This disclosure relates to methods and apparatus for heat transfer to and/or from glass articles by conduction more than convection. In certain embodiments, the disclosure relates to heating and/or thermally tempering glass articles by conduction more than convection.
Commonly-assigned U.S. patent application Ser. No. 14/814,232, which was filed on Jul. 30, 2015, and is entitled “Thermally Tempered Glass and Method and Apparatuses for Thermal Tempering of Glass” (Attorney Docket No. SP14-159T), discloses methods and apparatus for heating and/or thermally tempering glass articles more by conduction than by convection. U.S. patent application Ser. No. 14/814,232 will be referred to hereinafter as the “'232 application.” The contents of the '232 application are hereby incorporated herein by reference in their entirety.
The present disclosure provides methods and apparatus for the controlled transport of glass articles undergoing the heating and/or thermal tempering of the '232 application. In certain embodiments, the disclosure provides such controlled transport without mechanical contact with the glass article so as to avoid degradation of the surface properties of the article during the heating and/or thermal tempering.
The phrases “glass sheet(s)” and “glass ribbon(s)” are used broadly in the specification and in the claims and include sheet(s) and ribbon(s) that comprise one or more glasses and/or one or more glass-ceramics, as well as laminates or other composites that include one or more glass and/or one or more glass-ceramic components. The phrase “glass article(s)” is used to refer to glass sheet(s) and glass ribbon(s) collectively.
Heating or cooling (including thermally tempering) a glass article more by conduction than by convection shall mean heating or cooling under conditions which satisfy Equation (18) of the '232 application.
The word “move” includes both translation and rotation.
In accordance with an embodiment, a method is provided for heating or cooling (e.g., thermally tempering) a glass sheet (13) or a glass ribbon (15) by conduction more than convection, the glass sheet or the glass ribbon having opposing major surfaces (11), the method comprising:
(a) controlling the movement of the glass sheet (13) or the glass ribbon (15) while the glass sheet (13) or the glass ribbon (15) is in or is passing through a gap (23) in which pressure is applied to the opposing major surfaces (11) of the glass sheet (13) or the glass ribbon (15); and
(b) heating or cooling (e.g., thermally tempering) the glass sheet (13) or the glass ribbon (15) by conduction more than convection while it is in or is moving through the gap (23);
wherein step (a) comprises applying at least one gas-based force to the glass sheet (13) or the glass ribbon (15) which gas-based force has at least one component whose direction is parallel to a major surface (11) of the glass sheet (13) or the glass ribbon (15).
For example, as illustrated in
Vector 17 in
In certain embodiments, the gas-based force causes the glass sheet or the glass ribbon to move in a desired direction and/or to acquire a desired orientation, while in other embodiments, the gas-based force causes the glass sheet or the glass ribbon to retain a desired position and/or a desired orientation. The gas-based force can be applied to the glass sheet or the glass ribbon continuously or intermittently.
In certain embodiments, the gas-based force is applied by gas bearing outlets that are slanted, i.e., the outlets are at an angle relative to vertical. In other embodiments, the gas-based force is applied through one or more gas walls produced by a locally higher gas flow rate. The gas wall(s) can be arranged parallel to the direction of motion of the glass sheet or the glass ribbon (hereinafter referred to as longitudinal wall(s)) or can be transverse to the direction of motion (hereinafter referred to as transverse wall(s)). The glass wall(s) apply a reactive force (the gas-based force) to a glass sheet or a glass ribbon when the glass sheet or glass ribbon comes into contact with the flowing gas of the wall. The wall(s) can be used to align glass article(s) during treatment, to control their spacing, and/or to control their speed, including temporarily bringing one or more articles to rest.
In addition to the foregoing, embodiments are discussed in which: (1) a glass sheet or a glass ribbon is passed from a heating zone to a quench zone without the use of a transition zone, (2) a transition zone is used but is made short enough so that vertical support of the glass sheet or the glass ribbon while it is being passed through the transition zone is not required, (3) a transition zone is used which provides one-sided or two-sided vertical support to the glass sheet or the glass ribbon as it is being passed through the transition zone, and (4) a transition zone is used which provides vertical mechanical support to the glass sheet or the glass ribbon as it is being passed through the transition zone.
Apparatus for practicing the methods is also disclosed.
The reference numbers used above are only for the convenience of the reader and are not intended to and should not be interpreted as limiting the scope of the invention. More generally, it is to be understood that both the foregoing general description and the following detailed description are merely exemplary of the invention and are intended to provide an overview or framework for understanding the nature and character of the invention.
Additional features and advantages of the invention are set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from that description or recognized by practicing the invention as exemplified by the description herein. The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. It is to be understood that the various features of the invention disclosed in this specification and in the drawings can be used individually and in any and all combinations.
The reference numbers used in the drawings, which are not to scale, refer to the following:
As shown in these figures, the systems can include a heating zone 27, a transition zone 29, and a quench zone 31, it being understood that the controlled transport methods and apparatus disclosed herein can be applied to all of the zones, only one of the zones, e.g., just the quench zone, or only two of the zones, e.g., just the heating and quench zones, as desired. Also, some embodiments may employ only one of the zones, e.g., only the heating zone if only heating is desired.
In general terms, heating zone 27 heats the glass article(s) to a temperature sufficient for thermal tempering, and quench zone 31 lowers the surface temperature of the article(s) at a rate sufficient to achieve a desired level of thermal tempering. As its name implies, transition zone 29 (when used) serves as an interface between the high temperatures of the heating zone and the low temperatures of the quench zone. As shown in
When glass sheet(s) are being treated, the process can, for example, be characterized as a batch process, a semi-continuous process, or a continuous process. In a batch process, the glass sheet(s) can be moving at different speeds at different points in the process. For example, the glass sheet(s) can move through the heating zone at one speed or set of speeds, through the transition zone (when used) at another speed or set of speeds, and through the quench zone at still another speed or set of speeds. Likewise, for a semi-continuous process, the glass sheets can be moving at different speeds at different points in the process, with the spacings between glass sheets increasing and decreasing as the treatment takes place to avoid contact between the articles. As just one example, a given glass sheet can enter a zone and slow down or become stationary as a result of the application of a gas-based force, with the spacing to the next following glass sheet decreasing during the slow down or stationary period. The given glass sheet can then be accelerated by a gas-based force to restore the original spacing or some other spacing as appropriate.
For a glass ribbon, the process is continuous for any given ribbon. Nevertheless, the effects of different speeds can be achieved through adjustments in the lengths of the zones. Specifically, the effects of a higher speed can be achieved by a shorter zone (shorter residence time), and the effects of a slower speed by a longer zone (longer residence time). Such adjustments in the lengths of the zones can also be used with glass sheets if desired. Also, a combination of zone lengths and zone speeds can be used with glass sheets. In addition to speed considerations, zone lengths can change with the size of the glass sheets being processed, longer zones being used for longer glass sheets.
The temperature T of the glass article may be below, at, or above a desired T0 when the glass article enters the heating zone. If below, the temperature is raised to T0 or in some cases to T0+ΔT to compensate for heat loss that may occur in the transition zone (when used). If the temperature of the glass article is already at T0 at the start of the heating zone, then the heating zone can maintain that temperature or, alternatively, raise it to T0+ΔT. If the temperature is already at T0+ΔT, the heating zone can maintain that temperature. Alternatively, if the temperature of the article is already at T0 (or, if desired, at T0+ΔT), e.g., because it has been recently formed by, for example, a float or fusion process, the heating zone may be eliminated, with the article going directly to the transition zone (when used) or directly to the quench zone.
After leaving the heating zone (when used), the glass article can enter the transition zone (when used), which can serve to minimize adverse impacts to the glass article and/or the process as a result of the sharp change in temperature needed to achieve thermal tempering. The transition zone can also be used to change the thickness of gap 23 from that used in the heating zone to that used in the quench zone. For example, the gap may be thicker in the heating zone than in the quench zone. The transition zone can be used to provide a smooth transition between the gap dimensions.
Depending on its length and construction, the transition zone can use a gas bearing of the type shown in
If desired, the transition zone can in essence be eliminated with the glass article(s) passing directly from the heating zone to the quench zone. For example, the spacing between the heating zone and the quench zone can be less than about five times the thickness of the glass article. In connection with these embodiments, if the thickness of gap 23 is different in the heating and quench zones, the gap may be tapered (e.g., at a taper angle in the range of, for example, 0.001 to 90 degrees, with 90 degrees corresponding to a step change) in the region of the exit of the heating zone and/or in the region of the entrance to the quench zone.
If a transition zone is used and if vertical support in the transition zone is desired, the support can be either one-sided support where the supporting system acts from below the glass article or two-sided support where the supporting system acts both from above and from below the glass article. In either case, the magnitude of the upward force per unit area (upward pressure) needed to counteract the effect of gravity is small, as can be seen from the following calculation.
For a glass sheet having a density ρ, a thickness d, and major surfaces of area A, the weight (W) of the glass sheet is:
W=g*ρ*A*d,
where g is the gravitational constant (g=9.8 meters/second2). The weight per unit area (W/A) is then:
W/A=g*ρ*d.
Representative densities for glass sheets (and ribbons) are in the range of 2400-2800 kg/meter3, and representative thicknesses are in the range of 0.1-12 millimeters. Accordingly, the upward pressure needed to counteract the force of gravity in the transition zone are on the order of 2-300 Pascal (0.0003-0.04 psi).
Two-sided support can also be provided in a variety of ways.
Many of the systems used for one-sided support can also be used for two-sided support, with a second copy of the system (either identical or modified) used for the top support. For example, two-sided systems can be based on ultrasonic levitation, the Bernoulli principle, simple gas pressure, or the burner/substrate system of
As noted above, the more-heat-transfer-by-conduction-than-convection criterion is satisfied in quench zone 31 and may be satisfied in heating zone 27 and/or transition zone 29. When this criterion is satisfied, the flow of gas into gap 23 from gas bearing 33 is low. Consequently, the glass article(s) are in a low friction environment when in gap 23 and thus their motion can be controlled with relatively small gas-based forces. The following calculations illustrate the low force magnitudes associated with such a low friction environment.
We consider two representative cases, a higher force case and a lower force case. The higher force calculation is for a higher mass glass sheet undergoing a larger change (increase or decrease) in speed over a shorter time period, and the lower force case is for a lower mass glass sheet undergoing a smaller change in speed over a longer time period. For the higher mass sheet, we consider a 3 meter by 3 meter sheet having a thickness of 12 millimeters and a density of 2800 kg/meter3, and for the lower mass glass sheet, we consider a 25 millimeter by 25 millimeter glass sheet having a thickness of 1 millimeter and a density of 2400 kg/meter3. The masses for these two cases are 302.4 kilograms and 0.0015 kilograms, respectively. For the larger change in speed over the shorter time period, we consider a speed change of 1 meter/second in 0.1 seconds, and for the smaller change in speed over the longer time period, we consider a speed change of 0.001 meters/second over 1 second. In each case, we assume that a constant force is applied over the time period.
From Newton's laws, we can write: FΔt=mΔv, where F is the gas-based force, Δt is the time over which the force acts, m is the mass of the glass sheet, and Δv is the change in speed. Evaluating this equation for the higher and lower force cases, we have forces of 3027 Newtons and 1.5×10−6 Newtons, respectively. Including friction in the calculation has a minimal effect on these values, the frictional force for the higher mass glass sheet being only 3.0 Newtons for a coefficient of friction of 0.001 (a high estimate), and is much lower for the lower mass glass sheet.
Assuming the gas-based force acts on an edge of the glass sheet, these forces for the higher and lower force cases correspond to pressures of 84.1 kilopascal (12.2 psi) and 0.06 Pascal (8.7×10−6 psi), respectively, which are readily achieved in practice. For a gas-based force applied to a major surface of a glass sheet, the angle at which the gas impacts the glass sheet comes into play, as well as the velocity of the gas leaving the outlets and the gas density. Computational fluid dynamics (CFD) can be used to calculate the tangential sheer force applied to the surface of the glass article for any particular arrangement of outlets and gap thicknesses and areas. For example, the commercially available ANSYS CFD software (ANSYS Inc., Canonsburg, Pa.) can be used for this purpose. In general terms, an individual outlet at an angle from horizontal in the range of approximately 30° can generate a tangential sheer force at least in the micro-Newton range for a flow velocity on the order of a few hundred meters/second. The number of outlets can then be adjusted to achieve the accelerations/decelerations of the glass article that are desired.
When a gas wall is used, whether it be a longitudinal or a transverse wall, at least some of the gas flowing from the vertical outlets 37 of gas bearing 33 (and the slanted outlets 35, when used) will enter the gas flow which forms the wall, rather than exiting from the sides of the gas bearing as occurs in the absence of a gas wall(s). The gas flow in a gas wall, whether a longitudinal or traverse wall, will generally be at least 2-3 times the gas flow from a vertical outlet 37, the amount of flow being dependent on the magnitude of the gas-based force needed to achieve motion control (e.g., steering) of the glass article(s) at the location of the wall.
The gas used in the above embodiments, as well as in other embodiments, can have a variety of compositions. The gas can be one gas or a mixture of gases from different gas sources or the same gas source. Exemplary gases include air, nitrogen, carbon dioxide, helium or other noble gases, hydrogen and combinations thereof.
A variety of modifications that do not depart from the scope and spirit of the invention will be evident to persons having ordinary skill in the art from the foregoing disclosure. As just one example, as illustrated in
This application claims the benefit of priority under 35 U.S.C. § 119 of U.S. Provisional Application Ser. No. 62/288,566 filed on Jan. 29, 2016, the content of which is relied upon and incorporated herein by reference in its entirety. This application is related to and hereby incorporates herein by reference in full the following applications: Provisional Application Ser. No. 62/288,851, filed on Jan. 29, 2016, U.S. application Ser. No. 14/814,232, filed on Jul. 30, 2015; U.S. application Ser. No. 14/814,181, filed on Jul. 30, 2015; U.S. application Ser. No. 14/814,274, filed on Jul. 30, 2015; U.S. application Ser. No. 14/814,293, filed on Jul. 30, 2015; U.S. application Ser. No. 14/814,303, filed on Jul. 30, 2015; U.S. application Ser. No. 14/814,363, filed on Jul. 30, 2015; U.S. application Ser. No. 14/814,319, filed on Jul. 30, 2015; U.S. application Ser. No. 14/814,335, filed on Jul. 30, 2015; U.S. Provisional Application No. 62/031,856, filed Jul. 31, 2014; U.S. Provisional Application No. 62/074,838, filed Nov. 4, 2014; U.S. Provisional Application No. 62/031,856, filed Apr. 14, 2015; U.S. application Ser. No. 14/814,232, filed Jul. 30, 2015; U.S. application Ser. No. 14/814,181, filed Jul. 30, 2015; U.S. application Ser. No. 14/814,274, filed Jul. 30, 2015; U.S. application Ser. No. 14/814,293, filed Jul. 30, 2015; U.S. application Ser. No. 14/814,303, filed Jul. 30, 2015; U.S. application Ser. No. 14/814,363, filed Jul. 30, 2015; U.S. application Ser. No. 14/814,319, filed Jul. 30, 2015; U.S. application Ser. No. 14/814,335, filed Jul. 30, 2015; U.S. Provisional Application No. 62/236,296, filed Oct. 2, 2015; U.S. Provisional Application No. 62/288,549, filed Jan. 29, 2016; U.S. Provisional Application No. 62/288,566, filed Jan. 29, 2016; U.S. Provisional Application No. 62/288,615, filed Jan. 29, 2016; U.S. Provisional Application No. 62/288,695, filed on Jan. 29, 2016; U.S. Provisional Application No. 62/288,755, filed on Jan. 29, 2016.
Filing Document | Filing Date | Country | Kind |
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PCT/US2017/015280 | 1/27/2017 | WO | 00 |
Number | Date | Country | |
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62288566 | Jan 2016 | US |