The present disclosure is generally related to methods for and devices prepared from shape material alloy welding, in particular vaporizing foil actuator welding and laser impact welding.
Shape memory alloys are increasingly finding applications in a range of industries including the biomedical, automotive, electronics, and aerospace industries. These applications often take advantage of their shape memory effect, pseudoelasticity, and good actuation force-to-weight ratio. However, welding shape memory alloys while retaining good joint strength is very difficult. Many of the welding methods currently used on shape memory alloys create defects at the joint in the form of relatively wide heat affect zones (HAZ) or brittle intermetallics. These defects led to reduction of tensile strength and thermal distortion of parts.
There are a variety of existing competitive technologies that have been developed for joining SMAs for actuation purposes, none of which solve the pain point of a lack of a defect-free high strength joining process for SMA devices. Gluing and soldering are low strength, brittle, and add mass to devices. Fusion welding techniques such as micro-resistance welding damage the material with heat, and cause brittle joints due to the mixing of alloying elements forming brittle intermetallics Laser welding is widely used because of its low heat input, but unfortunately it still produces brittle joints even when employing interlayers or offsetting the laser to preferentially melt one of the alloys. Rotational friction welding has also been investigated; however, the joint geometry is unsuitable for actuation, and research in the area shows issues with small process windows. Ultrasonic welding can laminate thin layers of material, but there is a current lack of ability to achieve a metallurgical bonds with SMAs, and rather mechanical pull out strength is relied on, making it unsuitable for making a low weight high strength joint. The defects mentioned above have led to reduction of tensile strength and thermal distortion of parts. These methods are also limited with respect to joint geometry (and by extension device morphologies that can be manufactured).
Accordingly, improved methods for joining SMAs are needed.
Described herein are methods of joining shape memory alloys using welding processes such as vaporizing foil actuator welding (VFAW) and laser impact welding (LIW). These methods can efficiently form high strength joints between an SMA and another metal (e.g., another SMA or a dissimilar metal, such as aluminum, titanium, or stainless steel). In some examples, the methods can be used to join a nickel-titanium alloy such as nitinol to a dissimilar metal, such as aluminum, titanium, or stainless steel. In other examples, the methods can be used to join two pieces of shape memory alloy, such as two pieces of nitinol. The resulting welds can exhibit improved properties as compared to welds formed by other methods, including welds formed by alterative welding methods such as laser welding or ultrasonic welding. For example, the resulting weld can exhibit improved joint efficiency, defined as the ratio of the joint strength to the strength of the weaker of the two elements in the joining pair, in the loading mode used in service. In some embodiments, the resulting weld can exhibit improved joint efficiency, such as a joint efficiency of at least 63% (e.g., at least 65%, at least 70%, at least 75%, at least 80%, at least 85%, at least 90%, or at least 95%) relative to the ultimate tensile strength of the shape memory alloy. In some embodiments, the resulting weld can be substantially free of heat affected zones (HAZs). In some embodiments, the resulting weld can be substantially free of continuous layers of brittle intermetallics.
For example, provided herein are methods of joining a first metal to a second metal wherein the first metal, the second metal, or a combination thereof include a shape memory alloy that employ VFAW. These methods can include positioning a metallic consumable body proximate to a piece of the first metal, accelerating the piece of the first metal by vaporizing the metallic consumable body and directing the gas pressure generated by the vaporized metallic consumable body into the piece of the first metal, and colliding the accelerated piece of the first metal into a stationary piece of the second metal, thereby joining the piece of the first metal to the stationary piece of the second metal.
Also provided is another implementation of a method of joining a first metal to a second metal wherein the first metal, the second metal, or a combination thereof include a shape memory alloy that employ LIW. These methods can include positioning a piece of the first metal over an upper surface of a stationary piece of the second metal at a first distance, positioning a target layer over at least a first location of the piece of the first metal, directing a laser beam to be incidental to the first location of the piece of the first metal for a first duration, accelerating the piece of the first metal to a first velocity and towards the upper surface of the stationary piece of the second metal, thereby joining the piece of the first metal to the stationary piece of the second metal. In some implementations, the piece of the first metal is positioned at an oblique angle with respect to the upper surface of the stationary piece of the second metal.
The methods described herein can be used to form devices including a weld joining a first metal to a second metal wherein the first metal, the second metal, or a combination thereof comprises a shape memory alloy. In some implementations, the shape memory alloy used in the weld has an ultimate tensile strength, and the weld exhibits a joint efficiency of at least 63% (e.g., at least 65%, at least 70%, at least 75%, at least 80%, at least 85%, at least 90%, or at least 95%) relative to the ultimate tensile strength of the shape memory alloy. In some implementations, the weld includes substantially no heat affected zones. In some implementations, the weld includes substantially no brittle intermetallics. In some embodiments, the device can comprise a medical device (e.g., a stent or guidewire). In some embodiments, the device can comprise an actuator.
The accompanying figures, which are incorporated in and constitute a part of this specification, illustrate several aspects of the disclosure, and together with the description, serve to explain the principles of the disclosure.
Unless otherwise indicated, the abbreviations used herein have their conventional meaning in the art.
As used in this specification and the following claims, the terms “comprise” (as well as forms, derivatives, or variations thereof, such as “comprising” and “comprises”) and “include” (as well as forms, derivatives, or variations thereof, such as “including” and “includes”) are inclusive (i.e., open-ended) and do not exclude additional elements or steps. For example, the terms “comprise” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. Accordingly, these terms are intended to not only cover the recited element(s) or step(s), but may also include other elements or steps not expressly recited. Furthermore, as used herein, the use of the terms “a” or “an” when used in conjunction with an element may mean “one,” but it is also consistent with the meaning of “one or more,” “at least one,” and “one or more than one.” Therefore, an element preceded by “a” or “an” does not, without more constraints, preclude the existence of additional identical elements.
The use of the term “about” applies to all numeric values, whether or not explicitly indicated. This term generally refers to a range of numbers that one of ordinary skill in the art would consider as a reasonable amount of deviation to the recited numeric values (i.e., having the equivalent function or result). For example, this term can be construed as including a deviation of ±10 percent of the given numeric value provided such a deviation does not alter the end function or result of the value. Therefore, a value of about 1% can be construed to be a range from 0.9% to 1.1%. Furthermore, a range may be construed to include the start and the end of the range. For example, a range of 10% to 20% (i.e., range of 10%-20%) can includes 10% and also includes 20%, and includes percentages in between 10% and 20%, unless explicitly stated otherwise herein.
It is understood that when combinations, subsets, groups, etc. of elements are disclosed (e.g., combinations of components in a composition, or combinations of steps in a method), that while specific reference of each of the various individual and collective combinations and permutations of these elements may not be explicitly disclosed, each is specifically contemplated and described herein. By way of example, if an item is described herein as including a component of type A, a component of type B, a component of type C, or any combination thereof, it is understood that this phrase describes all of the various individual and collective combinations and permutations of these components. For example, in some embodiments, the item described by this phrase could include only a component of type A. In some embodiments, the item described by this phrase could include only a component of type B. In some embodiments, the item described by this phrase could include only a component of type C. In some embodiments, the item described by this phrase could include a component of type A and a component of type B. In some embodiments, the item described by this phrase could include a component of type A and a component of type C. In some embodiments, the item described by this phrase could include a component of type B and a component of type C. In some embodiments, the item described by this phrase could include a component of type A, a component of type B, and a component of type C. In some embodiments, the item described by this phrase could include two or more components of type A (e.g., A1 and A2). In some embodiments, the item described by this phrase could include two or more components of type B (e.g., B1 and B2). In some embodiments, the item described by this phrase could include two or more components of type C (e.g., C1 and C2). In some embodiments, the item described by this phrase could include two or more of a first component (e.g., two or more components of type A (A1 and A2)), optionally one or more of a second component (e.g., optionally one or more components of type B), and optionally one or more of a third component (e.g., optionally one or more components of type C). In some embodiments, the item described by this phrase could include two or more of a first component (e.g., two or more components of type B (B1 and B2)), optionally one or more of a second component (e.g., optionally one or more components of type A), and optionally one or more of a third component (e.g., optionally one or more components of type C). In some embodiments, the item described by this phrase could include two or more of a first component (e.g., two or more components of type C (C1 and C2)), optionally one or more of a second component (e.g., optionally one or more components of type A), and optionally one or more of a third component (e.g., optionally one or more components of type B). The phrases “combinations thereof” and “any combinations thereof are used synonymously herein.
As used herein, a “shape-memory alloy” includes those metals that have a predetermined geometry (i.e., shape) to which the structure made from the metal returns after being deformed. Such alloys can exhibit “pseudoelasticity” (also referred to as “superelasticity”), meaning they can exhibit reversible stress—strain behavior with strain values significantly higher than those of classic metals or alloys. Such alloys can also exhibit a shape memory effect resulting from the recovery of large strains that were induced through reorientation or detwinning. As a consequence, these alloys can undergo a reversible solid state phase transformation between a parent phase and a product phase. The shape memory alloys can include, but are not limited to, those that return to its predetermined geometry due to thermal energy (i.e., temperature), such as nitinol, and/or the influence of a magnetic field. Other examples of shape memory alloys include those composed of titanium-palladuim-nickel, nickel-titanium-copper, gold-cadmium, iron-zinc-copper-aluminum, titanium-niobium-aluminum, hafnium-titanium-nickel, iron-manganese-silicon, nickel-titanium, nickel-iron-zinc-aluminum, copper-aluminum-iron, titanium-niobium, zirconium-copper-zinc, and nickel-zirconium-titanium.
As used herein, the term “heat affected zone” refers to a non-melted area of metal that has undergone changes in material properties as a result of being exposed to high temperatures during a welding process.
As used herein, the term “intermetallic” refers to a phase that forms during similar and dissimilar metal welding. Intermetallics often have low ductility and high hardness, making them detrimental to joint properties, and in worst cases makes forming a joint impossible.
Methods
Described herein are methods of joining shape memory alloys using welding processes such as vaporizing foil actuator welding (VFAW) and laser impact welding (LIW). These methods can efficiently form high strength joints between an SMA and another metal (e.g., another SMA or a dissimilar metal, such as aluminum, titanium, or stainless steel). In some examples, the methods can be used to join a nickel-titanium alloy such as nitinol to a dissimilar metal, such as aluminum, titanium, or stainless steel. In other examples, the methods can be used to join two pieces of shape memory alloy, such as two pieces of nitinol. The resulting welds can exhibit improved properties as compared to welds formed by other methods, including welds formed by alterative welding methods such as laser welding or ultrasonic welding. For example, in some embodiments, the resulting weld can exhibit improved joint efficiency, such as a joint efficiency of at least 63% (e.g., at least 65%, at least 70%, at least 75%, at least 80%, at least 85%, at least 90%, or at least 95%) relative to the ultimate tensile strength of the shape memory alloy. In some embodiments, the resulting weld can be substantially free of heat affected zones (HAZs). In some embodiments, the resulting weld can be substantially free of brittle intermetallics.
For example, provided herein are methods of joining a first metal to a second metal wherein the first metal, the second metal, or a combination thereof include a shape memory alloy that employ VFAW. These methods can include positioning a metallic consumable body proximate to a piece of the first metal, accelerating the piece of the first metal by vaporizing the metallic consumable body and directing the gas pressure generated by the vaporized metallic consumable body into the piece of the first metal, and colliding the accelerated piece of the first metal into a stationary piece of the second metal, thereby joining the piece of the first metal to the stationary piece of the second metal.
Also provided is another implementation of a method of joining a first metal to a second metal wherein the first metal, the second metal, or a combination thereof include a shape memory alloy that employ LIW. These methods can include positioning a piece of the first metal over an upper surface of a stationary piece of the second metal at a first distance, positioning a target layer over at least a first location of the piece of the first metal, directing a laser beam to be incidental to the first location of the piece of the first metal for a first duration, accelerating the piece of the first metal to a first velocity and towards the upper surface of the stationary piece of the second metal, thereby joining the piece of the first metal to the stationary piece of the second metal. In some implementations, the piece of the first metal is positioned at an oblique angle with respect to the upper surface of the stationary piece of the second metal.
These methods are described in more detail below. Aspects of these methods are also described in U.S. Pat. No. 9,021,845 to Vivek et al., U.S. Pat. No. 9,192,056 to Rubenchik et al., and U.S. Patent Application Publication No. 2012/0103949 to Daehn et al., each of which is incorporated herein by reference in its entirety.
Vaporizing Foil Actuator Welding (VFAW)
Regarding the process behind vaporizing foil actuator welding (VFAW), a high amount of charge can be stored in a capacitor bank and rapidly discharged across a thin conductor, instantly vaporizing the thin conductor and thus creating a high pressure region around the area of vaporization. The gases or plasma created from this event can efficiently propel sheets, tubes, wires etc. to very high speeds. In these methods, a metallic consumable body can be rapidly vaporized by passing a high current through the metallic consumable body and the pressure created from the vaporization is used to drive a first piece of a first metal into a stationary piece of a second metal to form a VFAW weld. The first metal, the second metal, or a combination thereof including a shape memory alloy. The shape memory alloy may be pseudoelastic or shape memory. In some cases, when stainless steel and nitinol are welded together through VFAW, the weld can have a joint efficiency approaching 100% (e.g., greater than 90%, or greater than 95%) based off the ultimate tensile strength of nitinol. In some cases, when stainless steel and nitinol are welded together through VFAW, the weld can be substantially free of heat affected zones (HAZ) and/or brittle intermetallics.
Referring now to the example configuration shown in
The metallic consumable body 106 in
The flyer plate 105 can be a sheet of stainless steel. In some implementations, the flyer plate can comprise a shape memory alloy, a pseudoelastic alloy, a nickel alloy, a radio-opaque alloy, stainless steels, a titanium alloy, an aluminum alloy, an advanced structural metal, a refractory metal, a refractory alloy, or an amorphous metal. Possible shape memory alloys include but are not limited to nickel-titanium shape memory alloys, such as a nickel-titanium-iron (Ni—Ti—Fe) alloy, a nickel-titanium-copper (Ni—Ti—Cu) alloy, a nickel-titanium-lead (Ni—Ti—Pb) alloy, or a nickel-titanium-hafnium (Ni—Ti—Hf) alloy, Ni—Ti—Pd, Ni—Ti—Hf—Zr, NiTi—Zr, or NiTi—Er. Other possible shape memory alloys include, but are not limited to copper-aluminum SMAs (e.g., Cu—Al—Ni, Cu—Al—Nb), cobalt-based SMAs (Co—Al, Co—Ni—Al), nickel-aluminum SMAs (Ni—Al), nickel-manganese SMAs (Ni—Mn, Ni—Mn—Ga), Zr—Cu, U—Nb, titanium-based SMAs (Ti—Nb, Ti—Pd, Ti—Au, Ti—Pt—Ir), Ta—Ru, and Nb—Ru. Examples of advanced structural metal include but are not limited to high entropy alloys, nanostructured metals, nanostructured alloys, metallic glasses, bulk metallic glasses, superalloys, hot stamped steels, martensitic steels, and ultrahigh strength metals. In some implementations, the flyer plate can comprise a sheet. In other implementations, the flyer plate can comprise a wire, a group of wires previously welded together, or any other possible shape or configuration.
The two standoff sheets 103 can be, for example, rectangular sheets and each have a thickness of 0.8 mm. In some implementations, each standoff sheet has the same thickness. In some implementations, the thickness of each standoff sheet ranges from 0.1 mm to 1 cm. In some implementations, no standoff sheets are used.
In
In
When the metallic consumable body 103 vaporizes, the reaction forces are driven largely towards the flyer plate 105. The reaction forces accelerate the flyer plate 105 to a speed in the range of 300 to 1000 m/s towards the target plate 104 which is stood-off in accordance with the thickness of the standoff sheets 103. Upon impact, the flyer plate 105 and the target plate 104 weld with each other. The product of the aforementioned VFAW process is illustrated in
As shown in
In some implementations, the flyer plate 105 or target sheet 104 may have additional surface features to ensure oblique impact. Two, three, and four aluminum sheets have been welded together using this method in single shots. Furthermore, in some implementations, VFAW creates welds between dissimilar metal such as nitinol-stainless steel, nitinol-nitinol, aluminum-steel, aluminum-iron, titanium-stainless steel and magnesium-aluminum.
In some implementations, a layer of polyurethane (elastomer) between the metallic consumable body and the flyer plate helps in transferring the pressure and distributing it over a larger area of the flyer plate. Although the polyurethane is referred to as being part of the consumable body that accelerates the workpiece, it will be readily understood that, in many instances, the polyurethane will survive the process and be able to be re-used. As in the case of welding, in this setup also, an insulated aluminum foil is vaporized by passing a high amount of charge stored in a capacitor bank. Once the pressure wave created from rapid vaporization gets to the workpiece, it accelerates the latter to a velocity in excess of 200 m/s, almost instantly. The workpiece then gets formed into a die. Presently, stainless steel has been extruded into a perforated nitinol sheet as shown in
There are two noteworthy observations from
In order to get even higher discharge energies and flyer speeds, an exothermic chemical compound or mixture, such as an oxidizer fuel mixture can be placed between two layers of aluminum foil as shown in
Laser Impact Welding
Laser impact welding uses intense laser discharges or some other energy source to provide a mechanical impulse to a metal surface by one of a variety of mechanisms. Direct reflection of photons provides some level of force and impulse. Also, the surface of the metal may ablate under the beam and this generated gas can also produce a pressure that accelerates the flyer. The metal surface may also be coated with a polymer or other material that better absorbs optical energy and/or is more easily ablated. This can generate the same impulse at reduced laser energy. One additional way to increase the efficiency of converting the optical energy to mechanical impulse is by placing an optically transparent material opposed to the ablated surface to provide a surface to oppose the generation of the expanding gas. This will help to accelerate the flyer plate.
One advantage of this technique over electromagnetic or explosive launching is that the shock can be directed to a precise location (sub-micron precision) and at a precise time (precision of <10-5 seconds). The ability to apply enormous pressure at exact and localized points on a material interface and to do so with timing accuracy allows these methods to create welds in applications involving micro/nano interfaces.
LIW produces a spot impact weld between a first part and a second part. The method is conducted by providing the first and second parts, with a portion of the first part extending bent at an angle out of a generally planar surface of the remainder of the first part. The first and second parts are positioned on a support backing, with the second part between the first part and the support backing. The first part is positioned so that the second part underlies at least the bent portion of the first part with the bent portion bent away from the second part. A laser is aligned to direct its emitted energy at a top surface of the bent portion. At least one pulse of optical energy is directed from the laser onto the top surface, the amount of energy being sufficient to cause the bent portion to straighten and impact the underlying second part with a velocity of at least 300 m/s, resulting in a metallurgical bond between the respective parts.
The flyer plate 308 can be, for example, a sheet of stainless steel. In some implementations, the flyer plate can comprise a shape memory alloy, a pseudoelastic alloy, a nickel alloy, a radio-opaque alloy, stainless steels, a titanium alloy, an aluminum alloy, an advanced structural metal, a refractory metal, a refractory alloy, or an amorphous metal. Possible shape memory alloys include but are not limited to nickel-titanium shape memory alloys, such as a nickel-titanium-iron (Ni—Ti—Fe) alloy, a nickel-titanium-copper (Ni—Ti—Cu) alloy, a nickel-titanium-lead (Ni—Ti—Pb) alloy, or a nickel-titanium-hafnium (Ni—Ti—Hf) alloy, Ni—Ti—Pd, Ni—Ti—Hf—Zr, NiTi—Zr, or NiTi—Er. Other possible shape memory alloys include, but are not limited to copper-aluminum SMAs (e.g., Cu—Al—Ni, Cu—Al—Nb), cobalt-based SMAs (Co—Al, Co—Ni—Al), nickel-aluminum SMAs (Ni—Al), nickel-manganese SMAs (Ni—Mn, Ni—Mn—Ga), Zr—Cu, U—Nb, titanium-based SMAs (Ti—Nb, Ti—Pd, Ti—Au, Ti—Pt—Ir), Ta—Ru, and Nb—Ru. Examples of advanced structural metal include but are not limited to high entropy alloys, nanostructured metals, nanostructured alloys, metallic glasses, bulk metallic glasses, superalloys, hot stamped steels, martensitic steels, and ultrahigh strength metals. In some implementations, the flyer plate can comprise a sheet. In other implementations, the flyer plate is a wire, a group of wires previously welded together, or any other possible shape or configuration.
The target sheet 310 can be, for example, a sheet of nitinol. In some implementations, the target plate can comprise a shape memory alloy, a pseudoelastic alloy, a nickel alloy, a radio-opaque alloy, an advanced structural metal, a refractory metal, a refractory alloy, stainless steels, a titanium alloy, an aluminum alloy, or an amorphous metal. Possible shape memory alloys include but are not limited to nickel-titanium shape memory alloys, such as a nickel-titanium-iron (Ni—Ti—Fe) alloy, a nickel-titanium-copper (Ni—Ti—Cu) alloy, a nickel-titanium-lead (Ni—Ti—Pb) alloy, or a nickel-titanium-hafnium (Ni—Ti—Hf) alloy, Ni—Ti—Pd, Ni—Ti—Hf—Zr, NiTi—Zr, or NiTi—Er. Other possible shape memory alloys include, but are not limited to copper-aluminum SMAs (e.g., Cu—Al—Ni, Cu—Al—Nb), cobalt-based SMAs (Co—Al, Co—Ni—Al), nickel-aluminum SMAs (Ni—Al), nickel-manganese SMAs (Ni—Mn, Ni—Mn—Ga), Zr—Cu, U—Nb, titanium-based SMAs (Ti—Nb, Ti—Pd, Ti—Au, Ti—Pt—Ir), Ta—Ru, and Nb—Ru. Examples of advanced structural metal include but are not limited to high entropy alloys, nanostructured metals, nanostructured alloys, metallic glasses, bulk metallic glasses, superalloys, hot stamped steels, martensitic steels, and ultrahigh strength metals. In some implementations, the target plate can comprise a sheet.
The high power pulsed laser 302 is capable of depositing from 0.1 to 100 Joules of optical energy focused in a local area on the top surface of flyer plate tab 308a in the range of 5 ns and 500 ns and with a power density less than or equal to 100 GW/cm2. The energy focused on the flyer plate tab 308a is accelerated by the interaction of the incident laser beam 304 and the top surface of the flyer plate 308, causing the flyer plate tab 308a to impact target sheet 310 at a velocity in the range of 300 m/s to 1000 m/s to thereby develop a metallurgical bond upon impact.
In some embodiments, the metallurgical bond can have a surface area of at least 50 nm2 (e.g., at least 100 nm2, at least 250 nm2, at least 500 nm2, at least 750 nm2, at least 1 μm2, at least 10 μm2, at least 50 μm2, at least 100 μm2, at least 250 μm2, at least 500 μm2, at least 750 μm2, at least 1 mm2, at least 10 mm2, or at least 50 mm2). In some embodiments, the metallurgical bond can have a surface area of 100 mm2 or less (e.g., 50 mm2 or less, 10 mm2 or less, 1 mm2 or less, 750 μm2 or less, 500 μm2 or less, 250 μm2 or less, 100 μm2 or less, 50 μm2 or less, 10 μm2 or less, 1 μm2 or less, 750 nm2 or less, 500 nm2 or less, 250 nm2 or less, or 100 nm2 or less).
The metallurgical bond can have a surface area ranging from any of the minimum values described above to any of the maximum values described above. For example, in some embodiments, the metallurgical bond can have a surface area of from 50 nm2 to 100 mm2. In some implementations, the metallurgical bond may have a surface area on the order of square nanometers or square micrometers (e.g., from 50 nm2 to 1 μm2, or from 1 μm2 to 1 mm2).
The system 300 is augmented by placing a tamping, absorptive, and/or ablative layer 316 on the top surface of the flyer plate tab 308a and/or by placing a transparent backing 306 so as to allow it to react against the expanding gas caused by ablation emanating from the top surface of the flyer plate tab 308a.
The ablative layer 316 may be formed from a variety of materials that efficiently ablate when struck with laser beam 304. In some implementations, the ablative layer is a carbonaceous material, cellulosic material (e.g., a cellophane-type material), nitromethane-based material, azide-based material, oxidizer-oxidant material, nanopowder material, any material with a rapid exothermic reaction, or any combination thereof. In some implementations, the ablative layer is shaped (i.e., increasing in thickness in one direction, having a pyramidal shape, etc.) or provides as a film having a near constant thickness.
In some implementations, the system further includes a tamping layer that includes flowing water (e.g., de-ionized water) over the flyer plate 308 such that the water forms the tamping layer.
The transparent backing 306 may be formed of any material through which the laser beam 304 may pass without significant loss in optical energy in order to provide sufficient velocity so as to weld the flyer plate tab 308 to target sheet 310. In some implementations, the transparent backing includes sapphire, quartz, glasses, polymers or any combination thereof.
In some implementations, acceleration is also done with some other energy source such as focused non-coherent light or by VFAW. In some implementations, the flyer plate tab is bent away from an otherwise planar member as the surface that is being accelerated into a bond-forming collision with another member. In some implementations, the flyer plate is intermixed with the target sheet. It will be clear to one of skill in this art that the requisite features for practice of the concept described herein are an energy source that can generate the requisite amount of acceleration by impacting the surface and a gap between the members being joined.
The distance between the flyer plate tab 308a and the target sheet 311 ranges from 0.1 mm to 1 cm or any distance that is sufficiently large to allow the acceleration to occur, but, at the same instant, be sufficiently small to efficiently limit the power needed to effect the acceleration.
In some implementations, the target sheet includes a casting and the flyer plate includes a shape memory alloy.
A variety of devices benefit from the use of the aforementioned methods for joining shape memory alloys. The devices produced using either or both of the aforementioned methods include welds that have over a 63% joint efficiency based on the ultimate tensile strength of the shape memory alloy, substantially no brittle intermetallics, and substantially no heat affected zones (HAZ). The devices include a weld joining a first metal and a second metal. The first metal, second metal, or a combination thereof including a shape memory alloy. In some implementations, the devices produced from the joining of a shape memory alloy to itself, a dissimilar metal, or a similar metal. In some implementations, the first metal and/or the second metal is a sheet of a shape memory alloy, a pseudoelastic alloy, a nickel alloy, a radio-opaque alloy, an advanced structural metal, a refractory metal, a refractory alloy, stainless steels, a titanium alloy, an aluminum alloy, or an amorphous metal. Possible shape memory alloys include but are not limited to nickel-titanium shape memory alloys, such as a nickel-titanium-iron (Ni—Ti—Fe) alloy, a nickel-titanium-copper (Ni—Ti—Cu) alloy, a nickel-titanium-lead (Ni—Ti—Pb) alloy, or a nickel-titanium-hafnium (Ni—Ti—Hf) alloy, Ni—Ti—Pd, Ni—Ti—Hf—Zr, NiTi—Zr, or NiTi—Er. Other possible shape memory alloys include, but are not limited to copper-aluminum SMAs (e.g., Cu—Al—Ni, Cu—Al—Nb), cobalt-based SMAs (Co—Al, Co—Ni—Al), nickel-aluminum SMAs (Ni—Al), nickel-manganese SMAs (Ni—Mn, Ni—Mn—Ga), Zr—Cu, U—Nb, titanium-based SMAs (Ti—Nb, Ti—Pd, Ti—Au, Ti—Pt—Ir), Ta—Ru, and Nb—Ru. Examples of advanced structural metal include but are not limited to high entropy alloys, nanostructured metals, nanostructured alloys, metallic glasses, bulk metallic glasses, superalloys, hot stamped steels, martensitic steels, and ultrahigh strength metals. In some implementations the weld of the device is a single wire weld, a plurality of wire welds, a lap weld, a scarf weld, a ring/sleeve weld, a plug weld, or an additive flyer weld. Furthermore, such devices produced from the aforementioned methods are medical devices, compliant devices, locking devices, sensing devices, micro-electro-mechanical devices, actuators, tubes, or wires with similar or dissimilar metal ends.
Examples of medical devices include the entire spectrum of articles adapted for medical use, including scalpels, needles, scissors and other surgical tools used in invasive surgical, therapeutic or diagnostic procedures; implantable medical devices, including artificial blood vessels, guidewires, stents, catheters and other devices for the removal or delivery of fluids to patients, artificial hearts, artificial kidneys, orthopedic pins, plates and implants; catheters and other tubes (including urological and biliary tubes, endotracheal tubes, peripherably insertable central venous catheters, dialysis catheters, long term tunneled central venous catheters, peripheral venous catheters, short term central venous catheters, arterial catheters, pulmonary catheters, Swan-Ganz catheters, urinary catheters, peritoneal catheters), urinary devices (including long term urinary devices, tissue bonding urinary devices, artificial urinary sphincters, urinary dilators), shunts (including ventricular or arterio-venous shunts); prostheses (including breast implants, penile prostheses, vascular grafting prostheses, heart valves, artificial joints, artificial larynxes, otological implants), vascular catheter ports, wound drain tubes, hydrocephalus shunts, pacemakers and implantable defibrillators, and the like.
By way of non-limiting illustration, examples of certain embodiments of the present disclosure are given below.
General Methods
Joint efficiency is defined as the ratio of the strength of the joint, as measured in force to failure, divided by the strength of the weaker of the two elements of the joining pair in the mode of loading that is relevant to an application. Joint efficiency can be readily evaluated using mechanical tests to determine the failure loads of the joint and base materials. The joint efficiency is calculated as the failure load of the joint divided by the failure load of the weaker base metal. Generally, joint efficiencies scale between 0 and 100%.
The heat affected zone (HAZ) is the non-melted region bordering the weld, which has undergone changes in material properties as a result of being exposed to high temperatures. Joints can be evaluated for the presence of heat affected zones by measuring microhardness or nanohardness in a cross section of a weld interface (e.g., across the unaffected base material, HAZ, and weld). Heat affected zones have a hardness that is changed (usually depressed) in a statistically-significant way relative to the basis material. Microscopy methods including optical, scanning electron, and transmission electron can also be used to detect changes in the microstructure across these regions. Finally changes in the microstructure could also be detected by methods such as x-ray diffraction. In the case of VFAW or LIW, heat affected zones are dramatically narrower than those from fusion welds (e.g., less than 50 μm, less than 25 μm, less than 20 μm, less than 15 μm, less than 10 μm, less than 5 μm, or less than 1 μm). Such joints can be said to be substantially free of heat affected zones.
Intermetallics can be identified by standard cross-sectional metallography. Intermetallics tend to become brittle if continuous and thicker than about 10 μm. In the case of VFAW or LIW, intermetallics, if present, are dramatically thinner than those from fusion welds (e.g., usually less than 10 μm, less than 5 μm, or less than 1 μm; and they are usually discontinuous). Such joints can be said to be substantially free of brittle intermetallics. Detection of these phases can be completed using a variety of techniques. Micro-hardness measurements may provide indication of their presence but often need to be coupled with other techniques such as phase analysis by x-ray diffraction, selected area diffraction with transmission electron microscopy, or elemental analysis with scanning electron microscopy and energy-dispersive x-ray spectroscopy, or electron energy loss spectroscopy with transmission electron microscopy.
Experimental Design
0.5 mm square NiTi wires and 304 V SS wires, provided by Fort Wayne Metals, were selected as the experimental materials. A Magneform capacitor bank with maximum charging energy of 16 kJ and a current rise time of 9 μs was used as the power source. The input energy used in this work is 12 kJ for all samples. A 0.05 mm thick spot-type aluminum foil was used as the actuator. This type of foil under an input energy of 12 kJ will generate an impact speed of 500 to 600 m/s. The flyer and the target are formed by combining 30 wires with length of 80 mm. The standoff distance is 3.2 mm, and the standoff separation distance is 20 mm. As shown in
The interfacial microstructures of the NiTi/NiTi welds and NiTi/SS welds were examined through optical microscopy (OM) and scanning electron microscopy (SEM). The elemental distributions were measured by Energy-dispersive X-ray spectroscopy (EDS). The phase transformation characteristics of the NiTi base metal, NiTi/NiTi welds, and NiTi/SS welds were measured by differential scanning calorimetry (DSC) using a DSC2500 calorimeter made by TA instruments. DSC tests were conducted at temperatures ranging from −80 to 120° C. with a controlled heating/cooling rate of 10° C./min under an Argon atmosphere following the ASTM F2004-17 standard. All samples for DSC tests were prepared with a dimension of 1 mm by 0.5 mm by 1 mm and a weight of 10 to 12 mg. Microhardness tests were performed with a square-based pyramid diamond indenter operating at a load of 200 g and a dwell time of 5s. The cycling tests were performed with displacement control (0 to 2 mm to 0) under a crosshead displacement rate of 0.04 mm. min-1. mm-1 based on ASTM F2516-18 standard. The gauge length of the tested specimens is 50 mm so that the displacement rate is 2 mm/min and the cycling strain is 4% for all samples. A limited number of 100 cycles were performed on all the samples. Lap shear tests were conducted on an MTS EM Test Frame with a displacement rate of 2 mm/min for NiTi base metal, SS base metal, NiTi/NiTi welds and NiTi/SS welds. Three replicates for each type of samples.
Results
1.1. Microstructure Characterization
The weld interfaces of a typical NiTi/NiTi weld and a NiTi/SS weld were studied in
No elemental segregation as may take place during solidification or selective volatilization was observed in either the similar or dissimilar welds. BSE-SEM image in FIG. 13b of the NiTi/NiTi weld can barely show contrast at the weld interface, which was confirmed by the EDS maps of Ti and Ni. The EDS maps exhibited homogeneous distributions of Ni and Ti through the whole examined area. This homogeneous elemental distribution was also observed in the NiTi/SS weld interface, as shown in
1.2. Phase Transformation Characteristics
Phase transformation temperatures have been good indicators for the functional properties of nitinol welds. After impact welding, these temperatures can be expected to change due to the severe plastic deformation involved in the welding process. Phase transformation temperatures such as Ms, Mf, Rs, Rf, As and Af were determined through the intersection of the baseline with the line of maximum inclination of the transformation peaks based on the ASTM F2004-17 standard. However, due to the small joining area in VFAW welds, DSC samples for NiTi/NiTi and NiTi/SS welds retained certain amounts of NiTi and SS base metal. This will influence the DSC results due to the overlapping effect.
Table 1. Transformation temperatures (° C.) of the NiTi base metal, the NiTi/NiTi weld, and the NiTi/SS weld where As and Af indicate the austenite start and finish temperatures, respectively; Rs and Rf indicate the R phase start and finish temperatures, respectively; Ms and M f indicate the martensite start and finish temperatures, respectively.
1.3. Mechanical Properties
1.3.1. Microhardness Measurement
The severe plastic deformation involved in the VFAW process could induce grain refinement near the weld interface, which increases the hardness in the adjoining regions.
For NiTi/NiTi welds, the interface gained a slight hardening compared to the NiTi base metal. For NiTi/SS welds, the NiTi side exhibits the same hardening effect, and the interface near the SS side shows comparable hardness to the SS base metal. These hardness distributions show that no heat affected zones were formed in the VFAW nitinol welds. This phenomenon has also been observed in explosive welding of nitinol to steel and VFAW of other metal combinations such as Al/Fe and Ti/SS. This lack of HAZ formation and the strengthened weld interfaces contribute to the superior mechanical and functional properties compared to other traditional fusion-based and solid-state welding technologies which normally involve structural coarsening and softening.
1.3.2. Lap Shear Tests
Lap shear tests were conducted to measure the macro mechanical properties of similar and dissimilar nitinol welds.
The joint efficiencies of NiTi/NiTi and NiTi/SS welds made by different welding methods were compared in
1.3.3. Cycling Tests
To determine the superealstic behavior and its repeatability of the similar and dissimilar nitinol welds, 100 stress-strain cycles were conducted on the NiTi base metal, NiTi/NiTi welds, and NiTi/SS welds. The results in
Experimental Design
2.1 Vaporizing Foil Actuator Welding Process
In this work, 436 ferritic stainless steel (Fe-16Cr-1Mo-1Mn-0.5Nb-0.12C), with a thickness of 0.3 mm was chosen as the flyer. A 0.37 mm thick near equiatomic NiTi SMA with nominal compositions of 55.8 wt. % (50.7 at. %) Ni and 44.2 wt. % (49.3 at. %) Ti was selected as the target. Before welding, these NiTi SMA sheets were heat treated at 1000° C. for one hour in glass tubing filled with 0.2 atm of argon gas and furnace cooled to room temperature. This annealing treatment helped remove the residual cold work due to processing issues of NiTi base metals. The electrical storage and discharge source used in this work was a Maxwell Magneform capacitor bank with a maximum charging energy of 16 kJ, total capacitance of 426 g, inductance of 100 nH, and a rise time of 12 μs. The VFA patch welding process was introduced in a previous work. As shown in
Standoff sheets with thickness of 0.8 mm and span distance of 10 mm between supports were used to provide the acceleration distance and impact angle suitable for achieving collision welds. Three-channel Photon Doppler Velocimetry (PDV) were used to measure the impact velocity and collision angle at three locations with interval of 3.8 mm from the weld center to edge, as shown in
2.2. Microstructure Characterization and Mechanical Testing Methods
The NiTi/SS impact spot welds were cross-sectioned, mounted and then ground with sandpaper sequentially from 240 to 1200 fin. grits. The samples were further polished from 6 to 1 μm using microid diamond compound to obtain a proper surface finish for microstructure characterization. The interfacial microstructures of NiTi/SS impact welds were studied through optical microscopy (OM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Dual beam Focused Ion Beam (FIB) technique were used to obtain the TEM foil lifted out from a wavy interface that shows a nearly discontinuous change across the flyer and target. TEM observations were conducted on a Tecnai F20 with an accelerating voltage of 200 kV. Selective Area Diffraction (SAD) patterns were obtained across the interface between NiTi and SS. Chemical compositions of molten regions and interdiffusion between NiTi and SS were characterized by energy-dispersive Xray spectroscopy (EDS) with probe size of 1 nm. The phase transformation characteristics of the NiTi base metal and NiTi/SS welds were measured by differential scanning calorimetry (DSC) using a DSC2500 calorimeter made by TA instruments. DSC tests were conducted at temperatures ranging from −80 to 120° C. with a controlled heating/cooling rate of 10° C./min following the ASTM F2004-17 standard. Microhardness tests were done with a square-based pyramid diamond indenter operating at a load of 200 g and a dwell time of 5 s to measure the hardness distributions across the interfaces. Lap shear samples were created between SS sheets (20 mm by 70 mm by 0.3 mm) and NiTi sheets (13.7 mm by 6 mm by 0.37 mm). Three samples for each case were lap shear tested in a MTS EM Test Frame with a crosshead displacement rate of 1 mm/min. The two base metals were also tensile tested in the same MTS frame with the same displacement rate.
Results
3.1. Welding Process Characteristics
Impact velocity and impact angle are the primary parameters in understanding the impact welding process and microstructure evolution along the interface. The flyer velocity versus time traces for three channels are shown in
3.2.1. Macrostructure and Microstructure
The evolution of impact velocity and impact angle along the interface, shown in
Moving further outward from the nanoporous zone, the impact velocity decreases, and the impact angle decreases. This leads to the formation of a flat interface with continuous melting as shown in
Further along the interface, the shear cracks disappear, good bonding is apparent, and some shear banding is also shown (
Adiabatic shear banding and cracking have been seen before in high speed impact and welding. The reasons for the formation of shear banding could be ascribed to the localized plastic instability resulting from the sudden increase of temperature and thermal softening. In this work, no adiabatic shear bands or shear cracks were found in the SS side presumably because thermal softening required for shear banding is not as severe in the stainless steel, or is balanced by strain rate sensitivity.
3.2.2. TEM Analyses of the NiTi/SS Interface
In one particularly narrow (or discontinuous-appearing NiTi-SS interface as exemplified in
The results show that amorphization occurred at the NiTi-SS interface and over some region of the NiTi side, being particularly correlated with grain boundaries. The width of the amorphous-including layer is at least 100 nm. The grains in the NiTi side, with grain sizes ranging from 20 to 100 nm, are more equiaxed compared to those elongated and deformed grains found in the SS side. On the SS side, the structure is clearly crystalline, with fine grains and distortion. The mixed zone between the two materials is about 100 nm thick and diffraction indicates that region is amorphous. This is likely due to the formation of a multi-component melt and rapid solidification, as discussed later.
Moving into the NiTi side, SAD patterns 5-8 suggest a mixture of amorphous and crystalline structures. This is also not fully surprising as near-equiatomic NiTi structures have been observed to collapse into amorphous zones at high levels of plastic strain. These amorphous zones seem to be particularly associated with grain boundaries and triple points.
The composition of the amorphous layer could assist in the understanding of the bonding mechanism of NiTi/SS impact welds.
3.2.3. Formation Mechanisms of Amorphous Phases in NiTi/SS Impact Welds
It seems clear that at least some material pairs form amorphous intermediate regions in impact welding. In this work, the grain sizes of in the NiTi and SS near the amorphous layer are at nanometer scales, less than 100 nm. This indicates that solid-state amorphization probably happened in the interface of the NiTi/SS impact welds.
The amorphous zone can be explained as due to the rapid cooling and frustrated crystallization in a multi-component melt. In explosive welding, the heating rate could reach 10{circumflex over ( )}9 K/s and the cooling rate could reach 10{circumflex over ( )}7 K/s, results in the formation of various metastable phases including amorphous phases. High heating and cooling rates, on the order of 10{circumflex over ( )}7 K/s, were also observed in VFAW of single crystal copper. The amorphous zones are less than 100 nm (e.g., less than 75 nm, less than 50 nm, or less than 25 nm) in thickness and are so small such that they are negligible relative to the characteristics of the weld.
The easiest alloys to make amorphous are those with a wide range of elements and element sizes. The alloys system reaching the following three requirements should have good glass forming ability (GFA):
1) Contains at least 3 atomic species;
2) 12% or more difference in the size of the atoms, and
3) Negative enthalpy of mixing of the elements in the liquid phase.
In the present case, there are 4 major atomic species in the amorphous forming area. The atomic radius is 17.6 nm for Ti, 14.9 nm for Ni, 12.6 nm for Fe, and 128 nm for Cr. Therefore, the difference in radius between Ti and other elements is approximately 15.3% for Ni, 28.4% for Fe, and 27.3% for Cr. Furthermore, the mixing enthalpy of the studied composition is about −9.2 kJ/mol, calculated via Thermo-Calc listed in Table 2. All the three requirements are fulfilled in the amorphous interface of NiTi/SS impact welds. Clear methodologies have been developed for predicting GFA potential which showed that the alloy system with compositions at or near eutectics should have good glass forming ability. In an alloy at or near the eutectic composition, the liquid phase can be kept to the lowest temperature, at which viscosity increases, diffusion slows down, and the amorphous structure more easily forms. In addition, the material crystallizes at equilibrium into 2 phases, resulting in the need for alloying elements to partition between phases and complicating crystallization kinetics.
3.3. Phase Transformation Characteristics
Phase transformation characteristics are good indicators for functional properties of NiTi shape memory alloys. After high speed impact welding, phase transformation temperatures can be expected to change due to the high strain rate plastic deformation involved in the VFAW process. High strain rate plastic deformation is known to suppress the martensitic transformation and thus widen the transformation temperature range. The phase transformation curves of the NiTi base metal and NiTi/SS weld were shown in
After VFAW, no obvious transformation peak was observed in the cooling stage and a one step B19′→B2 transformation was shown in the heating stage. The martensitic transformation has been significantly suppressed by the high-speed impact. One reason is that the high strain rate plastic deformation makes the microstructure of NiTi more constricted, which impeded the martensitic transformation upon cooling. The other could be due to the influence of the inactive SS being half of the gauge length in the DSC sample. The limited transformation occurring at the heating stage could also be interpreted as the overlapping effect of NiTi base metal in the DSC sample for NiTi/SS weld, which is under the detection limits of the DSC instruments.
3.4. Mechanical Properties
The mechanical properties and behavior of these welds are interesting as they can provide macroscopic joints between these important dissimilar materials. This high-level behavior is the result of the complex and heterogeneous structure described to this point. The local hardness will be discussed first and then this will be integrated into the discussion of macroscopic behavior.
3.4.1. Hardness Distributions
The microstructural heterogeneity will result in variations of mechanical properties such as microhardness distributions among different interfaces.
3.4.2. Comparison of Joint Efficiency with Other Welding Technologies
A primary goal of undertaking this kind of research is the production of joints that have strength on par with, or exceeding, those of the base metals. In particular it is important that the full pseudo-elastic transition in the NiTi can be accessed after joining with SS, as shown in FIG. 34. Joint efficiency, the ratio of the weld strength to the ultimate tensile strength (UTS) of NiTi base metal, is a good indicator to compare welding technologies for a given material pair. Since strain is very heterogeneous over the sample and localized in the weaker material (NiTi), the UTS of NiTi base metal instead of that of SS is used to examine the joint efficiency.
The devices and methods of the appended claims are not limited in scope by the specific devices and methods described herein, which are intended as illustrations of a few aspects of the claims. Any compositions, systems, and methods that are functionally equivalent are intended to fall within the scope of the claims. Various modifications of the compositions, systems, and methods in addition to those shown and described herein are intended to fall within the scope of the appended claims. Further, while only certain representative compositions, systems, and method steps disclosed herein are specifically described, other combinations of the compositions, systems, and method steps also are intended to fall within the scope of the appended claims, even if not specifically recited. Thus, a combination of steps, elements, components, or constituents may be explicitly mentioned herein or less, however, other combinations of steps, elements, components, and constituents are included, even though not explicitly stated.
Unless defined otherwise, all technical and scientific terms used herein have the same meanings as commonly understood by one of skill in the art to which the disclosed invention belongs. Publications cited herein and the materials for which they are cited are specifically incorporated by reference
This application claims benefit of priority of U.S. Provisional Application No. 62/900,304, filed Sep. 13, 2019, which is incorporated herein by reference in its entirety.
Filing Document | Filing Date | Country | Kind |
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PCT/US2020/050723 | 9/14/2020 | WO |
Number | Date | Country | |
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62900304 | Sep 2019 | US |