfide is originally present in a gas mixture consisting of hydrogen sulfide and carbon dioxide said process comprising
- treating the gas mixture comprising hydrogen sulfide and carbon dioxide at atmospheric pressure with an aqueous solution consisting of dissolved bicarbonate ions in sufficient concentration to establish an equilibrium imbalance to prevent substantial dissolution of carbon dioxide, a catalytic quantity of ions of a transition metal and dissolved oxygen.
- 15. A process for preferentially removing hydrogen sulfide from a gas mixture comprising hydrogen sulfide and carbon dioxide and converting the hydrogen sulfide to elemental sulfur comprising
- treating the gas mixture at atmospheric pressure with an aqueous solution consisting of dissolved bicarbonate ions in sufficient concentration to establish an equilibrium imbalance to prevent substantial dissolution of carbon dioxide to preferentially dissolve the hydrogen sulfide and treating the said aqueous solution containing hydrogen sulfide with oxygen in a catalytic quantity of transition metal ions dissolved in an aqueous medium to convert the hydrogen sulfide to elemental sulfur.
- 16. A process for preferentially removing hydrogen sulfide from a gas mixture consisting of hydrogen sulfide and carbon dioxide and converting the hydrogen sulfide to elemental sulfur comprising
- treating said gas mixture at atmospheric pressure with an aqueous solution consisting of dissolved bicarbonate ions in sufficient concentration to establish an equilibrium imbalance to prevent substantial dissolution of carbon dioxide, a catalytic quantity of ions of a transition metal and dissolved oxygen.
Parent Case Info
This is a Continuation-in-Part of application, Ser. No. 263,911, filed June 19, 1972, and now abandoned.
US Referenced Citations (3)
Foreign Referenced Citations (1)
Number |
Date |
Country |
1,182,255 |
Feb 1970 |
UK |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
263911 |
Jun 1972 |
|