Patent Application
20160178129
The present invention concerns systems for storing energy and using the stored energy to generate electrical energy or drive a propeller.
Electrical energy storage systems store base-load energy during off-peak periods and use the stored energy to provide electrical power during peak periods. Such systems are essential to the power generation industries. In conventional power generation systems, an energy storage system can provide substantial benefits including load following, peaking power and standby reserve. By providing spinning reserve and a dispatched load, electrical energy storage systems can increase the net efficiency of thermal power sources while reducing harmful emissions.
Electrical energy storage systems are critically important to intermittent renewable energy supply systems such as solar photovoltaic and wind turbine supply systems. This is due to the intermittent nature of the sources of renewable energy; the source is not always available over an extended period of time. Such a disadvantage has become an obstacle to the green electricity industry. Therefore, there is a need for a suitable energy storage system. Moreover, there is a need for the electricity storage system to be green.
Furthermore, electrical energy storage systems are regarded as a key technology in energy distribution networks with distributed generators, in order to compensate for any power fluctuation and to provide uninterruptible power supply during periods of voltage drop due to, for example, line faults.
Several electrical energy storage systems have been developed in the past. These include pumped hydro storage systems, Compressed Air Energy Storage systems (CAES), secondary batteries, Superconducting Magnetic Energy Storage systems (SMES), flywheels and capacitors.
Pumped hydro is the most widely used form of energy storage system. It stores hydraulic potential energy by pumping water from a lower reservoir to a higher reservoir. The amount of stored energy is proportional to the height difference between the two reservoirs and the volume of water stored. During periods of high demand for electricity, water falls from the higher reservoir to the lower reservoir through a turbine generator in a manner similar to traditional hydroelectric facilities. Pumped hydro storage is a mature technology with high efficiency, large volume, long storage period and relatively low capital cost per unit energy. However, a scarcity of available sites for two large reservoirs and one or more dams is the major drawback of pumped hydro. A long lead time for construction (typically ˜10 years) and environmental issues (e.g. removing trees and vegetation from the land prior to the reservoir being flooded) are two other major drawbacks of the pumped hydro system.
Compressed Air Energy Storage (CAES) is based on conventional gas turbine technology. It uses the elastic potential energy of compressed air. Energy is stored by compressing air in an air tight space such as underground storage cavern. To extract the stored energy, compressed air is drawn from the storage vessel, heated and then expanded through a high pressure turbine, which captures some of the energy in the compressed air. The air is then mixed with fuel and combusted, with the exhaust expanded through a low pressure turbine. Both the high and low pressure turbines are connected to a generator to produce electricity. CAES has a relatively high energy density, long storage period, low capital costs and high efficiency. In comparison with pumped hydro and other currently available energy storage systems, CAES is not an independent system. It requires combustion in the gas turbine. It cannot be used in other types of power plants such as coal-fired, nuclear, wind turbine or solar photovoltaic plants. In addition, the combustion of fossil fuels leads to emission of contaminates such as nitrogen oxides and carbon oxides which render the CAES less attractive. Also, similar to pumped hydro systems, CAES suffers from a reliance on favourable geography such as caverns. CAES can only be economically feasible for power plants that have nearby rock mines, salt caverns, aquifers or depleted gas fields. In addition, a major barrier for the CAES is the relatively low pressures that can be achieved, typically 40-60 bar.
Secondary battery systems are in some ways ideally suited for electrical energy storage systems. They not only provide fuel flexibility and environmental benefits, but also offer a number of important operating benefits to the electricity supply industry. They can respond very rapidly to load changes, and they can accept co-generated and/or third-party power, thus enhancing system stability. The construction of a secondary battery system is facilitated by short lead times, the lack of geographical limitations on location, and the technology's modularity. However, until recently, utility battery storage has been rare because of the low energy densities, high maintenance costs, short lifetimes, limited discharge capabilities and toxic remains associated with such systems. There are several new battery technologies now regarded as potentially competitive with pumped hydro and CABS systems including lead acid batteries, sodium sulphur batteries, zinc bromine batteries and redox flow batteries.
Superconducting Magnetic Energy Storage (SMES) is the only known method for the bulk storage of energy directly as electricity. SMES stores electrical energy as electric current passing through an inductor. The inductor, made from a superconducting material, is circular so that current can circulate indefinitely with almost no losses. SMES exhibits very high energy storage efficiency (typically 90%) and rapid respond (<1 second) relative to other energy storage systems. The major problems confronting the implementation of SMES units are the high cost and environmental issues associated with the strong magnetic fields employed.
Flywheel systems are a form of energy storage system that have been used for thousands of years. The disadvantages of these systems are their short duration, relatively high frictional losses (windage) and low energy densities. Traditional flywheel systems with conventional metal rotors lack the necessary energy density to be considered seriously for large-scale energy storage applications. Recent advances in material science have started to change this picture. In particular, the development of low-density, high-strength, fibre-composite materials has allowed the design and construction of flywheel energy storage systems with a comparable energy density to other systems. Also, new bearing technologies are being developed, such as levitation bearings using high temperature superconductors which have the potential of reducing the windage losses that account for a large portion of the total energy loss.
Capacitors are a form of energy storage system that have been used for many years in the electronics industry. Double layer capacitors have been developed for a daily peak load in the summer of less than 1 hour with small capacities. Recent progress in the field of redox super capacitors could lead to the development of larger capacity systems. The major disadvantages of capacitors as energy storage systems are, similar to flywheels, their short duration and high energy dissipation due to self-discharge loss.
Accordingly, there is a need for an electrical energy storage system which has high energy density and potential output power, high energy efficiency, a long duration, a long lifetime, low capital costs, and offers a good commercial potential. The system should preferably be capable of being used with current power plants without requiring major modifications to the power plants except to the inputs and outputs for electricity. The system should also preferably be capable of working completely separately from the power plant. Start-up and suspension of the system should preferably be simple and reliable and the system should preferably be capable of being used with most types of existing medium to large scale power plants including coal-fired, gas turbine, nuclear, wind turbine and solar photovoltaic plants, irrespective of the geographical location of the plants. The system should also preferably not be detrimental to the environment, particularly by using the process in conjunction with non-polluting power plants (a Zero Emission System), and may even have the potential to reverse environmental impacts associated with the burning of fossil fuels.
The inventors of the present invention have attempted to provide an electrical energy storage system that addresses these requirements.
In addition, there is also a need for an improved environmentally friendly maritime power system for providing propulsion for boats. Environmental concerns arise constantly in the maritime sector with regard to both water and air pollution.
A typical power system for boats consists of main propulsion engines, propellers, donkey engines/generators, boilers, transition and control systems etc. The main propulsion engine is the most important component. Several types of main propulsion engines have been developed in the marine sector including steam turbine, diesel engines, gas turbine and nuclear engines. Among these types, diesel engines are the most widely used and occupy ˜90% of the total current power capacity. However, all these engines have environmental problems. Diesel engines, steam turbines and gas turbines need to combust fossil fuels. Contaminates (e.g. CO2, NOx and particulates) are inevitably produced in combustion processes. Nuclear power systems not only produce nuclear waste pollution and provide a radiation risk but also are at least an order of magnitude more expensive than other power systems.
Consequently, a combustion free power system with a non-polluting exhaust would be greatly welcomed by the marine industry and the general public. It would also be desirable if such a marine power system could be used to generate electricity for use within the boat and to heat and/or cool the boat as necessary.
The present invention concerns the use of a cryogenic working fluid for energy storage, energy generation and propulsion.
A cryogenic energy storage (CES) system according to an embodiment of the present invention stores a cryogen produced using electricity during off-peak hours, thus storing energy, and uses the stored cryogen to generate electricity during peak hours, thus releasing the stored energy. The cryogen may be pumped, heated and then expanded in a turbine.
Accordingly, the present invention provides a method of storing energy comprising:
The present invention also provides a cryogenic energy storage system comprising:
The turbine may be used to drive a generator and thus generate electricity.
Alternatively, or in addition, the turbine may be used to drive a propeller for example for use in a marine engine. Consequently, the CES may be used as a Cryogenic Propulsion System (CPS).
The turbine may comprise a multi-stage quasi-isothermal turbine. The turbine may include reheaters or interheaters.
A number of suitable cryogens may be used. Preferably, the cryogen comprises liquid air. Alternatively, the cryogen may comprise slush air, liquid nitrogen, liquid hydrogen, liquid natural gas (LNG) or any other cryogen.
The energy storage system may maximise the use of, and minimise the modification of, current available and mature technologies for cryogen formation, such as air liquefaction plants.
If the cryogen comprises liquid air, the liquid air may be produced by an air liquefaction plant and supplied to the CES at off-peak hours. In the meantime, other products such as O2, N2, Ar and CO2 in both gas and liquid states could be produced as commercial products if needed. The efficiency of the production of the cryogen may be improved by using waste cold from other sources such as from the regasification of LNG (liquid natural gas).
Modern large capacity cryogenic oxygen production plants have low running costs of ˜0.4 kWh/kg (1.44 MJ/kg). This cost is expected to decrease further to ˜0.3 kWh/kg (1.08 MJ/kg) by 2010-2020 (“Air separation and liquefaction: recent developments and prospects for the beginning of the new millennium”, Castle W. F., International Journal of Refrigeration, 25, 158-172, 2002; “Energy analysis of cryogenic air separation”, Cornelissen R. L. and Hirs G. G., Energy Conservation and Management, 39, 1821-1826, 1998). The CES may use a feedstock of liquid air from a cryogenic plant but will work completely separately from the cryogenic plant; this feedstock may be small depending on the ‘cold energy’ recycle and operation strategy. The production of liquid air may consume about 80% of the energy required to produce liquid oxygen given present production methods.
The cryogen may be expanded by heating. For example, the cryogen may be heated by thermal sources including ambient, geothermal, waste heat from power plants and/or other waste heat resources to heat the cryogenic working fluid and generate electricity during peak hours. The thermal sources may not previously have been utilised for electricity generation because the temperature difference between the working fluid and heat source would have been considered insufficient. The working fluid may be superheated by the waste heat. The waste heat may have originated from power plants or from the compression process of the input gas or even from the waste gas stream after being heated to ambient temperature by ambient air. To increase the energy density of the working fluid, the gaseous input may be at a high pressure before expansion because the ideal work per unit mass of gaseous input for an isothermal expansion for an ideal gas, WT, is given by
where R, T, Pin and Pout are the universal constant, gas temperature, and injection and exhaust pressures, respectively. Moreover, the cryogen may be pumped as a liquid to a high working pressure because little work is consumed in the pressurization of liquid. On the other hand, the gas temperature may be as high as possible before expansion. Use could be made of the waste heat contained in the flue gas from power plants for heating the cryogen. Most effectively, the ambient air could be used to heat the cryogen to approximately the environmental temperature and the waste heat could then be used to heat the working fluid further to improve the energy efficiency of the entire system. Because the temperature difference between the cryogen and ambient temperature is high, waste heat which previously would have been considered a poor source of energy can be used as a source of energy to heat the cryogen.
By using the waste heat, the CES can be used as a net energy generator. Therefore, the CES can operate as a stand-alone energy storage plant using electricity as an energy input along with ambient temperature heat from the atmosphere. The CES can be placed either at the point of generation or the point of demand.
The ‘cold’ energy contained in the cryogen as the working fluid is very high-grade cryogenic energy and at least a portion is recycled. In a preferred embodiment the ‘cold’ energy contained in the working fluid is extracted to cool down the gaseous input (before and/or after a compressor, a fan or a blower) through heat exchangers. The cold energy may be extracted from the exhaust gas from the system. Assuming that the cryogen is heated to the ambient temperature in an isobaric process before expansion, the heat absorbed from the atmosphere by the cryogen is given by Q=h0−hl where h0 and hl are enthalpy at ambient temperature and at liquid temperature, respectively. Considering a Carnot cycle operated between a low temperature reservoir at Tl=78.9K and a high temperature reservoir at an ambient temperature of T0=300K, the amount of work is given by
Therefore the amount of work is proportional to the temperature difference. The above equation also implies that the work required to achieve the cold energy Q is equivalent to several multiples of the cold energy, which should therefore be used effectively.
The input air can be compressed before, after or at the same time as passing through the heat exchangers depending on applications. Therefore, the compressor can be positioned either before the heat exchanger, after the heat exchanger, or even within the heat exchanger. If the cold air is to be used for air-conditioning or cooling of food and other products, then it is preferable for compression to be realised by a blower (low pressure) located before the heat exchangers. Alternatively, if the input air is used for producing liquid cryogen, then it is preferable for a compressor to be placed after the heat exchangers. Such a compressor could be a stand-alone compressor attached to the CES if the liquifaction plant is remote to the CES. Alternatively, if the CES is adjacent to the liquefaction plant, then the compressor of the liquefaction plant could be used.
If the cold cryogen is used to cool the gaseous input, the cooled gaseous input can then feed back into the cryogen plant as a feedstock or be liquefied to cryogen inside the CES.
In addition, or alternatively, the cold energy may be used to provide cooled air for refrigeration or air conditioning purposes. For example, in a maritime power system, the energy storage system can be used to drive a turbine to drive a propeller as well as to provide cooled air for air conditioning and/or refrigeration purposes.
Alternatively, or in addition, waste heat from the system could be used to provide heat to the immediate environment, e.g. to provide heating and/or hot water in a boat.
The present invention may make simultaneous use of ‘cold’ energy and ‘waste’ heat. By recovering the ‘cold’ energy from the expansion of the stored cryogen and using it to enhance the production of more cryogen whilst the system is operating in electricity generation mode, the efficiency of the system as a whole is increased. Cold energy is as useful in this system as hot energy. In addition the CES uses energy in the ambient air (heat) or water to heat the cryogen to close to the ambient temperature, followed by further heating with waste heat from, for example, flue gas and steam venting to the environment from a power generation plant. Also, heat released from the compression of gaseous input can also be recovered and used to heat the cryogen. The heat applied to the cryogen causes it to expand and this drives the cryogen.
As heat losses and hydraulic pressure drops always occur, the pressure of the gaseous input may be increased either before or after the one or more heat exchanger, for example at the inlet, using, for example, a blower or a compressor. The compression process could be adiabatic or isothermal. Assuming the ideal behaviour of air, the work required for the isothermal process is given by
whereas that for the adiabatic process, WQ, is given by
where k, P1, P0 are the specific heat ratio (=1.4 for air), and the outlet and inlet pressures of the compressor or blower, respectively. Therefore, the required work increases with increasing outlet pressure P1. Therefore, P1 should be kept as low as possible to save compression work.
Waste heat from the compressor could be used to provide heat to the immediate environment, for example, to provide heating and/or hot water in, for example, a boat.
In a preferred embodiment the cryogen production plant may be integrated with the energy storage system. Alternatively, the cryogen production plant may be remote from the energy storage system and the cryogen could be transported between the two plants.
A small amount of cryogen may be needed to top up the system after each cycle.
When a non-polluting source of energy is used to power the system, the system is environmentally benign with a potential to reverse environmental contamination by separating environmentally detrimental gases, such as CO2 and other contaminants, associated with the burning of fossil fuels from the gaseous input.
The system of the present invention does not involve any combustion process so it will not cause any emissions. The only working fluid is the cryogen. The effect on the environment is also minimised because less CO2 and other environmentally detrimental gas components such as NOX are produced or used.
The CES system can be used for storing energy produced from most existing power generation plants.
When the CES is configured as a CPS, the system can be used as a propulsion device instead of in a static energy storage or generation system. The CPS could therefore be used in a boat engine. The CES could be configured to drive both a propeller and a generator so that the power system could be used to both provide propulsion and electricity for a boat.
In addition, the CPS could be further configured to provide heat for heating a boat and/or its contents. The CPS could also be further configured to provide cold for refrigeration purposes on board the boat, or for air conditioning of the boat.
The present invention will now be described in more detail with reference to the following figures in which:
A conceptual design of the energy storage system of the present invention is shown in
Within the energy storage system 100, there are two major air streams. One stream 110 feeds air to the air liquefaction plant 200 to be liquefied and stored as liquid air in a cryogen tank. During peak time the liquid air is pumped, heated and then expanded in the CES 300 to generate electricity. Another air steam 120 is input air from the atmosphere. Input air 120 is fed to the CES 300 to supply heat for expansion of the working liquid air and to extract the ‘cold’ energy from the working liquid air. The cooled input air 130 can be directed to the air liquefaction plant 200 as a feedstock or be throttled to produce liquid air within the CES 300 to reduce the amount of cryogen required from the air liquefaction plant 200. At the same time, the air liquefaction plant 200 can produce other products 210 such as N2, O2, CO2, Ar etc if needed.
The cryogenic air liquefaction system 200 is a mature technology and many types of cryogenic air liquefaction systems are readily available “off-the-shelf”.
A CES 300 according to the present invention is shown in
Liquid air 250 from a cryogenic plant is introduced into the cryogen tank 370 (in state 5 in
There are three possible benefits in adopting option 3: recovery of lower grade heat, if usable, from the exhaust of the turbine; injection into the combustion chamber of the turbine to reduce NOx; and increasing the power output of the gas turbine as the injected air can act as a diluent that permits greater fuel consumption without exceeding the turbine inlet temperature limits. These benefits may be marginal but could bring the overall efficiency up if effectively used.
In the input air stream 120, air from the environment (state 0) is compressed (state 1) using compressor 310 and introduced to the first heat exchanger 340 (state 2) for use in heating up the working fluid. The compressor may be a multi-step compressor to approach an adiabatic compression. Some unwanted components in the input air such as water (which is bad for the turbine due to cavitation), carbon dioxide, NO and hydrocarbons can also be removed during this process.
The cleaned input air then goes through the second heat exchanger 350 (state 3) to extract more ‘cold energy’ from the working fluid.
The cooled input air is then either fed to the liquefaction plant 200 as feedstock or to the throttling valve 360 to be transformed into liquid air (state 4) for top-up of the cryogen tank 370. A small proportion of air after the throttling is in the gas state but is still at low temperature (state 6). This part of cold energy is recovered by introducing the gas back into the second heat exchanger 350. This part of the air may be rich in oxygen so it can further be used, for example, as an oxidant in a gas turbine or a coal-gasification turbine.
The first heat exchanger 340 may be an integrated heat exchanger so that two parallel heat exchanging processes occur, namely between the input air and the working fluid, and between the working fluid and the (relatively) high temperature flue gas from the power plant. The first heat exchanger 340 may alternatively be designed as two separate heat exchangers, one for each of these two processes.
The working processes of the CPS system 500 comprise:
Input air 3/4 under ambient conditions is introduced to extract cold energy via heat exchangers 530 and 535 to provide cool air for air conditioning (12˜18° C., from heat exchanger 530) and refrigeration (−24˜−18° C., from heat exchanger 535).
Four typical cycles for the CES system of
The ideal thermodynamics cycle is shown in
1) Process 5-7, Pumping process of working fluid: The working fluid (liquid air) from the cryogen tank is pumped from ambient pressure P0 to P2 adiabatically. The specific work (work per unit mass of liquid air) can be expressed by:
from the viewpoint of fluid mechanics. The work can also be expressed by the enthalpy difference between states 7 and 5 from the first law of thermodynamics: W5-7=h7−h5.
2) Process 7-8, Isobaric heating of working fluid: The working fluid is heated by the input air from Ts to the ambient temperature T0. The specific work done in this process is zero: W7-8=0. The specific heat absorbed by the working fluid from input air is: Q7-8=h8−h7. The exergy loss of the process is therefore: Ex7-8=T0 (S8−S7)−(h8−h7).
3) Process 8-0, Isothermal expansion of the working fluid: The working fluid at the high pressure expands in the turbine, which drives the generator to generate electricity at the ambient temperature T0. The specific ideal work done by the turbine in this process is given by: W8-0=T0 (S0−S8)−(h0−h8). The specific heat absorbed during the expansion by the working fluid from the atmosphere is: Q8-0=T0(S0−S8).
4) Process 0-6, Extraction of cold energy from the work fluid by the input air: The input air is used to extract the cold energy from the work fluid isobarically. No work is needed in theory in this process: W0-6=0. The specific cold absorbed by the input air from the working fluid is: Q0-6=h6−h0. The exergy obtained by the input air over the process is given by: Ex0-6=T0(S0−S6)−(h0−h6).
5) Process 6-5, Condensation of input air: The input air is condensed by the cold exergy released by the work fluid, which requires zero work to be done: W6-5=0. The specific cold energy absorbed by the input air from the work fluid is: Q6-5=h5−h6=λ where λ is the latent heat of vaporisation. The corresponding exergy obtained by the input air is: Ex6-5=T0(S6−S5)−(h6−h5). Assuming the mass flow of work fluid is 1, the mass flow of the input air is x, then a heat balance gives: Q7-8≧x(Q0-6+Q6-5) where Q7-8=h8−h7, Q0-6=h6−h0 and Q6-5=h5−h6. Inserting these expressions into the above equation gives: h8−h7≧x(h0−h5). If P2 is given, then h8, h7, h0, h5 can be determined and x can be expressed by:
According to the second law of thermodynamics, exergy of a system can only decrease without input energy, that is: Ex7-8≦x(Ex0-6+Ex6-5),
Therefore, the consumption of liquid air for a single cycle is (1−x) and the specific net work output of the cycle should be: Wnet=W8-0−W5-7=(S0−S8)−(h0−h8)−(h7−h5) and the energy density of CES can be expressed by:
Assuming that the energy consummation of the liquid air produced in the air liquefaction plant is EC, the energy efficiency of the whole energy storage system (Air liquefaction+CES), EE, can be calculated by:
Considering the efficiency of pump ηP and the efficiency of turbine ηT, the net work Wnet should become:
The energy density of CES ED becomes:
EE becomes:
However, the temperature difference between the working liquid and the input air cannot be avoided. This will decrease the temperature T8 and increase the temperature T6. Therefore, the ideal thermodynamics cycles overpredict the overall efficiency of the system. This is accounted for in the following, with reference to
In
The work, heat and/or exergy related to the processes shown in
1) Process 5-7, Pumping process of working fluid: This process in
which is equal to the enthalpy difference between state 7 and state 5: W5−7=h7−h5.
2) Process 7-8′, Isobaric heating of working fluid: The working fluid is heated by the input air from Ts to T8′ instead of ambient temperature T8 (=T0). The specific work done in this process is zero: W7-8=0. The specific heat absorbed by the working fluid from input air is: Q7-8′=h8−h7. The exergy loss in the process is therefore: Ex7-8′=T0(S8′−S7)−(h8′−h7).
3) Process 8′-0′, Isothermal expansion of the working fluid: The working fluid at a high pressure expands in the turbine, which drives the generator isothermally to produce electricity. The specific ideal work done by the turbine in this process is: W8′-0′=T0′(S0′−S8′)−(h0′−h8′). The specific heat absorbed during the expansion by the working fluid from the atmosphere is: Q8′-0′=T0′(S0′−S8′).
4) Process 0-6′, Extraction of cold energy from the work fluid by the input air: The input air is used to extract the cold from the work fluid isobarically. The specific work done in this process is zero, i.e: W0-6′=0. The specific cold extracted from the work fluid by the input air is: Q0-6′=h6′−h0. The exergy obtained by the input air in the process is therefore given by: Ex0-6′=T0(S0−S6′)−(h0−h6′).
5) Process 6′-6-5, Cooling and Condensation of input air: The input air is cooled and condensed in the air liquefaction plant. Assuming the mass flowrate of working fluid is 1, the mass flowrate of input air is x, heat balance of the cycle gives: Q7-8′≧xQ0-6′ where Q7-8′=h8′−h7, Q0-6′=h6′−h0 the above equation becomes: h8′−h7≧x(h0−h6′). If P2 and temperature differences between T8 and T8′ and T6 and T6′ are given, h8′, h7, h0, h6′ can be determined and x can then be expressed by:
According to the second law of thermodynamics, the relationship for the exergy is: Ex7-8′≦xEx0-6′,
the above relation
always holds. That implies that vaporization of 1 unit of working fluid can pre-cool
unit of input air. If the efficiency of heat exchanger is high enough, then x could be greater than 1. The specific cold recycled in this practical recycle is: Q7-8′=xQ0-6′=x(h0−h6′). As mentioned above, the cold energy in liquid air is very high-grade energy, assuming the air is an ideal gas, the above cold energy is equivalent to the ideal work given by: W7-8′=x[T0(S0−S6′)−(h0−h6′)]. The specific net work output of the cycle is therefore given by:
and the energy density of CES is:
The energy efficiency of the whole energy storage system (air liquefaction+CES) EE can be calculated by:
Considering the efficiency of pump ηP, the efficiency of turbine ηT and the efficiency of air liquefaction ηA, the net work Wnet should be:
The energy density of CES ED becomes:
and the energy efficiency of the whole energy storage system becomes:
Considering further the use of waste heat, if T0 is superheated to T9 using the waste heat from the power plant, as shown in
and the energy density of CRS is:
This leads to the following energy efficiency of the entire energy storage system (air liquefaction system+CES) EE2:
If T0=300K and neglecting the energy losses due to the turbine, pump and heat exchangers, the ideal work output for a unit mass of liquid air can be estimated on the basis of the above analysis by:
and the ideal energy density of CES is:
If EC=1440 kJ/kg (0.4 kWh/kg), the ideal energy efficiency of CES is:
If EC=1080 kJ/kg (0.3 kWh/kg), the ideal energy efficiency of CES becomes:
If T9 is superheated to 400K using the waste heat from the power plant, the specific ideal work is:
The ideal energy density of CES is:
If EC=1440 kJ/kg (0.4 kWh/kg), the ideal energy efficiency of CES is:
If EC=1080 kJ/kg (0.3 kWh/kg), the ideal energy efficiency of CES becomes:
Note that the energy consumption (0.3 and 0.4 kWh/kg) used above is for separation of oxygen from air. The actual energy requirement of liquid air production is approximately 80% of this figure so the estimation of the ideal energy efficiency is conservative. On the other hand, the probable actual efficiency is approximately 80% of that achieved in the ideal work cycle so the efficiency as estimated above should be close to the actual efficiency.
From the above analyses, it can be concluded that the work output of CES increases significantly for a given amount of cryogenic fuel consumption owing to the recovery of the cold energy. The extra work from cold recycle is equivalent to x[T0(S0−S6′)−(h0−h6′)] where x is determined by the temperature difference and energy losses of components. The specific work output and energy density of CES depends on the efficiency of the turbine ηT and the energy consumption per unit mass of liquid air in the air liquefaction plant EC. The efficiency of the pump is also a factor but not as important as ηT and EC because the work consumed by a pump is relatively small. An increase in the temperature differences of heat exchangers will increase the liquid air consumption or decrease the efficiency of the cycle. It can be seen that the energy efficiency and energy density of the energy storage system EE is competitive to other currently available energy systems. The system of the present invention also offers the advantages of producing other products from the air liquefaction plant and using the waste heat from the power plant.
The thermodynamics cycle of a CES for a low input air pressure case is shown in
1) Process 0-2, Isothermal pressurization of input air: The input air is compressed isothermally from the ambient pressure P0 to P1. The work done on the air by the compressor is: W0-2=T0(S0−S2)−(h0−h2). The heat Q0-2 of this isothermal process is: Q0-2=T0(S0−S2). Unfortunately, it is difficult to realize an absolute isothermal pressurization process, the actual process will be a polytropic process like 0-1.
2) Process 2-3′-3, Extraction of cold energy from the working fluid by input air: The compressed input air is used to extract the cold energy from the working fluid isobarically. The work done in this process is zero: W2-3=0. The heat released from the input air in the process 2-3 is: Q2-3′=h3′−h2. The heat released from input air in the process 3-3′ is: Q3′-3=h3′−h3=T3(S3′−S3)=λ. The exergy obtained from the process is therefore given by: Ex2-3=T0(S3−S2)−(h3−h2).
3) Process 3-4-5(-6), Throttling of compressed input air: The compressed input air is throttled to the ambient pressure for condensation. The work done in this process is zero: W3-4=0. The heat released from the input air is zero: Q3-4=0. Considering one unit of the working fluid, the total amount of input air is x units of which a fraction y is liquefied, the amount of liquefied air at state 5 will be xy, and the amount of gaseous air at state 6 will be x(1−y). A heat balance over the process 3-4-5(-6) will be: h3=yh5+(1−y)h6.
4) Process 5-7, Pumping process of working air: Process 5-7 in
The above work can also be expressed by the enthalpy difference between state 7 and state 5: W5-7=h7−h5.
5) Process 7-7′, Isobaric heating of the working fluid to condense input air: The working fluid is heated to condense the input air at T3. The specific work done in this process is zero: W7-7′=0. The specific heat absorbed from the input air is: Q7-7′=h7′−h7.
6) Process 7′-8, Isobaric heating of the working fluid to cool the input air: The working fluid is heated by the input air from T7′ to T8. The specific work done in this process is zero: Q7′-8=0. The specific heat absorbed from the input air is: Q7′-8=h8−h7′. The exergy released in the process 7-8 is: W7-8=T0(S8−S7)−(h8−h7).
7) Process 8-9, Isobaric superheating of the working fluid: The working fluid is superheated by from T8 to T9 in which no work is done, i.e.: W8-9=0 while the specific heat absorbed from the input air over this process is: Q8-9=h9−h8.
8) Process 9-10, Isothermal expansion of the working fluid: The working fluid with a high pressure expands in the turbine isothermally which delivers work to generate electricity. The specific ideal work done in this process is: W9-10=T9 (S10−S9)−(h10−h9). The specific heat absorbed by the working fluid from the ambient in the process is: Q9-10=T9(S10−S9). It should be noted that the T9 is higher than the ambient temperature, which requires energy from the waste heat from the power plant to ensure an isothermal expansion. If the expansion of air is an adiabatic process, the specific ideal work Wad will be:
which means no heat absorption namely: Qad=0. The actual work, however, is expected to be in the range between W9-10 and Wad. A factor called isothermicity γ is often used as an index, which is defined as the ratio of the actual work to the isothermal work:
Thus, the actual work Wac can expressed as:
9) Process 6-6′, Extraction of cold from exhaust air to condense the input air: The exhaust air (part of input air after the throttling) is used to condense the input air isobarically. The specific work done in this process is zero: W6-6′=0. The specific heat absorbed from input air is: Q6-6′=h6′−h6. The heat balance of 3′-3, 7-7′ and 6-6′ is therefore given by: xQ3-3′=Q7-7′+x(1−y)Q6-6′, x(h3−h3′)=(h7′−h7)+x(1−y)(h6′−h6).
10) Process 6′-0, Extraction of cold from exhaust air to cool the input air: The exhaust air is used to cool down the input air isobarically. The specific work done in this process is zero: W6′-0=0. The specific cold absorbed from the exhaust air by the input air is: Q6′-0=h0−h6′. The heat balance of 2-3′, 7′-8 and 6′-0 is expressed as: xQ2-3′≦Q7′-8+x(1−y)Q6′-0, x(h2−h3′)≦(h8−h7′)+x(1−y)(h0−h6′). The exergy obtained in process 6-0 is: Ex0-6=T0(S0−S6)−(h0−h6). From the heat and exergy balances of the cycle, x and y can be calculated by the following equations based on the T-S diagram in
From the above equations, the ratio of liquefaction of the input air y is:
Because (h6−h5)>(h6−h4)>0 always holds, therefore 1>y>0. Similarly, x can be expressed as:
As (h7′−h7)>0, [(h3−h3′)−(1−y)(h6′−h6)]>0 always holds, x>0. This means that vaporisation of one unit of the working fluid can produce xy units of liquid air, and the consumption of the cycle will be (1−xy). As a consequence, the specific net work output of the cycle is:
and the energy density of CES can be expressed by:
The energy efficiency of the entire energy storage system (Air liquefaction system+CES) EE can therefore be calculated by:
Considering the efficiencies of the pump ηP, the turbine ηT and the compressor ηCOM, the net work Wnet should be:
the energy density of CES ED becomes:
and EE becomes:
Based on the above analysis, it can be concluded that, in comparison with cryogenic (liquid nitrogen) powered engines, the consumption of cryogenic fuel is reduced by xy for 1 unit of working fluid but with a penalty of work required for compression W0-2=T0(S0−S2). The specific work output will be improved as the penalty is less than the benefit due to the reduction in the working fluid consumption. As the work of compression is much less than the work output of the turbine, the specific work output and the energy density of CES mainly depend on the efficiency of the turbine ηT and energy consumption for air liquefaction. This is similar to the case of using the ambient pressure. The efficiencies of pump and compressor are not key factors for improving the work output and energy density of CES. The efficiency of this cycle is expected to be lower than that of
The thermodynamic cycle of the CES for a high input air pressure case is shown in
1) Process 0-2, Isothermal pressurization of input air: The input air is compressed from ambient pressure P0 to P1 isothermally. The work done on the air by the compressor is: W0-2=T0 (S0−S2)−(h0−h2). The heat Q0-2 of this isothermal process is: Q0-2=T0 (S0−S2). Unfortunately, it is difficult to realize an absolute isothermal pressurisation process, the actual process will be 0-1.
2) Process 2-3, Extraction of cold energy from the working air by input air: The compressed input air is used to extract the cold energy from the work fluid isobarically. The work done in this process is zero: W2-3=0. The heat released from the input air for process 2-3 is: Q2-3=h3−h2. The exergy obtained from the process is: Ex2-3=T0 (S3−S2)−(h3−h2).
3) Process 3-4-5(-6), Throttling of compressed input air: The compressed input air is throttled to the ambient pressure for condensation. The work done in this process is zero: W3-4=0. The heat released from the input air is zero: Q3-4=0. Similar to the low input air pressure case, considering one unit of working fluid and assuming a total of x units of input air of which a fraction y is liquefied, the amount of liquid air produced by liquefaction at state 5 is xy, and the amount of gaseous air at state 6 is x(1−y). The heat balance of 3-4-5(6) is therefore expressed as: h3=yh5+(1−y)h6.
4) Process 5-7, Pumping of working fluid: This process is the same as that in
The work can also be expressed by enthalpy difference between the states 7 and 5: W5-7=h7−h5.
5) Process 7-8, Isobaric beating of the working fluid to cool input air: The working fluid is heated to condense the input air at T3, and there is work involved in this process: W7-8=0. The specific heat absorbed from the input air is: Q7-8=h8−h7. The exergy released in the process 7-8 is therefore: W7-8=T0 (S8−S7)−(h8−h7).
6) Process 8-9, Isobaric superheating of the working fluid: The working fluid is superheated by the input air from T8 to T9 in which zero work is done, i.e. W8-9=0. The specific heat absorbed from input air is: Q8-9=h9−h8.
7) Process 9-10: Isothermal expansion of the working fluid: The working fluid with a high pressure expands in the turbine and delivers work isothermally. The specific ideal work done in this process is: W9-10=T9 (S10−S9)−(h10−h9) while the specific heat absorbed in the process is: Q9-10=T9(S10−S9). Similar to the low pressure case, T9 is higher than the ambient temperature; the waste heat from the power plant is needed to keep this process isothermal. If the expansion of the working fluid is adiabatic, the specific ideal work Wad will be:
The specific heat absorbed in the process is: Qad=0. As a result of the above analysis, the actual work should be in the range between W9-10 and Wad. As mentioned before, the isothermicity γ is used to describe the non-ideality:
Thus, the actual work Wac should be expressed as: Wac=γW9-10=γ[T9 (S10−S9)−(h10−h9)].
8) Process 6-0, Extraction of cold energy from the exhaust air to cool the input air: The exhaust air after the throttling is used to cool the input air isobarically. The specific work done in this process is zero: W6-0=0. The specific cold absorbed by the input air is: Q6-0=h0−h6. The heat balance over processes 2-3, 7-8 and 6-0 is expressed as: xQ2-3=Q7-8+x(1−y)Q6-0, x(h2−h3=(h8−h7)+x(1−y)(h0−h6). The exergy obtained in the process 6-0 is: Ex0-6=T0 (S0−S6)−(h0−h6). Based on the heat and exergy balances of processes 2-3, 3-4-5-6, 7-8, 6-0, x and y can be calculated by the following equations on the basis of a T-S diagram for the air:
From the above equations, the ratio of liquefaction of the input airy can be expressed by:
Similar to the method in the low pressure case, 1>y>0 always holds, and x can be expressed as:
As (h8−h7)>0, [(h2−h3)−(1−y)(h0−h6)]>0 always holds, one has x>0. This means vaporisation of one unit of working fluid could produce xy units of liquid air, while the consumption of this cycle is 1−xy, and the specific net work output of the cycle will be:
and the energy density of CES is:
The energy efficiency of the entire energy storage system (Air liquefaction+CES) EE can therefore be calculated by:
Considering the efficiencies of the pump ηP, the turbine in ηT and the compressor ηCOM, one has the following net work Wnet:
As a result of the above, the energy density of CES ED becomes:
and EE becomes:
From the above analysis, it can be seen that, compared with the design of liquid nitrogen powered engines, the consumption of cryogenic fuel for this cycle is decreased by xy but with a penalty of work by W0-2=T0 (S0−S2)−(h0−h2). However, the specific work output is improved due to the decrease of liquid fuel consumption. The work required by the compressor should be comparable with that produced by the turbine. As a consequence, the efficiency of the compressor ηCOM becomes a key parameter determining the overall efficiency of the CES. This cycle is more suitable for producing liquid air through the CES part of the energy storage system.
The above thermodynamics analyses on the four typical cycles show that:
The results also show that the efficiency of the CES is competitive to other energy storage systems. Additionally, the system can make use of the waste heat and produce air products if needed.
1) 1-2: Pumping process of working fluid: The working fluid (liquid air) from the cryogen tank is pumped from the ambient pressure P0 to P2. The specific work done on the liquid air is:
The above work can also be expressed by the enthalpy difference between state 2 and state 1: W1-2=h2−h1.
2) 2-2′: Isobaric heating of working fluid to condense input air 1: The working fluid is heated to condense the input air at T7. The specific work done in this process is zero: W2-2′=0. The specific heat absorbed from the input air 1 is: Q2-2′=h2′−h2.
3) 2′-3: Isobaric heating of working fluid: The working fluid is heated by the input air from T2′ to T3. The specific work done in this process is zero: W2′-3=0. The specific heat absorbed from the input air is: Q2′-3=h3−h2′. The exergy released in the process 2-3 is: Ex2-3=T0(S3−S2)−(h3−h2).
4) 3-0: Isothermal expansion of working fluid: The working fluid with a high pressure expands in the turbine isothermally which delivers work to generate propulsion and electricity. The specific ideal work done in this process is: W3-0=T0 (S0−S3)−(h0−h3). The specific heat absorbed from the ambient in the process is: Q3-0=T0 (S0−S3). If the expansion of the working fluid is adiabatic, the specific ideal work Wad will be:
which means no heat absorption, namely: Qad=0. The actual work, however, is expected to be in the range between W3-0 and Wad. A factor called isothermicity, γ, is often used as an index, which is defined as the ratio of the actual work to the isothermal work:
Thus, the actual work Wac can be expressed as: Wac=γW3-0=γ[T0(S0−S3)−(h0−h3)].
5) 0-4: Polytropic pressurisation of input air 1: The input air 1 is compressed polytropically from the ambient pressure P0 to P1. The work done on the air by the compressor is:
where n is the polytropic coefficient. The heat, Q0-4, of this polytropic process is: Q0-4=cn(T4−T0) where Cn is the polytropic heat ratio:
T4 can be calculated by:
6) 4-5: Release of heat from input air 1 isobarically to input air 2: The heat of the input air 1 is released to the input air 2 or water to produce hot air/water. The work done in this process is zero: W4-5=0. The heat released from the input air 1 in the process 4-5 is: Q4-5=h4−h5.
7) 5-6-7: Cooling of input air 1 by working fluid: The compressed input air 1 is cooled by working fluid isobarically and the cold energy inside the working fluid is extracted at the same time. The work done in this process is zero: W5-7=0. The heat released from the input air 1 in the process 5-6 is: Q5-6=h5−h6. The heat released from input air in the process 6-7 is: Q6-7=h6−h7=T6(S6−S7)=. The exergy obtained from the process is therefore given by: EX5-6-7=T0 (S5−S7)−(h5−h7).
8) 7-8-9(-1): Throttling of compressed input air 1: The compressed input air 1 is throttled to the ambient pressure for condensation. The work done in this process is zero: W7-8=0. The heat released from the input air is zero: Q7-8=0.
9) 9-9′: Extraction of cold from exhaust air to condense the input air: The exhaust air (part of input air 1 after the throttling) is used to condense the input air isobarically. The specific work done in this process is zero: W9-9′=0. The specific heat absorbed from input air is: Q9-9′=h9′−h9.
10) 9′-0: Extraction of cold from exhaust air to cool the input air: The exhaust air (part of the input air 1) is used to cool down the input air 1 isobarically. The specific work done in this process is zero: W9′-0=0. The specific cold absorbed from the exhaust air by the input air 1 is: Q9′-0=h0−h9′. The exergy obtained in process 9-0 is: EX9-0=T0(S0−S9)−(h0−h9).
11) 0-10: Extraction of cold energy of the working fluid by input air 3 isobarically for air conditioning: The cold of the working fluid is extracted by input air 3 for cool air production to be used for air conditioning. The work done in this process is zero: W0-10=0. The cold energy from the working fluid in the process 0-10 is: Q0-10=h0−h10.
12) 0-10-11: Extraction of cold energy of the working fluid by input air 4 isobarically for refrigeration: The cold of the working fluid is extracted by input air 4 for refrigeration. The work done in this process is zero: W0-11=0. The cold energy from the working fluid in the process 0-11 is: Q0-11=h0−h11.
13) 0-12: Extraction of heat energy of the input air 1 by input air 2/water isobarically: The heat of the input air 1 is extracted by input air 2/water for hot air/water production. The work done in this process is zero: W0-12=0. The heat released from the input air 1 in the process 0-12 is: Q0-12=h12−h0.
Assuming that, for one unit of the working fluid, the total amount of input air 1 is x1, the total amount of input air 2 is x2, the total amount of input air 3/4 is x3+x4 with x3 units for air condition and x4 units for refrigeration. In the one unit of the working fluid, a1 units are used for the input air 1, a2+a3 units for cooling input air 3/4 in which a2 is for x3 and a3 is for x4. According to the first and second laws of thermodynamics, the following balances of heat and exergy can be obtained:
1) Heat balance in process 7-8-9(-1): Assuming that, for a1 units of the working fluid, y fraction of the input air 1 is liquefied, the amount of liquefied air at State 1 will be x1y, and the amount of gaseous air at State 9 will be x1(1−y). A heat balance over the process 7-8-9(-1) will be: h7=yh1+(1−y)h9. From the above equations, ratio of liquefaction of the input air y is:
Because (h9−h1)>(h9−h7)>0 always holds, therefore 1>y>0.
2) Heat balance in processes 6-7, 2-2′ and 9-9′: The heat balance of 6-7, 2-2′ and 9-9′ x1(h6−h7)=a1(h2′−h2)+x1(1−y)(h9′−h9). x1 can be expressed as:
3) Heat balance in processes 5-6, 2′-3 and 9′-0: The heat balance of 5-6, 2′-3 and 9′-0 can is expressed as: x1Q5-6≦a1Q2-3+x1(1−y)Q9′-0, x1(h5−h6)≦a1(h3−h2)+x1(1−y)(h0−h9′).
4) Heat balance in processes 4-5 and 0-12: The heat balance in processes 4-5 and 0-12 can be expressed by: x2(h12−h0)=x1(h5−h4). x2 can be expressed as:
5) Heat balance in processes 0-10 and 2-3: The heat balance in processes 0-10 and 2-3 can be expressed by: x3(h0−h10)=a2(h3−h2). x3 can be expressed as:
6) Heat balance in processes 0-11 and 2-3: The heat balance in processes 0-11 and 2-3 can be expressed by: x4(h0−h11)=a3 (h3−h2). x4 can be expressed as: x4=a3(h3−h2)/(h0−h11).
7) Exergy balance of processes 5-7, 2-3 and 9-0: The exergy balance of processes 5-7, 2-3 and 9-0 can be given by: x1Ex5-7≦a1Ex2-3+x1(1−y)Ex0-9, x1[T0(S5−S7)−(h5−h7)]≦a1[T0(S3−S2)−(h3−h2)]+x1[T0(S0−S9)−(h0−h9)].
8) Mass conservation of process 2-3:
a
1
+a
2
+a
3=1
The following analyses use the efficiency of work (electricity) defined as:
where Woutput and Winput are the total works converted by the input and output energies, respectively. To calculate the equivalent work of heat and cold energy, two coefficients of performance (COP), refrigeration COP (ε), and heat pump COP (ζ), are used in the conversion of heat to work. As a consequence, the specific net work output of the cycle
On the other hand, the productivity of liquid air by input air 1 is x1y. Therefore the consumption of the working fluid is (1−x1y). The energy density of CPS can be expressed by:
It is known that the maximum specific work of liquid air, WR, is: WR=T0(S0−S1)−(h0−h1). The energy efficiency of the CPS, EE, can therefore be calculated by:
Considering the efficiencies of the pump ηP, the turbine ηT and the compressor ηCOM, the net work Woutput should be:
the energy density of CPS, ED, becomes:
and EE becomes:
Based on the above analysis, it can be concluded that:
gives the lower limit of the CPS. If ambient temperature T0=300K (is used and the working pressure of liquid air is 200 bar, assuming the efficiencies turbine and pump are both 0.78, the specific work output would be ˜326 kJ/kg.
If the pressure of the input air 1 exceeds ˜38 bar, there will be no isothermal condensing process in
A computational code has been written in the Fortran 90 environment to simulate the influences of various parameters on the performance of the CES system. The code is written for thermodynamics cycles operated between pressures above the ambient pressure and 3.8 MPa (see
The effects of these six parameters on four efficiencies related to the performance of the CES have been analysed. The four efficiencies that have been considered are:
The four efficiencies of the thermodynamics cycles associated with the CES are shown in
At P1=0.1 MPa (
At pressures of P1=0.2-2.0 MPa (
At P1=4.0-20 MPa (
From the above analysis, it can be concluded that P2 should be higher than 10 MPa. However, the selection of P2 may be limited by the mechanical feasibility. At present, pressurisation of air to 20 MPa is very common practice in the air separation and liquefaction plants without any engineering difficulties. According to the analysis, P2=20 MPa is recommended for the CES as pressures higher than 20 MPa lead to a very marginal increase in efficiency. As a consequence, the following analyses are all based on P2=20 MPa.
The actual efficiencies of CES without and with superheating are plotted in
Therefore, if no waste heat is used by the CES system, P1=0.1 MPa should be selected as the working pressure of the input air, as the efficiency is highest and there is no need for a compressor, hence reducing the capital investment and maintenance costs. As a result of this analysis, the following analyses are conducted under the two pressure conditions of P1=0.1 MPa and P1=4.0 MPa.
As mentioned above, two sets of conditions are considered, namely, (P1=0.1 MPa, P2=20 MPa), and (P1=4.0 MPa, P2=20 MPa). The efficiencies of the compressor and pump are taken as 0.88 (ηCOM=ηP=0.88). The ambient temperature is assumed as T0=300K, the superheat temperature is T9=400K. The temperature differences across the heat exchangers are not considered. Simulations are performed with seven turbine efficiencies of 0.68, 0.72, 0.76, 0.80, 0.88, 0.92, 0.96 and 1.00 and the results are illustrated in
The figures also show that the rate of increase in the CES efficiency at P1=0.1 MPa is lower than that at P1=4.0 MPa, indicating that the cycle efficiency at P1=4.0 MPa relies more on the efficiency of the turbine than does the cycle efficiency at P1=0.1 MPa.
If there is no waste heat, the CES efficiency at P1=0.1 MPa is higher than that at P1=4.0 MPa for a turbine efficiency of from 0.68 to 1.0. This indicates that P1=0.1 MPa should be used for the CES operation in the absence of the waste heat recycle.
If waste heat is used, the CES efficiency at P1=0.1 MPa is lower than that at P1=4.0 MPa for a turbine efficiency over 0.80, but the reverse is seen when the turbine efficiency is lower than ˜0.8. As a consequence, there is a need for optimisation.
The effect of the compressor efficiency on the CES efficiency is illustrated in
The efficiency of the CES cycle for P1=0.1 MPa and P2=20 MPa is constant as no compression of the input air is needed for P1=0.1 MPa. The efficiency of the CES at P1=4.0 MPa and P2=20 MPa increase monotonically with increasing efficiency of the compressor. An increase in the compressor efficiency by one percent leads to an increase in the CES efficiency by 0.717% for P1=4.0 MPa without heat recycle, and an increase in the CES efficiency by 1.056% for P1=4.0 MPa with heat recycle. This indicates that for P1=4.0 MPa, the efficiency of the compressor contributes significantly to the CES efficiency.
From
Simulations are performed on seven pump efficiencies of 0.68, 0.72, 0.76, 0.80, 0.88, 0.92, 0.96 and 1.00 for P1=0.1 or 4.0 MPa, P2=20 MPa, T0=300K, T9=400K and ηT=ηCOM=0.88. The temperature differences across the heat exchangers are not considered. The results are illustrated in
This indicates that the efficiency of the CES depends little on the efficiency of the pump because the work consumed by the pump is about an order of magnitude smaller than that of turbine and the compressor.
The results show that the efficiency of the CES increases monotonically with a decrease in the energy consumption of cryogen production. An increase in the efficiency of the air separation plant by one percent results in an increase in the efficiency of the CES cycle by ˜0.972% for P1=0.1 MPa without heat recycle, an increase in the efficiency of the CES cycle by ˜1.181% for P1=0.1 MPa with heat recycle, an increase in the efficiency of the CES cycle by 0.590% for P1=4.0 MPa without heat recycle, and an increase in the efficiency of the CES cycle by 1.381% for P1=4.0 MPa with heat recycle.
Compared with efficiencies of the turbine, compressor and pump, the efficiency of the air liquefaction plant is a more important factor contributing significantly to the overall efficiency of the CES.
If the energy consumption of the liquid air production were reduced to ˜0.28 kWh/kg, then the efficiency of the CES without waste heat recycle would be increased to ˜0.670 and that with waste heat recycle to ˜0.951.
Accordingly, the results of the above parametric analysis show that P1=0.1 MPa and P2=20.0 MPa give the best performance for cases without waste heat recycle. The results also show that P1=4.0 MPa and P2=20.0 MPa could give a better performance for cases with waste heat recycle than P1=0.1 MPa and P2=20.0 MPa could do, depending on the efficiencies of the components of the CES. The efficiencies of the turbine (ηT), the compressor (ηCOM), and the air separation plant (ηA) are shown to be the most important parameters in determining the overall CES efficiency, whereas the pump efficiency (ηP) has very little influence on the performance of CES.
Two parts of energy have been incorporated into the total possible energy from liquid air: a) isothermal expansion of compressed gas to ambient pressure and b) cold exergy utilisation by pre-cooling the air input for the separation and liquefaction system. For a simple idealised case (P1=0.1 MPa, P2=20 MPa, T=300 K), the ideal work from liquid air could be ˜740 kJ/kg that includes the contribution of a) 450 kJ/kg and b) 290 kJ/kg.
For the gas expansion work (450 kJ/kg) non-isothermal expansion is inevitable. An external heat source has to be added to maintain a high isothermity. A conventional turbine may achieve energy efficiency up to 85% under optimised conditions. It is visible that similar efficiency could be achieved for the proposed turbine applications. However, due to the very high pressures ˜200 bar involved, multi-stage expansion could be considered. The nearly-ambient operation temperature of the turbine also requires considerations of the sealing and lubrication issues.
For the recycling of the cold exergy (290 kJ/kg) the amount of the cold exergy that can be recycled is dependent on the a) operational pressures model, b) charging and discharging modes, and c) existence of extra cold energy storage system.
For the operational pressure models, two optimum cases have been identified: I) input air at 0.1 MPa and the working fluid at 20.0 MPa for operation temperature ˜300 k (no waste heat added) and II) input air at 0.1 MPa or 4.0 MPa and working fluids at 20.0 MPa for operation temperature ˜400 K (with a waste heat recycle). Take the optimized case I) for example (P1=0.1 Mpa, P2=20 Mpa and T=300K), for an ideal compression (dS=0), the temperature of liquid air after compressing to 20 MPa is ˜84 K, which is the lowest temperature that incoming air can get. The liquefaction process needs to remove ˜230 kJ/kg (sensible heat) and another ˜200 kJ/kg (latent heat) at saturation temperature, e.g. 78 K for air under 1 bar. The only work that can be saved through a heat exchanger is some of the work needed to reduce temperature from ambient to ˜84 K (this normally involves multi-stage compression and throttling for a liquefaction factory). Approx. 50% of the energy (latent heat+some sensible heat) for air liquefaction can not be extracted by the cold energy from the heat exchanger. The extra electricity needed is ˜0.2 kWh/kg air during discharging hours if a 0.4 kWh/kg industrial rate is assumed.
For the optimized case II) where the waste heat is utilized, the analysis will be the same as above for the incoming air at 0.1 MPa (P1=0.1 MPa, P2=20 MPa and T=400K), but different for the incoming air pressure at 4 MPa (P1=4 MPa, P2=20 MPa and T=400K). Since the saturation temperature is ˜131K at 4 Mpa, incoming air can be cooled down directly to the liquid state through a heat exchanger, which means no extra electricity is needed for manufacturing liquid air during peak hours. However this comes with the penalty of the compression work needed to bring air to 4 Mpa. For a pure isothermal compression, ˜0.328 MJ/kg, ˜0.1 kWh electricity, is needed. The temperature rise is also significant: for an adiabatic compression with compressor efficiency of 0.9, the temperature rise is ˜620K. The temperature rise reduces to 283 K and 132K respectively for a poly constant of 1.2 and 1.1. Extra cooling facilities are requested for the compressor to achieve a nearly-isothermal compression.
The amount of cold energy recycled is also dependent on the flow rate ratio during charging and discharging periods. The cold exergy application (in the energy release process) is based on the simultaneous cooling of incoming air (in the energy storage process) in a liquefaction unit. In principle these two events do not occur at the same time. For a typical energy storage system, the duration of the energy release process is only a couple of hours in peak times. To maintain safety and extend the running time, a typical liquefaction unit will operate full load at off-peak time and continue to operate at low load at other times. For a model with 8 hrs of discharging and 16 hrs of charging, the steady flow ratio is ˜2:1. If running at a 50% load during peak times, the flow rate ratio is increased to 4:1. For every kilogram of liquid air produced at peak times, only the sensible heat ˜230 kJ/kg-air can be cooled down by the evaporation of liquid air for the optimized operational pressure case I). Therefore, a large amount of cold energy will not be fully utilized. The shorter the discharging ratio, the larger the amount of cold energy wasted. To fully utilize the energy, the load for liquefaction could be increased but this would risk the consumption of more electricity at peak times.
Alternatively, the cold energy could be stored. During the discharging period, part of the cold energy could be used to pre-cool the incoming air. At the same time, the extra part of the cold energy will be stored in a thermal energy storage system (TES) that will release cold during the off-peak time to pre-cool the incoming air. This could maximize the opportunities of using cold energy. The storage material may include phase change materials, cryogenic storage materials and others. The storage material is chosen based on its thermal conductivity, specific heat, thermal diffusivity, density, and kinetic behaviour etc. The rate of heat absorption and releasing is directly related to the energy efficiency especially for the phase change materials. The energy storage system may be in the form of fixed bed, suitable geological sites and others. The storage efficiency may be influenced by the properties of the storage materials, the storage temperature and pressure, and the heat transfer coefficient between gas and storage materials.
A computational code has been written in the Fortran 90 environment to simulate the influences of various parameters on the performance of the CPS system. The code is written for thermodynamics cycles operated between pressures above the ambient pressure and 38 bar (see
In the simulations, the pressure of working fluid is taken as 200 bar, the temperature of hot air/water supplied by CPS as 328 K(55° C.), the temperature of cold air for air condition supplied by CPS as 285 K (12° C.), the temperature of cold air for food refrigeration supplied by CPS as 249 K (−24° C.), the coefficient of performance (COP) of the heat pump (ζ) as 3.0, the COP of cooling air for air conditioning (ε1) as 5.0, and the COP of refrigeration (ε2) as 3.0.
The ideal and actual efficiencies of CPS are plotted in
From inspection of
A high pressure of the input air 1 can produce a high proportion of liquid air and therefore a further increase in the efficiency of CPS. However, a high pressure of the input air 1 also consumes more compression work. Therefore, an optimal pressure of the input air 1 should be selected for the best CPS performance. Since the optimal pressure is not significantly different for the three realistic efficiencies of 0.88, 0.84 and 0.80, the pressure of the input air 1 is selected as 8 bar, and the following calculations are based on this pressure. At P1=8 bar, P2=200 bar, ηT=ηP=ηCOM=0.88, the maximum energy efficiency of CPS is 67.7%, and the specific outputs of the work, heat and cold of the CPS are 401.9 kJ/kg, 29.40/kg, 342.8 kJ/kg, respectively. It can be seen that the amount of cold produced by CPS is very large. Therefore, the CPS is particularly suitable for refrigeration boats.
The effect of the compressor efficiency on the CPS efficiency is illustrated in
The effect of the pump efficiency on the CPS efficiency is illustrated in
Simulations are performed on seven polytropic coefficients of 1.05, 1.10, 1.15, 1.20, 1.25, 1.30, and 1.35 for P1=1 bar, P2=200 bar, T0=300K, ηT=ηCOM=ηp=0.88. The results are shown in
Five values of the isothelinicity of the expansion process in the turbine of 0.80, 0.85, 0.90, 0.95, 1.0 for P1=1 bar, P2=200 bar, T0=300K, ηT=ηCOM=ηP=0.88 are simulated and the results are shown in
The heat exchangers are critical components of the CES. Heat exchangers are widely used in the cryogenics and air liquefaction industries, which has led to establishment of a substantial technology base. In general, the following factors are considered when designing a heat exchanger:
(1) Heat transfer requirement
(2) Efficiency or temperature differences of the exchanger
(3) The dimensions of the space available
(4) The need for low heat capacity
(5) The cost
(6) The importance of pressure drop
(7) The operating pressure
In the following analysis, focus is on the assessment of heat transfer requirements, type and size of the exchangers and influences of various factors on the performance heat exchangers. The following assumptions are made:
(1) Thermodynamic equilibrium between fluid phases
(2) Even flow distribution within heat exchanger
(3) Fully developed turbulent flow
(4) Adiabatic shell wall
(5) Zero axial conduction
(6) No radiation between hot and cold fluids
(7) Constant overall heat transfer coefficient.
Considering a heat exchanger that exchanges an amount of heat, Q, between a hot and a cold fluid, the volume of the heat exchangers can be assessed by:
where V represents the volume of the heat exchanger, S is the heat transfer area, is the ratio of the compactness of heat exchangers defined as
q is the heat flux, Ū is the overall average heat transfer coefficient, and Δ
where Ui is the heat transfer coefficient between the tube wall and the tube side fluid, Uo is that between the tube wall and the shell side fluid, and Uw accounts for the heat conductivity across the tube wall expressed by:
with λ,δ respectively the wall thermal conductivity and wall thickness. There is a large amount of literature on the calculations of the heat transfer coefficients Ui and Uo. For a turbulent flow in a smooth cylindrical tube, the heat transfer coefficient between the tube side fluid and the tube wall is given approximately by Nu=0.023 Re0.08Pr0.4 where Nu is the Nusselt number defined as
Re is the Reynolds number defined as
and Pr is the Prandtl number given by
where ρ is the density of the fluid, D is the diameter of the tube, v is the fluid kinematic viscosity, α is the fluid thermal diffusivity and μ is the fluid dynamic viscosity. For the pressure drop of a Newtonian fluid in a smooth cylindrical tube, the frictional pressure drop can be calculated by
where f is the friction factor, u is the flow velocity, L is the length of the tube. For a turbulent flow in tubes, the Blasius equation is generally used for estimating f in a wide range of Reynolds number:
The flow in the heat exchangers in the CES of the present invention is likely to be in the two-phase region for which a full analysis of the pressure drop requires a 3-dimensional description of the flow and heat transfer involving phase changes. An engineering approach is to calculate first the pressure with a homogeneous model and then use a safety factor of 3˜5 in the design of the heat exchangers.
The CES system could have up to four heat exchangers:
(1) Heat exchanger 1 (350): for input air to extract cold from the working fluid (and take heat from the ambient air)
(2) Heat exchanger 2 (340): for waste heat to superheat the working fluid
(3) Heat exchanger 3: for the turbine to absorb heat from atmosphere
(4) Heat exchanger 4: for the compressor to ensure isothermal operation.
The specific heat transfer requirements for the four heat exchangers are, respectively:
Q
1
=h
8
−h
7 Heat Exchanger 1
Q
2
=h
9
−h
8 Heat Exchanger 2
Q
3
=T
9(S10−S9) Heat Exchanger 3
Q
4
=T
0(S0−S2) Heat Exchanger 4
By using the above four equations, the specific heat transfer requirements under different conditions are obtained and illustrated in Table 1, where the ambient temperature is 300 K and the superheat temperature is 400 K.
From table 1 it can be seen that for P1=0.1 MPa, since there is no need for a compressor, Q4 is zero. If there is no superheat, Q2 is zero. The total quantity of specific heat transfer requirement for a simple cycle without superheating at P1=0.1 MPa is therefore 858.6 kJ/kg. The maximum specific heat transfer requirement is 1308.2 kJ/kg, which corresponds to the cycle with superheating at P1=4.0 MPa. In the following sections, analyses will be based on the above two sets of heat transfer requirements.
As mentioned above, there is a substantial technology base for heat exchangers and there are a lot of types of heat exchangers available for the cryogenics and air separation and liquefaction industries. Tube-in-shell and plate-and-fin heat exchangers are among the most widely used types. Tube-in-shell heat exchangers are commonly used at relatively high temperatures. Tube-in-shell heat exchangers have a high transfer coefficient ranging from ˜300 to ˜3000 W/m2K when the fluid phase in both the shell and tube sides is liquid. A common technique to improve the performance of tube-in-shell heat exchangers is to foil fins helically around the tube thus forming a tube and fin heat exchanger in order to increase the ratio of compactness and the heat transfer coefficient. This is especially effective when the fluid is in a gaseous state in one or both sides of the heat exchanger. In addition, the temperature difference between hot and cold fluids is relative high (˜15 K), which leads to a relatively low efficiency.
Plate and fin heat exchangers have an advantage of a high degree of compactness, and a low temperature difference between the hot and cold fluids. This type of heat exchanger can be made of aluminium alloy so the capital cost is relatively low. Plate and fin heat exchangers are suitable for use in the cryogenic field because the innate flexibility of this type of heat exchanger allows the use of a multiplicity of fluids in the same unit. Plate and fin heat exchangers comprise flat plates of aluminium alloy separated by corrugated fins. The fins are brazed onto the plate by means of a thin foil of the same alloy as the plate with added silicon to cause melting of the foil at low temperatures and so to bond the fins to the plate. Aluminium is generally favoured on grounds of cost but copper is also acceptable. Due to the large ratio of compactness of ˜250˜5000 m2/m3, plate and fin heat exchangers are the most widely used heat exchangers in the air separation and liquefaction industry with a typical heat transfer coefficient of ˜30˜500 W/m2K and a temperature difference of up to ˜2˜6 K between the hot and cold fluids.
Other types of heat exchangers that could be used include regenerators, coiled tube heat exchangers, multiple tube heat exchangers, and coaxial tube heat exchangers.
The following is an estimation of the size of the heat exchangers based on the performance of the plate and fin type. The overall average heat transfer coefficient Ū is taken as 100 W/m2K; the average temperature difference between hot and cold fluids, Δ, is taken as 1000 m2/m3. The compactness could be much higher, so the estimation is on the conservative side. The maximum heat transfer requirements, HR, with and without superheating are respectively given as 858.6 and 1308.2 kJ/kg on the basis of the above calculation. Two cases of the CES with electricity storage volumes (Ev) of 1 MWh and 500 MWh are considered in the estimation. The operating time (OT) of the CES is assumed as 8 hours. This is according to peak hour operation. Different duty cycles could be used and should not greatly impact efficiency.
For Case 1 of the CES with the storage volume of 1 MWh, the heat transfer requirement without superheating is given by:
where ED is the energy density of liquid air (kJ/kg). The total size of the heat transfer exchangers can be calculated by:
For Case 1 with the superheating, the heat transfer requirement will be:
The total size of the heat transfer exchangers will be:
For Case 2 of the CES with a storage volume of 500 MWh, the heat transfer requirement without superheating is:
The total size of the heat exchangers will be:
If the heat exchanger is assumed to be cubic in shape, the length of each side will be 7.19 m. If a factor of safety of 4 is given, the length of each side will be 11.41 m.
For Case 2 of the CES with the storage volume of 500 MWh with superheating, the heat transfer requirement will be:
The total size of the heat exchangers will be:
If a cubic shape is assumed, then the length of each side of the heat exchanger will be 7.74 m. If a factor of safety of 4 is given, the length of each side will be 12.29 m.
The liquid nitrogen viscous pressure drop is reported to be about 0.05 MPa and the pressure drop of input air is about 400 Pa. If a safety factor of 4 is used, then the liquid air pressure drop would be about 0.2 MPa which is about 1.0% of the total pumping pressure, and the pressure drop of the input air would be 1600 Pa which is tiny compared with the compression ratio.
The influence of the temperature of the waste heat used for superheating on the efficiency of the CES for P1=0.1 MPa and P1=4.0 MPa is illustrated in
The efficiency of the CES increases monotonically with an increase in temperature of the flue gas containing the waste heat. If the waste heat temperature increases from 400K to 600K, the efficiency of the CES increases from 0.558 to 0.749 for P1=0.1 MPa, and from 0.654 to 1.714 for P1=4.0 MPa.
Making the best utilization of waste heat is therefore a very effective way to improve the performance of the CES. Note that the waste heat is not accounted for as the input energy, hence the efficiency can be more than 100%. In addition, the waste heat can be from geothermal, cement kilns, or other industrial sources.
The heat dissipation (leakage) of the cryogenic tank is about 1% per day in an insulated Dewar at ambient pressure. If more efforts are taken or cold energy dissipation is utilised, the loss of efficiency of CES due to the dissipation (leakage) may be less than 1% per day. This is important when considering the duration of the energy storage cycle of the CES, i.e. the liquid air must be used within a certain period of time in order to ensure the overall efficiency.
Table 2 shows the process for calculating CES efficiency for a number of thermodynamic cycles.
The heat exchangers play a critical role in the CPS. The flow and heat transfer in the heat exchangers in CPS involves three dimensional, viscous, turbulent and two-phase phenomena. In this analysis, the following assumptions are made:
(1) Thermodynamic equilibrium between fluid phases
(2) Even flow distribution within heat exchanger
(3) Fully developed turbulent flow
(4) Adiabatic shell wall
(5) Zero axial conduction
(6) No radiation heat transfer between hot and cold fluids
(7) Constant overall heat transfer coefficient.
The main CPS system has four heat exchangers and the turbine uses an additional heat exchanger for isothermal expansion (see
(1) Heat exchanger 1 (540): for input air 1 to extract cold from the working fluid for condensing the input air 1.
(2) Heat exchanger 2 (535): for input air 1 and 4 to extract cold from the working fluid
(3) Heat exchanger 3 (530): input air 1, 3 and 4 to extract cold from the working fluid
(4) Heat exchanger 4 (525): for input air 1 and 2 to absorb compression heat
(5) Heat exchanger 5: for turbine to absorb heat from atmosphere
The specific heat transfer requirements for the five heat exchangers are, respectively:
Q
1
−x
1(h6−h7) Heat Exchanger 1
Q
2
=x
1(h5′−h6)±x4(h10−h11) Heat Exchanger 2
Q
3
=x
1(h5−h5′)+x3(h0−h10)+x4(h0−h10) Heat Exchanger 3
Q
4
=x
1(h4−h5) Heat Exchanger 4
Q
5
=T
0(S0−S3) Heat Exchanger 5
By using the above equations, the specific heat transfer requirements for Q1 to Q5 are 47.9 kJ/kg, 165.9 kJ/kg, 225.4 kJ/kg, 57.8 kJ/kg and 597.7 kJ/kg respectively, where the ambient temperature is 300 K. The maximum specific heat transfer requirement of the entire CPS system, therefore, is 1102.0 kJ/kg. In the following sections, analyses will be based on this value of heat transfer requirements.
The following is an estimation of the size of the heat exchangers based on the performance of the plate and fin type. The overall average heat transfer coefficient Ū is taken as 100 W/m2K; the average temperature difference between hot and cold fluids, Δ, is taken as 1000 m2/m3. The compactness could be much higher, so the estimation is on the conservative side. The maximum heat transfer requirements, HR, is given as 1102.0 kJ/kg on the basis of the above calculation. For a CPS with a work output of 1 kW, the heat transfer requirement is given by:
where WR and EE are the maximum specific work of liquid air and the energy efficiency of CPS, respectively. The size of the heat exchanger for a 1 kW work output can be calculated by:
If a factor of safety is given as 4, the size of the heat exchanger for a unit work output would be 0.044 m3.
The liquid nitrogen viscous pressure drop is reported to be about 0.5 bar and the pressure drop of input air was about 400 Pa. If a safety factor of 4 is used, then the liquid air pressure drop would be about 2 bar which is about 1.0% of the total pumping pressure (200 bar), and the pressure drop of the input air would be 1600 Pa (0.016 bar) which is very small compared with the compression ratio (˜0.2% of 8 bar).
The heat dissipation (leakage) rate of the cryogenic tank is about 1% per day in an insulated Dewar at the ambient pressure. If more efforts are taken or cold energy dissipation is utilised, for example for air conditioning, the loss of efficiency of CPS due to the dissipation (leakage) may be less than 1% per day. The efficiency of heat dissipation as a function of time for four dissipation rates of 1%, 0.75%, 0.50%, 0.25% per day, is shown in
where Mideal refers to the total amount of mass of liquid air without dissipation, and Mac is the actual total amount of mass of liquid air with the dissipation.
It can be seen that the efficiency of heat dissipation decreases with increasing time and dissipation rate. This indicates that the CPS operation should be within a certain period of time in order to ensure a good overall efficiency. It is essential to decrease the heat dissipation especially for a long term journey. For a dissipation rate of ˜0.5% per day, the total loss over a duration of 30 days is ˜7.5%.
An exemplary small lab scale CES system with a capacity of 100 kWh is illustrated schematically in
The experimental system consists of 8 major components, a cryogenic tank 600, a pump 610, a heat exchanger 620, a turbine 630, a transmission box 640, a blower 650, a drier 660 and a three-way valve 670. The system works as follows:
1) Liquid air (working fluid) from a cryogen plant or a storage depot is fed into the cryogenic tank 600.
2) Working fluid is pumped and heated before flowing into the turbine 630, where it expands to produce power to drive the blower 650. The blower 650 has two functions, one is to provide the input air for recovery of the cold energy through the heat exchanger 620, and the other one is to provide a load to the turbine 630 (acting as a generator).
3) A small fraction of the air from the blower 650 (input air) is introduced to the heat exchanger 620 via the three-way valve 670 and the drier 660.
4) No liquid air is produced in the lab scale system to reduce the capital cost. This, however, does not affect assessment of the CES performance as the measured data are sufficient for such a purpose.
The thermodynamic cycle of the lab scale CES system is shown in
1) 1-2: Pumping of working fluid: The working fluid (liquid air) from the cryogenic tank is pumped from the ambient pressure P0 to P2. The specific work done on the liquid air is:
The above work can also be expressed by the enthalpy difference between state 2 and state 1: W1-2=h2−h1. The total cold exergy (maximum work availability) of the working fluid at state 1 is: Ex1=T0 (S0−S1)−(h0−h1).
2) 2-3: Isobaric heating of working fluid: The working fluid is heated by the input air from T2 to T3. The specific work done in this process is zero: W2-3=0. The specific heat absorbed from the input air is: Q2-3=h3−h2. The exergy released in the process 2-3 is: Ex2-3=T0 (S3−S2)−(h3−h2).
3) 3-4: Expansion of working fluid: The working fluid with a high pressure expands in the turbine to deliver work. If an ideal isothermal process is considered, the specific work done in the process is: W3-0=T0 (S0−S3)−(h0−h3). The specific heat absorbed from the ambient in an ideal isothermal process is: Q3-0=T0 (S0−S3). If the expansion of the working fluid is adiabatic, the specific ideal work Wad will be:
and there is no heat absorption in the process: Qad=0. The actual work, however, is expected to be in the range between W3-0 and Wad. A factor called isothermicity, γ, is often used as an index, which is defined as the ratio of the actual work to the isothermal work:
Thus, the actual work W3-4 can be expressed as: W3-4=γW3-0=γ[T0(S0−S3)−(h0−h3)].
4) 6-7: Extraction of cold energy of the working fluid by input air isobarically: The cold energy of the working fluid is extracted by the input air isobarically through the heat exchanger. The specific work done in this process is zero: W6-7=0. The cold energy from the working fluid in the process 6-7 is: Q6-7=h6−h7. The exergy obtained by the input air over the process is given by: Ex6-7=T6 (S6−S7)−(h6−h7). From the above analysis, the specific ideal net work output of the cycle should be:
where F1 and F2 are respectively the flowrates of the working fluid and input air, respectively.
The efficiency of the lab scale CES experimental system can therefore be expressed by:
where Ex1 is the total cold exergy contained in the working fluid. In the actual experimental system, a certain amount of work is needed to pump the input air through the heat exchanger; therefore the work of process 6-7 is not zero. The actual specific net work output should be:
The efficiency of the lab scale CES system therefore becomes
A suitable measurement system is shown schematically in
From the above thermodynamic analyses, it can be seen that seven variables are needed to obtain the actual efficiency of the lab scale experimental system, including W3-4, W1-2, EX6-7, WBlower, EX1, F1 and F2. The methodologies for obtaining these parameters follow:
(1) W3-4: actual work output of the turbine: A torque/speed meter is directly connected to the axis of the turbine 630, and the blower 650 is used as a load. The work output of the turbine 630 is obtained by multiplying the measured torque (M1) and speed (ω1): W3-4=M1·ω1.
(2) W1-2: work consumed by the pump: In the experimental system, the pump 610 is driven by a motor. The actual work consumed by the pump 610 can therefore be obtained by measuring the electric voltage (V1) and current (C1) of the motor: W1-2=V1·C1. The result of W1-2 accounts for both the efficiencies of the pump and the motor 610.
(3) Ex6-7: cold exergy recycled by input air: The cold exergy recovered by the input air can be calculated by: Ex6-7=T6 (S6−S7)−(h6−h7). To obtain the entropies and enthalpies of the input air, i.e. S6, S7, h6 and h7, two thermocouples and two pressure transducers are used in the experimental system at the inlet and outlet of the heat exchanger 620, respectively. Using the measured data of T6, T7, P6 and P7, the entropies and enthalpies of the input air can be found from the thermodynamics data tables for the air.
(4) W6-7: work needed for pumping the input air: The specific work consumed for pumping the input air is calculated by the pressure difference between the inlet and outlet of the heat exchanger 620: W6-7=P7−P6.
(5) F1: Flow rate of working fluid: The flow rate of the working fluid is measured by the flow meter installed at the inlet of the pump 610.
(6) F2: Flow rate of input air: The flow rate of the input air is measured by the flow meter installed at the outlet of the heat exchanger 620.
(7) Ex1: total cold exergy contained in working fluid: The total cold exergy recovered from the working fluid is calculated by: Ex1=T0 (S0−S1)−(h0−h1). To obtain the entropies and enthalpies of the working fluid, i.e. S0, S1, h0 and h1, two thermocouples and two pressure transducers are installed at the inlet and outlet of the heat exchanger 620, respectively. Using the data of T5, T1, P5 and P1, the entropies and enthalpies of the working fluid can be obtained by referring to the thermodynamic data tables for the air.
Parameters related to individual components that can be obtained from the experimental CES include:
(1) Cryogenic tank: The flow rate of the fuel (liquid air) can be calculated by:
where Fl, Po, η, ED and ρl are the flowrate of liquid air, power of the system, efficiency of the turbine 630, energy density of liquid air and density of liquid air, respectively. The volume of the fuel tank 600 is given by:
where Sf, Vl, Ot, Edis are respectively the safe factor, volume of liquid air, operating duration and efficiency of heat dissipation of the tank. If a cubic tank is assumed, the length of each side, d, is
If the working pressure of the working fluid is 20 MPa, the ambient temperature is 300 K, the ideal specific energy density of liquid air is ˜455 kJ/kg, the density of liquid air at the ambient pressure is ˜876 kg/m3, the efficiency of the turbine 630 is 0.8 and the total power of the lab scale experimental system is 12.5 kW, the flow rate of liquid air is:
If a safe factor of 1.3 is considered and the efficiency of heat dissipation is taken as 0.95, then the volume of the cryogenic tank 600 for a total capacity of 100 kWh is:
If a cubic tank is assumed, the length of each side is 1.14 m.
Due to heat transfer, liquid air evaporates in the cryogenic tank 600 and the pressure of liquid air at the outlet of the tank 600 (inlet of the pump 610) is higher than the ambient pressure which leads to a decrease in the work consumed by the pump 610. Given that self-pressurisation of the cryogenic tank 600 is unavoidable, a safety valve is included to relieve the pressure once it exceeds a certain level. It is possible to control the tank pressure through alternative systems a safety valve.
(2) Pump: Key Parameters Associated with the Pump Include the Working Fluid Flow Rate, inlet pressure, outlet pressure, working temperature and power consumption. The flow rate of the pump is the same as that for the cryogenic tank: Fl=141.0 l/h. The inlet pressure of liquid air is determined by the outlet pressure of the cryogenic tank. As a safety valve is used in the lab scale system, the pressure of the tank cannot be determined a priori. However, the cryogen pump can work over a certain range of inlet pressures at a given outlet pressure. Therefore, the inlet pressure of the pump is taken as P=0.1˜3.0 MPa. The outlet pressure of the cryogen pump is equal to the working pressure of the working fluid which is given as 20 MPa. Therefore, P2=20 MPa. The cryogen pump should work in the normal laboratory temperature. Therefore the working temperature is selected as 0° C.˜40° C. The temperature of the working fluid at the inlet of the pump is approximately the boiling point of liquid air (−196° C.). The temperature of the working fluid at the outlet of pump is expected to be ˜−192° C. after an adiabatic pressurisation process. The power consumed by the pump is determined by its efficiency given the outlet pressure and flow rate. If the efficiency of the pump is assumed as 0.8, the power requirement of the pump is:
If a safe factor of 1.5 is used for the motor of the cryogen pump, the power of the motor will be 1.5 kW.
(3) Heat Exchanger: Key parameters associated with the heat exchanger include working pressures, flow rates and pressure drops of both the working fluid and the input air, and temperatures of the working fluid and input air at the inlet and outlet of the heat exchanger. The working pressure of the working fluid is approximately equal to the outlet pressure of the pump: P2=20 MPa. The working pressure of the input air should be close to the ambient pressure to minimise the work consumed by the blower: P7=P0. The inlet pressure of the input air is approximately equal to the pressure drop across the heat exchanger: P6=PLoss+P7The flow rate of the working fluid has been given above: F1=141.0 l/h=(123 kg/h). The flow rate of the input air is influenced by the performance of the heat exchanger. An approximate value is obtained by thermodynamic calculation as F2=206.0 kg. The pressure drop of the working fluid across the heat exchanger depends on the engineering design of the heat exchanger. It is estimated, however, to be of an order of ˜1000 Pa. The pressure drop of the input air across the heat exchanger also depends on the design. It is also estimated to be ˜1000 Pa. The temperature of the working fluid at the inlet of the heat exchanger is approximately equal to that at the outlet of the pump if the heat loss of pipes/joints/valves etc is neglected, i.e. T2=192° C. The temperature of the working fluid at the outlet of the heat exchanger depends on the performance of the heat exchanger, it is estimated to be close to the ambient temperature with a temperature difference assumed (i.e. 5° C.), i.e. T3=22° C. The temperature of the input air at the inlet of the heat exchanger is approximately the ambient temperature. The temperature of the input air at the outlet of the heat exchanger also depends on the performance of the heat exchanger; but is estimated to be close to the temperature of the working fluid at the inlet of the heat exchanger (˜−192° C.).
(4) Turbine: In analysing the performance of the turbine a multistage adiabatic expansion process with inter-heating is considered. The pressure of the working fluid at the inlet of the turbine has been given above as P3=20 MPa. The temperature of the working fluid at the inlet of the turbine should be close to the ambient temperature after being heated by the heat exchanger. If a temperature difference of 5° C. (below ambient) is considered, the temperature of the working fluid at the inlet of the turbine is 22° C. (ambient temperature taken as 300K): T3=22° C.
The number of stages is a key parameter of the turbine; more stages mean nearer isothermal operation hence more work output (see
Ideal Case: The pressure of the working fluid at the inlet of the turbine is 20 MPa, the efficiency of the turbine is 100%, and the temperature of the working fluid at the inlet of each stage is 27° C.
Practical Case: The pressure of the working fluid at the inlet of the turbine is 20 MPa, the efficiency of the turbine is 89%, and the temperature of the working fluid at the inlet of each stage is 22° C.
Both the ideal and practical work outputs of the turbine increase with increasing number of stages and level off between 4 to 8 stages. The total number of stages is also limited by the maximum expansion ratio of the turbine, which is normally less than 3.0. FIG. shows the expansion ratio of each stage as a function of the number of stages of the turbine. It can be seen that the expansion ratio exceeds 3 if the number of stages is less than 4. As a consequence, the number of the stages of the turbine should be more than 4. Consequently, the number of stages should lie between 4 and 8.
The pressure of the working fluid at the outlet is generally a little higher than the ambient pressure to ensure the working fluid flows smoothly. The pressure of the working fluid at the outlet is often selected as ˜0.13 MPa. If the number of stages is 6 and the temperature of the working fluid at the inlet is 22° C., the temperature of the working fluid at the outlet is approximately −44° C. Air at such a temperature can be recycled for liquid air production in large CES systems. It could also be used for industrial freezing and air conditioning in summer. The flow rate of the working fluid is equal to the flow rate of the pump: 123 kg/h (141 l/hr). Due to the low flow rate and high pressure of the working fluid, the size of the first stage of the turbine will be several millimetres, which is classified as a micro turbine.
(5) Blower: Key parameters associated with the blower are the pressure, flow rate, power and efficiency. The rated power should be approximately equal to the work output of the turbine (˜12.5 kW), and the pressure should be higher than the pressure drop of the input air across the heat exchanger.
The following component selection is based on the analyses detailed above.
(1) Cryogenic tank: Product No. C404C1 (Model ZCF-2000/16) of Si-Chuan Air Separation Plant (Group) Co. Ltd is a suitable vertical type cryogenic tank having a double-walled and vacuum powder insulated structure; see
Component Integration:
Liquid air from a cryogen plant is transported to the laboratory by a cryogenic truck and fed into the cryogenic tank C404C1. The reciprocating piston cryogenic liquid pump B228 pressurises the liquid air and provides kinetic energy for the working fluid to flow through the heat exchanger. The working fluid is heated in the heat exchanger by the input air provided by the blower GXF-C-6.5C, which also serves as the load of the micro-turbine in which the working fluid expands to provide power of the blower. Only a fraction of air from the blower is used as the input air.
Technological and Economical Comparisons of CES with Other Storage Systems
Currently existing energy storage systems will now be evaluated and compared with the CES. The data of the CES is calculated based on a 500 MWh storage volume and a discharge time of 8 hours. The data for other energy storage systems are mainly taken from J. Kondoh et al. “Electrical energy storage systems for energy networks” (2000, Energy Conversion & Management, vol. 41, 1863-1874), P. Denholm et al. “Life cycle energy requirements and greenhouse gas emissions from large scale energy storage systems” (2004, Energy Conversion and Management, vol. 45, 2153-2172), and F. R. Mclamon et al. “Energy storage” (1989, Annual Review of Energy, vol. 14, 241-271).
Output Power and Output Duration:
The relationship between the output power and the output duration of the storage systems is shown in
Pumped hydro, CAES, batteries and CES are suitable to level daily load fluctuation. The superconducting magnet and flywheel with conventional bearing have a fast response and, therefore, can be utilised for the instantaneous voltage drop, flicker mitigation and short duration UPS.
Other systems such as the flywheel with levitation bearing, double-layer capacitor and redox supercapacitor are promising for small capacity energy storage and short output duration (less than 1 h).
The output power and duration of the CES is better than batteries, competitive with CAES and slightly lower than the pumped hydro. However, as discussed before, the pumped hydro requires special geographical location. Furthermore, as discussed below, pumped hydro requires a very high capital cost.
The relationship between the efficiency and the cyclic period is shown in
The energy storage densities of different energy storage systems are shown in
It can be seen that the CES and advanced secondary Na/S batteries have the highest energy densities among all systems. The energy density of the CES is higher than CAES by more than an order of magnitude and higher than pumped hydro by about two orders of magnitude.
The lifetimes of storage systems are shown in Table 3. The cycle durability of secondary batteries is not as high as other systems owing to the chemical deterioration with the operating time. Many of the components in CES are similar to those used in CAES. Therefore it is expected that the CES will have a similar life time to CAES.
In terms of the CES, the output adjusted capital cost of the CES is lower than that of the CAES because the life time of the CES is equal to that of the CAES, the initial investment of the CES is less than that of the CAES as no cavern is needed, and the energy density of the CES is higher than that of the CAES by at least an order of magnitude.
Therefore, the capital cost of the CES is lowest of all of the systems examined. In addition, the CES offers a flexibility in terms of commercial operations as products such as oxygen, nitrogen and argon can also be produced.
Construction of a pumped hydro storage system inevitably involves the destruction of trees and green land for in order to build the reservoirs. The construction of the reservoirs could also change the local ecological system which also presents environmental consequences. CAES is based on conventional gas turbine technology and involves the combustion of fossil fuel and consequently the emission of contaminates, whilst secondary batteries produce solid toxic waste.
However, CES is benign to the environment. For example, CO2 and SOX are removed during the liquefaction process, which help with mitigating the negative environmental issues associated with the burning of fossil fuels. Undesirable airborne particulates are also removed during production of liquid air.
Therefore it can be concluded that CES has a better performance than other energy storage systems in terms of energy density, lifetime, capital cost and environmental impact. It is very competitive in comparison to other systems in terms of the output power and duration and energy efficiency. Compared with cryogenic engines for vehicles, the work output and efficiency of CES are much higher due to the use of both ‘heat’ and ‘cold’ recycles. The optimal pressure of the working fluid is 20 MPa for the CES. The optimal pressure of the input air is found to be 0.1 MPa when there is no waste heat recycled. However, when waste heat is used, the optimal input pressure could be either 0.1 MPa or 4.0 MPa. Based on an efficiency of 0.4 kWh/kg for air liquefaction, an overall efficiency of the CES operated in an ideal cycle is estimated at 0.516 for cases without using the waste heat recycle, and at 0.612 for cases using waste heat from flue gas at a temperature of 127° C. If the efficiency of the air liquefaction is taken as 0.3 kWh/kg, then the overall efficiency of the CES operated in an ideal cycle would be 0.688 for cases which do not use the waste heat recycle and at 0.816 for cases which do use the waste heat from a flue gas at a temperature of 127° C.
The specific work output and energy density of the CES depend mainly on the efficiencies of the turbine ηT and the air liquefaction ηA. The efficiency of the compressor can also be important if the input air is compressed. The heat exchangers play an important role in determining the overall efficiency of the cycle. A higher temperature of waste heat and a higher temperature of environment give a higher efficiency.
The CES system has a number of critical inventive steps, including the recycling of waste cold as well as waste heat. These specifically improve the overall work cycle against previous systems designed using cryogenic liquid as the working fluid.
The CES system has the potential to achieve a better performance over the existing energy storage systems in terms of energy density, lifetime, capital cost and environmental impact and is a competitive technology with respect to the output power and duration, and the energy efficiency.
The CES system has the potential to harness low grade heat and no obvious barriers to engineering. The system can be built using existing technologies for the liquefaction plant, turbine, heat exchanges, compressors, pumps, etc.
The majority of work in a CES is achieved by harnessing energy attributed to the temperature difference between the cryogen (˜77K) and the ambient (˜300K), whereas a standard geothermal or waste heat energy system can only harness temperatures above ambient (˜300K).
Five marine engine models have been prepared using the CPS. These models are then compared against five known diesel engines. The details of the five known industrial diesel engines are shown in table 4.
CAT-3516 is a 78.1 litre 60° V-type 16-cylinder diesel engine. This engine is designed for medium transportation boats with medium speeds. CAT-3126 is a 7.2 litre turbocharged aftercooled in-line 6-cylinder engine adapted for small yachts. The ST3 engine is an air cooled diesel engine form Lister Petter company designed for narrow boats. The Cummins 6-cylinder T/C diesel engine is used by a Thames river liner suitable for public transport applications and pleasure cruising.
1Assuming a cubic tank.
CPS Model 1 corresponds to the CAT-3516 and is suitable for medium sized boats. As the CPS can provide a large quantity of cold, Model 1 is particularly designed for transportation of materials below sub-ambient conditions e.g. frozen meat and fish or other products. Model 1 also makes use of the cooling air and heat from the CPS for the occupants of the boat.
Models 2 to 4 correspond to the CAT-3126, the Ford Porbeagle and the Lister Petter ST3 engine and are suitable for small yachts or boats for which there is no need for large scale refrigeration, or for cool air for air conditioning. The CPS system is used to provide both propulsion and heat for use by the occupants of the boat e.g. for heating.
Model 5 corresponds to the Cummins Riverliner. The CPS system is used to provide propulsion, cooling air and heat for the boat occupants and cold for freezing foods. Only a small part (˜10%) of the cold capacity of CPS is assumed for freezing foods because the requirement for freezing food is much lower than that of model 1 for transportation of materials under sub-ambient conditions. However, a cruising range of only 60 miles (110 km) is required as the Cummins Riverliner is designed to provide 12 return journeys of 5 nautical miles per day.
The typical working conditions of all five models are P2=200 bar, P1=8 bar, T0=300K, ηT=ηCOM=ηp=0.88, n=1.2, γ=0.90, and Tdf=5.0K. The overall performance of Models 1 to 5 under these typical conditions is presented in table 5.
1 Assuming the quantities of cold for refrigeration and air condition are the same.
2 Assuming the quantities of cold for refrigeration and ⅕ of that for air condition.
For a given boat and a given power, the cruising speed vk can be calculated by:
where Po, Δ, vk, Co are power (work) of the engine, tonnage of the boat, cruising speed of the boat and a ship geometry related coefficient, respectively. Assuming the Model 1 CPS powered boat has the same boat body, tonnage Δ, and coefficient Co as the data used for the CAT-3516 engine, the cruising speed, vkl, is calculated using:
where WO1 is the work output of model 1. The cruising range of model 1 is therefore given by Cr1=vk1·Ot1 where Ot1 is the maximum working time.
It can be seen that for the same total power, the work output of model 1 CPS for propulsion is ˜22.6% lower than that of CAT-3516, while the cruising speed and range decrease only by ˜8%. Furthermore, model 1 CPS provides ˜169.6 kW heat, 962.0 kW refrigeration cold and 962.0 kW cold for air conditioning at the same time.
Similarly, the cruising speed and range for CPS models 2 to 4 powered boat can be obtained according to the data of CAT-3126. The cruising speed and range for a CPS model 2 powered boat are:
and Cr2=Vk2·Ot2. The cruising speed and range for a CPS model 3 powered boat are:
and Cr3=vk3·Ot3. The cruising speed and range for a CPS model 4 powered boat are:
and Cr4=vk4·Ot4. For the same total power, the work outputs of models 2 to 4 for propulsion are ˜2.8% lower than those of the corresponding diesel engine. However, models 2 to 4 can provide 22.0 kW, 6.5 kW and 2.1 kW heat at the same time, respectively. It can be seen that the cruising speed and the range of models 2 to 4 of the CPS are ˜99.0% of those of the corresponding diesel engines.
Similarly, the cruising speed and range for a CPS model 5 powered boat can be obtained according to the data of the Riverliner. The cruising speed and range for a CPS model 5 powered boat are:
and Cr5=vk5·Ot5. For the same work output for propulsion, the CPS model 5 provides ˜45.2 kW heat, 256.8 kW refrigeration cold and 51.4 kW cold for air conditioning although the total power is 14.8% higher than that of the corresponding diesel engine.
The flow rate of the fuel (liquid air) can be calculated by:
where Fl, Po, ED, ρl are flow rate of liquid air, power of the engine, energy density of CPS and density of liquid air, respectively. The volume of the fuel tank is expressed as:
where Vl, Ot, Edis are volume of liquid air, operation time and efficiency of heat dissipation of the tank. If a cubic tank is assumed, the length of each side, d, is
The maximum heat transfer requirement has been analysed and estimated above. For the CPS with a unit work output (1 kW), the heat transfer requirement is: Q=2.184 kW. The size of the heat transfers exchangers for a unit work output is: V=0.011 m3. If a factor of safety is given as 4, the size of the heat transfer exchangers for a unit work output would be 0.044 m3.
On the basis of above data, a conservative estimation of the total volume of heat exchangers for models 1 to 5 CPS are listed in table 5.
Comparison of CPS with Diesel Engines
Energy Density and Price:
A comparison between tables 4 and 5 shows that the fuel consumptions of models 1 to 5 CPS are 37.70, 44.36, 42.08, 42.5 and 42.3 times those of the corresponding diesel engines respectively. Therefore, the energy densities of models 1 to 5 are 1/37.70, 1/44.36, 1/42.08, 1/42.5 and 1/42.3 of those of the corresponding diesel engines.
To compare the price of specific power of the eight engines, the price of electricity is taken as Price_e=6 pence/kWh and that of diesel as Price_d=90 pence/litre, the energy consumption to produce 1 kg of liquid air is taken as 0.4 kWh (W. F. Castle. 2002). The price of the specific power (Price_p) of the four models is calculated as: CAT-3516=22.0 p/kWh, M1=25.0 p/kWh, CAT-3126=23.4 p/kWh, M2=31.3 p/kWh, Ford Porbeagle=24.7 p/kWh, M3=31.3 p/kWh, Lister Petter ST3=24.8 p/kWh, M4=31.3 p/kWh, Cummins=22.1 p/kWh, and M5=28.8 p/kWh.
The price of specific power for the CPS models is comparable to the corresponding diesel models. If model 1 CPS is used for boats for transportation of frozen materials, the price of specific power would be very competitive to the counterpart diesel model.
If the energy consumption to produce 1 kg of liquid air is taken as 0.3 kWh, then the price of specific power (Price_p) for models 1 to 4 CPS become respectively 18.8, 23.4, 23.4, 23.4 and 21.6 p/kWh
Energy Efficiency:
The comparison of well-to-wheel efficiencies among the five models is shown in table 6. The CPS data is based on 0.4 kWh to produce 1 kg liquid air. It can be seen that the efficiency of model 1 CPS is similar to that of CAT-3516 and the efficiency of models 2 to 4 CPS using liquid air as fuel is lower than that of the corresponding diesel engines. The medium sized CPS boats have a higher efficiency when used for transportation of frozen materials than the small yachts do because the small yachts do not fully recover the cold. The efficiencies of CPS models 1 to 4 shown in brackets is that if the consumption of producing 1 kg liquid air is taken to be 0.3 kWh.
Life Time and Capital Cost:
Since all major components of the CPS are similar to the CES, the life time of a CPS system is also estimated to be about 20 to 40 years. The life time of the diesel engines is considered to be about 17 years. However, it is believed that the life time of CPS is higher than that of diesel engines because there is no combustion process at high temperatures involved in CPS, and there is no strong friction between pistons and cylinders.
It is believed that the CPS is competitive in terms of capital cost because there is little special requirement in teens of components. In addition, a refrigeration system is made obsolete in the case of refrigeration transportation boats.
Influences of Systems on the Environment:
Diesel engines involve combustion of fossil fuels and hence lead to emission of contaminates. CPS is a totally zero emission and environmentally benign system. If liquid air is produced by renewable energy, the CPS system would be a complete ‘Green’ power system. Furthermore, contaminates can be removed during liquefaction process, which would help with mitigating the negative environmental issues associated with burning of fossil fuels. Undesirable airborne particulates can also be removed during production of liquid air.
Accordingly, Cryogenic Propulsion System (CPS) using liquid air can be used to provide combustion free and non-polluting maritime transportation. CPS has a competitive performance against the diesel engines in terms of energy price, energy efficiency, life time and capital cost and impact on the environment. CPS can have a higher efficiency if the cold energy is recovered for e.g. on-boat refrigeration and air-conditioning.
It will of course be understood that the present invention has been described by way of example, and that modifications of detail can be made within the scope of the invention as defined by the following claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 0603895.4 | Feb 2006 | GB | national |
| 0608959.3 | May 2006 | GB | national |
| 0621972.9 | Nov 2006 | GB | national |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 12280739 | Mar 2009 | US |
| Child | 15053840 | US |
