The present application relates generally to heat generation, and more specifically to triggering an exothermic reaction for excess heat generation.
For decades, scientists have been searching for alternative energy sources to replace fossil fuels and nuclear power. Over the past thirty years, scientists have, on many occasions, observed the phenomenon of excess heat generation when hydrogen/deuterium has reached a high loading level in a variety of metals or alloys. This excess heat generation phenomenon has been attributed to exothermic reactions between occluded nuclei. In one theory that is based on the Heisenberg uncertainty principle, two deuterium nuclei, when trapped in the small confinement inside a metal lattice, have a wide spread of momentum. The combined probability of two deuterium nuclei having requisite momenta to overcome the Coulomb barrier may become statistically significant, triggering fusion reactions in the trapped deuterium gas. According to a second theory, the two trapped deuterium nuclei overcome the Coulomb barrier by tunneling through a quantum tunnel to reach a lower energy state, i.e., to form a 4He nucleus.
Although these experiments have been replicated around the world, efforts to generate excess heat in a metal or alloy loaded with hydrogen/deuterium in a consistent manner have not been successful. Scientists have explored different conditions in which generation of excess heat can be triggered at will and with control. However, research in the triggering conditions of exothermic reactions so far has been largely inconclusive.
The present application teaches advantageous methods and apparatus for triggering and maintaining exothermic reactions.
Methods and apparatus for triggering an exothermic reaction are disclosed.
In some embodiments, a device comprising a metal container and an electrode is used for triggering an exothermic reaction. The metal container is plated with a hydrogen absorbing material. The metal container has one or more open ends. The electrode is received through a first open end into the metal container. The metal container is filled with a pressurized hydrogen gas. To trigger an exothermic reaction, a voltage between the metal container and the electrode is applied. In some embodiments, the magnetic field may be optionally applied. The strength of the magnetic field is set above a pre-determined threshold. For example, the strength of the magnetic field may be between 500 and 700 Gauss. In some embodiments, the voltage applied between the metal container and the electrode is selected to be dependent on a dimension of the metal container. For example, the voltage may be dependent on the distance between the metal container and the electrode. In one embodiment, the hydrogen absorbing material plated on the interior wall of the metal container comprises nickel, palladium or other metals or metal alloys capable of forming a hydride or deuteride. In one embodiment, a layer of gold is plated underneath the hydrogen absorbing material. In another embodiment, a layer of silver or other metals that do not dissociate hydrogen or deuterium is plated underneath the hydrogen absorbing material.
In some embodiments, the device used for triggering an exothermic reaction comprises a metal container and an electrode. The electrode is received through an open end of the metal container. The electrode is plated with a hydrogen absorbing material. In some embodiments, the electrode is first plated with a layer of gold and the hydrogen absorbing material is plated on top of the layer of gold. The metal container may have one or more open ends and the open ends are sealed. The metal container is filled with a pressurized hydrogen gas. To trigger an exothermic reaction, a voltage between the metal container and the electrode is applied. The voltage is dependent on a dimension of the metal container, for example, the distance between the metal container and the electrode. Optionally, a magnetic field may be applied and the magnitude of the magnetic field is set above a pre-determined threshold.
In some embodiments, a device used for hosting an exothermic reaction comprises a metal container and an electrode, and preparation of the device for exothermic reactions comprises the following steps. The preparation starts with plating. In one embodiment, the metal container is plated with a hydrogen absorbing material. In another embodiment, the hydrogen absorbing material is plated on the electrode. After the plating, the electrode is inserted into the metal container and the metal container is sealed and filled with a pressurized hydrogen gas. An optional magnetic field of a pre-determined magnitude and a pre-specified voltage between the metal container and the electrode are applied to trigger an exothermic reaction.
The metal container 102 may have one or more open ends. In
The electrode 104, as shown in
In some embodiments, the electrode 104 is made of the same shape as the metal container 102, to create a uniform electric field inside the metal container 102. In some embodiments, the electrode 104 is shaped as a rod with a diameter of 1/16 in. The metal container 102 is in the shape of a tube with an outer diameter of one inch and an inner diameter of 0.875 in. The length of the metal container 102 is 12 in and the electrode 104 extends into the metal container 102. The distance between the end of the electrode 104 and the bottom of the metal container 102 (d in
The voltage control device 116 is a removable electrical pass-through. The voltage control device 116 holds the electrode 104 in place at the center of the metal container 102. The voltage control device 116 is preferably made of ceramic, but can be of any electrically insulating material. The voltage control device 116 uses a safe high voltage connector to connect the electrode 104 to a high voltage power supply. A lid made of aluminum is placed over the electrical pass-through to provide accommodation for pressure controlling devices 114 configured for removing or supplying gas to the metal container 102 and for monitoring gas pressure inside the metal container 102. In another embodiment, the lid may be made of stainless steel or any other suitable metal.
To prepare the device 100 for exothermic reactions, the first step is to provide a hydrogen absorbing material for occluding hydrogen or deuterium. In a preferred embodiment, the hydrogen absorbing material 110 is plated either on the interior of the metal container 102 or on the electrode 104. Well known hydrogen absorbing materials include palladium, nickel, titanium, and other metals and alloys known to form hydrides or deuterides. In some embodiments, palladium, palladium alloy or a palladium product is used as the hydrogen absorbing material and is plated on the interior wall of the metal container via an electrolytic process. In one embodiment, the thickness of the plating is around 7 microns. On a macro scale, the thickness of the plating is uniform across the sidewalls and the bottom of the metal container 102. However, in a preferred embodiment, the surface of the plated hydrogen absorbing material is made rough on a micro scale, by performing the plating procedure under special conditions to force rough deposits.
In some embodiments, a layer of gold 108 is plated underneath the hydrogen absorbing material 110. In one embodiment, the thickness of the layer 108 is approximately 10 microns and is uniform across the sidewalls and the bottom of the metal container 102 on a macro scale. As with the hydrogen absorbing material 110, the layer of gold 108 is preferably rough, achieved during plating in the electrolysis process. The layer of gold 108 functions as a seal to maintain high hydrogen loading in the hydrogen absorbing material and may serve other functions as well, such as providing an interface between the container and the hydrogen absorbing material. Other metals, such as silver, which do not absorb hydrogen may be used to replace gold.
In some embodiments, when electrolysis is used as the plating method, the hydrogen absorbing material 110 and gold 108 are plated to cover the sidewalls and the bottom of the metal container 102 except a strip near the top of the metal container. This strip exposes the metal container to the high voltage differential applied between the metal container 102 and the electrode 104. To prevent sparking between the electrode 104 and the metal container 102 when a high voltage is applied, the portion of the electrode 104 that is parallel to the exposed area of the metal container is coated with an insulator 118, for example, Teflon.
In the device 100 shown in
Both
It is contemplated that resonant voltages exist inside the cylindrical metallic container described herein. The deuterium gas in the container is ionic and can be accelerated by the electric field produced by high voltage. The velocity achieved by the deuterium ions is determined by the mean free path of the deuterium ions. The deuterium ion velocity in turn determines the magnitude of the Debroglie pilot wave associated with the deuterium ion, which determines the size of the confinement space into which the deuterium ions can fit. In a metal hydride, there may be several relevant confinement dimensions. For example, the average separation distance between two deuterium atoms in a deuterium gas molecule in free space is 0.741 Angstroms. The average separation distance for D2 molecular ions is 1.058 Angstroms. The lattice dimension for deuterated palladium in the beta phase is 4.026 Angstroms and the size of a palladium vacancy is conjectured to be one half of the lattice dimension, or 2.013 Angstroms. There is experimental evidence suggesting that D-D exothermic reactions are possible in the vacancies of certain metal deuterides, most notably palladium. It has been experimentally observed that exothermic reactions are triggered in palladium deuterides when the voltage, temperature, and pressure are set to accelerate deuterium ion to achieve a Debroglie wavelength of 2.013 Angstroms, which is numerically equal to the conjectured size of a palladium lattice vacancy, as shown below. The equation below, Eq. (1), provides the relationship between the voltage V0 and the Debroglie wavelength X under a given pressure P and temperature T.
In some embodiments, an exothermic response was observed when the Debroglie wavelength of the deuterium ions was approximately 0.741 A and 2.013 Angstroms. These wavelengths correspond to the distance between two deuterium atoms in molecular deuterium and the conjectured size of a palladium vacancy respectively.
In an exemplary palladium lattice shown in
In some experiments, an exothermic reaction was observed experimentally when the deuterons were accelerated with 1,237 volts and on a separate occasion with 176 volts. The experimental conditions at that time were such that Debroglie wavelengths of 2.014 Angstroms and 0.74 Angstroms were produced as the deuterons accelerated toward the reactor wall and into the palladium. This suggests that there may be a connection between the deuterium ion's Debroglie wavelength and one or more physical lattice dimensions where the ions may be trapped. To accelerate the deuterons to achieve a Debroglie wavelength that corresponds to the dimensions of the physical lattice the ions may be trapped in, the voltage V0 applied between the metal container 102 and the electrode 104 can be determined using Eq. (1).
To summarize, a palladium lattice provides at least two locations where deuterium ions can be trapped, providing an opportunity for the wave functions of two deuterium ions to overlap: in the open space between palladium atoms, or in a vacancy in the palladium lattice as shown in
In some embodiments, the open ends of the reactor 100 are sealed to achieve and maintain different pressures needed at different operational stages. In some embodiments, the reactor 100 can have two open ends and the two open ends can be configured to receive separately the electrode 104 and the pressure and voltage controlling devices, 114 and 116. In some embodiments, one open end may be permanently sealed via welding, orbital welding, for example, to avoid chemical reactions. The open end or ends that receive the electrode 104 and the pressure and voltage controlling devices, 114 and 116, require non-permanent sealing, as described above. The pressure controlling devices 114 and the voltage controlling device 116 include an array of control devices shown in
In
The exemplary system 400 includes a plurality of thermocouples 412, which are placed in various positions inside the system 400 for calorimetric measurements. The exemplary system 400 also includes the voltage controlling device 116 and the pressure controlling devices 114. The voltage-controlling device 116 further includes a connector (not shown), a power supply 416, and an optional RF signal generator 418. In some embodiments, the voltage applied to the anode 104 includes only a DC component that is approximately 5000 volts with a 5 mA current. In some embodiments, the voltage applied to the anode 104 includes both a DC component and an RF component that are combined in the voltage control device 116. An example of a voltage combining component is a Bias Tee 420, which overlays the RF signal onto the DC offset without amplifying either signal. The pressure controlling devices 114 also include a pressure gauge 414 for measuring the pressure inside the system 400, a mass flow control 402 for controlling the quantity of input gas, and a number of gas canisters 406.
In preparing the system 400 for an exothermic reaction in the hydrogen occluded metal 110 that is plated on the cathode 105, the reactor chamber (i.e., the sealed space between the anode 104 and the cathode 105) is pumped down to a high vacuum of pressure, e.g., 10−6 Torr, by connecting the system to a vacuum chamber (not shown). After the reactor chamber has been cleared of unwanted gas residuals, different types of reaction gases, each stored in a gas container 406, can be introduced into the reactor chamber via the mass flow controller 402 for exothermic reactions. The reaction gas may include deuterium gas, hydrogen gas, or a mixture of hydrogen and deuterium gases. Once the reaction gas in the reaction chamber reaches a desired pressure set point, a valve is closed to seal the chamber. To trigger an exothermic reaction in the hydrogen infused metal, a triggering condition is applied.
In some embodiments, the triggering condition includes applying a voltage differential between the cathode 105 and the anode 104. The voltage differential may be set to a resonant RF voltage as described above. The resonant voltage is dependent on a geometric dimension or dimensions of the reaction chamber. In some embodiments, the power supply used to provide the resonant voltage may include a DC component only. In some embodiments, the power supply may include both a DC component and an RF signal.
In some embodiments, the triggering condition further includes applying a magnetic field in the reaction chamber. The magnitude of the magnetic field is preferably set to be above a pre-determined threshold. The magnetic field may be supplied through the magnets 112 or through currents using Helmholtz coils (not shown). The magnetic field can also be a component of the earth's magnetic field.
In some experiments, following the triggering of an exothermic reaction, a sample of gas may be extracted from the reaction chamber via the pressure controlling devices 114, and stored in a sample chamber 410. The sample may then be analyzed, using e.g., mass spectroscopy, to ascertain chemical or physical changes that may reveal details of the reaction. For example, the presence of helium may indicate a nuclear fusion reaction of hydrogen nuclei.
The experiment runs for about three and half days. At the beginning, the temperatures of the metal container 102 and the control reactor coincide. At time t1, a power source supplying a voltage of approximately 5,000V and a current of 0.0001 amperes is turned on for about 4 hours. From time t1, the temperature of the metal container 102 and that of the control reactor start to diverge. Between time t1 and time t4, the difference between the two temperatures increases with time despite the fact that no significant voltage is applied during this time period, except for a short time period between t2 and t3. During the time period between t2 and t3, a relatively small voltage was applied. More notable is the apparent increase in the temperature of the metal container 102 during the time period between t3 and t4 as there is no apparent input of power from the high voltage stimulation. During the remainder time of the experiment, the temperature of the metal container 102 remains several Celsius degrees higher than that of the control reactor.
The invention disclosed herein may be carried out in other specific ways than those herein set forth without departing from the scope and essential characteristics of the invention. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive, and all changes coming within the meaning and equivalency range of the appended claims are intended to be embraced therein.
This application is a U.S. National Stage application of International Application No. PCT/US17/013931, filed on Jan. 18, 2017, which claims priority to U.S. Provisional Application No. 62/263,121, titled Methods and Apparatus for Triggering Exothermic Reactions, which was filed on Dec. 4, 2015, and the entire contents of which are hereby incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/US2017/013931 | 1/18/2017 | WO | 00 |
Number | Date | Country | |
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62263121 | Dec 2015 | US |