Methods and apparatus for isolating carboxylic acid

Abstract

Disclosed are methods and apparatus for isolating a carboxylic acid. The processes employ at least two decanter centrifuges and at least one reslurry zone as a product isolation system in a carboxylic acid production process. The product isolation system is employed to isolate purified carboxylic acid particles from an isolation feed slurry comprising an aliphatic acid.

Description

BRIEF DESCRIPTION OF THE DRAWING FIGURES

A preferred embodiment of the present invention is described in detail below with reference to the attached drawing figures, wherein:

FIG. 1 is process flow diagram illustrating a system for isolating carboxylic acid particles from a slurry, particularly illustrating a configuration where an isolation feed slurry is subjected to solid/liquid separation and reslurry. in an alternating sequence with a counter current wash;

FIG. 2 is a side view of a decanter centrifuge that may be used as a solid/liquid separation device in accordance with one embodiment of the present invention with certain sections being cut away to more clearly illustrate the operation of the decanter centrifuge;

FIG. 3 is a process flow diagram illustrating a system for the production and purification of carboxylic acid constructed in accordance with the present invention, particularly illustrating a configuration where the crude slurry from the oxidation reactor is subjected to purification, the resulting purified slurry is subjected to product isolation, and a portion of the mother liquor from the product isolation zone is employed as a feed to a purge treatment system;

FIG. 4 is a process flow diagram illustrating a system for the production and purification of carboxylic acid constructed in accordance with the present invention, particularly illustrating a configuration where the crude slurry from the oxidation reactor is subjected to purification, the resulting purified slurry is subjected to product isolation, and a portion of the mother liquor from the product isolation zone is employed as a feed to a concentration zone;

FIG. 5 is a process flow diagram illustrating a system for the production and purification of carboxylic acid constructed in accordance with the present invention, particularly illustrating a configuration where the crude slurry from the oxidation reactor is subjected to purification, the resulting purified slurry is subjected to product isolation, and a portion of the mother liquor from the product isolation zone is employed as a feed to a non-benzoic acid (non-BA) byproduct removal zone; and

FIG. 6 is a process flow diagram illustrating a system for the production and purification of carboxylic acid constructed in accordance with the present invention, particularly illustrating a configuration where the crude slurry from the oxidation reactor is subjected to purification, the resulting purified slurry is subjected to concentration, the resulting solvent rich stream is returned to the oxidation reactor and the resulting concentrated isolation feed slurry is subjected to product isolation.

Claims

1. A method for isolating purified particles comprising an aromatic dicarboxylic acid, said method comprising: treating an isolation feed slurry comprising said purified particles and a liquid phase in a product isolation zone to thereby produce a final wet cake comprising said aromatic dicarboxylic acid in an amount of at least about 10 weight percent, wherein said product isolation zone comprises a first decanter centrifuge, a second decanter centrifuge, and a first reslurry zone disposed substantially between said first and second decanter centrifuges, and wherein said liquid phase comprises an aliphatic acid in an amount of at least about 10 weight percent.

2. The method of claim 1, wherein said aliphatic acid comprises an aliphatic carboxylic acid having 1 to 6 carbon atoms.

3. The method of claim 1, wherein said aliphatic acid comprises acetic acid.

4. The method of claim 1, wherein said slurry comprises said purified particles in an amount in the range of from about 1 to about 50 weight percent.

5. The method of claim 1, wherein said final wet cake comprises said purified particles in an amount of at least about 70 weight percent.

6. The method of claim 1, wherein said liquid phase comprises said aliphatic acid in an amount of at least about 60 weight percent.

7. The method of claim 1, wherein said liquid phase comprises said aliphatic acid in an amount of at least about 75 weight percent, wherein said liquid phase further comprises water.

8. The method of claim 1, wherein said product isolation zone comprises a third decanter centrifuge and a second reslurry zone disposed substantially between said second and third decanter centrifuges.

9. The method of claim 8, wherein said treating comprises removing at least a portion of said liquid phase from said isolation feed slurry in said first decanter centrifuge thereby producing an initial wet cake and a mother liquor.

10. The method of claim 9, further comprising directly or indirectly routing at least a portion of said mother liquor to a purge treatment zone and directly or indirectly routing at least a portion of said mother liquor to an oxidation zone where at least a portion of said purified particles are formed.

11. The method of claim 9, further comprising treating at least a portion of said mother liquor in a concentration zone thereby producing a solvent rich stream and a catalyst and oxidation byproduct rich stream, wherein at least a portion of said catalyst and oxidation byproduct rich stream is routed to a purification zone where at least a portion of said purified particles are formed and/or wherein at least a portion of said catalyst and oxidation byproduct rich stream is routed to said product isolation zone.

12. The method of claim 9, wherein said treating further comprises adding a first wash liquor to said initial wet cake in said first reslurry zone thereby producing a first reslurried stream comprising at least a portion of said purified particles.

13. The method of claim 12, wherein said treating further comprises removing at least a portion of said first wash liquor from at least a portion of said first reslurried stream in said second decanter centrifuge thereby producing an intermediate wet cake and a second wash liquor.

14. The method of claim 13, wherein said treating further comprises adding a wash feed stream to at least a portion of said intermediate wet cake in said second reslurry zone thereby producing a second reslurried stream comprising at least a portion of said purified particles.

15. The method of claim 14, wherein said treating further comprises removing at least a portion of said wash feed stream from at least a portion of said second reslurried stream in said third decanter centrifuge thereby producing said final wet cake and said first wash liquor.

16. The method of claim 1, wherein said purified particles are purified terephthalic acid (PTA) particles.

17. The method of claim 1, further comprising subjecting a purification feed slurry to oxidative digestion to thereby produce a purified slurry comprising said purified particles.

18. The method of claim 17, wherein said purification feed slurry comprises said aliphatic acid in an amount of at least about 10 weight percent.

19. The method of claim 17, wherein at least a portion of said purified slurry is employed as said isolation feed slurry.

20. The method of claim 1, wherein said purified particles have an average concentration of said aromatic dicarboxylic acid of at least about 50 weight percent.

21. A method for isolating purified terephthalic acid (PTA) particles, said method comprising: (a) introducing a slurry comprising said PTA particles and a liquid phase into a product isolation zone;(b) removing at least a portion of said liquid phase to thereby produce a wet cake and a mother liquor; and(c) separating said mother liquor into a first mother liquor stream and a second mother liquor stream both comprising one or more catalyst components, oxidation byproducts, and solvent, wherein said product isolation zone comprises at least two decanter centrifuges and at least one reslurry zone, and wherein said liquid phase comprises an aliphatic acid in an amount of at least about 10 weight percent.

22. The method of claim 21, wherein said aliphatic acid comprises an aliphatic carboxylic acid having 1 to 6 carbon atoms.

23. The method of claim 21, wherein said aliphatic acid comprises acetic acid.

24. The method of claim 21, wherein said liquid phase comprises said aliphatic acid in an amount of at least about 60 weight percent.

25. The method of claim 21, wherein said liquid phase comprises said aliphatic acid in an amount of at least about 75 weight percent, wherein said liquid phase further comprises water.

26. The method of claim 21, wherein said product isolation zone comprises X number of reslurry zones, wherein said product isolation zone comprises X+1 number of decanter centrifuges.

27. The method of claim 21, wherein said at least two decanter centrifuges and at least one reslurry zone are arranged in an alternating sequence beginning with an initial decanter centrifuge followed by an initial reslurry zone and ending with a final reslurry zone followed by a final decanter centrifuge.

28. The method of claim 27, wherein said initial reslurry zone and said final reslurry zone comprise one reslurry zone.

29. The method of claim 27, said removing of step (b) further comprising introducing at least a portion of said slurry into said initial decanter centrifuge thereby producing said mother liquor and an initial wet cake comprising at least a portion of said PTA particles, and introducing at least a portion of said initial wet cake into said initial reslurry zone.

30. The method of claim 27, said removing of step (b) further comprising introducing a wash stream into said final reslurry zone thereby producing a reslurried stream comprising at least a portion of said PTA particles.

31. The method of claim 30, said removing of step (b) further comprising treating at least a portion of said reslurried stream in said final decanter centrifuge thereby producing a wash liquor and said wet cake comprising at least a portion of said PTA particles, further comprising introducing at least a portion of said wash liquor into said initial reslurry zone.

32. The method of claim 21, wherein said catalyst components comprise cobalt, manganese, and/or bromine, wherein said oxidation byproducts comprise benzoic acid (BA) and non-BA byproducts, wherein at least a portion of said oxidation byproducts are byproducts from the at least partial oxidation of para-xylene.

33. The method of claim 21, further comprising directly or indirectly routing at least a portion of said first mother liquor stream to an oxidation zone where at least a portion of said PTA particles are formed.

34. The method of claim 21, further comprising treating at least a portion of said second mother liquor stream in a purge treatment zone thereby producing a BA rich stream, a non-BA byproduct rich stream, and a catalyst rich stream.

35. The method of claim 34, wherein said PTA particles are produced in a PTA production process, further comprising routing at least a portion of said non-BA byproduct rich stream to one or more locations that cause at least about 5 weight percent of said non-BA byproducts present in said non-BA byproduct rich stream to exit said PTA production process with a PTA product produced therein and/or to be combined with said PTA product downstream of said PTA production process.

36. The method of claim 21, further comprising treating at least a portion of said second mother liquor stream in a concentration zone thereby producing a catalyst and oxidation byproduct rich stream and a solvent rich stream.

37. The method of claim 36, further comprising directly or indirectly routing at least a portion of said solvent rich stream to an oxidation zone where at least a portion of said PTA particles are formed, and/or directly or indirectly routing at least a portion of said catalyst and oxidation byproduct rich stream to a purification zone where at least a portion of said slurry is formed and/or to said product isolation zone.

38. The method of claim 21, further comprising treating at least a portion of said second mother liquor stream in a non-BA byproduct removal zone thereby producing a solvent rich stream, a catalyst and BA rich stream, and a non-BA byproduct rich stream.

39. The method of claim 38, further comprising directly or indirectly routing at least a portion of said catalyst and BA rich stream and said solvent rich stream to an oxidation zone where at least a portion of said PTA particles are formed.

40. The method of claim 38, further comprising directly or indirectly routing at least a portion of said non-BA byproduct rich stream to a drying zone to thereby produce a dried non-BA byproduct rich stream, and/or directly or indirectly routing at least a portion of said non-BA byproduct rich stream to a reslurry zone to thereby produce a reslurried non-BA byproduct rich stream.

41. A method for treating a slurry comprising purified terephthalic acid (PTA) particles, said method comprising: treating said slurry in a catalyst removal zone to thereby produce a wet cake comprising at least a portion of said PTA particles and a mother liquor, wherein said slurry comprises said PTA particles in an amount of at least about 15 weight percent, wherein said slurry comprises acetic acid, and wherein said catalyst removal zone comprises at least two decanter centrifuges and one or more reslurry zones.

42. The method of claim 41, wherein said decanter centrifuges and reslurry zones are arranged in an alternating sequence such that said catalyst removal zone comprises a first decanter centrifuge followed by a first reslurry zone followed by a second decanter centrifuge followed by a second reslurry zone followed by a third decanter centrifuge.

43. The method of claim 42, further comprising treating said slurry in said first decanter centrifuge to thereby produce said mother liquor.

44. The method of claim 42, further comprising introducing a wash feed stream into said second reslurry zone to wash at least a portion of said PTA particles thereby producing a reslurried stream comprising at least a portion of said PTA particles.

45. The method of claim 44, further comprising treating at least a portion of said reslurried stream in said third decanter centrifuge to thereby produce a wash liquor and said wet cake.

46. The method of claim 45, further comprising introducing at least a portion of said wash liquor into said first reslurry zone.

47. The method of claim 41, wherein said slurry comprises oxidation byproducts produced in a PTA production process.

48. The method of claim 47, wherein said oxidation byproducts exit said PTA production process with said wet cake at substantially the same rate as the make rates of said oxidation byproducts in said PTA production process.

49. The method of claim 41, further comprising treating at least a portion of said mother liquor in a concentration section to thereby produce a solvent rich stream and a concentrated stream comprising oxidation byproducts and one or more catalyst components.

50. The method of claim 49, further comprising routing at least a portion of said concentrated stream to a post-oxidation section where at least a portion of said PTA particles are formed.