This device is in the field of insulating materials for appliances. More specifically, this device relates to various methods for dispensing and compacting insulation material to form a vacuum sealed structure.
In at least one aspect, a method of forming an insulated structure for an appliance includes forming a structural enclosure having an outer wrapper and an inner liner and an insulating cavity defined therebetween. An insulating powder material is formed and the insulating powder material is compacted to form a pre-densified core material. The pre-densified core material is disposed within an insulating cavity, wherein the insulating cavity is defined between the outer wrapper and the inner liner. At least a portion of the gas contained within the insulating cavity is expressed, wherein the insulating cavity is hermetically sealed to define a vacuum insulated structure.
In at least another aspect, a method of forming an insulated structure for an appliance includes providing a base formation, wherein a surface of the base formation defines a shape of an insulating enclosure. A first planar sheet is formed to the surface of the base formation, wherein the first planar sheet includes one of an outer wrapper and an inner liner of an insulating structure. An insulating powder material is compacted to define a pre-densified core material. The pre-densified core material is positioned in engagement with the first planar sheet. A second planar sheet is formed proximate the pre-densified core material, wherein the second planar sheet includes the other of the outer wrapper and the inner liner. The outer wrapper and inner liner are sealed together to define an insulating cavity between the outer wrapper and the inner liner, wherein the pre-densified core material is disposed within the insulating cavity. At least a portion of the gas contained within the insulating cavity is expressed wherein the insulating cavity is hermetically sealed to define a vacuum insulated structure.
In at least another aspect, a method of forming an insulated structure for an appliance includes providing a base formation, wherein a surface of the base formation defines a shape of an insulating enclosure. A first planar sheet is formed to the surface of the base formation, wherein the first planar sheet includes an inner liner of an insulating structure. An insulating powder material is compacted to define a pre-densified core material and the pre-densified core material is positioned in engagement with an outward facing surface of the inner liner. A second planar sheet is formed to the shape of the pre-densified core material, wherein the second planar sheet defines the outer wrapper. The outer wrapper and inner liner are sealed together to define an insulating cavity between the outer wrapper and the inner liner, wherein the pre-densified core material is disposed within the insulating cavity to define the insulating structure. The insulating structure is then removed from the base formation.
These and other features, advantages, and objects of the present device will be further understood and appreciated by those skilled in the art upon studying the following specification, claims, and appended drawings.
In the drawings:
For purposes of description herein the terms “upper,” “lower,” “right,” “left,” “rear,” “front,” “vertical,” “horizontal,” and derivatives thereof shall relate to the device as oriented in
As illustrated in
Referring now to
Referring again to
Referring now to
According to various alternate embodiments, it is contemplated that the pre-densified core material 26 can be disposed within the insulating cavity 18 through an inlet port 40 defined in one of the outer wrapper 14 and inner liner 16. In such an embodiment, it is contemplated that the pre-densified core material 26 is disposed within the insulating cavity 18 after the outer wrapper 14 and inner liner 16 are attached and, in certain embodiments, sealed together. It is also contemplated that a compaction of the pre-densified core material 26 into the finally compacted three-dimensional insulating member 24 of the vacuum insulating structure 10 can occur during expression of gas 28 from the insulated cavity. In such an embodiment, the expression of gas 28 from the insulating cavity 18 can result in a negative compressive force being exerted upon the pre-densified core material 26 to further compress the pre-densified core material 26 into a finally compacted three-dimensional insulating member 24 disposed within the insulating cavity 18. Where the pre-densified core material 26 is disposed in the insulating cavity 18 via the inlet port 40, the compaction of the pre-densified core material 26 can be assisted through various vibrating and/or rotating mechanisms that serve to position the particles of the pre-densified core material 26 in a more densified state and throughout the insulating cavity 18. The vibrating and rotating mechanisms adjust the positioning of the pre-densified core material 26 such that the insulating structure 12 is shaken and rotated to manipulate the pre-densified core material 26 to occupy the entire insulating cavity 18.
Referring now to
Referring again to
Referring again to
Referring again to
Referring again to
Referring again to
Referring again to
According to the various embodiments of the methods described herein, the insulating powder material 20 is disposed into direct engagement with the inner liner 16 and the outer wrapper 14. This is the case whether the insulating powder material 20 is in powder form, granular form, or in the form of the three-dimensional insulating member 24. In this manner, the vacuum insulated structure 32 can be formed without the use of barrier films or porous bags that may separate the insulating material 20 from the inner liner 16 and/or the outer wrapper 14.
Referring again to
According to various embodiments, the outer wrapper 14 can be formed against a separate base formation 52, or can be formed around a portion of the pre-densified core material 26 (step 810). It is contemplated that the inner liner 16 and outer wrapper 14 can take the form of a metal panel that is shaped, pressed, punched, or otherwise manipulated to take the form of the inner liner 16 and/or the outer wrapper 14. It is further contemplated that the inner liner 16 and outer wrapper 14 can be made of a polymer-type material. In such an embodiment, the polymer-type material can be blow molded, vacuum formed, thermoformed, injection-molded, compression molded, or otherwise shaped to form the inner liner 16 and/or the outer wrapper 14. Where a plastic-type material is used, the outer wrapper 14 and the inner liner 16 can include various barrier layers or films that can vary depending on the design of the insulating structure 10 and the insulating requirements thereof.
According to the method 800, as exemplified in
According to the various embodiments, aspects of the step 806 of compacting the insulating powder material 20 and/or the granular insulating material 72 into the three-dimensional insulating member 24 or 2D VIP or 2D core panels can be performed either between the inner liner 16 and outer wrapper 14, or can be performed in a separate pressing assembly 116 where the insulating material 20 is disposed within a compression cavity 118 and a compression member 120 is disposed within the compression cavity 118 to compress the insulating material 20 into the three-dimensional insulating member 24. It is contemplated that the binder material 70 can be disposed within the compression cavity 118 and mixed in with the insulating material 20 such that when the three-dimensional insulating member 24 is formed, the binder material 70 substantially retains the three-dimensional insulating member 24 in its shape for removal from the compression cavity 118 and placement on either the inner liner 16 or within the outer wrapper 14 to form the insulating structure 10.
It is contemplated that the various aspects of the devices and methods described herein can be utilized to form various insulating forms that include, but are not limited to, three-dimensional insulating members 24, insulating panels, planar core members, plural and contoured three-dimensional vacuum insulated panels, and others. It is also contemplated that the insulating member or members formed using the aspects of the device can be used within various appliances 10. Such appliances 10 can include, but are not limited to, refrigerators, freezers, warmers, ovens, dishwashers, laundry appliances, water heaters, furnaces, and other similar appliances.
It will be understood by one having ordinary skill in the art that construction of the described device and other components is not limited to any specific material. Other exemplary embodiments of the device disclosed herein may be formed from a wide variety of materials, unless described otherwise herein.
For purposes of this disclosure, the term “coupled” (in all of its forms, couple, coupling, coupled, etc.) generally means the joining of two components (electrical or mechanical) directly or indirectly to one another. Such joining may be stationary in nature or movable in nature. Such joining may be achieved with the two components (electrical or mechanical) and any additional intermediate members being integrally formed as a single unitary body with one another or with the two components. Such joining may be permanent in nature or may be removable or releasable in nature unless otherwise stated.
It is also important to note that the construction and arrangement of the elements of the device as shown in the exemplary embodiments is illustrative only. Although only a few embodiments of the present innovations have been described in detail in this disclosure, those skilled in the art who review this disclosure will readily appreciate that many modifications are possible (e.g., variations in sizes, dimensions, structures, shapes and proportions of the various elements, values of parameters, mounting arrangements, use of materials, colors, orientations, etc.) without materially departing from the novel teachings and advantages of the subject matter recited. For example, elements shown as integrally formed may be constructed of multiple parts or elements shown as multiple parts may be integrally formed, the operation of the interfaces may be reversed or otherwise varied, the length or width of the structures and/or members or connector or other elements of the system may be varied, the nature or number of adjustment positions provided between the elements may be varied. It should be noted that the elements and/or assemblies of the system may be constructed from any of a wide variety of materials that provide sufficient strength or durability, in any of a wide variety of colors, textures, and combinations. Accordingly, all such modifications are intended to be included within the scope of the present innovations. Other substitutions, modifications, changes, and omissions may be made in the design, operating conditions, and arrangement of the desired and other exemplary embodiments without departing from the spirit of the present innovations.
It will be understood that any described processes or steps within described processes may be combined with other disclosed processes or steps to form structures within the scope of the present device. The exemplary structures and processes disclosed herein are for illustrative purposes and are not to be construed as limiting.
It is also to be understood that variations and modifications can be made on the aforementioned structures and methods without departing from the concepts of the present device, and further it is to be understood that such concepts are intended to be covered by the following claims unless these claims by their language expressly state otherwise.
The above description is considered that of the illustrated embodiments only. Modifications of the device will occur to those skilled in the art and to those who make or use the device. Therefore, it is understood that the embodiments shown in the drawings and described above is merely for illustrative purposes and not intended to limit the scope of the device, which is defined by the following claims as interpreted according to the principles of patent law, including the Doctrine of Equivalents.
The present application is a continuation of U.S. patent application Ser. No. 14/961,952 filed Dec. 8, 2015, entitled METHODS FOR DISPENSING AND COMPACTING INSULATION MATERIALS INTO A VACUUM SEALED STRUCTURE, the entire disclosure of which is hereby incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
1849369 | Frost | Mar 1932 | A |
1921576 | Muffly | Aug 1933 | A |
2191659 | Hintze | Feb 1940 | A |
2432042 | Richard | Dec 1947 | A |
2451884 | Stelzer | Oct 1948 | A |
2729863 | Kurtz | Jan 1956 | A |
3290893 | Haldopoulos | Dec 1966 | A |
3338451 | Kesling | Aug 1967 | A |
3353301 | Heilweil et al. | Nov 1967 | A |
3353321 | Heilweil et al. | Nov 1967 | A |
3408316 | Mueller et al. | Oct 1968 | A |
3597850 | Jenkins | Aug 1971 | A |
3607169 | Coxe | Sep 1971 | A |
3632012 | Kitson | Jan 1972 | A |
3633783 | Aue | Jan 1972 | A |
3634971 | Kesling | Jan 1972 | A |
3670521 | Dodge, III et al. | Jun 1972 | A |
3769770 | Deschamps et al. | Nov 1973 | A |
3862880 | Feldman | Jan 1975 | A |
3868829 | Mann et al. | Mar 1975 | A |
3875683 | Waters | Apr 1975 | A |
3910658 | Lindenschmidt | Oct 1975 | A |
3933398 | Haag | Jan 1976 | A |
3935787 | Fisher | Feb 1976 | A |
4005919 | Hoge et al. | Feb 1977 | A |
4170391 | Bottger | Oct 1979 | A |
4242241 | Rosen et al. | Dec 1980 | A |
4260876 | Hochheiser | Apr 1981 | A |
4303730 | Torobin | Dec 1981 | A |
4303732 | Torobin | Dec 1981 | A |
4330310 | Tate, Jr. et al. | May 1982 | A |
4396362 | Thompson et al. | Aug 1983 | A |
4529368 | Makansi | Jul 1985 | A |
4583796 | Nakajima et al. | Apr 1986 | A |
4681788 | Barito et al. | Jul 1987 | A |
4781968 | Kellerman | Nov 1988 | A |
4865875 | Kellerman | Sep 1989 | A |
4870735 | Jahr et al. | Oct 1989 | A |
4914341 | Weaver et al. | Apr 1990 | A |
5084320 | Barito et al. | Jan 1992 | A |
5094899 | Rusek, Jr. | Mar 1992 | A |
5121593 | Forslund | Jun 1992 | A |
5168674 | Molthen | Dec 1992 | A |
5171346 | Hallett | Dec 1992 | A |
5227245 | Brands et al. | Jul 1993 | A |
5251455 | Cur et al. | Oct 1993 | A |
5375428 | LeClear et al. | Dec 1994 | A |
5500287 | Henderson | Mar 1996 | A |
5500305 | Bridges et al. | Mar 1996 | A |
5505810 | Kirby et al. | Apr 1996 | A |
5509248 | Dellby et al. | Apr 1996 | A |
5532034 | Kirby et al. | Jul 1996 | A |
5533311 | Tirrell et al. | Jul 1996 | A |
5599081 | Revlett et al. | Feb 1997 | A |
5600966 | Valence et al. | Feb 1997 | A |
5768837 | Sjoholm | Jun 1998 | A |
5792801 | Tsuda et al. | Aug 1998 | A |
5826780 | Neeser et al. | Oct 1998 | A |
5834126 | Sheu | Nov 1998 | A |
5866247 | Klatt et al. | Feb 1999 | A |
5918478 | Bostic et al. | Jul 1999 | A |
5950395 | Takemasa et al. | Sep 1999 | A |
5952404 | Simpson et al. | Sep 1999 | A |
6013700 | Asano et al. | Jan 2000 | A |
6063471 | Dietrich et al. | May 2000 | A |
6163976 | Tada et al. | Dec 2000 | A |
6164739 | Schultz et al. | Dec 2000 | A |
6187256 | Aslan et al. | Feb 2001 | B1 |
6209342 | Banicevic et al. | Apr 2001 | B1 |
6210625 | Matsushita et al. | Apr 2001 | B1 |
6244458 | Frysinger et al. | Jun 2001 | B1 |
6266970 | Nam et al. | Jul 2001 | B1 |
6294595 | Tyagi et al. | Sep 2001 | B1 |
6485122 | Wolf et al. | Jan 2002 | B2 |
6428130 | Banicevic et al. | Aug 2002 | B1 |
6430780 | Kim et al. | Aug 2002 | B1 |
6519919 | Takenouchi et al. | Feb 2003 | B1 |
6629429 | Kawamura et al. | Oct 2003 | B1 |
6655766 | Hodges | Dec 2003 | B2 |
6689840 | Eustace et al. | Feb 2004 | B1 |
6736472 | Banicevic | May 2004 | B2 |
6860082 | Yamamoto et al. | Mar 2005 | B1 |
7008032 | Chekal et al. | Mar 2006 | B2 |
7197792 | Moon | Apr 2007 | B2 |
7197888 | LeClear et al. | Apr 2007 | B2 |
7207181 | Murray et al. | Apr 2007 | B2 |
7234247 | Maguire | Jun 2007 | B2 |
7263744 | Kim et al. | Sep 2007 | B2 |
7360371 | Feinauer et al. | Apr 2008 | B2 |
7475562 | Jackovin | Jan 2009 | B2 |
7517031 | Laible | Apr 2009 | B2 |
7614244 | Venkatakrishnan et al. | Nov 2009 | B2 |
7665326 | LeClear et al. | Feb 2010 | B2 |
7703217 | Tada et al. | Apr 2010 | B2 |
7703824 | Kittelson et al. | Apr 2010 | B2 |
7757511 | LeClear et al. | Jul 2010 | B2 |
7794805 | Aumaugher et al. | Sep 2010 | B2 |
7845745 | Gorz et al. | Dec 2010 | B2 |
7938148 | Carlier et al. | May 2011 | B2 |
7992257 | Kim | Aug 2011 | B2 |
8049518 | Wern et al. | Nov 2011 | B2 |
8074469 | Hamel et al. | Dec 2011 | B2 |
8079652 | Laible et al. | Dec 2011 | B2 |
8108972 | Bae et al. | Feb 2012 | B2 |
8157338 | Seo et al. | Apr 2012 | B2 |
8162415 | Hagele et al. | Apr 2012 | B2 |
8182051 | Laible et al. | May 2012 | B2 |
8197019 | Kim | Jun 2012 | B2 |
8266923 | Bauer et al. | Sep 2012 | B2 |
8382219 | Hottmann et al. | Feb 2013 | B2 |
8434317 | Besore | May 2013 | B2 |
8439460 | Laible et al. | May 2013 | B2 |
8491070 | Davis et al. | Jul 2013 | B2 |
8516845 | Wuesthoff et al. | Aug 2013 | B2 |
8590992 | Lim et al. | Nov 2013 | B2 |
8717029 | Chae et al. | May 2014 | B2 |
8752921 | Gorz et al. | Jun 2014 | B2 |
8763847 | Mortarotti | Jul 2014 | B2 |
8764133 | Park et al. | Jul 2014 | B2 |
8776390 | Hanaoka et al. | Jul 2014 | B2 |
8840204 | Bauer et al. | Sep 2014 | B2 |
8881398 | Hanley et al. | Nov 2014 | B2 |
8905503 | Sahasrabudhe et al. | Dec 2014 | B2 |
8943770 | Sanders et al. | Feb 2015 | B2 |
8944541 | Allard et al. | Feb 2015 | B2 |
9009969 | Choi et al. | Apr 2015 | B2 |
RE45501 | Maguire | May 2015 | E |
9056952 | Eilbracht et al. | Jun 2015 | B2 |
9074811 | Korkmaz | Jul 2015 | B2 |
9080808 | Choi et al. | Jul 2015 | B2 |
9102076 | Doshi et al. | Aug 2015 | B2 |
9103482 | Fujimori et al. | Aug 2015 | B2 |
9125546 | Kleemann et al. | Sep 2015 | B2 |
9140480 | Kuehl et al. | Sep 2015 | B2 |
9140481 | Curr et al. | Sep 2015 | B2 |
9170045 | Oh et al. | Oct 2015 | B2 |
9170046 | Jung et al. | Oct 2015 | B2 |
9188382 | Kim et al. | Nov 2015 | B2 |
8955352 | Lee et al. | Dec 2015 | B2 |
9221210 | Wu et al. | Dec 2015 | B2 |
9228386 | Thielmann et al. | Jan 2016 | B2 |
9267727 | Lim et al. | Feb 2016 | B2 |
9303915 | Kim et al. | Apr 2016 | B2 |
9328951 | Shin et al. | May 2016 | B2 |
9353984 | Kim et al. | May 2016 | B2 |
9410732 | Choi et al. | Aug 2016 | B2 |
9423171 | Betto et al. | Aug 2016 | B2 |
9429356 | Kim et al. | Aug 2016 | B2 |
9448004 | Kim et al. | Sep 2016 | B2 |
9463917 | Wu et al. | Oct 2016 | B2 |
9482463 | Choi et al. | Nov 2016 | B2 |
9506689 | Carbajal et al. | Nov 2016 | B2 |
9518777 | Lee et al. | Dec 2016 | B2 |
9568238 | Kim et al. | Feb 2017 | B2 |
D781641 | Incukur | Mar 2017 | S |
D781642 | Incukur | Mar 2017 | S |
9605891 | Lee et al. | Mar 2017 | B2 |
9696085 | Seo et al. | Jul 2017 | B2 |
9702621 | Cho et al. | Jul 2017 | B2 |
9759479 | Ramm et al. | Sep 2017 | B2 |
9777958 | Choi et al. | Oct 2017 | B2 |
9791204 | Kim et al. | Oct 2017 | B2 |
9833942 | Wu et al. | Dec 2017 | B2 |
20020004111 | Matsubara et al. | Jan 2002 | A1 |
20020114937 | Albert et al. | Aug 2002 | A1 |
20020144482 | Henson et al. | Oct 2002 | A1 |
20030041612 | Piloni et al. | Mar 2003 | A1 |
20030056334 | Finkelstein | Mar 2003 | A1 |
20030157284 | Tanimoto et al. | Aug 2003 | A1 |
20030167789 | Tanimoto et al. | Sep 2003 | A1 |
20030173883 | Koons | Sep 2003 | A1 |
20040144130 | Jung | Jul 2004 | A1 |
20040226141 | Yates et al. | Nov 2004 | A1 |
20050042247 | Gomoll et al. | Feb 2005 | A1 |
20050229614 | Ansted | Oct 2005 | A1 |
20060064846 | Espendola et al. | Mar 2006 | A1 |
20060261718 | Miseki et al. | Nov 2006 | A1 |
20060266075 | Itsuki et al. | Nov 2006 | A1 |
20070266654 | Noale | Nov 2007 | A1 |
20080044488 | Zimmer et al. | Feb 2008 | A1 |
20080048540 | Kim | Feb 2008 | A1 |
20080138458 | Ozasa et al. | Jun 2008 | A1 |
20080196441 | Ferreira | Aug 2008 | A1 |
20090032541 | Rogala et al. | Feb 2009 | A1 |
20090131571 | Fraser et al. | May 2009 | A1 |
20090205357 | Lim et al. | Aug 2009 | A1 |
20090302728 | Rotter et al. | Dec 2009 | A1 |
20090322470 | Yoo et al. | Dec 2009 | A1 |
20100206464 | Kleo et al. | Aug 2010 | A1 |
20100218543 | Duchame | Sep 2010 | A1 |
20100287843 | Oh | Nov 2010 | A1 |
20100287974 | Cur et al. | Nov 2010 | A1 |
20110011119 | Kuehl et al. | Jan 2011 | A1 |
20110023527 | Kwon et al. | Feb 2011 | A1 |
20110052897 | Goto et al. | Mar 2011 | A1 |
20110095669 | Moon et al. | Apr 2011 | A1 |
20110215694 | Fink et al. | Sep 2011 | A1 |
20110220662 | Kim et al. | Sep 2011 | A1 |
20110309732 | Horil et al. | Dec 2011 | A1 |
20120011879 | Gu | Jan 2012 | A1 |
20120060544 | Lee et al. | Mar 2012 | A1 |
20120099255 | Lee et al. | Apr 2012 | A1 |
20120240612 | Wuesthoff et al. | Sep 2012 | A1 |
20120280608 | Park et al. | Nov 2012 | A1 |
20130026900 | Oh et al. | Jan 2013 | A1 |
20130043780 | Ootsuka et al. | Feb 2013 | A1 |
20130221819 | Wing | Aug 2013 | A1 |
20130270732 | Wu et al. | Oct 2013 | A1 |
20130285527 | Choi et al. | Oct 2013 | A1 |
20130293080 | Kim et al. | Nov 2013 | A1 |
20130328472 | Shim et al. | Dec 2013 | A1 |
20140009055 | Cho et al. | Jan 2014 | A1 |
20140097733 | Seo et al. | Apr 2014 | A1 |
20140166926 | Lee et al. | Jun 2014 | A1 |
20140190978 | Bowman et al. | Jul 2014 | A1 |
20140196305 | Smith | Jul 2014 | A1 |
20140216706 | Melton et al. | Aug 2014 | A1 |
20140232250 | Kim et al. | Aug 2014 | A1 |
20140346942 | Kim et al. | Nov 2014 | A1 |
20150011668 | Kolb et al. | Jan 2015 | A1 |
20150015133 | Carbajal et al. | Jan 2015 | A1 |
20150017386 | Kolb et al. | Jan 2015 | A1 |
20150059399 | Hwang et al. | Mar 2015 | A1 |
20150115790 | Ogg | Apr 2015 | A1 |
20150159936 | Oh et al. | Jun 2015 | A1 |
20150176888 | Cur et al. | Jun 2015 | A1 |
20150184923 | Jeon | Jul 2015 | A1 |
20150190840 | Muto et al. | Jul 2015 | A1 |
20150224685 | Amstutz | Aug 2015 | A1 |
20150241115 | Strauss et al. | Aug 2015 | A1 |
20150241118 | Wu | Aug 2015 | A1 |
20150285551 | Aiken et al. | Oct 2015 | A1 |
20160084567 | Fernandez et al. | Mar 2016 | A1 |
20160116100 | Thiery et al. | Apr 2016 | A1 |
20160123055 | Ueyama | May 2016 | A1 |
20160161175 | Benold et al. | Jun 2016 | A1 |
20160178267 | Hao et al. | Jun 2016 | A1 |
20160178269 | Niemeyer et al. | Jun 2016 | A1 |
20160235201 | Soot | Aug 2016 | A1 |
20160240839 | Umeyama et al. | Aug 2016 | A1 |
20160258671 | Allard et al. | Sep 2016 | A1 |
20160290702 | Sexton et al. | Oct 2016 | A1 |
20160348957 | Hitzelberger et al. | Dec 2016 | A1 |
20170038126 | Lee et al. | Feb 2017 | A1 |
20170157809 | Deka et al. | Jun 2017 | A1 |
20170176086 | Kang | Jun 2017 | A1 |
20170184339 | Liu et al. | Jun 2017 | A1 |
20170191746 | Seo | Jul 2017 | A1 |
Number | Date | Country |
---|---|---|
6526838 | May 1961 | CA |
201748744 | Feb 2011 | CN |
102717578 | Oct 2012 | CN |
202973713 | Jun 2013 | CN |
104816478 | Aug 2015 | CN |
105115221 | Dec 2015 | CN |
2014963379 | Jan 2016 | CN |
4110292 | Oct 1992 | DE |
4311510 | Oct 1994 | DE |
4409091 | Sep 1995 | DE |
69401889 | Sep 1997 | DE |
19914105 | Sep 2000 | DE |
102010040346 | Mar 2012 | DE |
102011051178 | Dec 2012 | DE |
0260699 | Mar 1988 | EP |
0645576 | Mar 1995 | EP |
1602425 | Dec 2005 | EP |
1624263 | Aug 2006 | EP |
2543942 | Jan 2013 | EP |
2878427 | Jun 2015 | EP |
2991698 | Dec 2013 | FR |
404165197 | Jun 1992 | JP |
04165197 | Oct 1992 | JP |
04309778 | Nov 1992 | JP |
H071479 | Jan 1995 | JP |
11159693 | Jun 1999 | JP |
2000320958 | Nov 2000 | JP |
2002068853 | Mar 2002 | JP |
3438948 | Aug 2003 | JP |
2005069596 | Mar 2005 | JP |
2005098637 | Apr 2005 | JP |
2006161834 | Jun 2006 | JP |
2006200685 | Aug 2006 | JP |
2007085696 | Apr 2007 | JP |
2008190815 | Aug 2008 | JP |
2013050267 | Mar 2013 | JP |
2013076471 | Apr 2013 | JP |
20050095357 | Sep 2005 | KR |
100620025 | Sep 2006 | KR |
1020070065743 | Jun 2007 | KR |
20090026045 | Mar 2009 | KR |
20150089495 | Aug 2015 | KR |
547614 | May 1977 | RU |
2061925 | Jun 1996 | RU |
2077411 | Apr 1997 | RU |
2081858 | Jun 1997 | RU |
2132522 | Jun 1999 | RU |
2162576 | Jan 2001 | RU |
2166158 | Apr 2001 | RU |
2187433 | Aug 2002 | RU |
2234645 | Aug 2004 | RU |
2252377 | May 2005 | RU |
2253792 | Jun 2005 | RU |
2349618 | Mar 2009 | RU |
2414288 | Mar 2011 | RU |
2422598 | Jun 2011 | RU |
142892 | Jul 2014 | RU |
2529525 | Sep 2014 | RU |
2571031 | Dec 2015 | RU |
203707 | Dec 1967 | SU |
00476407 | Jul 1975 | SU |
648780 | Feb 1979 | SU |
01307186 | Apr 1987 | SU |
9614207 | May 1996 | WO |
9721767 | Jun 1997 | WO |
9920961 | Apr 1999 | WO |
9920964 | Apr 1999 | WO |
03072684 | Sep 2000 | WO |
200160598 | Aug 2001 | WO |
200202987 | Jan 2002 | WO |
2002052208 | Apr 2002 | WO |
02060576 | Aug 2002 | WO |
2004010042 | Jan 2004 | WO |
2006045694 | May 2006 | WO |
2006073540 | Jul 2006 | WO |
2007033836 | Mar 2007 | WO |
2007106067 | Sep 2007 | WO |
2008065453 | Jun 2008 | WO |
2008077741 | Jul 2008 | WO |
2008118536 | Oct 2008 | WO |
2008122483 | Oct 2008 | WO |
2009013106 | Jan 2009 | WO |
2009112433 | Sep 2009 | WO |
2010007783 | Jan 2010 | WO |
2010127947 | Nov 2010 | WO |
2011058678 | May 2011 | WO |
2012152646 | Nov 2012 | WO |
2013116103 | Aug 2013 | WO |
2013116302 | Aug 2013 | WO |
2014038150 | Mar 2014 | WO |
2014121893 | Aug 2014 | WO |
2014184393 | Nov 2014 | WO |
2013140816 | Aug 2015 | WO |
2016082907 | Jun 2016 | WO |
2017029782 | Feb 2017 | WO |
Entry |
---|
Cai et al., “Generation of Metal Nanoparticles by Laser Ablation of Microspheres,” J. Aerosol Sci., vol. 29, No. 5/6 (1998), pp. 627-636. |
Raszewski et al., “Methods for Producing Hollow Glass Microspheres,” Powerpoint, cached from Google, Jul. 2009, 6 pages. |
Number | Date | Country | |
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20180313599 A1 | Nov 2018 | US |
Number | Date | Country | |
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Parent | 14961952 | Dec 2015 | US |
Child | 16026234 | US |