Patent Application
20180243726
A subject matter of the invention is a process for the treatment by an ion beam of a powder based on cerium oxide, in particular of a promoter based on cerium oxide, with the aim of increasing the mobility of the oxygen at the surface of and inside the promoter, of reducing the temperature for reduction of the promoter, of increasing the yield of the reactions with which the promoter is associated and of reducing the amount of catalyst, the catalytic power of which it promotes.
It should be remembered that, in catalysis, a promoter is a compound, generally provided in the powder form, which increases the catalytic power of a catalyst, without itself having an intrinsic catalytic power.
Promoter based on cerium oxide is understood to mean a promoter comprising at least one atom of cerium and of oxygen. This family of promoters is known for its ability to store and to release oxygen and is used in particular in motor vehicle mufflers. Promoters based on cerium oxide act as a reservoir of oxygen for oxidation/reduction reactions involving the Ce4+/Ce3+ pair. They make it possible, for example, to increase the three-way catalytic deposition effectiveness by widening the air/fuel adjustment window.
For some years, the problems related to the environment have been increasing in scale. One of the major problems is the atmospheric pollution caused by motor vehicles. In order to limit pollution by motor vehicles and in particular emissions of carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxides (NOx), cars have been progressively equipped with catalytic converters. The role of the latter is to convert harmful pollutant molecules (CO, HC and NOx) into nontoxic entities (CO2, N2 and H2O): this is “three-way” catalysis. In recent years, ceria-zirconia solid solutions have appeared dominant in the formulations of three-way catalysts at the expense of ceria, as they exhibit a high oxygen storage capacity and furthermore withstand high-temperature treatments. However, the conditions of use of catalytic converters during startup of the engines under cold conditions make desirable, indeed even force, a further improvement in the redox efficiency of these oxides at low temperature. Recent studies on the Ce—Sn—O ternary system indicate that Ce2Sn2O7—Ce2Sn2O8 oxides of pyrochlore type also exhibit oxygen storage properties.
This results in a need for a method for the treatment of powders based on cerium oxide, in particular of promoters in the powder form based on cerium oxide, exhibiting an improved redox efficiency at low temperature, preferably according to methods which can be easily operated on the industrial scale, so as to be able to present such powders, in particular promoters, in a significant amount and at reasonable costs.
It is an aim of the invention to present a method for the production of cerium oxide promoter in the powder form which is relatively inexpensive and which makes it possible to obtain amounts of powders corresponding to the requirements of numerous applications.
The invention thus provides a process for the treatment by an ion beam of a cerium oxide powder, in particular of a cerium oxide promoter in the powder form, where:
In the context of the present invention, “to mix” or “mixing” is understood to mean the fact of stirring a powder so as to mingle the grains thereof.
According to one embodiment, the cumulative total dose of ions at the end of the treatment per unit of weight of powder to be treated within a range is between 1018 ions/gram of powder and 1020 ions/gram of powder.
According to one embodiment, the powder is arranged in the form of a layer of powder, and the layer of powder is mixed one or more times according to a repetitive out-of-beam process, which can consist, for example, before each treatment, in combining the powder into a point of the treatment area and in then spreading it again by means of a fine brush over the same spreading surface. This spread powder exhibits a mean thickness substantially equal to its weight divided by the product of its density and its spreading surface area. In view of the limited distance covered by the ions in the powder, which can be less than the spreading thickness of the powder, it may be desirable to repeat this spreading operation a certain number of times in order to make it possible for the grains located in deep layers, not affected by the beam, to have a sufficiently high probability of being exposed at least once to the beam. This mixing method is not limiting; it might, for example, be possible to choose another continuous method of mixing under a beam by means of a vibrating device (bowl, plate, and the like) which collects, mixes and exposes the powder to the beam throughout the treatment.
According to one embodiment which makes it possible to ensure optimum mixing, the mixing of the powder is repeated a minimum number of times in order to have the assurance that a significant amount of powder grains in order to obtain an effect on the decrease in the reduction temperature have been statistically subjected to the treatment. The inventors have been able to experimentally confirm that this minimum number of times corresponds to the following rule: the minimum number of times is approximately equal to the thickness of the powder spread over the surface divided by the distance covered by the ions of the beam in the powder; this number must be greater than or equal to 2 in order to prevent negative edge effects. The distance covered by the ions can be estimated by software developed and sold in order to facilitate or carry out such calculations, such as, for example, the software sold under the “SRIM” (“The Stopping and Range of Ions in Matter”) and “TRIM” (“The Transport of Ions in Matter”) names, which have been developed in particular by James F. Ziegler.
As can be indicated above, according to another embodiment, the powder is mixed under a beam by vibrating it during the treatment (for example in a vibrating bowl or plate), so as to make it possible for the powder grains located in the deep layers to have a significant probability of rising to the surface in order to be exposed at least once to the beam during the treatment. It may be considered that the duration of the treatment depends on the total dose of ions required to treat a given amount of powder (expressed in grams) with a beam of fixed intensity. It is desirable for the treatment to be sufficiently effective to make it possible for a significant amount of grains to be treated in order to obtain the desired effect under optimum conditions. For high intensity, in other words for a rather short treatment time, it is desirable to favor very efficient and thus expensive mixing means (for example, ultrasonic mixing means) in order to make it possible for the powder grains to have a not insignificant probability of being exposed at least once under the beam. On the other hand, if the mixing of the powder proves to be excessively slow due to the use of less expensive means, it is possible to envisage reducing the beam intensity and thus increasing the treatment time in order to make it possible for the powder grains to have a greater probability of being exposed to the beam. Poor mixing may be reflected by overexposure of some grains to the beam, which can be harmful by excessive dosing to the optimum effect desired, to the detriment of other grains, which themselves may remain unexposed to any treatment.
The inventors have been able to establish the two relevant parameters of the ion beam which make it possible to obtain the effect desired by the process of the invention: the acceleration voltage of the ions and the treatment dose (expressed in number of ions) relative to an amount of powder to be treated (expressed in grams), that is to say the cumulative total dose of ions at the end of the treatment per unit weight of powder to be treated.
The degree of treatment of the powder can be associated with the effectiveness of the mixing carried out by various and varied means, in particular according to nonlimiting forms, two examples of which have been mentioned above. For a treatment dose (expressed in number of ions) associated with an amount of powder (expressed in grams), “degree of treatment of a powder” denotes the ratio of the number of grains of powder which have been exposed at least once to the beam, with respect to the total number of grains of starting powder. For example, for a degree of 90%, it is estimated that 10% of the grains have not been exposed to the beam due to being maintained, throughout the treatment, in deep layers not affected by the ions of the beam. 90% of remaining grains were exposed at least once, indeed even several times. This degree of treatment, of between 0% (the powder is unexposed) and tending towards 100% without ever reaching it (since there existed no certainty statistically for whether it is), constitutes a characteristic quantity which quantifies the effectiveness of mixing of the powder. This degree of treatment corresponds to the probability for a grain of powder to be treated once, indeed even several times.
According to one embodiment of the process of the present invention, a powder based on cerium oxide after treatment is composed of treated or untreated grains, each grain being treated one or more times, partially or completely over its entire surface, in a thickness not exceeding the distance covered by the ion, in order to increase the mobility of the oxygen at the surface and in the body, in order to decrease the temperature for reduction of said powder.
According to one embodiment, for a fixed dose of ions relative to a given amount of powder, the required degree of treatment of the powder is greater than or equal to 10%. According to one embodiment, the required degree of treatment of the powder is greater than or equal to 50% and does not exceed 80%. The desired effect can thus be accentuated with relatively acceptable treatment times.
Generally but nonlimitingly, the powder based on cerium oxide is composed of grains of different shape (which can be approximated under spherical form) and size. The distribution in size can be established by particle size analysis, which is the study of the statistical distribution of the sizes of a collection of finished components of natural or fractional material. The particle size analysis is the combination of operations which make it possible to determine the distribution of the sizes of the components making up the collection. The powder based on cerium oxide is generally composed of grains, the size of which can vary from 10 nm to 5 micrometers, with a very high proportion of grains with a mean size corresponding to approximately 100 nanometers, in other words with a size substantially comparable to the distance covered by the ions of the beam. It is possible, without being too mistaken, to estimate that the powder grains can be traversed right through by the ions, leaving not much grain surface untreated.
The powder grains can be dense or porous. They are generally provided in the form of multiple channels for facilitating circulating of the oxygen.
The choice of the bombardment conditions and of the mixing conditions according to the invention makes it possible to advantageously obtain powders based on cerium oxide exhibiting a high mobility of the oxygen at the surface and in depth, and also a decrease in their reduction temperature.
The inventors have been able to find that the ranges chosen according to the invention, in combination with the type of the ionic bombardment ions, and relating to the acceleration voltage (in other words, the energy) and the dose of ions per unit of weight of powders to be treated, make it possible to select experimental conditions where the production of powders based on cerium oxide exhibits advantageous properties. In order to optimize the results, it may be of use to consider the degree of treatment of the powder grains.
In addition, they have been able to find that the process according to the invention can be carried out “under cold conditions”, in particular at ambient temperature, and that it is advisable for the temperature of the cerium-based powder to remain less than or equal to the value Tm/3 during the implementation of the process. It is thus advantageously possible to prevent the powder grains from splitting or melting. The Tm value of cerium oxide is approximately 2400° C., i.e. 2673 K; the Tm/3 value of cerium oxide is thus approximately 890 K, i.e. approximately 620° C.
Without wishing to be committed to any one scientific theory, it may be thought that the bombardment of the ions under the conditions according to the invention produces the effect of a “nanopiercing” at the nanometric scale by virtue of which nanoholes are created by the impact of the ions in the powder, in particular in the porous structure of the powder. These nanoholes make possible better circulation of the oxygen, both with regard to storage and with regard to release. Within the meaning of the present invention, nanoholes are empty spaces, the greatest dimension of which is greater than or equal to 10 nanometers and the smallest dimension of which is greater than or equal to one nanometer. These nanoholes have a depth which is in keeping with the distance covered by the ion in the powder, and a diameter which is in keeping with the weight and the energy of the incident ion. For a light ion, the nanoholes are generally long (for example, a few hundred nm) and narrow (for example, a few nm, indeed even a few tens of nm); for heavier ions, the holes are generally shorter and broader.
According to different embodiments, which can be combined with one another:
According to one embodiment of the process according to the invention, the treatment of the powder in order to create long and narrow holes is carried out with light ions chosen from the ions of the elements of the list consisting of helium (He), boron (B), carbon (C), nitrogen (N), oxygen (O) and neon (Ne). The choice of light ions can make possible an advantageous oxygen storage or release mechanism.
According to different embodiments of the process according to the present invention, which can be combined with one another:
The invention is also targeted at a powder based on cerium oxide, where the grains of said powder exhibit a degree of treatment of between 1% and 99%, comprising nano-holes.
The invention also relates to a heterogeneous catalysis device comprising a region for transformation of a gas or of a liquid comprising at least one powder based on cerium oxide treated according to the process of the present invention or comprising at least the powder comprising nano-holes which is mentioned above. According to one embodiment, the heterogeneous catalysis device comprises a honeycomb support, for example made of alumina, the walls of which are coated with a powder based on cerium oxide treated according to the process of the present invention or with a powder comprising nanoholes which is mentioned above.
According to one embodiment, the heterogeneous catalysis device is a catalytic converter, targeted at limiting the harmfulness of the exhaust gases from motor vehicles. Promoters based on cerium oxide having an improved low-temperature reactivity in combination with oxidation catalysts, such as platinum (Pt), are thus obtained. It is thus possible to envisage advantageously reducing the amount and the cost of a catalyst used in a catalytic converter.
The working temperature of a powder based on cerium oxide treated according to the process of the present invention or of a powder comprising nanoholes which is mentioned above is greater than or equal to 50° C., indeed even greater than or equal to 100° C., during heterogeneous catalysis in a catalytic converter.
The substrates using promoters based on cerium oxide which are treated according to the invention can be used in many other technical fields, such as, for example, those relating to fuel cells or to the treatment of oil or petroleum products, for example to facilitate the oxidation of CO during the regeneration of a catalyst in a fluid bed catalytic cracking process.
Other distinguishing features and advantages of the present invention will emerge in the description below of nonlimiting implementation of examples, in particular with reference to the appended drawings, in which:
For reasons of clarity, the dimensions of the different components represented in these figures are not necessarily in proportion with their true dimensions. The same numerical references in the different figures correspond to the same parts.
According to examples of the implementation of the present invention, samples, ceria (CeO2) and also ceria-zirconia (Ce0.7Zr0.3O2) powders, were mixed and spread before each treatment over a surface made of aluminum and formed the subject of experimental studies for treatment with nitrogen ions emitted by an ECR source. The treatment consisted in repeating 16 times the same procedure comprising the following stages: firstly, mixing and uniform spreading of 150 mg of powder over a square surface of 100 cm2 with a fine brush, secondly, treatment of the spread powder with a beam with a diameter of 40 mm, moving at a rate of 80 mm/s, with an amplitude of movement of 60×40 cm, 11 passes (corresponding to an advance of the beam of 30%), in order to achieve a dose of ions per unit of surface area equal to 5×1015 ions/cm2 at the end of each treatment; after having repeated the procedure 16 times, the total treatment dose accumulated by the 150 mg of powder spread over 100 cm2 is equal to 16×5×1015×100, i.e. 8×1018 ions, which amounts to a total treatment dose per unit of weight of powder equal to 5×1019 ions/gram of powder. The inventors estimate that the dose range in order to have a particularly effective treatment should preferably be between 1018 ions/gram and 1020 ions/gram of powder. The degree of treatment was evaluated at 80%, for a distance covered by the nitrogen ion at 50 keV in a ceria or ceria-zirconia powder evaluated at 0.2 microns and a thickness of ceria or ceria-zirconia powder, spread over 100 cm2, evaluated at 2 microns, i.e. 10 times the distance covered by the ion.
The ion beam which was used to treat the preceding powders comprises N+ ions, the intensity of which is substantially equal to 0.58 mA, N2+ ions, the intensity of which is substantially equal to 0.32 mA, and finally N3+ ions, the intensity of which is substantially equal to 0.1 mA; the extraction and acceleration voltage of these ions is 35 kV; the N+ energy is 35 keV, the N2+ energy is 70 keV and the N3+ energy is 105 keV. It is estimated that the mean energy of these ions is approximately 50 keV.
An experimental study in order to evaluate the impact of the treatment on the conversion of hydrogen into water as a function of the temperature was subsequently carried out on virgin and treated ceria and ceria-zirconia powders. This study consisted in injecting, into a cell, a stream of 5% hydrogen (H2) in a stream of argon (Ar), in a proportion of 25 cm3 min−1, the temperature being varied between 30 and 800° C. according to a gradual rise in the temperature of 7.5° C./min. The degree of formation of water was measured as a function of the temperature at the surface or in the body of the virgin and treated powder.
Such tests are representative of the reactions encountered in three-way catalytic converters, where cerium oxide compounds-buffers are added to alumina of a support in order to limit the impact of the variations in composition of the gases by storing oxygen when it is in excess in order to discharge it when it is in deficit.
In order to validate the impact of the treatment by ionic bombardment of the cerium oxide powders for three-way catalytic converters, the inventors thus studied the reaction for the oxidation of hydrogen under the water form in the presence of cerium oxide, with or without contribution of platinum. This is because the reaction for the oxidation of hydrogen under the water form is very similar to and representative with regard to the chemical reactions of both types of oxidation reactions occurring in the three-way catalytic converter, namely that of carbon monoxide to give carbon dioxide and that of the nonincinerated gases with formation of water. Tables 1 and 2 and associated figures illustrate the improvements observed by the inventors and based on this reaction for the oxidation of hydrogen are obtained with cerium oxide powders treated according to the process of the invention. These observed improvements can be easily transposed, in terms of efficiency, to the oxidation reactions occurring in the three-way catalytic converter.
Experimental results obtained for the reduction temperature at the surface and in the body for a virgin and treated ceria are recorded in table 1 and experimental results obtained for a virgin and treated ceria-zirconia are recorded in table 2.
It is found, in table 1, that, for the treated ceria, the reduction temperature at the surface is very advantageously decreased, changing from 340 to 280° C., i.e. a decrease of 60° C.; the temperature in the body is decreased much less, changing only from 780° C. to 770° C.
It is observed, in table 2, that, for the treated ceria-zirconia, the reduction temperature at the surface is very advantageously decreased at the surface, changing from 358 to 270°, i.e. a decrease of 88° C.; it is decreased much more in the body, changing from 561° C. to 408° C., i.e. a decrease of 153° C.
The inventors were thus able to experimentally identify a particularly advantageous operating point of the process of the invention applied to powders based on cerium oxide, for a total dose per unit of weight of powder to be treated (5×1019 ion/g of powder) and a degree of treatment (80%). The inventors recommend broadening this operating point, preferably to a total dose range, as number of ions per unit by weight of powder to be treated, of 1018 and 1020 ion/g and to a range of degree of treatment of greater than 10%, preferably greater than 50%.
The total dose per unit of weight of powder to be treated being fixed within the range recommended be; pw, the inventors have attempted, on the basis of a simple empirical model set out in
The impact of the spreading of a given amount of powder based on cerium oxide on the degree of treatment of the powder is represented in
The impact of the spreading of a given amount of powder based on cerium oxide on the degree of treatment of the powder is represented in
Under the experimental conditions expressed above, 0.15 mg of powder spread and treated over 100 cm2 has a thickness of approximately 2 microns. The reach of the ions is approximately 0.2 micron. For 16 mixing operations, the inventors estimated that the powder had been treated with a degree of 80%. In order to increase the amount of powder to be treated by a factor of 2, the number of mixing operations can be increased by a factor of 2 in order to obtain an identical degree of treatment.
In order to experimentally evaluate the impact of the surface area on the treatment of 150 mg of alumina powders with a total dose of 8×1017 nitrogen ions, i.e. 5×1019 ion/g of alumina powder, according to different spreading surface areas equal to 1200 cm2, 100 cm2 and 100 cm2, associated with a number of respective mixing operations equal to 2, 2 and 16, the inventors carried out an X-ray photoelectron spectroscopy (XPS analysis), also known as electron spectroscopy for chemical analysis (ESCA), of the powder. They were able to observe that the spectrum of the powder showed virtually no change in the first two cases, as if the powder grains had not been significantly exposed to the beam, unlike the third case, for which the electrostatic charges deposited by the beam on the powders made it impossible to carry out the XPS analysis. The inventors concluded that, in the first case, the powder thickness, estimated on average at 0.3 micron, which may be much less than 0.1 micron in places, appeared too low to be effectively treated by a beam, the distance covered of which in the powder is approximately 0.3 to 0.4 micron. The inventors recommend, preferably, spreading a given amount of powder over a surface area calculated in order for the thickness (e) to be at least equal to twice the mean distance covered by the ion in said powder. In the example of the second case, the mixing number was not sufficient; the inventors evaluated a degree of treatment of approximately 10% (based on the model of
The impact of the choice of the type of ion on the degree of treatment, for 150 mg of powder based on cerium oxide spread over 100 cm2, is illustrated in
It should be remembered that the calculation of the degree of treatment of a powder based on the distance covered by an ion in a given metal oxide, a given incident ion with a given energy is based on the principles of the physics of the interactions of particles with matter. Methods and data which make it possible to carry out these calculations are disclosed in particular in the publications “The Stopping and Range of Ions in Matter” by J. F. Ziegler, volumes 2-6, Pergamon Press, 1977-1985, “The Stopping and Range of Ions in Solids” by J. F. Ziegler, J. P. Biersack and U. Littmark, Pergamon Press, New York, 1985 (new edition in 2009), and J. P. Biersack and L. Haggmark, Nucl. Instr. and Meth., vol. 174, 257, 1980.
In addition, software has been developed and sold in order to facilitate or carry out such calculations, such as, for example, the software sold under the “SRIM” (“The Stopping and Range of Ions in Matter”) and “TRIM” (“The Transport of Ions in Matter”) names, developed in particular by James F. Ziegler.
It is obvious that it is possible to combine the calculations and results set out so as to determine the desired number of mixing operations on a given spreading surface, in order to carry out the treatment of an amount of powder with a degree of treatment desired for the possible combinations, in particular of type of metal oxide powder, of type of ion for the treatment, of the energy of these ions.
It is thus possible to carry out the choice of the dose of ions per gram of powder to be treated and of the number of mixing operations to be carried out on a spreading surface so as to treat the latter predictively.
It should be noted that experimental observations on samples which have formed the subject of treatment by an ion beam can make it possible to confirm or adjust the range of dose of ions selected and the mixing number selected. Such observations can in particular be carried out by XPS, in order to refine the mixing, or by measurement of the temperature for reduction of the treated powder, in order to optimize the dose required.
In order to extrapolate the preceding results to a system of vibrating mixing (bowl, plate, and the like) under a beam, the inventors recommend, for example, characterizing a system by depositing a layer of powder based on cerium oxide colored white on a layer of powder based on cerium oxide colored black and observing, as a function of the vibration time, the statistical mixing of the white and black grains at the surface of the powder as a function of the time with the aim of establishing a connection between the number of mixing operations and the vibration time of the device. At the time t0=0, 100% of the powder grains at the surface are white. When, at a characteristic time t1, 25% of the grains are white and 75% of the grains are black, the inventors estimate that 50% of the blended black and white powder grains have been exposed at least once to the beam. A correspondence between the mixing system with a vibrating device and the mixing system described above can thus be established, for which system it is possible to determine, with the binomial statistical model of
The methodologies presented in the examples above allow a person skilled in the art to easily find the means for employing the process of the present invention via simple preliminary tests liable to specify the favorable treatment conditions in accordance with the ranges indicated.
The invention is not limited to the implementational types exemplified and should be interpreted nonlimitingly and encompasses any equivalent embodiment. It should be noted that, while implementational examples with powders based on cerium oxide have been presented, the process according to the invention can be employed with a great many mixing systems and a great many metal oxide powders comprising cerium for the purpose of obtaining an increase in the porosity making possible better storage and better release of oxygen at the nanoscopic scale.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1301847 | Aug 2013 | FR | national |
This application is a continuation of U.S. patent application Ser. No. 14/909,363, which is a U.S national phase of International Patent Application No. PCT/FR2014/051919 filed Jul. 24, 2014, which in turn claims the priority benefit of France Patent Application No. FR1301847 filed Aug. 1, 2013, the respective disclosure of which are each incorporated herein by reference in their entireties.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 14909363 | Feb 2016 | US |
| Child | 15967475 | US |
