The present invention relates to ceramic greenware, and in particular relates to systems and methods for ceramic greenware drying during manufacture using an electrode concentrator.
As used herein, ceramic greenware, or greenware, refers to bodies comprised of ceramic-forming components that form ceramic bodies when fired at high temperature. The greenware may include ceramic components such as a mixture of various ceramic-forming components and a ceramic component. The various components can be mixed together with a liquid vehicle, such as water, and extruded with a formed shape such as a honeycomb structure. Immediately after extrusion, the greenware contains some water, and typically at least some of the water must be removed and the greenware must be dried prior to firing at high temperature, which forms a refractory material.
In certain instances, the greenware is sometimes not evenly dried. This is particularly true in certain two-step drying process wherein the first drying step causes some drying unevenness and the second step cannot compensate for this unevenness. Uneven drying leads to production losses. There is therefore a need for systems and methods to accomplish uniform (even) drying of extruded ceramic greenware.
One aspect of the invention is a method of drying a piece of ceramic greenware having opposite end portions and a center portion in between and comprising a liquid at an initial liquid content. The method includes exposing the piece to electromagnetic radiation at a first frequency so as to heat the end portions more than the center portion. The method also includes exposing the piece to electromagnetic radiation at a second frequency different from the first frequency so as to heat the center portion of the piece more than the end portions.
Another aspect of the invention is a method of drying a piece of ceramic greenware having opposite end portions and a center portion in between and comprising a liquid at an initial liquid content. The method includes partially drying the piece such that the end portions are drier than the middle portion. The method also includes further drying the piece with radio-frequency (RF) radiation generated by an electrode system by conveying the piece past the electrode system. The electrode system has a central section configured to concentrate more RF radiation at the center portion of the piece than at the ends of the piece when the piece is conveyed through the electrode system.
Another aspect of the invention is a method of drying a piece of ceramic greenware having opposite end portions and a center portion in between and comprising a liquid at an initial liquid content. The method includes exposing the piece to electromagnetic radiation at a first frequency so as to heat at least one of the end portions to a first end temperature greater than a first center temperature in the center portion. The method also includes exposing the piece to electromagnetic radiation at a second frequency different from the first frequency so as to heat the center portion to a second center temperature that is higher than the first center temperature.
Another aspect of the invention is a method of drying a piece of ceramic greenware having a center portion and opposite end portions and comprising water at an initial water content. The method includes performing a first exposure of the piece with first electromagnetic radiation so as to remove a first portion of the water more from the opposite end portions of the piece than from the center portion of the piece. The method also includes performing a second exposure of the piece with second electromagnetic radiation so as to remove a second portion of the liquid more from the center portion of the piece than from the end portions of the piece.
These and other advantages of the invention will be further understood and appreciated by those skilled in the art by reference to the following written specification, claims and appended drawings.
Reference is now made in detail to the embodiments of the invention, examples of which are illustrated in the accompanying drawings. Whenever possible, the same or similar reference numbers and symbols are used throughout the drawings to refer to the same or similar parts.
Ceramic greenware can be formed by extruding a plasticized batch comprising ceramic-forming components, or ceramic precursors, through a die, such as a die that produces a honeycomb structure, to form an extrudate of the ceramic-forming material. The extrudate that exits the extruder is cut transversely to the direction of extrusion to form a greenware piece. The piece may itself be transversely cut into shorter pieces; in some cases, the longer piece is referred to as a “log.” Extruded pieces of greenware contain water (for example, 10-25% by weight), and the greenware needs to be dried prior to forming the final product.
The greenware is typically placed on trays or supports and then sent through an oven or “applicator.” Microwave (MW) applicators apply microwave radiation. As used herein, microwave radiation corresponds to electromagnetic radiation in the frequency range from about 900 MHz to about 2500 MHz. RF (radio-frequency) applicators apply RF radiation. As used herein, RF radiation corresponds to electromagnetic radiation in the frequency range of about 27 MHz to about 35 MHz. Both MW and RF radiation are absorbed by the greenware, albeit to different extents in some cases. Water can thus be driven off by either form of radiation, leaving a dry (or drier) piece of greenware.
The greenware can be made up of material(s) transparent to MW and RF radiation as well other materials that are not, i.e. MW-susceptible materials such as graphite, as found, for example, in at least some batches and greenware that form aluminum titanate or “AT”. Greenware containing MW-susceptible material is more prone to the occurrence of hot spots during drying.
The systems and methods disclosed herein reduce the occurrence and/or intensity of non-uniform heating and drying that result from drying the greenware to the extent that is sufficient for preparing the greenware for firing at high temperature. Certain known drying methods include, for example, a first MW drying step and a second RF drying step. However, even if the overall moisture content of a piece of greenware is substantially reduced in a first drying step, the non-uniformity of the heating and drying that results generally prevents uniform heating and drying from occurring in the second drying step. Attempting to dry the greenware further in the second step without accounting for the non-uniform heating and drying of the first drying step can produce cracks in the piece.
The present invention can be practiced with various types of greenware-forming systems 4, including one-step and two-step systems such as those shown in
When extruder 6 (see
Other exemplary ceramic bodies are comprised of ceramic materials that include aluminum titanate (AT). Such AT-based bodies are used as an alternative to cordierite and silicon carbide (SiC) bodies for high-temperature applications such as automotive emissions control applications. The systems and methods disclosed herein apply to any type of greenware 20 capable of being dried utilizing RF techniques.
With continuing reference to
MW applicator 40 includes a housing 44 with an input end 46, an output end 48, an interior 50, and a MW source 56 that generates microwave radiation (i.e., MW radiation or “microwaves”) 58 of frequency fMW. RF applicator 70 includes a housing 74 with an input end 76, an output end 78, an interior 80, and a RF source 86 that generates radio waves (or “RF energy” or “RF radiation”) 88 of frequency fRF in electrode system 130.
In the general operation of drying system 10, cut pieces 22 of greenware 20 extruded from extruder 6 (
Pieces 22 are then conveyed to input end 76 of RF applicator 70 via central conveyor section 30C and enter interior 80, where they are exposed to RF radiation 88 as they pass underneath electrode system 130 of RF source 86. The partially dried pieces 22 that enter RF applicator 70 are substantially (i.e., completely or nearly completely) dried when they exit the RF applicator at exit end 78 via an output conveyor section 30O. Upon exiting RF applicator 70, pieces 22 contain less than about 2 wt % water in an one example embodiment and less than about 1% water in another example embodiment.
In the two-step drying process considered herein, only partial drying of pieces 22 is performed by exposing the pieces to MW radiation 58. Pieces 22 are not completely dried using MW applicator 40 because MW drying can cause “hot spots” to form on the greenware that can damage the piece. This is particularly true for greenware that contains a microwave-susceptible material such as graphite. In addition, MW radiation 58 does not penetrate ceramic-based greenware 20 as deeply as RF radiation.
Consequently, we have found it beneficial to use a two-step drying process wherein pieces 22 are only partially dried using MW radiation 58 and then substantially completely dried using RF radiation 88.
We also discovered that when a prior art RF applicator 70 was used in two-step drying system 10, partially dried pieces 22 made from AT with a graphite poreformer (the combination having a dry dielectric constant>5 and a dry Loss Factor>2) that exited from MW applicator 40 were not uniformly dried when they were subsequently further dried in RF applicator 70. In particular, it was found that end portions 22E of such pieces 22 were heated more than their center portions 22C so that the end portions were drier than the center portions.
In addition, the overall “percent dryness” was found in certain instances to be between 90% to 93% as compared to a required overall dryness of 98% or greater. The non-uniform drying of pieces 22 during RF drying resulted in pieces that did not meet this specification. This, in turn, reduced the throughput of the two-step drying system 10, leading to increased production costs, product costs, and diminished process stability.
RF Electrode System with Concentrator
The above-described problems with non-uniform RF drying led us to develop a modification to RF source 86—and in particular to electrode system 130—such that RF applicator 70 can compensate for the non-uniform drying of the MW applicator 40 SO that the two-step process can achieve substantially uniform drying. It is noted here that the modification to electrode system 130 allows for compensating any greenware-drying process that otherwise introduces drying non-uniformities or that results in drying unevenness.
With continuing reference to
In an example embodiment as illustrated in
A portion of bottom 103 of housing 74 directly beneath electrode 130 is electrically grounded via electrical ground GR and serves as a “bottom electrode” that forms—with main electrode 131E and electrode concentrator 131C—a large capacitor in central region 120.
Control unit 150 is configured to provide a RF-frequency AC voltage signal VRF (“RF voltage”) to electrode system 130. This results in a RF-varying electric field that is substantially contained within a sub-region 122 (“electrode region”) of central region 120 underneath electrode system 130. Electrode region 122 has a length essentially the same as main electrode length LE as indicated by vertical dashed lines 123. Electrode region 122 is where the RF drying of pieces 22 takes place.
In an example embodiment, control unit 150 is operably coupled to and controls the operation of central conveyor section 30C.
It is noted here that one or more of the components of controller unit 150 can reside outside of the controller unit and are shown included within the controller unit for the sake of illustration. In an example embodiment, DC/AC converter 250 is a high-frequency DC/AC converter. In the example embodiment of control unit 150, the input voltages V1, V2 and V3 are equal and the output voltage VT is cycled between output lines 202A, 202B and 202C.
In an example embodiment, electrode concentrator length LC is in the range defined by 12′≦LC≦15′, and in a more specific example embodiment is in the range defined by 13′≦LC≦14′. In addition, in an example embodiment, electrode concentrator width WC is in the range defined by 28″≦WC≦36″, and in a more specific example embodiment is in the range defined by 30″≦WC≦34″.
In an example embodiment, electrode concentrator 131C has a shape that is symmetric about axis AZ and includes a central section 140 that is centered on axis AZ and that runs in the direction of the electrode longitudinal axis AE. In the U-shaped example embodiment of
As shown in
Electrode concentrator central section width WCS is in the range defined by 10″≦WCS≦20″ in an example embodiment, is in the ranged defined by 12″≦WCS≦16″ in a specific example embodiment, and is about 14.25″ in a more specific example embodiment. Electrode concentrator 131C is made of aluminum having a thickness TC that is in the range defined by ⅛″≦TC≦¼″ in an example embodiment and that is about 3/16″ in a specific embodiment.
In an example embodiment, a number of through-holes 144 are formed in each flat outer section 142, and electrode concentrator 131C is attached to main electrode 131E at lower surface 132E via screws or bolts 145.
Given the large size of main electrode 131E, it may be difficult to find large enough metal sheets (e.g., aluminum sheets) to form electrode concentrator 131C as a unitary structure. Thus in an example embodiment, with reference to
In an example embodiment, the two or more electrode concentrator sections 131CS need not be identical. Thus, in an example embodiment, two or more electrode sections 131CS having different dimensions are used to tailor the RF drying process. For example, a first section 131CS closest to input end 76 of RF applicator 70 can have a first height HC of, for example, 1.125″ and a central section width length WCS of, for example 12″, while a second section can have a second height HCS of, for example, 2″ and a central section width WCS of, for example, 16″. This configuration would provide for a slightly greater amount of heating of central portion 22C of each piece 22 and while being conveyed through the second electrode concentrator section 131CS as compared to when the piece is conveyed through the first electrode concentrator section.
In an example embodiment of the two-step drying process using RF electrode system 130 for RF drying in the second step, in the first drying step (e.g., MW radiation exposure), the piece 22 is dried so that end portions 22E of the piece have a moisture content between 10% to 30% greater than that of the center portion 22C. The second RF exposure using RF electrode system 130 is performed so that the end portions 22E and central portion 22C have moisture contents that differ by no more than 2%.
As discussed above in connection with
The drying method can also be used for a two-step RF-based drying system 10 as shown in
It will be apparent to those skilled in the art that various modifications to the example embodiments of the invention as described herein can be made without departing from the spirit or scope of the invention as defined in the appended claims. Thus, it is intended that the present invention covers the modifications and variations of this invention provided they come within the scope of the appended claims and the equivalents thereto.