Patent Grant
10570563
This application is a 371 of PCT/US/32381 filed 13 May 2016
There is a growing interest in displacing the use of petroleum-based materials such as thermoplastics across many industries, for example, packaging, automotive parts, adhesives, coatings, and composite materials. While cellulose is an additive used in some applications, its use in many areas, such as thermoplastics, is hampered by significant processing difficulties resulting from its material properties.
The present invention provides, inter alia, methods for modulating the hydrophilicity of cellulose. Cellulose normally is able to strongly interact with water, resulting in the formation of strong hydrogen bonds between cellulose surfaces upon drying. This propensity results in certain limits on the industrial applicability of cellulose, such as nanocellulose, due, among other reasons, to the difficulty in drying resulting compositions. Provided methods allow for modulation of the hydrophilicity of cellulose in various forms, thus allowing for the use of cellulose in processes and reactions previously considered unattractive for such use. By way of particular example, previous methods were unable to overcome the propensity of cellulose, and particularly nanocellulose, to form hydrogels, even at very low concentrations. As such, production of dry forms of the material were either unattainable, or prohibitively expensive for use. According to various aspects, provided methods overcome these and other issues with previously known methods.
In some embodiments, the present invention provides methods including the steps of providing cellulosic material, associating the cellulosic material with an organic acid (e.g., lactic acid) to form a mixture, and heating the mixture to a temperature between 100° C. and 120° C. for at least ten minutes to form a treated cellulosic material, wherein the water retention value of the treated cellulosic material is decreased by at least 10% as compared to untreated cellulosic material. In some embodiments, the organic acid is associated with the cellulosic material in a ratio of at least 1:1 by weight. In some embodiments, the organic acid is associated with the cellulosic material in a ratio of at least 6:1 by weight.
According to various embodiments, any of a variety of cellulosic materials may be used in provided methods. In some embodiments, the cellulosic material is selected from the group consisting of wood, wood waste, spent pulping/fractionation liquors, algal biomass, food waste, grasses, straw, corn stover, corn fiber, agricultural products and residuals, forest residuals, saw dust, wood shavings, sludges and municipal solid waste, bacterial cellulose and mixtures thereof. In some embodiments, the cellulosic material is nanocellulose. In some embodiments, the nanocellulose is or comprises cellulose nanofibrils or cellulose nanocrystals.
According to various embodiments, the mixture may be heated for any application-appropriate period of time. In some embodiments, the mixture is heated for at least 1 minute (e.g., 1, 2, 3, 4, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, or 55 minutes or more). In some embodiments, the mixture is heated for at least 1 hour (e.g., 1.5, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, or 12 hours or more). In some embodiments, the mixture is heated for at least 24 hours (e.g., 30 hours, 40 hours, 48 hours, 72 hours, 96 hours, 120 hours or more).
Various embodiments will allow for varying degrees of reduced water retention value in a particular cellulosic material. In some embodiments, the WRV of a treated cellulosic material is decreased by at least 10% (e.g., 20%, 30%, 40%, 50%, 60%, 70% or more) as compared to untreated cellulosic material. In some embodiments, the WRV is decreased by at least 50%.
In some embodiments, at least one of the associating and heating steps is carried out at a pressure at or below atmospheric pressure. In some embodiments, at least one of the associating and heating steps is carried out at a pressure above atmospheric pressure.
In some embodiments, the present invention also provides compositions comprising at least 20% (e.g., 30%, 40%, 50%, 60%, 70%, 80% or more) by weight of a treated cellulosic material (e.g., fibers) produced by a method according to any method provided herein.
As used in this application, the terms “about” and “approximately” are used as equivalents. Any citations to publications, patents, or patent applications herein are incorporated by reference in their entirety. Any numerals used in this application with or without about/approximately are meant to cover any normal fluctuations appreciated by one of ordinary skill in the relevant art.
Other features, objects, and advantages of the present invention are apparent in the detailed description that follows. It should be understood, however, that the detailed description, while indicating embodiments of the present invention, is given by way of illustration only, not limitation. Various changes and modifications within the scope of the invention will become apparent to those skilled in the art from the detailed description.
In order for the present invention to be more readily understood, certain terms are first defined below. Additional definitions for the following terms and other terms are set forth throughout the specification.
Approximately or about: As used herein, the term “approximately” or “about,” as applied to one or more values of interest, refers to a value that is similar to a stated reference value. In certain embodiments, the term “approximately” or “about” refers to a range of values that fall within 25%, 20%, 19%, 18%, 17%, 16%, 15%, 14%, 13%, 12%, 11%, 10%, 9%, 8%, 7%, 6%, 5%, 4%, 3%, 2%, 1%, or less in either direction (greater than or less than) of the stated reference value unless otherwise stated or otherwise evident from the context (except where such number would exceed 100% of a possible value).
Cellulose Nanofibrils: As used herein, the term “cellulose nanofibrils” refers to the state of cellulosic material wherein at least 75% of the cellulosic material would be considered to be “fines”. In some embodiments, the proportion of cellulosic material that may be considered fines may be much higher such as 80%, 85%, 90%, 95%, 99% or higher. In this disclosure, the terms “nanofibrils”, nanocellulose, highly fibrillated cellulose, super-fibrillated cellulose are all considered synonymous with cellulose nanofibrils.
Cellulose Nanocrystals: As used herein, the term “cellulose nanocrystals” refers to the state of cellulosic material wherein at least 75% of the cellulosic material would be considered to be “fines” and more that 50% of the original unorganized or amorphous cellulose content has been removed. In some embodiments, the proportion of cellulosic material that may be considered fines may be much higher such as 80%, 85%, 90%, 95%, 99% or higher, and more that 50% of the original unorganized or amorphous cellulose content has been removed.
Fines: As used herein, the term “fines” refers to cellulosic material, or a portion of a cellulosic fiber with a length weighted fiber length of less than 0.2 mm. In some embodiments, “fines” may refer to a cellulosic material that has a diameter of between 5 nm-100 nm, inclusive, and has a high surface to volume ratio. Improve, increase, or reduce: As used herein, the terms “improve,” “increase” or “reduce,” or grammatical equivalents, indicate values that are relative to a baseline measurement, such as a measurement in the same sample prior to initiation of a treatment described herein, or a measurement in a control sample (or multiple control samples) in the absence of a treatment described herein.
Substantially: As used herein, the term “substantially” refers to the qualitative condition of exhibiting total or near-total extent or degree of a characteristic or property of interest. One of ordinary skill in the chemical arts will understand that biological and chemical phenomena rarely, if ever, go to completion and/or proceed to completeness or achieve or avoid an absolute result. The term “substantially” is therefore used herein to capture the potential lack of completeness inherent in many biological and chemical phenomena.
Water retention value: As used herein, the term “water retention value,” or WRV, refers to the ratio of mass (weight) of water retained after centrifugation under specified conditions by a wet (i.e., undried) sample to the oven-dry mass (weight) of the same sample.
The present invention provides, inter alia, novel methods of modulating the hydrophilicity of cellulose, including nanocellulose, as well as compositions created using provided methods.
In some embodiments, the present invention provides methods including the steps of providing cellulosic material, associating the cellulosic material with an organic acid to form a mixture, and heating the mixture to a temperature between 100° C. and 120° C. for at least ten minutes to form a treated cellulosic material, wherein the water retention value of the treated cellulosic material is decreased by at least 10% as compared to untreated cellulosic material. In some embodiments, the organic acid is associated with the cellulosic material in a ratio of at least 1:1 by weight. In some embodiments, the organic acid is associated with the cellulosic material in a ratio of at least 6:1 by weight.
Cellulosic Material
According to various embodiments, any of a variety of cellulosic materials may be used in provided methods. In some embodiments, the cellulosic material is selected from the group consisting of wood, wood waste, spent pulping/fractionation liquors, algal biomass, food waste, grasses, straw, corn stover, corn fiber, agricultural products and residuals, forest residuals, saw dust, wood shavings, sludges and municipal solid waste, bacterial cellulose and mixtures thereof. In some embodiments, the cellulosic material is or comprises pulp fibers, microcrystalline cellulose, and cellulosic fibril aggregates. In some embodiments, the cellulosic material is nanocellulose. In some embodiments, the nanocellulose is or comprises cellulose nanofibrils. In some embodiments, the cellulose nanofibrils are or comprise microfibrillated cellulose, nanocrystalline cellulose, and bacterial nanocellulose.
Acids
According to various embodiments, provided methods allow for the use of a range of acids, as desired or required by a specific application thereof. In some embodiments, an acid may be any organic acid. In some embodiments, an acid may be a carboxylic acid. In some embodiments, an acid is lactic acid. In some embodiments, an acid is selected from the group consisting of lactic acid, levulinic acid, formic acid, acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, oxalic acid, oleic acid, malic acid, citric acid, benzoic acid, and carbonic acid. In some embodiments, only a single acid is used. In some embodiments, an acid may be a modified organic acid, including, but not limited to, Di-(2 ethylhexyl) phosphoric acid. In some embodiments, two or more acids are used. In some embodiments, an acid is a fluid (e.g., a liquid). In some embodiments, an acid (e.g., lactic acid) is not in solid form.
According to various embodiments, the amount/ratio of acid as compared to the amount of cellulosic material may vary considerably during the association step (s). In some embodiments, the ratio of acid to cellulosic material may be between 1:1 and 10:1 by weight. In some embodiments, the ratio of acid to cellulosic material is 6:1 by weight. In some embodiments, the ratio of acid to cellulosic material may be at least 1:1, 2:1, 3:1, 4:1, 5:1, 6:1, 7:1, 8:1, 9:1, or 10:1 by weight. In some embodiments, the ratio of acid to cellulosic material may be greater than 10:1 by weight (e.g., 11:1 or more). In some embodiments, the ratio of acid to cellulosic material may be less than 1:1. For example, in some embodiments, the ratio of acid to cellulosic material may be between 1:1 and 1:10 (e.g., 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, or 1:10).
Associating
According to various embodiments, one or more forms of cellulosic material may be associated with an organic acid (e.g., lactic acid) to form a mixture in any application-appropriate manner, with certain examples being shown in the Examples below. In some embodiments, associating will be or comprise: simple mixing of an organic acid and cellulosic material. In some embodiments, associating the organic acid(s) with cellulosic material under high shear, kneading or folding conditions may be beneficial.
Treatment
According to various embodiments, a provided mixture may be treated in any of a variety of ways. For example, in some embodiments, a mixture may be heated and/or exposed to a metal catalyst. In some embodiments, a metal catalyst may be or comprise nickel, cobalt, hafnium, zirconium, palladium, gold, ruthemium, rhodium, combinations thereof, and/or compounds containing one or more of these metal catalysts. One of skill in the art will recognize additional metal catalysts that may be used as a substitute or additional metal catalyst to the exemplary metal catalysts listed herein. In some embodiments, a mixture may be heated to at least the boiling temperature of water. In some embodiments, a mixture may be heated to between 100° C. and 200° C. (e.g., 100° C. to 190° C., 100° C. to 180° C., 100° C. to 170° C., 100° C. to 160° C., 100° C. to 150° C., 100° C. to 140° C., 100° C. to 130° C.). In some embodiments, a mixture may be heated to between 100° C. and 120° C. According to various embodiments, provided mixtures may be heated using any known method of heating a substance including, by way of non-limiting example only, heating in an oven, heating via friction or mixing, microwave energy absorption, or radiant heating.
In some embodiments, a mixture may be heated for any application-appropriate period of time. In some embodiments, the mixture is heated for at least 1 minute (e.g., 1, 2, 3, 4, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, or 55 minutes or more). In some embodiments, the mixture is heated for at least 1 hour (e.g., 1.5, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, or 12 hours or more). In some embodiments, the mixture is heated for at least 24 hours (e.g., 30 hours, 40 hours, 48 hours, 72 hours, 96 hours, 120 hours or more).
Water Retention Value (WRV)
In some embodiments, provided methods allow for the production of modified cellulosic materials exhibiting a significantly reduced water retention values as compared to untreated cellulosic materials (control cellulosic materials) and/or those treated with previously known methods. Various embodiments will allow for varying degrees of reduced water retention value in a particular cellulosic material. In some embodiments, the WRV is decreased by at least 10% (e.g., 20%, 30%, 40%, 50%, 60%, 70% or more). In some embodiments, the WRV is decreased by at least 50%.
Methods of ascertaining the WRV of a sample are known in the art, including, for example, the methods described in Cheng et al, Cellulose water retention value, 2010, Bioresources, 5(3): 1945-1954. The Technical Association of Pulp and Paper Industry has also published a useful test method, TAPPI UM 256 um-15, that is also used to determine WRV of cellulose materials.
In some embodiments, the WRV can be measured under different conditions. In some embodiments, the WRV can be measured by determination of the quantity of water that fibers can absorb and retain under strictly controlled conditions. In some embodiments, factors that may influence WRV measurements include sample weights, centrifugal time and force, pore size of filters used in the measurement setup, and cellulosic particle/fibril size.
Percent Esterification
In some embodiments, provided methods allow for the production of modified cellulosic materials exhibiting a significantly increased degree of esterification as compared to untreated cellulosic materials (control cellulosic materials) and/or those treated with previously known methods. The degree of esterification may be assessed using any known method, including, as non-limiting examples, Fourier Transform Infrared Spectroscopy (FT-IR) and nuclear magnetic resonance (NMR). In some embodiments, provided modified cellulosic materials exhibit a degree of esterification that is at least 10% (e.g., at least 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90%, 100% or more) higher than untreated/control cellulosic materials.
Other Exemplary Conditions and Considerations
Various embodiments may include reaction conditions occurring at any of a variety of pressures. In some embodiments, at least one of the associating and heating steps is carried out at a pressure at or below atmospheric pressure. In some embodiments, at least one of the associating and heating steps is carried out at a pressure above atmospheric pressure, for example, at a pressure between about 20 torr and about 3 bar (e.g., 15 torr to 3 bar, 10 torr to 3 bar, 5 torr to 3 bar, or 1 torr to 3 bar). In some embodiments, at least one of the associating and heating steps is carried out at a pressure equal to or greater than 20 torr. In some embodiments, at least one of the associating and heating steps is carried out at a pressure equal to or less than 3 bar.
Compositions/Treated Cellulosic Materials
In some embodiments, the present invention also provides compositions comprising at least 20% by weight of treated cellulosic material (e.g., fibers) produced according to any method provided herein. In some embodiments, provided compositions comprise at least 25% (e.g., 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85% or more) treated cellulosic material (e.g., fibers) produced according to provided methods.
According to various embodiments, provided compositions comprising treated cellulosic materials may be produced in a variety of forms. In some embodiments, compositions comprising provided treated cellulosic materials may be provided in a format selected from fibers, coatings, mats, films, foams, gels, granules, or powders. As used herein, the term “powder” refers to a mixture of finely divided substances, for example, chemicals, in dry form, while “granules” refers to agglomerates of powdered materials prepared into larger, free flowing particles. In some embodiments, use of provided treated cellulosic materials in a particular composition result in one or more of the following enhancements as compared to untreated cellulosic materials: decreased water retention value (WRV), increased tensile modulus, decreased tensile strength, decreased stretch, decreased total energy absorption (TEA), increased flexural strength, increased flexural modulus, and increased impact strength.
Moisture pickup of a modified cellulose sample in a controlled humidity and temperature room (50% RH, 70 F TAPPI standard test room) is shown in
Untreated CNF shows a higher equilibrium moisture content that CNF treated with lactic acid. Bleached softwood kraft pulp has a high, but slightly lower equilibrium moisture content compared to CNF. Treating the softwood fiber with lactic acid also lowers the equilibrium moisture pick-up of the fibers.
Table 1 shows the numerical data also presented in
In this example, bleached southern hardwood kraft pulp (Canadian Standard Freeness [CSF] ˜385) was treated with lactic acid. This pulp was adjusted to 5% consistency and lactic acid was mixed in using a bench top mixer. The ratio of dry fiber to lactic acid in the resulting mixture was 1:1 by weight. This mixture was placed in an oven at 120° C. for approximately 48 hours, allowing the reaction between the lactic acid and fibers to proceed, as well as driving off the initial water and any water generated as a reaction product.
Several handsheets were made using the bleached southern hardwood kraft pulp, with various levels of esterified cellulose added to the handsheet. Table 2 contains test results for 0%, 5%, 10%, 20% and 30% addition, by weight, of the modified fibers added to the handsheets.
The data shows that as the % lactic acid treatment increases, the bonding between fibers is reduced. Without wishing to be held to a particular theory, this hypothesis is supported by the increase in caliper, decrease in tensile strength, stretch, total energy absorbed (TEA) and internal bond of the hand sheets with increasing lactic acid treatment.
This example shows how lactic acid treated fibers exhibit lower water holding capacity compared to untreated fiber. Water Retention Value test method (WRV) is a measure of the water content of fiber after it has been subjected to an elevated g force for a specific amount of time. The lower the ratio of gm of Water per gram of fiber, the lower the capacity of the fiber to interact and hold water within its structure.
As shown in
This example demonstrates the improved compatibility of lactic acid-treated fibers with hydrophobic thermoplastic resins—specifically polypropylene and polylactic acid.
The following data was generated at the University of Maine Advanced Structures and Composites Center (Orono, Me.) testing the properties of polypropylene test pieces with and without the addition of lactic acid treated nanocellulose (both in the form of 3.5 mm granules and a ball milled powder). Unless otherwise specified, the granules were produced by passing dried esterified nanocellulose through a Wiley mill with a 0.5 mm screen, and the balled milled sampled was produced by processing the granules in a ball mill for several days.
Surface modified cellulose nanofibrils (CNFs) were mixed with polypropylene (PP) and polylactic acid (PLA) using thermal compounding processes. A batch mixing process was applied. The lactic acid modified CNFs will be treated as an additive. Masterbatches of highly loaded CNFs at 40 wt. % in polymers were prepared as the first step and then the masterbatches were diluted using fresh polymer to the final loading of CNFs using a twin-screw co-rotating extruder. The compounding formulations for the final CNFs polymer composites in weight ratios are shown in Table 3. After compounding, an injection molding process was used to manufacture samples for tensile, flexural, and impact tests according to the ASTM standards D638, D790 and D256. The tensile modulus, tensile strength, flexural modulus, flexural strength, and impact strength are reported herein.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US2016/032381 | 5/13/2016 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2016/183453 | 11/17/2016 | WO | A |
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| Entry |
|---|
| Cheng, Q. et al, Water Retention Value Measurements of Cellulosic Materials Using a Centrifuge Technique, BioResources, 5(3): 1945-1954 (2010). |
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| Number | Date | Country | |
|---|---|---|---|
| 20180142411 A1 | May 2018 | US |
| Number | Date | Country | |
|---|---|---|---|
| 62161341 | May 2015 | US |
