Patent Application
20060194705
The present disclosure relates to methods of treating polymeric substrates, and more specifically, to methods of applying a mixture of cleaning solvent with titanate adhesion promoter.
The treatment of polymeric substrates presents difficulties in many types of manufacturing operations, including aircraft manufacturing. Conventional treatment of polymeric substrates, particularly those that are considered to be aged rather than fresh, include scuff-sanding and chemical treatment methods. Although desirable results have been achieved using these methods, there is room for improvement. For example, because scuff-sanding methods are relatively labor intensive, such methods may be time-consuming and costly. Similarly, chemical treatment methods may involve relatively-complex and expensive processes. In addition to being complex and expensive, chemical treatment in preparation for adhesion often consists solely of a cleaning step, which is sometimes insufficient for effective adhesion to subsequent material layers. Typically, performing the abrasive process of scuff-sanding must be accompanied by a separate process of chemical cleaning, but a single step process is desirable for efficiency. Therefore, current treatments may lack economic and production efficiency.
The present invention is directed to methods of applying a cleaning solvent with a titanate promoter compound. Embodiments of the present invention may provide an effective solution to production and labor issues, including cost and time, associated with preparing various treated surfaces for the application of a fresh material to the surface. Furthermore, embodiments of the present invention may create a single-step method of simultaneously cleaning and promoting adhesion that eliminates the need for using scuff sanding and other layer-removal methods. Embodiments of the present invention may be capable of use in the aerospace industry and any other industry where surface preparation and adhesion are important.
In one embodiment, a polymeric substrate surface is treated with a reactivation solution comprising a chemical blend of volatile organic compounds and a suitable titanate adhesion promoter compound. The reactivation solution may also include co-solvents and surfactants and other desired ingredients as necessary to promote cleaning and adhesion of the surface. Upon combining the cleaning agent, adhesion promoter compound and other desired ingredients to form the reactivation solution, the solution is applied to the polymeric surface, and the treated surface, herein referred to as the substrate, is simultaneously cleaned and reactivated. Here, reactivation means that the substrate is restored to a condition whereby adhesion between the substrate and a second material is promoted.
Preferred and alternate embodiments of the present invention are described in detail below with reference to the following drawings.
The present invention relates to methods of applying a cleaning solvent with a titanate adhesion promoter compound to form a reactivation solution. Many specific details of certain embodiments of the invention are set forth in the following description and in
In general, embodiments of methods in accordance with the present invention provide an efficient and cost-effective solution to production and labor issues associated with preparing various polymeric substrate surfaces for adhesion between the substrate and a second material. Because embodiments of the present invention are adapted to handle a wide variety of substrate surfaces, multiple applications may be suitable.
The reactivation solution in accordance with embodiments of the present invention may advantageously include a mixture of a cleaning agent and an adhesion promoter. In particular embodiments, the reactivation solution includes a chemical blend of volatile organic compounds, including but not limited to, Methyl Ethyl Ketone (MEK), Toluene, Isopropyl Alcohol (IPA), and Methyl Isobutyl Ketone (MIBK), and a suitable titanate adhesion promoter compound. In one particular embodiment, the four organic solvents listed above for the reactivation solution may currently be found in DESOCLEAN® 45 commercially-available from PRC-DeSoto International, Inc. of Glendale, Calif. The vapor pressure of the reactivation solution may be below about 45 mm Hg so as to meet environmental standards. Additional solvents, such as Oxol, may be added to the cleaning agent, as necessary, to assist in the solubility of the promoter. In the reactivation solution, there may be approximately equal volume ratios of MEK and Toluene. The volume ratio of MEK and Toluene may be adjusted so as to meet the vapor pressure standards and to achieve solubility of the adhesion promoter.
While not intending to be bound by theory, it is believed that, at least in some embodiments, methods in accordance with the present invention operate by at least one of 1) helping to ensure that the paint surface is clean (free of contaminants); 2) helping to remove loose components of the paint (in effect, these could behave as contaminants); and 3) swelling the coating (causing the entangled network of polymer chains to expand). The swelling of the coating may advantageously allow spaces (pores) for chains of the freshly-applied polymer to fit into, analogous to a lock and key mechanism.
Furthermore, and not intending to be bound by theory, methods in accordance with the present invention use a reactivation solution including an adhesion promoter that may reactivate paint by providing a chemical “bridge” between reactive sites on the fresh coating and reactive sites on the coating.
In addition, it is believed that combining solvent treatment with adhesion promoter (i.e. treating the surface with a solution of adhesion promoter dissolved in or dispersed in the solvent) can yield a more effective result than either treatment is capable of separately. Without being bound by theory, at least in some embodiments, cleaning with the solvent may remove surface oxidation that would expose more reactive sites for the adhesion promoter to bond to. Moreover, while the coating is swollen with solvent, adhesion promoter that has already bonded on one end to the fresh coating's reactive sites may locate itself inside the pores of the coating. At that point, two types of adhesion promoting phenomena may have occurred. First, paint chains may have bonded to the promoter which is bonded to the fresh paint, in which case the bonds between the coating and promoter are much more likely inside the swollen pores than they would have been at the surface, because there are more reactive sites (e.g. sites that haven't reacted with air to become oxidized and thus unreactive) beneath the coating surface. Second, promoter bonded to the fresh paint can be positioned inside the paint pores and may provide mechanical interlocking even if the promoter hasn't bonded to the paint. Mechanical interlocking may occur when chains of the promoter become entangled with chains of the coating. After the solvent evaporates, these entanglements may tighten as the system shrinks. Although entanglement benefits may occur with solvent alone, the entanglement benefit may be greater with the presence of adhesion promoter because the “keys” (free chains of promoter linked to fresh primer as well as free chains on the fresh primer itself) may be longer and more prevalent.
Those skilled in the art will readily recognize that embodiments of the present invention may be used to treat surfaces of a wide variety of components incorporated into a wide variety of different systems. For example,
Although the aircraft 300 shown in
Embodiments of the present invention may provide significant advantages over prior art treatment of polymeric substrates in preparation of applying a fresh coat to that surface. For example, embodiments of the present invention eliminate the administration of scuff sanding to a polymeric substrate, thereby providing an efficient and cost-effective solution to the labor and production issues related to scuff sanding. Embodiments of the present invention also present an economical single-step method of preparing a treated surface for the application of a new substrate. Furthermore, because embodiments of the present invention are capable of being applied to a variety of polymeric substrates, such embodiments are suitable for use in association with multiple functions.
While preferred and alternate embodiments of the invention have been illustrated and described, as noted above, many changes can be made without departing from the spirit and scope of the invention. Accordingly, the scope of the invention is not limited by the disclosure of these preferred and alternate embodiments. Instead, the invention should be determined entirely by reference to the claims that follow.
