Methods and systems for mini-split liquid desiccant air conditioning

Information

  • Patent Grant
  • 10619867
  • Patent Number
    10,619,867
  • Date Filed
    Thursday, January 25, 2018
    6 years ago
  • Date Issued
    Tuesday, April 14, 2020
    4 years ago
Abstract
A split liquid desiccant air conditioning system is disclosed for treating an air stream flowing into a space in a building. The split liquid desiccant air-conditioning system is switchable between operating in a warm weather operation mode and a cold weather operation mode.
Description
BACKGROUND

The present application relates generally to the use of liquid desiccants to dehumidify and cool, or heat and humidify an air stream entering a space. More specifically, the application relates to the replacement of conventional mini-split air conditioning units with (membrane based) liquid desiccant air conditioning system to accomplish the same heating and cooling capabilities as those conventional mini-split air conditioners.


Desiccant dehumidification systems—both liquid and solid desiccants—have been used parallel to conventional vapor compression HVAC equipment to help reduce humidity in spaces, particularly in spaces that require large amounts of outdoor air or that have large humidity loads inside the building space itself. (ASHRAE 2012 Handbook of HVAC Systems and Equipment, Chapter 24, p. 24. 10). Humid climates, such as for example Miami, Fla. require a lot of energy to properly treat (dehumidify and cool) the fresh air that is required for a space's occupant comfort. Desiccant dehumidification systems—both solid and liquid—have been used for many years and are generally quite efficient at removing moisture from the air stream. However, liquid desiccant systems generally use concentrated salt solutions such as ionic solutions of LiCl, LiBr or CaCl2 and water. Such brines are strongly corrosive, even in small quantities, so numerous attempts have been made over the years to prevent desiccant carry-over to the air stream that is to be treated. In recent years efforts have begun to eliminate the risk of desiccant carry-over by employing micro-porous membranes to contain the desiccant. These membrane based liquid desiccant systems have been primarily applied to unitary rooftop units for commercial buildings. However, residential and small commercial buildings often use mini-split air conditioners wherein the condenser is located outside and the evaporator cooling coil is installed in the room or space than needs to be cooled, and unitary rooftop units are not an appropriate choice for servicing those spaces.


Liquid desiccant systems generally have two separate functions. The conditioning side of the system provides conditioning of air to the required conditions, which are typically set using thermostats or humidistats. The regeneration side of the system provides a reconditioning function of the liquid desiccant so that it can be re-used on the conditioning side. Liquid desiccant is typically pumped between the two sides, and a control system helps to ensure that the liquid desiccant is properly balanced between the two sides as conditions necessitate and that excess heat and moisture are properly dealt with without leading to over-concentrating or under-concentrating the desiccant.


In many smaller buildings a small evaporator coil is hung high up on a wall or covered by a painting as for example the LG LAN126HNP Art Cool Picture frame. A condenser is installed outside and high pressure refrigerant lines connect the two components. Furthermore a drain line for condensate is installed to remove moisture that is condensed on the evaporator coil to the outside. A liquid desiccant system can significantly reduce electricity consumption and can be easier to install without the need for high pressure refrigerant lines that need to be installed on site.


Mini-split systems typically take 100% room air through the evaporator coil and fresh air only reaches the room through ventilation and infiltration from other sources. This often can result in high humidity and cool temperatures in the space since the evaporator coil is not very efficient for removing moisture. Rather, the evaporator coil is better suited for sensible cooling. On days where only a small amount of cooling is required the building can reach unacceptable levels of humidity since not enough natural heat is available to balance the large amount of sensible cooling.


There thus remains a need to provide a retrofitable cooling system for small buildings with high humidity loads, wherein the cooling and dehumidification of indoor air can be accommodated at low capital and energy costs.


BRIEF SUMMARY

Provided herein are methods and systems used for the efficient cooling and dehumidification of an air stream especially in small commercial or residential buildings using a mini-split liquid desiccant air conditioning system. In accordance with one or more embodiments, the liquid desiccant flows down the face of a support plate as a falling film. In accordance with one or more embodiments, the desiccant is contained by a microporous membrane and the air stream is directed in a primarily vertical orientation over the surface of the membrane and whereby both latent and sensible heat are absorbed from the air stream into the liquid desiccant. In accordance with one or more embodiments, the support plate is filled with a heat transfer fluid that ideally is flowing in a direction counter to the air stream. In accordance with one or more embodiments, the system comprises a conditioner that removes latent and sensible heat through the liquid desiccant into the heat transfer fluid and a regenerator that rejects the latent and sensible heat from the heat transfer fluid to the environment. In accordance with one or more embodiments, the heat transfer fluid in the conditioner is cooled by a refrigerant compressor or an external source of cold heat transfer fluid. In accordance with one or more embodiments, the regenerator is heated by a refrigerant compressor or an external source of hot heat transfer fluid. In accordance with one or more embodiments, the refrigerant compressor is reversible to provide heated heat transfer fluid to the conditioner and cold heat transfer fluid to the regenerator and the conditioned air is heat and humidified and the regenerated air is cooled and dehumidified. In accordance with one or more embodiments, the conditioner is mounted against a wall in a space and the regenerator is mounted outside of the building. In accordance with one or more embodiments, the regenerator supplies liquid desiccant to the conditioner through a heat exchanger. In one or more embodiments, the heat exchanger comprises two desiccant lines that are bonded together to provide a thermal contact. In one or more embodiments, the conditioner receives 100% room air. In one or more embodiments, the regenerator receives 100% outside air. In one or more embodiments, the conditioner and evaporator are mounted behind a flat screen TV or flat screen monitor or some similar device.


In accordance with one or more embodiments a liquid desiccant membrane system employs an indirect evaporator to generate a cold heat transfer fluid wherein the cold heat transfer fluid is used to cool a liquid desiccant conditioner. Furthermore in one or more embodiments, the indirect evaporator receives a portion of the air stream that was earlier treated by the conditioner. In accordance with one or more embodiments, the air stream between the conditioner and indirect evaporator is adjustable through some convenient means, e.g., through a set of adjustable louvers or through a fan with adjustable fan speed. In one or more embodiments, the water supplied to the indirect evaporator is potable water. In one or more embodiments, the water is seawater. In one or more embodiments, the water is waste water. In one or more embodiments, the indirect evaporator uses a membrane to prevent carry-over of non-desirable elements from the seawater or waste water. In one or more embodiments, the water in the indirect evaporator is not cycled back to the top of the indirect evaporator such as would happen in a cooling tower, but between 20% and 80% of the water is evaporated and the remainder is discarded. In one or more embodiments, the indirect evaporator is mounted directly behind or directly next to the conditioner. In one or more embodiments, the conditioner and evaporator are mounted behind a flat screen TV or flat screen monitor or some similar device. In one or more embodiments, the exhaust air from the indirect evaporator is exhausted out of the building space. In one or more embodiments, the liquid desiccant is pumped to a regenerator mounted outside the space through a heat exchanger. In one or more embodiments, the heat exchanger comprises two lines that are thermally bonded together to provide a heat exchange function. In one or more embodiments, the regenerator receives heat from a heat source. In one or more embodiments, the heat source is a solar heat source. In one or more embodiments, the heat source is a gas-fired water heater. In one or more embodiments, the heat source is a steam pipe. In one or more embodiments, the heat source is waste heat from an industrial process or some other convenient heat source. In one or more embodiments, the heat source can be switched to provide heat to the conditioner for winter heating operation. In one or more embodiments, the heat source also provides heat to the indirect evaporator. In one or more embodiments, the indirect evaporator can be directed to provide humid warm air to the space rather than exhausting the air to the outside.


In accordance with one or more embodiments, the indirect evaporator is used to provide heated, humidified air to a supply air stream to a space while a conditioner is simultaneously used to provide heated, humidified air to the same space. This allows the system to provide heated, humidified air to a space in winter conditions. The conditioner is heated and is desorbing water vapor from a desiccant and the indirect evaporator can be heated as well and is desorbing water vapor from liquid water. In combination the indirect evaporator and conditioner provide heated humidified air to the building space for winter heating conditions.


In no way is the description of the applications intended to limit the disclosure to these applications. Many construction variations can be envisioned to combine the various elements mentioned above each with its own advantages and disadvantages. The present disclosure in no way is limited to a particular set or combination of such elements.





BRIEF DESCRIPTION OF THE FIGURES


FIG. 1 illustrates an exemplary 3-way liquid desiccant air conditioning system using a chiller or external heating or cooling sources.



FIG. 2 shows an exemplary flexibly configurable membrane module that incorporates 3-way liquid desiccant plates.



FIG. 3 illustrates an exemplary single membrane plate in the liquid desiccant membrane module of FIG. 2.



FIG. 4 shows a schematic of a conventional mini-split air conditioning system.



FIG. 5A shows a schematic of an exemplary chiller assisted mini-split liquid desiccant air conditioning system in a summer cooling mode in accordance with one or more embodiments.



FIG. 5B shows a schematic of an exemplary chiller assisted mini-split liquid desiccant air conditioning system in a winter heating mode in accordance with one or more embodiments.



FIG. 6 shows an alternate embodiment of a mini-split liquid desiccant air conditioning system using an indirect evaporative cooler and an external heat source in accordance with one or more embodiments.



FIG. 7 shows the liquid desiccant mini-split system of FIG. 6 configured for operation in a winter heating mode in accordance with one or more embodiments.



FIG. 8 is a perspective view of an exemplary liquid desiccant mini-split system similar to FIG. 5A.



FIG. 9A illustrates a cut-away rear-view of the system of FIG. 8.



FIG. 9B illustrates a cut-away front-view of the system of FIG. 8.



FIG. 10 shows a three dimensional view of a liquid desiccant mini-split system of FIG. 6 in accordance with one or more embodiments.



FIG. 11 shows a cut-away view of the system of FIG. 10 in accordance with one or more embodiments.



FIG. 12 illustrates an exemplary liquid desiccant supply and return structure comprising two bonded plastic tubes creating a heat exchange effect in accordance with one or more embodiments.





DETAILED DESCRIPTION


FIG. 1 depicts a new type of liquid desiccant system as described in more detail in U.S. Patent Application Publication No. US 20120125020, which is incorporated by reference herein. A conditioner 101 comprises a set of plate structures that are internally hollow. A cold heat transfer fluid is generated in cold source 107 and entered into the plates. Liquid desiccant solution at 114 is brought onto the outer surface of the plates and runs down the outer surface of each of the plates. The liquid desiccant runs behind a thin membrane that is located between the air flow and the surface of the plates. Outside air 103 is now blown through the set of wavy plates. The liquid desiccant on the surface of the plates attracts the water vapor in the air flow and the cooling water inside the plates helps to inhibit the air temperature from rising. The treated air 104 is put into a building space.


The liquid desiccant is collected at the bottom of the wavy plates at 111 and is transported through a heat exchanger 113 to the top of the regenerator 102 to point 115 where the liquid desiccant is distributed across the wavy plates of the regenerator. Return air or optionally outside air 105 is blown across the regenerator plate and water vapor is transported from the liquid desiccant into the leaving air stream 106. An optional heat source 108 provides the driving force for the regeneration. The hot transfer fluid 110 from the heat source can be put inside the wavy plates of the regenerator similar to the cold heat transfer fluid on the conditioner. Again, the liquid desiccant is collected at the bottom of the wavy plates 102 without the need for either a collection pan or bath so that also on the regenerator the air flow can be horizontal or vertical. An optional heat pump 116 can be used to provide cooling and heating of the liquid desiccant. It is also possible to connect a heat pump between the cold source 107 and the hot source 108, which is thus pumping heat from the cooling fluids rather than the desiccant.



FIG. 2 describes a 3-way heat exchanger as described in further detail in U.S. patent application Ser. No. 13/915,199 filed on Jun. 11, 2013, Ser. No. 13/915,222 filed on Jun. 11, 2013, and Ser. No. 13/915,262 filed on Jun. 11, 2013, which are all incorporated by reference herein. A liquid desiccant enters the structure through ports 304 and is directed behind a series of membranes as described in FIG. 1. The liquid desiccant is collected and removed through ports 305. A cooling or heating fluid is provided through ports 306 and runs counter to the air stream 301 inside the hollow plate structures, again as described in FIG. 1 and in more detail in FIG. 3. The cooling or heating fluids exit through ports 307. The treated air 302 is directed to a space in a building or is exhausted as the case may be.



FIG. 3 describes a 3-way heat exchanger as described in more detail in U.S. Provisional Patent Applications Ser. No. 61/771,340 filed on Mar. 1, 2013, which is incorporated by reference herein. The air stream 251 flows counter to a cooling fluid stream 254. Membranes 252 contain a liquid desiccant 253 that is falling along the wall 255 that contain a heat transfer fluid 254. Water vapor 256 entrained in the air stream is able to transition the membrane 252 and is absorbed into the liquid desiccant 253. The heat of condensation of water 258 that is released during the absorption is conducted through the wall 255 into the heat transfer fluid 254. Sensible heat 257 from the air stream is also conducted through the membrane 252, liquid desiccant 253 and wall 255 into the heat transfer fluid 254.



FIG. 4 illustrates a schematic diagram of a conventional mini-split air conditioning system as is frequently installed on buildings. The unit comprises a set of indoor components that generate cool, dehumidified air and a set of outdoor components that release heat to the environment. The indoor components comprise a cooling (evaporator) coil 401 through which a fan 407 blows air 408 from the room. The cooling coil cools the air and condenses water vapor on the coil which is collected in drain pan 418 and ducted to the outside 419. The resulting cooler, drier air 409 is circulated into the space and provides occupant comfort. The cooling coil 401 receives liquid refrigerant at pressures of typically 50-200 psi through line 412, which has already been expanded to a low temperature and pressure by expansion valve 406. The pressure of the refrigerant in line 412 is typically 300-600 psi. The cold liquid refrigerant 410 enters the cooling coil 401 where it picks up heat from the air stream 408. The heat from the air stream evaporates the liquid refrigerant in the coil and the resulting gas is transported through line 404 to the outdoor components and more specifically to the compressor 402 where it is re-compressed to a high pressure of typically 300-600 psi. In some instances the system can have multiple cooling coils 410, fans 407 and expansion valves 406, for example a cooling coil assembly could be located in various rooms that need to be cooled.


Besides the compressor 402, the outdoor components comprise a condenser coil 403 and a condenser fan 417. The fan 417 blows outside air 415 through the condenser coil 403 where it picks up heat from the compressor 402 which is rejected by air stream 416. The compressor 402 creates hot compressed refrigerant in line 411. The heat of compression is rejected in the condenser coil 403. In some instances the system can have multiple compressors or multiple condenser coils and fans. The primary electrical energy consuming components are the compressor through electrical line 413, the condenser fan electrical motor through supply line 414 and the evaporator fan motor through line 405. In general the compressor uses close to 80% of the electricity required to operate the system, with the condenser and evaporator fans taking about 10% of the electricity each.



FIG. 5A illustrates a schematic representation of a liquid desiccant air conditioner system. A 3-way conditioner 503 (which is similar to the conditioner 101 of FIG. 1) receives an air stream 501 from a room (“RA”). Fan 502 moves the air 501 through the conditioner 503 wherein the air is cooled and dehumidified. The resulting cool, dry air 504 (“SA”) is supplied to the room for occupant comfort. The 3-way conditioner 503 receives a concentrated desiccant 527 in the manner explained under FIGS. 1-3. It is preferable to use a membrane on the 3-way conditioner 503 to ensure that the desiccant is generally fully contained and is unable to get distributed into the air stream 504. The diluted desiccant 528, which contains the captured water vapor is transported to the outside regenerator 522. Furthermore the chilled water 509 is provided by pump 508, enters the conditioner module 503 where it picks up heat from the air as well as latent heat released by the capture of water vapor in the desiccant 527. The warmer water 506 is also brought outside to the heat exchanger 507 on the chiller system 530. It is worth noting that unlike the mini-split system of FIG. 4, which has high pressure between 50 and 600 psi, the lines between the indoor and outdoor system of FIG. 5A are all low pressure water and liquid desiccant lines. This allows the lines to be inexpensive plastics rather than refrigerant lines in FIG. 4, which are typically copper and need to be braised in order to withstand the high refrigerant pressures. It is also worth noting that the system of FIG. 5A does not require a condensate drain line like line 419 in FIG. 4. Rather, any moisture that is condensed into the desiccant is removed as part of the desiccant itself. This also eliminates problems with mold growth in standing water that can occur in the conventional mini-split systems of FIG. 4.


The liquid desiccant 528 leaves the conditioner 503 and is moved through the optional heat exchanger 526 to the regenerator 522 by pump 525. If the desiccant lines 527 and 528 are relatively long they can be thermally connected to each other, which eliminates the need for heat exchanger 526.


The chiller system 530 comprises a water to refrigerant evaporator heat exchanger 507 which cools the circulating cooling fluid 506. The liquid, cold refrigerant 517 evaporates in the heat exchanger 507 thereby absorbing the thermal energy from the cooling fluid 506. The gaseous refrigerant 510 is now re-compressed by compressor 511. The compressor 511 ejects hot refrigerant gas 513, which is liquefied in the condenser heat exchanger 515. The liquid refrigerant 514 then enters expansion valve 516, where it rapidly cools and exits at a lower pressure. It is worth noting that the chiller system 530 can be made very compact since the high pressure lines with refrigerant (510, 513, 514 and 517) only have to run very short distances. Furthermore, since the entire refrigerant system is located outside of the space that is to be conditioned, it is possible to utilize refrigerants that normally cannot be used in indoor environments such as by way of example, CO2, Ammonia and Propane. These refrigerants are sometimes preferable over the commonly used R410A, R407A, R134A or R1234YF refrigerants, but they are undesirable indoor because of flammability or suffocation or inhaling risks. By keeping all of the refrigerants outside, these risks are essentially eliminated. The condenser heat exchanger 515 now releases heat to another cooling fluid loop 519 which brings hot heat transfer fluid 518 to the regenerator 522. Circulating pump 520 brings the heat transfer fluid back to the condenser 515. The 3-way regenerator 522 thus receives a dilute liquid desiccant 528 and hot heat transfer fluid 518. A fan 524 brings outside air 523 (“OA”) through the regenerator 522. The outside air picks up heat and moisture from the heat transfer fluid 518 and desiccant 528 which results in hot humid exhaust air (“EA”) 521.


The compressor 511 receives electrical power 512 and typically accounts for 80% of electrical power consumption of the system. The fan 502 and fan 524 also receive electrical power 505 and 529 respectively and account for most of the remaining power consumption. Pumps 508, 520 and 525 have relatively low power consumption. The compressor 511 will operate more efficiently than the compressor 402 in FIG. 4 for several reasons: the evaporator 507 in FIG. 5A will typically operate at higher temperature than the evaporator 401 in FIG. 4 because the liquid desiccant will condense water at much higher temperature without needing to reach saturation levels in the air stream. Furthermore the condenser 515 in FIG. 5A will operate at lower temperatures than the condenser 403 in FIG. 4 because of the evaporation occurring on the regenerator 522 which effectively keeps the condenser 515 cooler. As a result the system of FIG. 5A will use less electricity than the system of FIG. 4 for similar compressor isentropic efficiencies.



FIG. 5B shows essentially the same system as FIG. 5A except that the compressor 511's refrigerant direction has been reversed as indicated by the arrows on refrigerant lines 514 and 510. Reversing the direction of refrigerant flow can be achieved by a 4-way reversing valve (not shown) or other convenient means. It is also possible to instead of reversing the refrigerant flow to direct the hot heat transfer fluid 518 to the conditioner 503 and the cold heat transfer fluid 506 to the regenerator 522. This will in effect provide heat to the conditioner which will now create hot, humid air 504 for the space for operation in winter mode. In effect the system is now working as a heat pump, pumping heat from the outside air 523 to the space supply air 504. However unlike the system of FIG. 4, which is oftentimes also reversible, there is much less of a risk of the coil freezing because the desiccant 525 usually has much lower crystallization limit than water vapor. In the system of FIG. 4, the air stream 523 contains water vapor and if the condenser coil 403 gets too cold, this moisture will condense on the surfaces and create ice formation on those surfaces. The same moisture in the regenerator of FIG. 5B will condense in the liquid desiccant which—when managed properly will not crystalize until −60° C. for some desiccants such as LiCl and water.



FIG. 6 illustrates an alternate embodiment of a mini-split liquid desiccant system. Similar to FIG. 5A, a 3-way liquid desiccant conditioner 503 receives an air stream 501 (“RA”) moved by fan 502 through the conditioner 503. However unlike the case of FIG. 5A, a portion 601 of the supply air stream 504 (“SA”) is directed towards an indirect evaporative cooling module 602 through sets of louvers 610 and 611. Air stream 601 is usually between 0 and 40% of the flow of air stream 504. The dry air stream 601 is now directed through the 3-way indirect evaporative cooling module 602 which is constructed similarly to the 3-way conditioner module 503, except that instead of using a desiccant behind a membrane, the module now has a water film behind such membrane supplied by water source 607. This water film can be potable water, non-potable water, seawater or waste water or any other convenient water containing substance that is mostly water. The water film evaporates in the dry air stream 601 creating a cooling effect in the heat transfer fluid 604 which is then circulated to the conditioner module as cold heat transfer fluid 605 by pump 603. The cold water 605 then cools the conditioner module 503, which in turn creates cooler drier air 504, which then results in an even stronger cooling effect in the indirect evaporative module 602. As a result the supply air 504 will ultimately be both dry and cold and is supplied to the space for occupant comfort. Conditioner module 503 also receives a concentrated liquid desiccant 527 that absorbs moisture from the air stream 501. Dilute liquid desiccant 528 is then returned to the regenerator 522 similar to FIG. 5A. It is of course possible to locate the indirect evaporative cooler 602 outside of the space rather than inside, but for thermal reasons it is probably better to mount the indirect evaporator 602 in close proximity to the conditioner 503. The indirect evaporative cooling module 602 does not evaporate all of the water (typically 50 to 80%) and thus a drain 608 is employed. The exhaust air stream 606 (“EA1”) from the module evaporative cooling module 602 is brought to the outside since it is warm and very humid.


As in FIG. 5A, the concentrated liquid desiccant 527 and dilute liquid desiccant 528 pass through a heat exchanger 526 by pump 525. As before one can thermally connect the lines 527 and 528 which eliminates the need for heat exchanger 526. The 3-way regenerator 522 as before receives an outdoor air stream 523 through fan 524. And as before a hot heat transfer fluid 518 is applied to the 3-way regenerator module 522 by pump 520. However unlike the system of FIG. 5A, there is no heat from a compressor to use in the regenerator 522, so an external heat source 609 needs to be provided. This heat source can be a gas water heater, a solar module, a solar thermal/PV hybrid module (a PVT module), it can be heat from a steam loop or other convenient source of heat or hot water. In order to prevent over-concentration of the desiccant 528, a supplemental heat dump 614 can be employed which can temporarily absorb heat from the heat source 609. An additional fan 613 and air stream 612 are then necessary as well. Of course other forms of heat dumps can be devised and may not always be required. The heat source 609 ensures that the excess water is evaporated from the desiccant 528 so that it can be re-used on the conditioner 503. As a result the exhaust stream 521 (“EA2”) comprises hot, humid air. It is worth noting that again no high pressure lines are needed between the indoor and outside components of the system. A single water line for water supply is needed and a drain line for the removal of excess water. However a compressor and heat exchanger are no longer required in this embodiment. As a result this system will use significantly less electricity than the system of FIG. 4 and the system of FIG. 5A. The major consumption of electricity are now the fans 502 and 524 through electrical supply lines 505 and 529 respectively and the liquid pumps 603, 520 and 525. However these devices consume considerably less power than the compressor 402 in FIG. 4.



FIG. 7 illustrates the system of FIG. 6 reconfigured slightly to allow for operation in winter heating mode. The heat source 609 now provides hot heat transfer fluid to the conditioner module 503 through lines 701. As a result the supply air to the space 504 will be warm and humid. It is also possible to provide hot heat transfer fluid 703 to the indirect evaporative cooler 602 and to direct the hot, humid exhaust air 702 to the space rather than to the outside. This increases the available heating and humidification capacity of the system since both the conditioner 503 and the indirect evaporative “cooler” 602 (or “heater” may be a better moniker) are operating to provide the same hot humid air and this can be handy since heating capacity in winter typically needs to be larger than cooling capacity in summer.



FIG. 8 shows an embodiment of the system of FIG. 5A. The air intake 801 allows for air from space 805 to enter the conditioner unit 503 (not shown). The air supply exits from roster 803 into the space. A flat screen television 802 or painting, or monitor or any other suitable device can be used to visually hide the conditioner 503. An external wall 804 would be a logical place to mount the conditioner system. A regenerator and chiller system 807 can be mounted in a convenient outside location 806. Desiccant supply and return lines 809 and cold heat transfer fluid supply and return lines 808 connect the two sides of the system.



FIG. 9A shows a cut-away view of the rear side of the system in FIG. 8. The regenerator module 522 receives liquid desiccant from lines 809. A compressor 511 an expansion valve 516 and two refrigerant to liquid heat exchangers 507 and 515 are also shown. Other components have not been shown for convenience.



FIG. 9B shows a cut-away view of the front side of the system in FIG. 8. The flat screen TV 802 has been omitted to allow a view of the conditioner module 503.



FIG. 10 shows an aspect of an embodiment of the system of FIG. 6. The system has an air intake 801 and a supply roster 803 similar to the system of FIG. 8. As in FIG. 8, a TV 802 or something similar can be used to cover the conditioner module 503. The unit can be mounted to wall 804 and provide conditioning of the space 805. The system also has an exhaust 606 that penetrates the wall 804. On the outside 806, the regenerator module 902 provides concentrated liquid desiccant to the conditioner section (not shown) through desiccant supply and return lines 809. A water supply line 901 is also shown. A source of hot heat transfer fluid can be the solar PVT module 903 which provides hot water through line 905 which after being cooled through the regenerator returns heat transfer fluid to the PVT module 903 through line 904. An integrated hot water storage tank 906 can provide both a hot water buffer as well as a ballast for the PVT module 903.



FIG. 11 shows a cut-away view of the system of FIG. 10. The conditioner module 503 can be clearly seen as can the indirect evaporator module 602. Inside the regenerator module 902 one can see the regenerator module 522 as well as the optional heat dump 614 and fan 612.



FIG. 12 illustrates a structure 809 for the supply and return of the liquid desiccant to the indoor conditioning unit. The structure comprises a polymer material such as for example an extruded High Density Polypropylene or High Density Polyethylene material the comprises two passages 1201 and 1202 for the supply and return of desiccant respectively. The wall 1203 between the two passages could be manufactured from a thermally conductive polymer, but in many cases that may not be necessary because the length of the structure 809 is by itself sufficient to provide adequate heat exchange capacity between the supply and return liquids.


Having thus described several illustrative embodiments, it is to be appreciated that various alterations, modifications, and improvements will readily occur to those skilled in the art. Such alterations, modifications, and improvements are intended to form a part of this disclosure, and are intended to be within the spirit and scope of this disclosure. While some examples presented herein involve specific combinations of functions or structural elements, it should be understood that those functions and elements may be combined in other ways according to the present disclosure to accomplish the same or different objectives. In particular, acts, elements, and features discussed in connection with one embodiment are not intended to be excluded from similar or other roles in other embodiments. Additionally, elements and components described herein may be further divided into additional components or joined together to form fewer components for performing the same functions. Accordingly, the foregoing description and attached drawings are by way of example only, and are not intended to be limiting.

Claims
  • 1. A split liquid desiccant air conditioning system for cooling and dehumidifying an air stream flowing into a space in a building, the split liquid desiccant air conditioning system comprising: a conditioner located inside the building, said conditioner including a plurality of first structures, each first structure having at least one surface across which a liquid desiccant flows, each first structure including a passage through which a heat transfer fluid flows, wherein the air stream flows between the first structures such that the liquid desiccant dehumidifies and cools the air stream, the conditioner further comprising a sheet of material positioned proximate to the at least one surface of each first structure between the liquid desiccant and the air stream, said sheet of material permitting transfer of water vapor between the liquid desiccant and the air stream;a regenerator located outside the building connected to the conditioner by liquid desiccant pipes for exchanging the liquid desiccant with the conditioner, said regenerator including a plurality of second structures, each second structure having at least one surface across which the liquid desiccant flows, each second structure including a passage through which the heat transfer fluid flows, said regenerator causing the liquid desiccant to desorb water to an air stream flowing through the regenerator;an indirect evaporative cooling unit coupled to the conditioner for receiving the heat transfer fluid that has flowed through the first structures and a portion of the air stream that has been dehumidified and cooled by the conditioner, said indirect evaporative cooling unit including a plurality of third structures arranged in a substantially vertical orientation, each third structure having at least one surface across which water is flowed, each third structure including a passage through which the heat transfer fluid from the conditioner is flowed, wherein the portion of the air stream received from the conditioner flows between the third structures such that the water is evaporated by the air stream, resulting in cooling of the heat transfer fluid which is returned to the conditioner, and wherein the air stream treated by the indirect evaporative cooling unit is exhausted to the atmosphere;an apparatus for moving the air stream through the conditioner and the indirect evaporative cooling unit;an apparatus for circulating the liquid desiccant through the conditioner and regenerator; andan apparatus for circulating the heat transfer fluid through the conditioner and the indirect evaporative cooling unit; anda heat source for heating the heat transfer fluid in the regenerator.
  • 2. The system of claim 1, wherein the liquid desiccant pipes comprise a first pipe for transferring the liquid desiccant from the conditioner to the regenerator and a second pipe for transferring the liquid desiccant from the regenerator to the conditioner, wherein the first and second pipes are in close contact to facilitate heat transfer from the liquid desiccant flowing in one of the first and second pipes to the liquid desiccant flowing in another of the first and second pipes.
  • 3. The system of claim 2, wherein the first and second pipes comprise an integrally formed structure.
  • 4. The system of claim 3, wherein the integrally formed structure comprises a polymer material.
  • 5. The system of claim 4, wherein at least a wall of the integrally formed structure between the first and second pipes comprises a thermally conductive polymer.
  • 6. The system of claim 1, wherein the conditioner is mounted on a wall inside the building.
  • 7. The system of claim 1, wherein the conditioner has a flat configuration adapted to be hidden behind a computer display, television, or painting.
  • 8. The system of claim 1, wherein the indirect evaporative cooling unit is located inside the building.
  • 9. The system of claim 1, wherein the indirect evaporative cooling unit is located outside the building.
  • 10. The system of claim 1, wherein the heat source for heating the heat transfer fluid in the regenerator comprises a gas water heater, a solar module, a solar thermal/photovoltaic module, or a steam loop.
  • 11. A split liquid desiccant air conditioning system for heating and humidifying an air stream flowing into a space in a building, the split liquid desiccant air conditioning system comprising: a conditioner located inside the building, said conditioner including a plurality of first structures, each first structure having at least one surface across which a liquid desiccant flows, each first structure including a passage through which a heat transfer fluid flows, wherein the air stream flows between the first structures such that the liquid desiccant humidifies and heats the air stream, the conditioner further comprising a sheet of material positioned proximate to the at least one surface of each first structure between the liquid desiccant and the air stream, said sheet of material permitting transfer of water vapor between the liquid desiccant and the air stream;a regenerator located outside the building connected to the conditioner by liquid desiccant pipes for exchanging the liquid desiccant with the conditioner, said regenerator including a plurality of second structures, each second structure having at least one surface across which the liquid desiccant flows, each second structure including a passage through which the heat transfer fluid flows, said regenerator causing the liquid desiccant to absorb water from an air stream flowing through the regenerator;an indirect evaporative cooling unit coupled to the conditioner for receiving the heat transfer fluid that has flowed through the first structures and a portion of the air stream that has been humidified and heated by the conditioner, said indirect evaporative cooling unit including a plurality of third structures arranged, each third structure having at least one surface across which water is flowed, each third structure including a passage through which the heat transfer fluid from the conditioner is flowed, wherein the portion of the air stream received from the conditioner flows between the third structures such that the water vapor is evaporated from the water, resulting in humidification of the air stream, and wherein the air stream treated by the indirect evaporative cooling unit is exhausted inside the building;an apparatus for moving the air stream through the conditioner and the indirect evaporative cooling unit;an apparatus for circulating the liquid desiccant through the conditioner and regenerator; andan apparatus for circulating the heat transfer fluid through the conditioner and the indirect evaporative cooling unit; anda heat source for heating the heat transfer fluid in the conditioner and the indirect evaporative cooling unit.
  • 12. The system of claim 11, wherein the liquid desiccant pipes comprise a first pipe for transferring the liquid desiccant from the conditioner to the regenerator and a second pipe for transferring the liquid desiccant from the regenerator to the conditioner, wherein the first and second pipes are in close contact to facilitate heat transfer from the liquid desiccant flowing in one of the first and second pipes to the liquid desiccant flowing in another of the first and second pipes.
  • 13. The system of claim 12, wherein the first and second pipes comprise an integrally formed structure.
  • 14. The system of claim 13, wherein the integrally formed structure comprises a polymer material.
  • 15. The system of claim 14, wherein at least a wall of the integrally formed structure between the first and second pipes comprises a thermally conductive polymer.
  • 16. The system of claim 11, wherein the conditioner is mounted on a wall inside the building.
  • 17. The system of claim 11, wherein the conditioner has a flat configuration adapted to be hidden behind a computer display, television, or painting.
  • 18. The system of claim 11, wherein the indirect evaporative cooling unit is located inside the building.
  • 19. The system of claim 11, wherein the indirect evaporative cooling unit is located outside the building.
  • 20. The system of claim 11, wherein the heat source for heating the heat transfer fluid in the conditioner and the indirect evaporative cooling unit comprises a gas water heater, a solar module, a solar thermal/photovoltaic module, or a steam loop.
CROSS REFERENCE TO RELATED APPLICATIONS

This application is a divisional of U.S. patent application Ser. No. 14/212,097 filed on Mar. 14, 2014 entitled METHODS AND SYSTEMS FOR MINI-SPLIT LIQUID DESICCANT AIR CONDITIONING, which claims priority from U.S. Provisional Patent Application No. 61/783,176 filed on Mar. 14, 2013 entitled METHODS AND SYSTEMS FOR MINI-SPLIT LIQUID DESICCANT AIR CONDITIONING, both of which applications are hereby incorporated by reference.

US Referenced Citations (311)
Number Name Date Kind
1791086 Sperr Feb 1931 A
2221787 Downs et al. Nov 1940 A
2235322 Martin Mar 1941 A
2433741 Crawford Dec 1947 A
2634958 Simpelaar Apr 1953 A
2660159 Hughes Nov 1953 A
2708915 Mandelburg May 1955 A
2939686 Wildermuth Jun 1960 A
2988171 Arnold et al. Jun 1961 A
3119446 Weiss Jan 1964 A
3193001 Meckler Jul 1965 A
3276634 Arnot Oct 1966 A
3409969 Simons Nov 1968 A
3410581 Christensen Nov 1968 A
3455338 Pollit Jul 1969 A
3718181 Reilly et al. Feb 1973 A
4100331 Fletcher et al. Jul 1978 A
4164125 Griffiths Aug 1979 A
4176523 Rousseau Dec 1979 A
4205529 Ko Jun 1980 A
4209368 Coker et al. Jun 1980 A
4222244 Meckler Sep 1980 A
4235221 Murphy Nov 1980 A
4239507 Benoit et al. Dec 1980 A
4259849 Griffiths Apr 1981 A
4324947 Dumbeck Apr 1982 A
4399862 Hile Aug 1983 A
4429545 Steinberg Feb 1984 A
4435339 Kragh Mar 1984 A
4444992 Cox, III Apr 1984 A
4583996 Sakata et al. Apr 1986 A
4607132 Jarnagin Aug 1986 A
4612019 Langhorst Sep 1986 A
4649899 Moore Mar 1987 A
4660390 Worthington Apr 1987 A
4691530 Meckler Sep 1987 A
4703629 Moore Nov 1987 A
4730600 Harrigill Mar 1988 A
4744414 Schon May 1988 A
4766952 Onodera Aug 1988 A
4786301 Rhodes Nov 1988 A
4832115 Albers et al. May 1989 A
4872578 Fuerschbach et al. Oct 1989 A
4882907 Brown, II Nov 1989 A
4887438 Meckler Dec 1989 A
4900448 Bonne et al. Feb 1990 A
4910971 McNab Mar 1990 A
4939906 Spatz et al. Jul 1990 A
4941324 Peterson et al. Jul 1990 A
4955205 Wilkinson Sep 1990 A
4971142 Mergler Nov 1990 A
4976313 Dahlgren et al. Dec 1990 A
4979965 Sannholm Dec 1990 A
4984434 Peterson Jan 1991 A
4987750 Meckler Jan 1991 A
5005371 Yonezawa et al. Apr 1991 A
5181387 Meckler Jan 1993 A
5182921 Yan Feb 1993 A
5186903 Cornwell Feb 1993 A
5191771 Meckler Mar 1993 A
5221520 Cornwell Jun 1993 A
5351497 Lowenstein Oct 1994 A
5361828 Lee et al. Nov 1994 A
5375429 Tokizaki et al. Dec 1994 A
5448895 Coellner et al. Sep 1995 A
5462113 Wand Oct 1995 A
5471852 Meckler Dec 1995 A
5528905 Scarlatti Jun 1996 A
5534186 Walker et al. Jul 1996 A
5582026 Barto, Sr. Dec 1996 A
5595690 Filburn et al. Jan 1997 A
5605628 Davidson et al. Feb 1997 A
5606865 Caron Mar 1997 A
5638900 Lowenstein et al. Jun 1997 A
5641337 Arrowsmith et al. Jun 1997 A
5661983 Groten et al. Sep 1997 A
5685152 Sterling Nov 1997 A
5685485 Mock et al. Nov 1997 A
5797272 James Aug 1998 A
5816065 Maeda Oct 1998 A
5832993 Ohata et al. Nov 1998 A
5860284 Goland et al. Jan 1999 A
5860285 Tulpule Jan 1999 A
5928808 Eshraghi Jul 1999 A
5933702 Goswami Aug 1999 A
5950442 Maeda Sep 1999 A
6012296 Shah Jan 2000 A
6018954 Assaf Feb 2000 A
6035657 Dobak, III et al. Mar 2000 A
6083387 LeBlanc et al. Jul 2000 A
6103969 Bussey Aug 2000 A
6131649 Pearl et al. Oct 2000 A
6134903 Potnis Oct 2000 A
6138470 Potnis et al. Oct 2000 A
6156102 Conrad et al. Dec 2000 A
6171374 Barton et al. Jan 2001 B1
6216483 Potnis et al. Apr 2001 B1
6216489 Potnis et al. Apr 2001 B1
6244062 Prado Jun 2001 B1
6247604 Taskis et al. Jun 2001 B1
6266975 Assaf Jul 2001 B1
6417423 Koper et al. Jul 2002 B1
6442951 Maeda et al. Sep 2002 B1
6463750 Assaf Oct 2002 B2
6487872 Forkosh et al. Dec 2002 B1
6488900 Call et al. Dec 2002 B1
6497107 Maisotsenko et al. Dec 2002 B2
6497749 Kesten et al. Dec 2002 B2
6502807 Assaf et al. Jan 2003 B1
6514321 Lehto et al. Feb 2003 B1
6539731 Kesten et al. Apr 2003 B2
6546746 Forkosh et al. Apr 2003 B2
6557365 Dinnage et al. May 2003 B2
6660069 Sato et al. Dec 2003 B2
6684649 Thompson Feb 2004 B1
6739142 Korin May 2004 B2
6745826 Lowenstein et al. Jun 2004 B2
6766817 da Silva et al. Jul 2004 B2
6848265 Lowenstein et al. Feb 2005 B2
6854278 Maisotsenko et al. Feb 2005 B2
6854279 Digiovanni et al. Feb 2005 B1
6918404 Dias da Silva et al. Jul 2005 B2
6938434 Fair Sep 2005 B1
6945065 Lee et al. Sep 2005 B2
6976365 Forkosh Dec 2005 B2
6986428 Hester et al. Jan 2006 B2
7066586 da Silva et al. Jun 2006 B2
RE39288 Assaf Sep 2006 E
7143597 Hyland et al. Dec 2006 B2
7191821 Gronwall et al. Mar 2007 B2
7197887 Maisotsenko et al. Apr 2007 B2
7228891 Shin et al. Jun 2007 B2
7258923 van den Bogerd et al. Aug 2007 B2
7269966 Lowenstein et al. Sep 2007 B2
7279215 Hester et al. Oct 2007 B2
7306650 Slayzak et al. Dec 2007 B2
7337615 Reidy Mar 2008 B2
7430878 Assaf Oct 2008 B2
7758671 Kesten et al. Jul 2010 B2
7930896 Matsui et al. Apr 2011 B2
7938888 Assaf May 2011 B2
8141379 Al-Hadhrami Mar 2012 B2
8337590 Herencia et al. Dec 2012 B2
8353175 Wohlert Jan 2013 B2
8496732 Culp et al. Jul 2013 B2
8499576 Meijer Aug 2013 B2
8500960 Ehrenberg et al. Aug 2013 B2
8623210 Manabe et al. Jan 2014 B2
8641806 Claridge et al. Feb 2014 B2
8648209 Lastella Feb 2014 B1
8695363 Tang et al. Apr 2014 B2
8696805 Chang et al. Apr 2014 B2
8769971 Kozubal et al. Jul 2014 B2
8790454 Lee et al. Jul 2014 B2
8800308 Vandermeulen et al. Aug 2014 B2
8876943 Gottlieb et al. Nov 2014 B2
8881806 Xie et al. Nov 2014 B2
8943844 Forkosh Feb 2015 B2
8943850 Vandermeulen et al. Feb 2015 B2
8968945 Fasold et al. Mar 2015 B2
9000289 Vandermeulen et al. Apr 2015 B2
9086223 Vandermeulen et al. Jul 2015 B2
9101874 Vandermeulen Aug 2015 B2
9101875 Vandermeulen et al. Aug 2015 B2
9243810 Vandermeulen et al. Jan 2016 B2
9273877 Vandermeulen et al. Mar 2016 B2
9308490 Vandermeulen et al. Apr 2016 B2
9377207 Vandermeulen et al. Jun 2016 B2
9429332 Vandermeulen et al. Aug 2016 B2
9470426 Vandermeulen Oct 2016 B2
9506697 Vandermeulen Nov 2016 B2
9631823 Vandermeulen et al. Apr 2017 B2
9631848 Vandermeulen et al. Apr 2017 B2
9709285 Vandermeulen Jul 2017 B2
9709286 Vandermeulen et al. Jul 2017 B2
9835340 Vandermeulen et al. Dec 2017 B2
10006648 Vandermeulen et al. Jun 2018 B2
10024558 Vandermeulen Jul 2018 B2
10024601 Vandermeulen Jul 2018 B2
10168056 Vandermeulen Jan 2019 B2
10323867 Vandermeulen Jun 2019 B2
20010008148 Ito et al. Jul 2001 A1
20010013226 Potnis Aug 2001 A1
20010015500 Shimanuki et al. Aug 2001 A1
20020023740 Lowenstein et al. Feb 2002 A1
20020026797 Sundhar Mar 2002 A1
20020038552 Maisotsenko et al. Apr 2002 A1
20020098395 Shimanuki et al. Jul 2002 A1
20020104439 Komkova et al. Aug 2002 A1
20020139245 Kesten et al. Oct 2002 A1
20020139320 Shimanuki et al. Oct 2002 A1
20020148602 Nakamura Oct 2002 A1
20030000230 Kopko Jan 2003 A1
20030029185 Kopko Feb 2003 A1
20030033821 Maisotsenko et al. Feb 2003 A1
20030051498 Sanford Mar 2003 A1
20030106680 Serpico et al. Jun 2003 A1
20030121271 Dinnage et al. Jul 2003 A1
20030230092 Lowenstein et al. Dec 2003 A1
20040040697 Pierre et al. Mar 2004 A1
20040061245 Maisotsenko et al. Apr 2004 A1
20040101698 Yamanaka et al. May 2004 A1
20040109798 Chopard et al. Jun 2004 A1
20040112077 Forkosh Jun 2004 A1
20040118125 Potnis et al. Jun 2004 A1
20040134212 Lee et al. Jul 2004 A1
20040168462 Assaf Sep 2004 A1
20040194944 Hendricks et al. Oct 2004 A1
20040211207 Forkosh et al. Oct 2004 A1
20040230092 Thierfelder et al. Nov 2004 A1
20040231512 Slayzak et al. Nov 2004 A1
20040261440 Forkosh et al. Dec 2004 A1
20050095433 Bogerd et al. May 2005 A1
20050106021 Bunker et al. May 2005 A1
20050109052 Albers et al. May 2005 A1
20050133082 Konold et al. Jun 2005 A1
20050210907 Gillan et al. Sep 2005 A1
20050217485 Olapinski et al. Oct 2005 A1
20050218535 Maisotsenko et al. Oct 2005 A1
20050257551 Landry Nov 2005 A1
20060042295 Assaf Mar 2006 A1
20060070728 Shin et al. Apr 2006 A1
20060124287 Reinders Jun 2006 A1
20060156750 Lowenstein et al. Jul 2006 A1
20060156761 Mola et al. Jul 2006 A1
20060278089 Theilow Dec 2006 A1
20070169916 Wand et al. Jul 2007 A1
20070175234 Pruitt Aug 2007 A1
20070234743 Assaf Oct 2007 A1
20080127965 Burton Jun 2008 A1
20080156471 Han et al. Jul 2008 A1
20080196758 McGuire Aug 2008 A1
20080203866 Chamberlain Aug 2008 A1
20080302357 DeNault Dec 2008 A1
20080314567 Noren Dec 2008 A1
20090000732 Jacobine et al. Jan 2009 A1
20090056919 Hoffman et al. Mar 2009 A1
20090095162 Hargis et al. Apr 2009 A1
20090126913 Lee et al. May 2009 A1
20090173096 Wohlert Jul 2009 A1
20090183857 Pierce et al. Jul 2009 A1
20090200022 Bravo et al. Aug 2009 A1
20090238685 Santa Ana Sep 2009 A1
20100000247 Bhatti et al. Jan 2010 A1
20100012309 Uges Jan 2010 A1
20100018322 Neitzke et al. Jan 2010 A1
20100051083 Boyk Mar 2010 A1
20100077783 Bhatti et al. Apr 2010 A1
20100084120 Yin et al. Apr 2010 A1
20100170776 Ehrenberg et al. Jul 2010 A1
20100319370 Kozubal et al. Dec 2010 A1
20110073290 Chang et al. Mar 2011 A1
20110100618 Carlson May 2011 A1
20110101117 Miyauchi et al. May 2011 A1
20110126885 Kokotov et al. Jun 2011 A1
20110132027 Gommed et al. Jun 2011 A1
20120052785 Nagamatsu et al. Mar 2012 A1
20120114527 Hoglund et al. May 2012 A1
20120118148 Culp et al. May 2012 A1
20120118155 Claridge et al. May 2012 A1
20120125020 Vandermeulen May 2012 A1
20120125021 Vandermeulen et al. May 2012 A1
20120125031 Vandermeulen et al. May 2012 A1
20120125581 Allen et al. May 2012 A1
20120131937 Vandermeulen et al. May 2012 A1
20120131938 Vandermeulen et al. May 2012 A1
20120131939 Vandermeulen et al. May 2012 A1
20120132513 Vandermeulen et al. May 2012 A1
20120152318 Kee Jun 2012 A1
20120186281 Vandermeulen et al. Jul 2012 A1
20130056177 Coutu et al. Mar 2013 A1
20130101909 Fasold et al. Apr 2013 A1
20130186121 Erb et al. Jul 2013 A1
20130199220 Ma et al. Aug 2013 A1
20130227982 Forkosh Sep 2013 A1
20130255287 Forkosh Oct 2013 A1
20130340449 Kozubal et al. Dec 2013 A1
20140054004 LePoudre et al. Feb 2014 A1
20140054013 LePoudre et al. Feb 2014 A1
20140150481 Vandermeulen Jun 2014 A1
20140150656 Vandermeulen Jun 2014 A1
20140150657 Vandermeulen et al. Jun 2014 A1
20140150662 Vandermeulen et al. Jun 2014 A1
20140223947 Ranjan et al. Aug 2014 A1
20140245769 Vandermeulen et al. Sep 2014 A1
20140250935 Prochaska et al. Sep 2014 A1
20140260367 Coutu et al. Sep 2014 A1
20140260369 LePoudre Sep 2014 A1
20140260371 Vandermeulen Sep 2014 A1
20140260398 Kozubal et al. Sep 2014 A1
20140260399 Vandermeulen Sep 2014 A1
20140262125 Erb et al. Sep 2014 A1
20140262144 Erb et al. Sep 2014 A1
20140264968 Erb et al. Sep 2014 A1
20140360373 Peacos et al. Dec 2014 A1
20140366567 Vandermeulen Dec 2014 A1
20150107287 Forkosh Apr 2015 A1
20150184876 Vandermeulen et al. Jul 2015 A1
20150300754 Vandermeulen et al. Oct 2015 A1
20150323216 Wallin Nov 2015 A1
20150338140 Vandermeulen Nov 2015 A1
20160187011 Vandermeulen Jun 2016 A1
20160290665 Vandermeulen et al. Oct 2016 A1
20170074530 Kozubal Mar 2017 A1
20170102155 Vandermeulen Apr 2017 A1
20170106639 Vandermeulen et al. Apr 2017 A1
20170167794 Vandermeulen Jun 2017 A1
20170184319 Vandermeulen et al. Jun 2017 A1
20170292722 Vandermeulen Oct 2017 A1
20180051897 Vandermeulen et al. Feb 2018 A1
20180163977 Vandermeulen Jun 2018 A1
Foreign Referenced Citations (74)
Number Date Country
100366981 Feb 2008 CN
101336358 Dec 2008 CN
100476308 Apr 2009 CN
101636630 Jan 2010 CN
102282426 Dec 2011 CN
202229469 May 2012 CN
0781972 Jul 1997 EP
1120609 Aug 2001 EP
1563229 Aug 2005 EP
1781995 May 2007 EP
2256434 Dec 2010 EP
2306100 Apr 2011 EP
2787293 Oct 2014 EP
1172247 Nov 1969 GB
S54-77443 Jun 1979 JP
S62-297647 Dec 1987 JP
02306067 Dec 1990 JP
H03-125830 May 1991 JP
H03-213921 Sep 1991 JP
H08-105669 Apr 1996 JP
H09-184692 Jul 1997 JP
H10-220914 Aug 1998 JP
H11-137948 May 1999 JP
H11-197439 Jul 1999 JP
H11-351700 Dec 1999 JP
2000-230730 Aug 2000 JP
2001-517773 Oct 2001 JP
2002-206834 Jul 2002 JP
2004-524504 Aug 2004 JP
2005-134060 May 2005 JP
2006-263508 Oct 2006 JP
2006-529022 Dec 2006 JP
2008-020138 Jan 2008 JP
2009-517622 Apr 2009 JP
04273555 Jun 2009 JP
2009-180433 Aug 2009 JP
2009-192101 Aug 2009 JP
2009-281668 Dec 2009 JP
2009-293831 Dec 2009 JP
201054136 Mar 2010 JP
2010-247022 Nov 2010 JP
2011064359 Mar 2011 JP
2011-511244 Apr 2011 JP
201192815 May 2011 JP
2011-163682 Aug 2011 JP
2012-073013 Apr 2012 JP
2013-064549 Apr 2013 JP
10-2001-0017939 Mar 2001 KR
2004-0026242 Mar 2004 KR
10-0510774 Aug 2005 KR
2014-0022785 Feb 2014 KR
201009269 Mar 2010 TW
WO-1997021061 Jun 1997 WO
WO-1999022180 May 1999 WO
WO-2000011426 Mar 2000 WO
WO-2000055546 Sep 2000 WO
WO-2002066901 Aug 2002 WO
WO-2002086391 Oct 2002 WO
WO-2003004937 Jan 2003 WO
WO-2004046618 Jun 2004 WO
WO-2006006177 Jan 2006 WO
WO-2008037079 Apr 2008 WO
WO-2009094032 Jul 2009 WO
WO-2009144880 Dec 2009 WO
WO-2009157277 Dec 2009 WO
WO-2011062808 May 2011 WO
WO-2011150081 Dec 2011 WO
WO-2011161547 Dec 2011 WO
WO-2012071036 May 2012 WO
WO-2012082093 Jun 2012 WO
WO-2013172789 Nov 2013 WO
WO-2014152905 Sep 2014 WO
WO-2014201281 Dec 2014 WO
WO-2015077364 May 2015 WO
Non-Patent Literature Citations (25)
Entry
Lachner, “An Investigation into the Feasibility of the Use of Water as a Refrigerant,” International Refrigeration and Air Conditioning Conference, 723:1-9 (2004).
Refrigerant—Random House Kernerman Webster's College Dictionary, “Refrigerant,” Random House, <https://thefreedictionary.com/refrigerant> (2010).
1—Open Absorption System for Cooling and Air Conditioning using Membrane Contactors—Annual Report 2005, Publication No. Publication 260097, Project: 101310—Open Absorption System for Cooling and Air Conditioning using Membrane Contactors, Date of publication: Jan. 31, 2006, Author: Manuel Conde-Petit, Robert Weber, Contractor: M. Conde Engineering.
3—Open Absorption System for Cooling and Air Conditioning Using Membrane Contactors—Final Report, Publication No. Publication 280139, Project: 101310—Open Absorption System for Cooling and Air Conditioning using Membrane Contactors, Date of publication: Jul. 8, 2008, Author: Viktor Dorer, Manuel Conde-Petit, Robert Weber, Contractor: M. Conde Engineering.
2—Open Absorption System for Cooling and Air Conditioning using Membrane Contactors—Annual, Report 2006, Publication No. Publication 260098, Project: 101310—Open Absorption System for Cooling and Air Conditioning using Membrane Contactors, Date of publication: Nov. 14, 2006, Author: Manuel Conde-Petit, Robert Weber, Contractor: M. Conde Engineering.
4—Conde-Petit, M. 2007. Liquid Desiccant-Based Air-Conditioning Systems—LDACS, Proc. of the 1st European Conference on Polygeneration—Technologies and Applications, 217-234, A. Coronas, ed., Tarragona-Spain, Oct. 16-17, Published by CREVER—Universitat Rovira I Virgili, Tarragona, Spain.
5—Conde-Petit, M. 2008. Open Absorption Systems for Air-Conditioning using Membrane Contactors,Proceedings '15. Schweizerisches Status-Seminar «Energie- and Umweltforschung im Bauwesen»', Sep. 11-12—ETH Zurich, Switzerland. Published by BRENET—Eggwilstr. 16a, CH-9552 Bronschhofen—Switzerland (brenet@vogel-tech.ch).
6—Third Party Observations for PCT/US2011/037936, dated Sep. 24, 2012.
Ashrae, et al., “Desiccant Dehumidification and Pressue Drying Equipment,” 2012 ASHRAE Handbook—HVAC Systems and Equipment, Chapter 24, pp. 24.1-24.12.
Beccali, et al., “Energy and Economic Assessment of Desiccant Cooling,” Solar Energy, Issue 83, pp. 1828-1846, Aug. 2009.
Fimbres-Weihs, et al., “Review of 3D CFD modeling of flow and mass transfer in narrow spacer-filled channels in membrane modules,” Chemical Engineering and Processing 49 (2010) pp. 759-781.
Li, F., et al., “Novel spacers for mass transfer enhancement in membrane separations,” Journal of Membrane Science, 253 (2005), pp. 1-12.
Li, Y., et al., “CFD simulation of fluid flow through spacer-filled membrane module: selecting suitable cell types for periodic boundary conditions,” Desalination 233 (2008) pp. 351-358.
Liu, et al., “Research Progress in Liquid Desiccant Air Conditioning Devices and Systems,” Frontiers of Energy and Power Engineering in China, vol. 4, Issue 1, pp. 55-65, Feb. 2010.
Lowenstein, “A Solar Liquid-Desiccant Air Conditioner,” Solar 2003, Proceedings of the 32nd ASES Annual Conference, Austin, TX, Jul. 2003.
Mathioulakis, “Desalination by Using Alternative Energy,” Desalination, Issue 203, pp. 346-365, 2007.
Russell, et al., “Optimization of Photovolatic Thermal Collector Heat Pump Systems,” ISES International Solar Energy Conference, Atlanta, GA, vol. 3, pp. 1870-1874, May 1979.
Perry “Perry's Chemical Engineers handbook” 1999 McGraw Hill p. 11-52,11-53.
“Siphon.” Encyclopedia Americana. Grolier Online, 2015. Web. Apr. 3, 2015. 1 page.
Welty, “Liquid Desiccant Dehumidification,” Engineered Systems, May 2010, vol. 27 Issue 5, p. 34.
International Search Report and Written Opinion for PCT/US2014/028184, dated Aug. 6, 2014.
European Search Report for EP14769878.1, dated Nov. 24, 2016.
Chinese Patent Application 201480014508.5, Office Action dated Aug. 26, 2016.
Korean Patent Application 10-2015-7025386, Office Action dated Feb. 22, 2017.
Korean Patent Application 10-2015-7025386, Office Action dated Aug. 22, 2017.
Related Publications (1)
Number Date Country
20180163977 A1 Jun 2018 US
Provisional Applications (1)
Number Date Country
61783176 Mar 2013 US
Divisions (1)
Number Date Country
Parent 14212097 Mar 2014 US
Child 15880275 US