Glass parts used in a vehicle as a windshield, window, or the like often need to be curved to a specific degree before being included in the vehicle. Curving or bending the glass assembly can include exposing the glass part to an amount of heat that will cause the glass part to bend. If the heat applied to the glass part and other aspects of the forming are not properly controlled, defects may be imparted to the glass part or other deficiencies such as laminate separation can result. These defects and/or deficiencies can result in poor geometrical match to specification, poor optics quality and other undesirable properties.
The present disclosure provides a method for bending a glass substrate comprising at least a first ply substrate of a first composition and a second ply substrate of a second composition. The first ply substrate can have a thickness that differs from a thickness of the second ply substrate. The method can optionally comprise any one or any combination of: heating the glass laminate structure comprising at least the first ply substrate and the second ply substrate; engaging an edge portion of one or both of a first major surface and a second major surface of the glass laminate structure; and subsequent to engaging the edge portion, pressing the glass laminate structure to bend the glass laminate structure and obtain a desired curvature of the glass laminate structure along one or both of the first major surface and the second major surface.
The present disclosure provides a method of bending a glass substrate comprising only a first ply substrate of a first composition and a second ply substrate of a second composition. The first ply substrate can have a thickness that differs from a thickness of the second ply substrate. The method can optionally comprise any one or any combination of: heating the glass laminate structure; engaging a first major surface with a press mold to bend the glass laminate structure and obtain a desired curvature of the glass laminate structure along one or both of a first major surface and a second major surface; and pressure forming the glass laminate structure against the press mold with a compressed gas applied to the second major surface of the glass laminate structure.
The present disclosure further provides a system for bending a glass substrate. The system optionally includes any one or combination of a contour ring configured to extend along an x-direction and a y-direction of the glass laminate structure and configured to engage an edge portion of a first major surface of the glass laminate structure; a support ring extending along the x-direction and the y-direction of the glass laminate structure and comprising a support for the glass laminate structure along an edge portion of a second major surface of the glass laminate structure opposing the edge portion of the first major surface; and a press mold configured to engage a remainder of one of the first major surface or the second major surface outside the edge portion; wherein the contour ring is configured to be moveable relative to the press mold to selectively engage the edge portion of the first major surface of the glass laminate structure independent of the press mold.
The present disclosure further provides a glass laminate structure that is a windshield for a vehicle. The glass laminate structure can optionally comprise: a first curved glass substrate comprising a soda lime silicate glass, alkali aluminosilicate glass, alkali containing borosilicate glass, alkali aluminophosphosilicate glass, alkali aluminoborosilicate glass, or a mixture thereof, wherein the first glass substrate has a first thickness in a range from about 1.5 mm to about 10 mm; and a second curved glass substrate comprising one of a chemically strengthened glass or glass-ceramic material, and wherein the second glass substrate has a second thickness is in a range of from about 0.1 mm to about 1.7 mm.
The drawings illustrate generally, by way of example, but not by way of limitation, various embodiments discussed in the present document.
Reference will now be made in detail to certain embodiments of the disclosed subject matter, examples of which are illustrated in part in the accompanying drawings. While the disclosed subject matter will be described in conjunction with the enumerated claims, it will be understood that the exemplified subject matter is not intended to limit the claims to the disclosed subject matter.
Throughout this document, values expressed in a range format should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a range of “about 0.1% to about 5%” or “about 0.1% to 5%” should be interpreted to include not just about 0.1% to about 5%, but also the individual values (e.g., 1%, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.1% to 0.5%, 1.1% to 2.2%, 3.3% to 4.4%) within the indicated range. The statement “about X to Y” has the same meaning as “about X to about Y,” unless indicated otherwise. Likewise, the statement “about X, Y, or about Z” has the same meaning as “about X, about Y, or about Z,” unless indicated otherwise.
In this document, the terms “a,” “an,” or “the” are used to include one or more than one unless the context clearly dictates otherwise. The term “or” is used to refer to a nonexclusive “or” unless otherwise indicated. The statement “at least one of A and B” has the same meaning as “A, B, or A and B.” In addition, it is to be understood that the phraseology or terminology employed herein, and not otherwise defined, is for the purpose of description only and not of limitation. Any use of section headings is intended to aid reading of the document and is not to be interpreted as limiting; information that is relevant to a section heading may occur within or outside of that particular section.
In the methods described herein, the acts can be carried out in any order without departing from the principles of the disclosure, except when a temporal or operational sequence is explicitly recited. Furthermore, specified acts can be carried out concurrently unless explicit claim language recites that they be carried out separately. For example, a claimed act of doing X and a claimed act of doing Y can be conducted simultaneously within a single operation, and the resulting process will fall within the literal scope of the claimed process.
The term “about” as used herein can allow for a degree of variability in a value or range, for example, within 10%, within 5%, or within 1% of a stated value or of a stated limit of a range, and includes the exact stated value or range.
The term “substantially” as used herein refers to a majority of, or mostly, as in at least about 50%, 60%, 70%, 80%, 90%, 95%, 96%, 97%, 98%, 99%, 99.5%, 99.9%, 99.99%, or at least about 99.999% or more, or 100%.
Although discussed in the context of a windshield, the methods and systems disclosed herein are also applicable to other components formed of glass structures such as displays, molding, trim, etc. Thus, the present disclosure should not be interpreted as limited to a windshield or even a vehicle. Similarly, the systems and methods of the present application should not be interpreted as limited to glass laminate structures only but can be used with other glass structures, glass laminate structures having further plies than the two illustrated and the like.
As shown in
The first ply substrate 106 can comprise an inner pane of the windshield 102 (
The first ply substrate 106 can have any suitable thickness T1 smaller than that of the second thickness T2 of the second ply substrate 108. For example, the first thickness T1 of the first ply substrate 106 can be in a range of from about 0.1 mm to about 1.7 mm, about 0.25 mm to about 1 mm, about 0.5 mm to about 0.75 mm, less than, equal to, or greater than about 0.1 mm, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45 . . . etc., to about 1.7 mm.
The first ply substrate 106 can comprise a glass material or a glass-ceramic material such as Gorilla Glass® that has been formed to be a strengthened material (i.e., has been chemically strengthened (e.g., ion-exchanged treated) or thermally strengthened). As used herein, the term “strengthened material” generally refers to a glass material or a glass-ceramic material that has been chemically strengthened, for example through ion-exchange of larger ions for smaller ions in the surface of the glass or glass-ceramic material. However, other strengthening methods known in the art, such as thermal tempering, can be utilized to form strengthened glass materials and/or glass-ceramic materials. For example, an option contemplates the Gorilla Glass® can be non-ion exchanged.
The strengthened material described herein with regard to the first ply substrate 106 can be chemically strengthened by an ion-exchange process. The ion-exchange process can be performed by immersion of a glass or glass-ceramic material into a molten salt bath for a predetermined period of time. Ions at or near the surface(s) of the glass or glass-ceramic material are exchanged for larger metal ions from the salt bath. In one example, the temperature of the molten salt bath is in the range from about 400° C. to about 430° C. and the predetermined time period is about four to about twenty four hours; however the temperature and duration of immersion may vary according to the composition of the material and the desired strength attributes. The incorporation of the larger ions into the glass or glass-ceramic material strengthens the material by creating a compressive stress in a near surface region or in regions at and adjacent to the surface(s) of the material. A corresponding tensile stress is induced within a central region or regions at a distance from the surface(s) of the material to balance the compressive stress. Glass or glass-ceramic materials utilizing this strengthening process can be described more specifically as chemically-strengthened or ion-exchanged glass or glass-ceramic materials.
In one example, sodium ions in a glass or glass-ceramic material such as that of the first ply substrate 106 can replaced by potassium ions from the molten bath, such as a potassium nitrate salt bath, though other alkali metal ions having larger atomic radii, such as rubidium or cesium, can replace smaller alkali metal ions in the glass. According to embodiments of the present disclosure, smaller alkali metal ions in the glass or glass-ceramic can be replaced by Ag+ ions. Similarly, other alkali metal salts such as, but not limited to, sulfates, phosphates, halides, and the like can be used in the ion exchange process.
In contrast to the first ply substrate 106, the second ply substrate 108 may not be formed of a strengthened material. Thus, suitable material glass for the second ply substrate 108 can comprise soda lime silicate glass, alkali aluminosilicate glass, alkali containing borosilicate glass, alkali aluminophosphosilicate glass, alkali aluminoborosilicate glass, or a mixture thereof. In some embodiments, the soda lime silicate glass is substantially free of iron, iron oxide, or mixtures thereof.
The second ply substrate 108 can have any suitable thickness T2 larger than that of the first thickness T1 of the first ply substrate 106. For example, the second thickness T2 of the second ply substrate 108 can be in a range of from about 1 mm to about 10 mm, about 1.5 mm to about 5 mm, about 1.75 mm to about 2.5 mm, less than, equal to, or greater than about 1.75 mm, 2, 2.5, 3, 3.5, 4, 4.5, or about 5 mm.
The support ring 202 can comprise an open frame having an opening 209 in the middle configured to receive the glass structure when bent as further described and illustrated herein. The support ring 202 can be configured to be a stationary structure. Alternatively, the support ring 202 can be configured to be a mobile structure. For example, the support ring 202 can have wheels or skids attached to a bottom surface. This can be helpful in applications where the system 200 may be moved from one location to another, such as between zones in a furnace.
The contour ring 204 can be received in a recess 212 (best illustrated in
To the end of facilitating a guided movement of the contour ring 204, the contour ring 204 can have one or more guide rods 210 or other structures configured to guide movement of the contour ring 204 relative to the press mold 206 and/or the support ring 202. These guide rods 210 can be received in and can extend through the press mold 206. Guide rods 210 can comprise handles and other features that facilitate contour ring 204 to be manipulated (moved) independent of the press mold 206 to provide a different amount and/or desired amount of force via engagement at the edge portion 110A of the glass structure than the press mold 206. The contour ring 204 can have a major surface 214 configured to engage the glass structure with the desired amount of force during the one or more of the processes discussed and further illustrated subsequently. The major surface 214 can extend along the x, y, and z directions and can be configured to provide a desired geometry such as a curvature to the edge portion 110A (
Returning to
As shown in
The press mold 206 can be powered by a hydraulic mechanism, by gravity, electronically, or manually. In some embodiments, the press mold 206 can include heating or cooling mechanisms that can, in turn, heat or cool a glass substrate to which it is positioned proximately or in contact with. In further embodiments, heating or cooling mechanisms can be used to maintain the thermal conditions in the glass substrate (e.g., to maintain a desired temperature).
As shown in
The size of the vacuum ports 220, 222 can individually be in a range of from about 0.2 mm to about 10 mm, about 2 mm to about 6 mm, less than, equal to, or greater than about 2 mm, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, or about 10 mm in diameter. Moreover, the vacuum ports 220, 222 can individually account for about 1 vol % to about 8 vol % of the press mold 206 and/or the contour ring 204, about 2 vol % to about 7 vol %, about 4 vol % to about 6 vol %, less than, equal to, or greater than about 1 vol %, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, or about 8 vol %. A cross sectional geometry of the vacuum ports 220, 222 can substantially conform to a circular shape or polygonal shape. Examples of suitable circular shapes can include an elongated or non-elongated circle. Examples of suitable polygonal shapes include a triangular shape, a quadrilateral shape, a pentagonal shape, a hexagonal shape, or any higher order polygonal shape.
As shown in
Referring now to
As an example, the glass laminate structure 104 can be heated to a temperature in a range of from about 600° C. to about 800° C., about 700° C. to about 750° C., less than, equal to, or greater than about 600, 605, 610, 615, 620, 625, 630, 635, 640, 645, 650, 655, 660, 665, 670, 675, 680, 685, 690, 695, 700, 705, 710, 715, 720, 725, 730, 735, 740, 745, 750, 755, 760, 765, 770, 775, 780, 785, 790, 795, or about 800° C.
Optionally, as shown
As a result of the methods and systems described herein, by which the glass laminate structure 104 can be formed, the glass laminate structure 104 can be formed to more precise specifications and can avoid distortions or defects such as the rippling effect as discussed herein.
As discussed previously, the glass laminate structure 104, or indeed another glass structure not specifically illustrated herein, can utilize the systems and methods disclosed herein and can be included in a vehicle such as an automobile, watercraft, or aerospace vehicle. However, as noted previously, the system and methods are not only limited to glass structures for vehicles but can be utilized in other components.
The following exemplary embodiments are provided, the numbering of which is not to be construed as designating levels of importance:
Embodiment 1 provides a method of bending a glass laminate structure, the method can optionally comprise any one or any combination of: heating the glass laminate structure comprising at least a first ply substrate and a second ply substrate, wherein the first ply substrate has a first composition and a first thickness that differ from a second composition and a second thickness of the second ply substrate; engaging an edge portion of one or both of a first major surface and a second major surface of the glass laminate structure; and subsequent to engaging the edge portion, pressing the glass laminate structure to bend the glass laminate structure and obtain a desired curvature of the glass laminate structure along one or both of the first major surface and the second major surface.
Embodiment 2 provides the method of Embodiment 1, optionally wherein engaging the edge portion comprises moving a contour ring relative to a first mold portion to apply a force on the edge portion at the first major surface of the first ply substrate.
Embodiment 3 provides the method of Embodiment 2, optionally wherein the mold further comprises a second mold portion configured as a bending ring to engage the edge portion at the second major surface of the second ply substrate.
Embodiment 4 provides the method of any one or combination of Embodiments 1-3, optionally further comprising subsequent to pressing, applying a vacuum to at least one of the edge portion, the first major surface and the second major surface.
Embodiment 5 provides the method of any one or combination of Embodiments 1-4, optionally wherein the first composition of the first ply substrate comprises soda lime silicate glass, alkali aluminosilicate glass, alkali containing borosilicate glass, alkali aluminophosphosilicate glass, alkali aluminoborosilicate glass, or a mixture thereof, and wherein the first thickness of the first ply substrate is in a range from about 1.5 mm to about 5 mm.
Embodiment 6 provides the method of any one or any combination of Embodiments 1-5, optionally wherein the second ply substrate comprises one of a chemically strengthened glass or glass-ceramic material, and wherein the second thickness is in a range of from about 0.1 mm to about 1.7 mm.
Embodiment 7 provides the method of any one or any combination of the Embodiments 1-6, optionally wherein engaging the edge portion forms a seal at the edge portion to seal a region between the first ply substrate and the second ply substrate.
Embodiment 8 provides the method of any one or any combination of Embodiments 1-7, optionally further comprising providing a compressed gas to at least one of the first major surface and the second major surface of the glass laminate structure.
Embodiment 9 provides a method of bending a glass laminate structure, the method can optionally comprise any one or any combination of: heating the glass laminate structure comprising only a first ply substrate and a second ply substrate, wherein the first ply substrate has a first composition and a first thickness that differ from a second composition and a second thickness of the second ply substrate; engaging a first major surface with a press mold to bend the glass laminate structure and obtain a desired curvature of the glass laminate structure along one or both of a first major surface and a second major surface; and pressure forming the glass laminate structure against the press mold with a compressed gas applied to the second major surface of the glass laminate structure.
Embodiment 10 provides the method of Embodiment 9, optionally further comprising: prior to engaging the first major surface with the press mold, pressing the glass laminate structure with a contour ring at an edge portion of one of the first major surface or the second major surface; wherein engaging the first major surface with the press mold comprises engaging a portion of the first major surface other than the edge portion of the glass laminate structure with the press mold.
Embodiment 11 provides the method of any one or combination of Embodiments 9-10, optionally further comprising vacuum forming the glass laminate structure after engaging the first major surface with the press mold.
Embodiment 12 provides a system for bending a glass laminate structure, the system can optionally comprise any one or any combination of: a contour ring configured to extend along an x-direction and a y-direction of the glass laminate structure and configured to engage an edge portion of a first major surface of the glass laminate structure; a support ring extending along the x-direction and the y-direction of the glass laminate structure and comprising a support for the glass laminate structure along an edge portion of a second major surface of the glass laminate structure opposing the edge portion of the first major surface; and a press mold configured to engage a portion of one of the first major surface or the second major surface other than the edge portion; wherein the contour ring is configured to be moveable relative to the press mold to selectively engage the edge portion of the first major surface of the glass laminate structure independent of the press mold.
Embodiment 13 provides the system of Embodiment 12, optionally further comprising a gas supply conduit configured to provide a compressed gas to the second major surface inward of the support ring.
Embodiment 14 provides the system of any one or any combination of Embodiments 12-13, optionally wherein one or both of the press mold and the contour ring have a plurality of vacuum ports therein.
Embodiment 15 provides the system of any one or any combination of Embodiments 12-14, optionally wherein the contour ring further comprises guide rods received in the press mold.
Embodiment 16 provides the system of any one or any combination of Embodiments 12-15 optionally wherein the contour ring is weighted with a mass and the contour ring with the mass is configured to engage the glass laminate structure with a desired force at the edge portion.
Embodiment 17 provides the system of any one or any combination of Embodiments 12-16, optionally wherein the contour ring comprises a hollow frame configured to engage the glass laminate structure with a force at the edge portion.
Embodiment 18 provides the system of any one or any combination of Embodiments 12-17, wherein the press mold comprises a recess configured to receive the contour ring.
Embodiment 19 provides an apparatus comprising glass laminate structure that is a windshield for a vehicle. The glass laminate structure can optionally comprise: a first curved glass substrate comprising a soda lime silicate glass, alkali aluminosilicate glass, alkali containing borosilicate glass, alkali aluminophosphosilicate glass, alkali aluminoborosilicate glass, or a mixture thereof, and wherein the first glass substrate has a first thickness in a range from about 1.5 mm to about 10 mm; and a second curved glass substrate comprising one of a chemically strengthened glass or glass-ceramic material, wherein the second glass substrate has a second thickness is in a range of from about 0.1 mm to about 1.7 mm.
Embodiment 20 provides the glass laminate substrate of Embodiment 19, optionally wherein the first and second glass substrates are formed by a method for bending the glass laminate structure that includes at least one of engaging an edge portion of a first major surface of the glass laminate structure with a contour ring prior to press molding or pressure forming the glass laminate structure against the press mold with a compressed gas applied to the second major surface of the glass laminate structure.
This application claims the benefit of priority under 35 U.S.C. § 119 of U.S. Provisional Application Ser. No. 62/928,001 filed on Oct. 30, 2019 the content of which is relied upon and incorporated herein by reference in its entirety.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/US20/54700 | 10/8/2020 | WO |
Number | Date | Country | |
---|---|---|---|
62928001 | Oct 2019 | US |