Method to incorporate pigment into paint by formation of resin beads

Abstract

A coating composition is prepared by polymerizing an addition polymer with a Tg of at least about 60° C. in the presence of a particulate pigment having substantially primary aggregate particles to form encapsulated pigment particles, isolating and drying the encapsulated pigment product, and combining the dried encapsulated pigment product with a coating vehicle.

Description

Claims

1. A method of preparing a coating composition, comprising: (a) preparing a mixture of water, a portion of addition polymerizable monomer or monomers, and a particulate pigment having substantially primary aggregate particles;(b) emulsion polymerizing the portion of addition polymerizable monomer or monomers to produce an addition polymer, wherein the portion of addition polymerizable monomer or monomers is selected so that the addition polymer has a glass transition temperature of at least about 60° C. and at least substantially encapsulates the pigment particles to form encapsulated pigment particles;(c) removing the encapsulated pigment particles from the water to form a dry, particulate, encapsulated pigment product; and(d) combining the pigment product with a vehicle comprising at least one resin, at least one crosslinker for the resin, and at least one member selected from the group consisting of water and organic liquids to form a coating composition.

2. A method according to claim 1, wherein the pigment particles have an average particle size of from about 0.1 micron to about 5 microns.

3. A method according to claim 1, wherein the addition polymer has a glass transition temperature of at least about 100° C.

4. A method according to claim 1, wherein the addition polymer is a homopolymer or copolymer of styrene.

5. A method according to claim 1, wherein, when the coating composition is applied to a substrate and cured to form a coating film, the addition polymer forms a part of the coating film.

6. A method according to claim 5, wherein the addition polymer reacts with a component of the vehicle when the composition applied to the substrate is cured.