Patent Application
20220168669
Oxygen rich hydrocarbon feedstocks are naturally occurring and plentiful—as this is the major component of life on earth which has accumulated in the Earth's crust for millions of years. This material is the most widely consumed material for chemical and energy production, in the form of fossil fuels, which are simply prehistoric biomass that has underwent natural processing over geological timescales. This geological processing often leads to a reduction in the amount of oxygen in the prehistoric biomass. In essence, the earth is a geological reactor which reduces biomass to more pure hydrocarbon forms, and the higher the conversion the higher their value: e.g. light sweet oils vs. heavy oils, or high rank anthracite coal vs subbituminous coal. Biomass, lower rank prehistoric biomass (high oxygen content), oxidized prehistoric biomass and oxidized carbon from man-made materials contain oxygen which can create a wide range of undesirable traits such as excessive viscosity, increased boiling point, lower BTU value, increased stiffness, embrittlement, hydrogen-bonding, hydrophilic behavior, hydroscopic traits leading to swelling, hydroscopic effects leading to debonding from surfaces, changes in interfacial tension, surfactant behavior, etc. Since hydrocarbons with oxygen are ubiquitous, new ways should be developed to utilize this valuable feedstock in non-destructive ways to provide new, or enhanced, materials or chemical feedstocks. Presented here are some new and unexpected methods which seek to tune and modulate the properties of oxygen rich hydrocarbons.
Amines are common in biological systems and are commercially produced at large scales for use in several industries. They can be products themselves, but they are generally more useful as intermediate feedstocks to perform a wide range of chemistry to make new products. For instance the diamine, hexamethylenediamine, is used to produce many synthetic polymers, based on aliphatic or semi-aromatic polyamides, such as Nylon (
By taking advantage of the amine-oxygen chemistry, sources such as (and with no limitations) biomass, lignin, tannic acid, terpenoids, cellulose, sugars, carbohydrates, proteins, fatty acids, naphthenic acids, chars, partially combusted materials, recycled waste, food wastes, coal, petroleum, asphaltenes, graphene oxide, oxidized asphalts, natural surfactants, oxidized plastics, hydroxylated or carboxylated polymers, functionalized polymers including polyethylene terephthalate, polyurethane resin, polyacetates and acrylates of ethylene, oxidized composites and oxidized asphaltenes can be reacted with amines to increase extraction of organic components, change their solubility, mechanical properties and add functionality to derive more useful chemical and material feedstocks.
It should be understood that the present invention includes a variety of aspects, which may be combined in different ways. The following descriptions are provided to list elements and describe some of the embodiments of the present invention. These elements are listed with initial embodiments; however, it should be understood that they may be combined in any manner and in any number to create additional embodiments. The variously described examples and preferred embodiments should not be construed to limit the present invention to only the explicitly described systems, techniques, and applications. The specific embodiment or embodiments shown are examples only. The specification should be understood and is intended as supporting broad claims as well as each embodiment, and even claims where other embodiments may be excluded. Importantly, disclosure of merely exemplary embodiments is not meant to limit the breadth of other more encompassing claims that may be made where such may be only one of several methods or embodiments which could be employed in a broader claim or the like. Further, this description should be understood to support and encompass descriptions and claims of all the various embodiments, systems, techniques, methods, devices, and applications with any number of the disclosed elements, with each element alone, and also with any and all various permutations and combinations of all elements in this or any subsequent application.
Examples of how amine or amide chemistry can be used to tune properties of oxygen containing hydrocarbons:
Asphaltenes from oxidized asphalts, by reaction with amines or amides, can be rendered more soluble, improving relaxation properties and restoring mechanical properties of oxidized asphalt. This reaction also reduces the hydrophilic and hydroscopic nature of asphaltenes produced from oxidation, and other oxygen rich asphaltenes or other oxygen rich material, to render them more hydrophobic, lyophilic or oleophilic. Oxidized asphaltenes from reclaimed asphalt shingles (RAS) or reclaimed asphalt pavements (RAP) can be reacted after isolation, or in-situ the RAS or RAP or in-situ blends of RAS and/or RAP with fresh asphalt, with amines to reduce the content of polar asphaltenes leading to a decrease in the brittleness of this material.
Likewise plastics or polymers with oxygen functions can be reacted with amines to give them new functions and properties, or help them to be recycled in various applications such as asphalt. Additionally it has been shown that highly cross-linked oxygen rich aged biomass can be reacted with amines to convert as much as 82% to 74% into toluene-soluble liquids (where not indicated otherwise, a % refers to wt. %). Depending on the reaction conditions and the type of amine, the amount of this extracted material that is soluble in heptane can be tuned.
It has been demonstrated that naturally occurring oxygen rich surfactants from petroleum—that produce strong emulsions—can be rendered interfacially inactive by a reaction with amines.
Laboratory Oxidized Asphalt Reacted with Decyalmine
The SHRP core asphalt AAA-1 was oxidized by RTFO+40 hr PAV according to respectively ASTM D4887 and ASTM D6521 was treated with excess amine (20 volumes) at 120° C. and at 180° C. for 24 hrs with simple stirring at 200 rpm. Note that this time duration is not critical, as times within other ranges are possible (e.g., 5 seconds to 1 minute, 5 seconds to 30 minutes, 5 seconds to one hour, and 5 seconds to 24 hours). After the reaction the excess decylamine was removed by vacuum distillation. It was found that there was higher conversion of the oxidized asphaltenes to more soluble fractions by SAR-AD at 180° C. The SAR-AD data in Table 3 shows how the asphaltenes decreased upon heat treatment, by more than 50% after 180° C. treatment, and that the more soluble and less polar and associating Resins and Aromatics 3 fractions increased in concentration. This leads to a much better stability of the asphalt as shown by the colloidal instability index (CII).
FTIR spectra in
AAA-1 RTFO+40 hr PAV was treated with decylamine at different concentrations (0, 2, 4, 8, and 32%) at asphalt blending and storage conditions around 160-180° C. for 30 minutes using simple stirring at 200 rpm. SAR-AD results in Table 4 showed that the amount of asphaltenes decreased steadily with the amount of amine until about 8% amine, the Resins and Aromatics 3 increase, and the CII improves. This shows how amines can be reacted with oxidized asphalt to change the oxidized components into more soluble fractions and softens the asphalt significantly, restoring relaxation. This is an example of how to chemically reverse the effects of oxidative aging.
Additional blending experiments were performed by blending AAA-1 RTFO+40 hr PAV with decylamine at 160° C. for 30 minutes followed by vacuum distillation to ensure that any excess residual decylamine, if any, was removed from the asphalt. For comparison the aged AAA-1 RTFO+40 hrs PAV sample was also treated in the same way. DSR characterization of the material according to ASTM D7552 showed that as the amount of amine increased the asphalt became significantly softer (upper PG) at higher temperature and that the low temperature PG decreased with no detriment to the relaxation properties of the asphalt (Table 5) as measured by the m-value parameter—the higher the m-value, the higher the relaxation capability.
Asphalt Blended with Precipitated Asphaltenes and Stabilized with Decylamine.
The reaction of amines can also be used to help compatibilize asphaltenes containing oxygen functional groups produced from industrial processes such as partial upgrading, paraffinic froth treatment, naphthenic froth treatment, deasphalting, supercritical deasphalting, emulsion deasphalting, aliphatic solvent precipitation, naphthenic solvent precipitation, centrifugation, ultracentrifugation or by other methods that are used to produce asphaltenes. This is shown by blending in asphaltenes from an emulsion precipitation process with asphalt AAA-1 (further named AAA-1) and then blending the asphaltenes with AAA-1 with 2% decylamine. When decylamine is not used and AAA-1 is blended with 10 wt % asphaltenes the upper PG properties increase significantly, however the low temperature PG also increases very significantly and the ΔTc value is decreases. When decylamine is used the low temperature properties are significantly improved. By adding decylamine with the asphaltenes the lower PG decrease by 6° C. and the ΔTc improved by 2° C., relative to the blend with no decylamine. As ΔTc decreases, usually due to a greater change in the m-value (or rate of relaxation) compared to the S (stiffness) the material becomes more brittle and prone to cracking, especially at low temperatures. The m-value related to the binder relaxation and S being its stiffness modulus are traditionally measured by bending beam rheometry, but they can also be measured by dynamic shear rheometry (ASTM D7552 and TechBrief FHWA-HRT-15-053). The ΔTc is simply the subtraction of the critical (or continuous) S and critical (or continuous) m-value temperatures, as the value goes more negative there is a loss in relaxation relative to the stiffness (ASTM D7643). For paving applications, it is desirable that after laboratory RTFO and PAV (or equivalent USAT aging (TechBrief FHWA-HRT-15-054)) oxidative aging that the asphalt binders maintain a ΔTc above −5° C., values below −5 are considered at risk of cracking. It must be noted that these ΔTc values are not strictly applicable to polymer modified asphalts since the properties form the interacting polymer modifier begin to dominate over the properties of the asphalt. Typically, asphalts are more sensitive towards changes in the m-value, so an improvement in the m-value generally leads to an improvement in the ΔTc.
Reacting amines or amides to compatibilize asphaltenes with asphalt, to rejuvenate or restore properties of RAP or RAS, or to compatibilize other oxygen containing material in asphalt for performance enhancement or recycling has the added benefit of introducing antistripping properties. Nitrogen is well known to reduce moisture damage which occurs at the rock aggregate surface and between adsorbed asphalt molecules. Moisture damage is increased when the adsorbed asphalt molecules contain oxygen but mitigated when nitrogen is present. The amine reaction also acts to increase the solubility of materials; this not only improves the ΔTc and m-values as discussed, it also leads to a lowering of the stiffens (S), lower PG and upper PG. These are all desirable traits, to one degree or another, to restore or chemically rejuvenate oxidized asphalt pavements and shingles. Ideally, the upper PG would like to be least affected. This rejuvenation or softening of the material also produces other added benefits such as improved workability, lower application temperature, better compaction and lowered emissions.
Examples from above only deal with the reaction of materials with mono-amines. Many other useful materials can be produced by adding diamines to form dimers, oligomers or polymers. If a large excess of the diamines or polyamines are used then it is possible to create functionalized asphaltenes with pendent amine groups to perform additional chemistry. If the oxygen containing feedstocks on average contains several molecules with two more oxygen atoms of the appropriate functional group, and this is reacted with a diamine, then highly polymerized or cross-linked polymeric materials can be formed. Additional polymerization and cross-linking can be modulated by using polyamines alone or in combination with diamines and monoamines. The degree of polymerization and cross-linking can also be modulated by using molecules with the appropriate di-oxygen or poly-oxygen functional groups in desired geometries and reactivities. Other polymeric materials can be produced with oxygen containing feedstocks and diamines or polyamines by using a combination of comonomers from dialcohols, diketones, dialdehyes, dicarboxylic acids, or dianhydrides or any combination of these, or by sequential reaction.
Similarly, amines containing unsaturated alkyl functional groups can be used to do additional cross-linking through the unsaturated bonds thermally or by addition of other cross-linking agents like sulfur or others. The double bonds may also be used for activation by photosensitizers or by thermal activators to produce cross-linking that are useful for 3-d printing resins. Other options, besides epoxidation, are to perform other chemistry on the unsaturated bond such as formation of epoxides. Additional useful chemistry that can be applied to the unsaturated bond are addition reactions, hydration, halogenation, hydrohalogenation, halohydrin, oxidation, photooxygenation, hydroamination, hydroformylation, carboxylation, carbonalkoxylation, alkylation, ozonolysis, olefin metathesis, hydroacylation.
Reacting amines with oxygen containing hydrocarbons do not preclude decomposition of the amine to form nitriles, do hydrogen donation, or reactions promoting alkyl chain transfer or reaction at other active hydrocarbon sites. Primary amine and alkyl substituents, and secondary amines will also work as well as amines with aryl and cyclic groups.
Amines can also be reacted with feedstock such as oxygen rich biomass, peat, coal, oxidized reclaimed coal, activated carbon, lignin, tannic acid, terpenoids, cellulose, carbohydrates, sugars, carbohydrates, proteins, fatty acids, lipids, nucleic acids, naphthenic acids, municipal waste, food wastes, sewage graphene oxide, hole containing graphene oxide, oxygen containing carbon nanoparticles, oxygen containing carbon nano-tubes, oxygen containing carbon nano-ribons, oxidized plastics, oxygen containing plastics like polyethylene terephthalate, oxidized composite materials, oxygen containing composite material, kerogen, oxidized kerogen, combusted material, partially combusted material, chars, petroleum, asphaltenes, interfacial asphaltenes, oxidized asphalts, oxidized asphaltene, asphaltenes produced from oxidation of hydrocarbon sources, natural surfactants, autoxidation products from petroleum, autoxidation products from natural gas, autoxidation products from biomass, autoxidation products from chemical refining, epoxy, epoxy form wind turbine blades, hydroxylated or carboxylated polymers, functionalized polymers including polyethylene terephthalate, polyurethanes, polyacetates and acrylates of ethylene to extract smaller molecules that are soluble in common solvents provide very soluble fractions as feedstocks for chemicals or materials for the following applications (non exclusive):
While the invention has been described in connection with some preferred embodiments, it is not intended to limit the scope of the invention to the particular form set forth, but on the contrary, it is intended to cover such alternatives, modifications, and equivalents as may be included within the spirit and scope of the invention as defined by the statements of inventions. Examples of alternative claims (clauses) may include:
1. A method of processing an oxygen comprising feedstock to an amine/amide reacted liquid phase with a different solubility, polarity and functionality, the method comprising the steps of:
As can be easily understood from the foregoing, the basic concepts of the present invention may be embodied in a variety of ways. It involves both material modulation techniques (e.g., by contacting the amine with an oxygen containing hydrocarbon with temperature to facilitate reactions to reduce the oxygen content and change the solubility, polarity, melt properties and/or functionality of the products), as well as devices to accomplish the appropriate modulation. In this application, the modulation techniques are disclosed as part of the results shown to be achieved by the various devices described and as steps which are inherent to utilization. They are simply the natural result of utilizing the devices as intended and described. In addition, while some devices are disclosed, it should be understood that these not only accomplish certain methods but also can be varied in a number of ways. Importantly, as to all of the foregoing, all of these facets should be understood to be encompassed by this disclosure.
The discussion included in this provisional application is intended to serve as a basic description. The reader should be aware that the specific discussion may not explicitly describe all embodiments possible; many alternatives are implicit. It also may not fully explain the generic nature of the invention and may not explicitly show how each feature or element can actually be representative of a broader function or of a great variety of alternative or equivalent elements. As one example, terms of degree, terms of approximation, and/or relative terms may be used. These may include terms such as the words: substantially, about, only, and the like. These words and types of words are to be understood in a dictionary sense as terms that encompass an ample or considerable amount, quantity, size, etc. as well as terms that encompass largely but not wholly that which is specified. Further, for this application if or when used, terms of degree, terms of approximation, and/or relative terms should be understood as also encompassing more precise and even quantitative values that include various levels of precision and the possibility of claims that address a number of quantitative options and alternatives. For example, to the extent ultimately used, the existence or non-existence of a substance or condition in a particular input, output, or at a particular stage can be specified as substantially only x or substantially free of x, as a value of about x, or such other similar language. Using percentage values as one example, these types of terms should be understood as encompassing the options of percentage values that include 99.5%, 99%, 97%, 95%, 92% or even 80% of the specified value or relative condition; correspondingly for values at the other end of the spectrum (e.g., substantially free of x, these should be understood as encompassing the options of percentage values that include not more than 0.5%, 1%, 3%, 5%, 8%, 10%, 15% or even 20% of the specified value or relative condition, all whether by volume or by weight as either may be specified. For example, using percentage values as one example, for a product to be substantially only the desired product, it should be understood that embodiments of the invention may encompass the option of percentage values that include 99.5%, 99%, 97%, 95%, 92% or even 90% of the output being the desired product. Correspondingly for values at the other end of the spectrum (e.g., substantially free of a substance, embodiments of the invention should be understood as encompassing the options of percentage values that include not more than 0.5%, 1%, 3%, 5%, 8% or even 10% of the substance, whether by volume or by weight.} In context, these should be understood by a person of ordinary skill as being disclosed and included whether in an absolute value sense or in valuing one set of or substance as compared to the value of a second set of or substance. Again, these are implicitly included in this disclosure and should (and, it is believed, would) be understood to a person of ordinary skill in this field. Where the invention is described in device-oriented terminology, each element of the device implicitly performs a function. Any specific indication in this application of a certain percentage (e.g., a wt % of one material in another) should be understood to also include disclosure of a range centered on that certain percentage (%), bounded by inclusive endpoints that are equal to that certain % plus and minus 2 percentage points, 5 percentage points, 7 percentage points, 10 percentage points, and 15 percentage points (so a specifically disclosed percentage of 20% should be understood as including disclosure of a range of, e.g., 18-22% (inclusive), 15-25% (inclusive), etc.) Similar implied disclosure is intended to take place with respect to other specific parameter values (i.e., accompanying such explicit disclosure is an implicit disclosure of a range centered on that explicit value that is bounded by inclusive endpoints that are equal to that certain value plus and minus 2 percentage points (of that value), 5 percentage points, 7 percentage points, 10 percentage points, and 15 percentage points. So an explicitly disclosed temperature of 20° C. includes disclosure of a temperature that is at least 18° C. up to and including 2° C. (i.e., plus and minus 10%). Apparatus claims may not only be included for the device described, but also method or process claims may be included to address the functions the invention and each element performs. Neither the description nor the terminology is intended to limit the scope of the claims that will be included in any subsequent patent application.
It should also be understood that a variety of changes may be made without departing from the essence of the invention. Such changes are also implicitly included in the description. They still fall within the scope of this invention. A broad disclosure encompassing both the explicit embodiment(s) shown, the great variety of implicit alternative embodiments, and the broad methods or processes and the like are encompassed by this disclosure and may be relied upon when drafting the claims for any subsequent patent application. It should be understood that such language changes and broader or more detailed claiming may be accomplished at a later date (such as by any required deadline) or in the event the applicant subsequently seeks a patent filing based on this filing. With this understanding, the reader should be aware that this disclosure is to be understood to support any subsequently filed patent application that may seek examination of as broad a base of claims as deemed within the applicant's right and may be designed to yield a patent covering numerous aspects of the invention both independently and as an overall system.
Further, each of the various elements of the invention and claims may also be achieved in a variety of manners. Additionally, when used or implied, an element is to be understood as encompassing individual as well as plural structures that may or may not be physically connected. This disclosure should be understood to encompass each such variation, be it a variation of an embodiment of any apparatus embodiment, a method or process embodiment, or even merely a variation of any element of these. Particularly, it should be understood that as the disclosure relates to elements of the invention, the words for each element may be expressed by equivalent apparatus terms or method terms—even if only the function or result is the same. Such equivalent, broader, or even more generic terms should be considered to be encompassed in the description of each element or action. Such terms can be substituted where desired to make explicit the implicitly broad coverage to which this invention is entitled. As but one example, it should be understood that all actions may be expressed as a means for taking that action or as an element which causes that action. Similarly, each physical element disclosed should be understood to encompass a disclosure of the action which that physical element facilitates. Regarding this last aspect, as but one example, the disclosure of a “process” should be understood to encompass disclosure of the act of “processing”—whether explicitly discussed or not—and, conversely, were there effectively disclosure of the act of “processing”, such a disclosure should be understood to encompass disclosure of a “process” and even a “means for processing” Such changes and alternative terms are to be understood to be explicitly included in the description. Further, each such means (whether explicitly so described or not) should be understood as encompassing all elements that can perform the given function, and all descriptions of elements that perform a described function should be understood as a non-limiting example of means for performing that function.
Any patents, publications, or other references mentioned in this application for patent are hereby incorporated by reference. Any priority case(s) claimed by this application is hereby appended and hereby incorporated by reference. In addition, as to each term used it should be understood that unless its utilization in this application is inconsistent with a broadly supporting interpretation, common dictionary definitions should be understood as incorporated for each term and all definitions, alternative terms, and synonyms such as contained in the Random House Webster's Unabridged Dictionary, second edition are hereby incorporated by reference. Finally, all references listed in the list of References To Be Incorporated By Reference In Accordance With The Provisional Patent Application or other information statement filed with the application are hereby appended and hereby incorporated by reference, however, as to each of the above, to the extent that such information or statements incorporated by reference might be considered inconsistent with the patenting of this/these invention(s) such statements are expressly not to be considered as made by the applicant(s).
Thus, the applicant(s) should be understood to have support to claim and make a statement of invention to at least: i) each of the method-related devices as herein disclosed and described, ii) the related methods disclosed and described, iii) similar, equivalent, and even implicit variations of each of these devices and methods, iv) those alternative designs which accomplish each of the functions shown as are disclosed and described, v) those alternative designs and methods which accomplish each of the functions shown as are implicit to accomplish that which is disclosed and described, vi) each feature, component, and step shown as separate and independent inventions, vii) the applications enhanced by the various systems or components disclosed, viii) the resulting products produced by such processes, methods, systems or components, ix) each system, method, and element shown or described as now applied to any specific field or devices mentioned, x) methods and apparatuses substantially as described hereinbefore and with reference to any of the accompanying examples, xi) an apparatus for performing the methods described herein comprising means for performing the steps, xii) the various combinations and permutations of each of the elements disclosed, xiii) each potentially dependent claim or concept as a dependency on each and every one of the independent claims or concepts presented, and xiv) all inventions described herein.
With regard to claims whether now or later presented for examination, it should be understood that for practical reasons and so as to avoid great expansion of the examination burden, the applicant may at any time present only initial claims or perhaps only initial claims with only initial dependencies. The office and any third persons interested in potential scope of this or subsequent applications should understand that broader claims may be presented at a later date in this case, in a case claiming the benefit of this case, or in any continuation in spite of any preliminary amendments, other amendments, claim language, or arguments presented, thus throughout the pendency of any case there is no intention to disclaim or surrender any potential subject matter. It should be understood that if or when broader claims are presented, such may require that any relevant prior art that may have been considered at any prior time may need to be re-visited since it is possible that to the extent any amendments, claim language, or arguments presented in this or any subsequent application are considered as made to avoid such prior art, such reasons may be eliminated by later presented claims or the like. Both the examiner and any person otherwise interested in existing or later potential coverage, or considering if there has at any time been any possibility of an indication of disclaimer or surrender of potential coverage, should be aware that no such surrender or disclaimer is ever intended or ever exists in this or any subsequent application. Limitations such as arose in Hakim v. Cannon Avent Group, PLC, 479 F.3d 1313 (Fed. Cir 2007), or the like are expressly not intended in this or any subsequent related matter. In addition, support should be understood to exist to the degree required under new matter laws—including but not limited to European Patent Convention Article 123(2) and United States Patent Law 35 USC 132 or other such laws—to permit the addition of any of the various dependencies or other elements presented under one independent claim or concept as dependencies or elements under any other independent claim or concept. In drafting any claims at any time whether in this application or in any subsequent application, it should also be understood that the applicant has intended to capture as full and broad a scope of coverage as legally available. To the extent that insubstantial substitutes are made, to the extent that the applicant did not in fact draft any claim so as to literally encompass any particular embodiment, and to the extent otherwise applicable, the applicant should not be understood to have in any way intended to or actually relinquished such coverage as the applicant simply may not have been able to anticipate all eventualities; one skilled in the art, should not be reasonably expected to have drafted a claim that would have literally encompassed such alternative embodiments.
Further, if or when used, the use of the transitional phrase “comprising” is used to maintain the “open-end” claims herein, according to traditional claim interpretation. Thus, unless the context requires otherwise, it should be understood that the term “comprise” or variations such as “comprises” or “comprising”, are intended to imply the inclusion of a stated element or step or group of elements or steps but not the exclusion of any other element or step or group of elements or steps. Such terms should be interpreted in their most expansive form so as to afford the applicant the broadest coverage legally permissible. The use of the phrase, “or any other claim” is used to provide support for any claim to be dependent on any other claim, such as another dependent claim, another independent claim, a previously listed claim, a subsequently listed claim, and the like. As one clarifying example, if a claim were dependent “on claim 20 or any other claim” or the like, it could be re-drafted as dependent on claim 1, claim 15, or even claim 25 (if such were to exist) if desired and still fall with the disclosure. It should be understood that this phrase also provides support for any combination of elements in the claims and even incorporates any desired proper antecedent basis for certain claim combinations such as with combinations of method, apparatus, process, and the like claims.
Finally, any claims set forth at any time are hereby incorporated by reference as part of this description of the invention, and the applicant expressly reserves the right to use all of or a portion of such incorporated content of such claims as additional description to support any of or all of the claims or any element or component thereof, and the applicant further expressly reserves the right to move any portion of or all of the incorporated content of such claims or any element or component thereof from the description into the claims or vice-versa as necessary to define the matter for which protection is sought by this application or by any subsequent continuation, division, or continuation-in-part application thereof, or to obtain any benefit of, reduction in fees pursuant to, or to comply with the patent laws, rules, or regulations of any country or treaty, and such content incorporated by reference shall survive during the entire pendency of this application including any subsequent continuation, division, or continuation-in-part application thereof or any reissue or extension thereon.
This international, PCT application claims priority to, and benefit of, U.S. Provisional Patent Application No. 62/817,754, filed Mar. 13, 2019, said provisional application hereby incorporated herein in its entirety.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US2020/022467 | 3/12/2020 | WO | 00 |
| Number | Date | Country | |
|---|---|---|---|
| 62817754 | Mar 2019 | US |
