Patent Application
20160083673
The present invention relates to a novel method for preparing stabilised oil formulations by means of certain carbodiimides.
A series of base oils and lubricant base substances, e.g. triglycerides, synthetic carboxylic esters, phosphoric acid triesters, olefin-dicarboxylic acid copolymers and silicone oils, are attacked by water or oxidizing agents forming acidic cleavage products and alcohols. These acidic cleavage products are a measure of the degree of decomposition. They can be quantitatively specified in the form of the acid number such that these serve as a measure of the degree of ageing of the lubricant oils.
The presence of acids or acidic cleavage products accelerates the hydrolysis autocatalytically. Since water is always present in low amounts under industrial conditions, the service life of lubricants is limited accordingly. As described in DE 4435548 A1, the addition of oil-soluble carbodiimides can effectively prevent hydrolytic decomposition. The methods described in the prior art for preparing oil formulations stabilised with carbodiimides have the disadvantage, however, that solid carbodiimides are used. These must first be melted and subsequently be stirred into the warmed oil formulations. This procedure is very inconvenient and moreover uneconomic. Ideally, the carbodiimides should be stirred in at low temperatures. In addition, in this process the carbodiimides tend to eliminate toxic isocyanates and isocyanates volatile at the temperatures used.
The object of the present invention, therefore, consists of providing methods not having the disadvantages of the prior art.
It has now been found, surprisingly, that oil formulations can be stabilised in a simple manner by the method according to the invention and thereby rendering this process economic for the lubricant industry. Furthermore, the method according to the invention also makes a significant contribution to improving occupational hygiene and environmental protection.
The present invention therefore relates to a novel method for preparing oil formulations, in which at least one carbodiimide of the formula (I)
where
R1═CH3 or CH(CH3)2 and R2═H or CH(CH3)2,
is added to at least one oil at temperatures of 10-40° C., preferably 15-30° C.
In a particularly preferred embodiment of the invention, R1═CH3 and R2═H.
In a further preferred embodiment of the invention, R1═R2═CH(CH3)2.
The carbodiimides of the formula (I) are commercially available compounds obtainable from, for example, Rhein Chemie Rheinau GmbH under the trade names Stabaxol® or Additin®.
Particular preference is given to bis-o-tolylcarbodiimide, commercially available from Rhein Chemie Rheinau GmbH under the trade name Stabaxol®MTC.
In the context of the invention, the oil preferably takes the form of mineral oils, particularly preferably low-sulphur naphthenic base oils and/or natural fats, oils or waxes,—triglycerides, preferably soybean oil, rapeseed oil or sunflower oil and also synthetically prepared esters, for example, starting from methanol, 2-ethylhexanol, glycol, glycerol, trimethylpropanol (TMP), pentaerythritol or neopentyl glycol esterified with, e.g. stearic acid, oleic acid, adipic acid, terephthalic acid and trimellitic acid.
In a preferred embodiment of the present invention, the oil is a trimethylolpropane ester (TMP) of the general formula (II)
Suitable trimethylolpropane esters are known from the German patent application DE 10 2004 025 939 A. In the general formula (II) above, the residues R3, R4 and R5, which may each be the same or different, have a linear or branched alkyl group having 5 to 22 carbon atoms. In a further preferred embodiment of the present invention, the residues R3, R4 and R5, which may each be the same or different, define a linear or branched alkyl group having 7 to 18 carbon atoms.
Particular preference is given here to trimethylolpropane trioleate (TMP oleate).
With regard to the synthetically prepared esters based on methanol, rapeseed oil methyl ester is preferred.
In a further preferred embodiment of the invention, a mixture of oils is used.
The oil formulations stabilised by the method according to the invention may also further comprise customary additives for this field of application. For example, these may be antioxidants or metal deactivators.
In a further embodiment, the oil formulation therefore comprises in addition 0.005 to 1.0% by weight of an antioxidant and/or 0.01 to 2.0% by weight of a metal deactivator, based in each case on the oil formulation.
The preferred amount of antioxidant is between 0.1 and 0.5% by weight and particularly 0.1-0.2% by weight, based on the oil formulation.
The preferred amount of metal deactivator is between 0.1 and 1.0% by weight and particularly 0.1-0.2% by weight, based on the oil formulation.
The antioxidants are preferably selected from the group consisting of bishydroxytoluene, hydroquinone, 4-tert-butylcatechol, naphthol, phenylnaphthylamines, diphenylamines, phenolic thioethers, tocopherols and mixtures of the substances listed.
The metal deactivator is preferably selected from the group consisting of organic heteroatom compounds, particularly preferably triazoles, tolyitnazoles, dimercaptothiadiazoles and mixtures of the substances listed.
To stabilise the oil formulations prepared in accordance with the invention, concentrations of 0.05-2% by weight, preferably 0.1-1% by weight and particularly preferably 0.2-0.5% by weight of carbodiimide are used, based on the oil formulation.
The carbodiimide is preferably added in a mixing or storage vessel, particularly preferably directly in the container, preferably in a drum or container.
In a preferred embodiment of the invention, the carbodiimide is poured into the oil or pumped in via a pipe. Mixing generally already occurs while metering in, which can be enhanced, however, by stirring units such as paddle stirrers, helical stirrers or anchor stirrers, dispersants, drum or container stirrers.
In a further preferred embodiment of the invention, the carbodiimide is charged in the mixing or storage vessel, particularly preferably directly in the container, preferably in a drum or container, and the oil subsequently poured in. On pouring in the oil, generally an adequate mixing already occurs.
The invention further relates also to oil formulations prepared by the method according to the invention and also the use thereof as process oils, fuels, heat transfer oils, motor oils, fats, metalworking fluids, turbine and transformer oils.
The examples which follow serve to illustrate the invention but have no limiting effect.
In the examples which follow, the following substances were used:
SXL MTC=StabaxolfMTC, a liquid carbodiimide of the formula (I) where R1═CH3, R2═H from Rhein Chemie Rheinau GmbH.
SXL I Liq=Stabaxol® I Liq, a carbodiimide of the formula (I) where R1=2=CH(CH3)2.
SXL I=Stabaxol® I, a solid monomeric carbodiimide based on 2,6-diisopropylphenyl isocyanate from Rhein Chemie Rheinau GmbH.
TMP oleate=Synative® ES TMP 05 from BASF SE.
Rapeseed oil methyl ester (RME) from ADM Hamburg AG.
The “Beverage bottle test” ASTM D 2619 is part of internationally recognised oil formulation specifications and is used to test the hydrolytic stability of liquids. The increase in the acid number is monitored as a measure of the hydrolytic stability.
The results in Table 1 show that the hydrolytic stability of the oil formulations prepared by the method according to the invention is increased even when using lower carbodiimide concentrations. In addition, the temperature must be increased to 80° C. for the compounds of the prior art in order to be able to prepare a solution at all, which is inconvenient and is accompanied by undesirable decomposition processes releasing toxic substances.
It was shown that the mixture according to the invention, even at temperatures of 30° C., lead to a distinctly reduced acid number.
| Number | Date | Country | Kind |
|---|---|---|---|
| 13166762.8 | May 2013 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2014/059217 | 5/6/2014 | WO | 00 |
