The present disclosure relates to glass-laminate structures and, more particularly, to methods of finishing laminated glass structures.
Laminated glass structures may be used as components in the fabrication of various appliances, automobile components and architectural structures or electronic devices. For example, laminated glass structures may be incorporated as cover glass for various end products such as refrigerators, backsplashes, decorative glazing or televisions. However, it may be difficult to cut or otherwise shape and finish the laminated glass structures using methods typically used in the field without causing fractures in the glass layer given limitations of the machining and finishing methods that might be used and properties of the laminated glass structures. For example, many such finishing methods are not used to polish glass, plastic or adhesives. Accordingly, there is a need for methods of finish laminated glass structures using finishing methods used in the field to minimize the effort and cost of glass laminate use and installation.
One technique to improve the mechanical reliability of flexible glass is to laminate, or bond, the flexible glass to one or more laminate materials or substrates of unique structures. Flexible glass may be glass having a thickness of 300 microns or less, including but not limited to, 300, 275, 250, 225, 200, 190, 180, 170, 160, 150, 140, 130, 120, 110, 100, 90, 80, 70, 60, 50, 40, 30, 20, or 10 microns. Additionally, the flexible glass may have a thickness in a range of from 100 to 200 microns. Depending on the mechanical strength and impact resistance requirements of a laminated glass structure, as well as the expected bending stresses and direction of the intended application, a laminated glass structure can be designed to meet various mechanical requirements. When used properly, the laminated glass structures can offer improved mechanical reliability and impact resistance performance over unlaminated flexible glass.
Once the laminated glass structures are formed, it can become necessary to cut or otherwise shape them. Once cut, in order to achieve a predetermined edge strength, finishing processes may be used to remove undesirable cracks and fractures in the flexible glass layer. To this end, methods of finishing the laminated glass structures are described herein where finishing devices are used to effectively finish the laminated glass structures to desired edge strengths. The laminated glass structures can be used, for example, as a backsplash for kitchen installation, wherein a larger laminated glass structure can be cut down in the field to a preselected size and then edge finished to achieve a predetermined edge strength.
Additional features and advantages will be set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from the description or recognized by practicing the disclosure as exemplified in the written description and the appended drawings. It is to be understood that both the foregoing general description and the following detailed description are merely exemplary of the disclosure, and are intended to provide an overview or framework to understanding the nature and character of the disclosure as it is claimed.
The accompanying drawings are included to provide a further understanding of principles of the disclosure, and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiment(s), and together with the description serve to explain, by way of example, principles and operation of the disclosure. It is to be understood that various features of the disclosure disclosed in this specification and in the drawings can be used in any and all combinations. By way of non-limiting example the various features of the disclosure may be combined with one another according to the following aspects.
According to a first aspect, a method of finishing a laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive layer is provided. The method includes applying a compressive force against a cut edge of the flexible glass sheet using an abrasive surface of a hand-held finishing tool. Material of the laminated glass structure is removed at the cut edge such that a glass edge strength of the flexible glass sheet is at least 50 MPa or greater.
According to a second aspect, there is provided the method of aspect 1, wherein the abrasive surface comprises an abrasive material having an ISO/FEPA grit designation of at least 180 or finer.
According to a third aspect, there is provided the method of aspect 1 or aspect 2, further comprising directing a liquid over the cut edge during the step of removing material of the laminated glass structure.
According to a fourth aspect, there is provided the method of any one of aspects 1-3, further comprising positioning the abrasive surface at an angle of between about 1 and about 20 degrees to a plane transverse to a broad surface of the flexible glass sheet during the step of removing material of the laminated glass structure.
According to a fifth aspect, there is provided the method of any one of aspects 1-4, wherein the finishing tool is a sanding block and the abrasive surface is provided by sandpaper.
According to a sixth aspect, there is provided the method of any one of aspects 1-4, wherein the finishing tool is an orbital sander comprising a head that includes the abrasive surface.
According to a seventh aspect, there is provided the method of any one of aspects 1-4, wherein the finishing tool is a belt sander comprising a belt that includes the abrasive surface.
According to an eighth aspect, there is provided the method of any one of aspects 1-4, wherein the finishing tool comprises a compliant sanding ball that includes the abrasive material.
According to a ninth aspect, there is provided the method aspect 8, wherein the compliant sanding ball has a durometer rating of between 20 Shore A and 35 Shore A.
According to a tenth aspect, there is provided the method of any one of aspects 1-4, wherein the finishing tool comprises an inflatable bulb and sanding sleeve carried by the inflatable bulb and including the abrasive material.
According to an eleventh aspect, a method of finishing a laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive material is provided. The method includes supporting the preform laminated glass structure on a support surface such that the non-glass substrate is located between the flexible glass sheet and the support surface. Material of the laminated glass structure is removed at a cut edge using an abrasive surface of a finishing tool. The abrasive surface is positioned at an angle of between about 1 and about 20 degrees to a plane transverse to a broad surface of the flexible glass sheet during the step of removing material of the laminated glass structure.
According to a twelfth aspect, there is provided the method of aspect 11, wherein the abrasive surface comprises an abrasive material having an ISO/FEPA grit designation of at least 180 or finer.
According to a thirteenth aspect, there is provided the method of aspect 11 or aspect 12, further comprising directing a liquid over the cut edge during the step of removing material of the laminated glass structure.
According to a fourteenth aspect, there is provided the method of any one of aspects 11-13, wherein the finishing tool is a sanding block and the abrasive surface is provided by sandpaper.
According to a fifteenth aspect, there is provided the method of any one of aspects 11-13, wherein the finishing tool is an orbital sander comprising a head that includes the abrasive surface.
According to a sixteenth aspect, there is provided the method of any one of aspects 11-13, wherein the finishing tool is a belt sander comprising a belt that includes the abrasive surface.
According to a seventeenth aspect, there is provided the method of any one of aspects 11-13, wherein the finishing tool comprises a compliant sanding ball that includes the abrasive material.
According to an eighteenth aspect, there is provided the method of aspect 17, wherein the compliant sanding ball has a durometer rating of between 20 Shore A and 35 Shore A.
According to a nineteenth aspect, there is provided the method of any one of aspects 11-13, wherein the finishing tool comprises an inflatable bulb and sanding sleeve carried by the inflatable bulb and including the abrasive material.
According to an twentieth aspect, a method of finishing a laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive material is provided. The method includes supporting the preform laminated glass structure on a support surface such that the non-glass substrate is located between the flexible glass sheet and the support surface. Material of the laminated glass structure is removed at a cut edge using an abrasive surface of a finishing tool. The abrasive surface of the finishing tool is compliant and resiliently deflects as a compressive force is applied against the cut edge of the flexible glass sheet using the abrasive surface during the step of removing the material of the laminated glass structure.
According to a twenty-first aspect, there is provided the method of aspect 20, wherein the step of removing material of the laminated glass structure at the cut edge is such that a glass edge strength of the flexible glass sheet is at least about 50 MPa.
According to a twenty-second aspect, there is provided the method of aspect 20 or aspect 21, wherein the abrasive surface comprises an abrasive material having an ISO/FEPA grit designation of at least 180 or finer.
According to a twenty-third aspect, there is provided the method of any one of aspects 20-22, further comprising directing a liquid over the cut edge during the step of removing material of the laminated glass structure.
According to a twenty-fourth aspect, there is provided the method of any one of aspects 20-23, wherein the finishing tool is a sanding block and the abrasive surface is provided by sandpaper.
According to a twenty-fifth aspect, there is provided the method of any one of aspects 20-23, wherein the finishing tool is an orbital sander comprising a head that includes the abrasive surface.
According to a twenty-sixth aspect, there is provided the method of any one of aspects 20-23, wherein the finishing tool is a belt sander comprising a belt that includes the abrasive surface.
According to a twenty-seventh aspect, there is provided the method of any one of aspects 20-23, wherein the finishing tool comprises a compliant sanding ball that includes the abrasive material.
According to a twenty-eighth aspect, there is provided the method of aspect 27, wherein the compliant sanding ball has a durometer rating of between 20 Shore A and 35 Shore A.
According to a twenty-ninth aspect, there is provided the method of any one of aspects 20-23, wherein the finishing tool comprises an inflatable bulb and sanding sleeve carried by the inflatable bulb and including the abrasive material.
According to a thirtieth aspect, there is provided the method of any one of aspects 20-29, further comprising positioning the abrasive surface at an angle of no more than about 45 degrees to a plane transverse to a broad surface of the flexible glass sheet during the step of removing material of the laminated glass structure.
These and other features, aspects and advantages of the present disclosure are better understood when the following detailed description of the disclosure is read with reference to the accompanying drawings, in which:
In the following detailed description, for purposes of explanation and not limitation, example embodiments disclosing specific details are set forth to provide a thorough understanding of various principles of the present disclosure. However, it will be apparent to one having ordinary skill in the art, having had the benefit of the present disclosure, that the present disclosure may be practiced in other embodiments that depart from the specific details disclosed herein. Moreover, descriptions of well-known devices, methods and materials may be omitted so as not to obscure the description of various principles of the present disclosure. Finally, wherever applicable, like reference numerals refer to like elements.
Ranges can be expressed herein as from “about” one particular value, and/or to “about” another particular value. When such a range is expressed, another embodiment includes from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by use of the antecedent “about,” it will be understood that the particular value forms another embodiment. It will be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint, and independently of the other endpoint.
Directional terms as used herein—for example up, down, right, left, front, back, top, bottom—are made only with reference to the figures as drawn and are not intended to imply absolute orientation.
Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is no way intended that an order be inferred, in any respect. This holds for any possible non-express basis for interpretation, including: matters of logic with respect to arrangement of steps or operational flow; plain meaning derived from grammatical organization or punctuation; the number or type of embodiments described in the specification.
As used herein, the singular forms “a,” “an” and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to a “component” includes aspects having two or more such components, unless the context clearly indicates otherwise.
Although glass is an inherently strong material, its strength and mechanical reliability is a function of its surface defect or flaw size density distribution and the cumulative exposure of stress to the material over time. During an entire product life cycle, a laminated glass structure may be subjected to various kinds of static and dynamic mechanical stresses. Embodiments described herein generally relate to methods of finishing laminated glass structures at an installation location or machining environment. Particular examples may relate to laminated glass structures where the non-glass substrate is a wood, fiberboard, laminate, polymer and/or metal or metal alloy, such as stainless steel, aluminum, nickel, magnesium, brass, bronze, titanium, tungsten, copper, cast iron or a noble metal.
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The non-glass substrate 18 may be formed using a polymer material, for example, any one or more of polyethylene teraphthalate (PET), polyethylene Naphthalate (PEN), ethylene tetrafluoroethylene (ETFE), or thermopolymer polyolefin (TPO™—polymer/filler blends of polyethylene, polypropylene, block copolymer polypropylene (BCPP), or rubber), polyesters, polycarbonate, polyvinylbuterate, polyvinyl chloride, polyethylene and substituted polyethylenes, polyhydroxybutyrates, polyhydroxyvinylbutyrates, polyetherimides, polyamides, polyethylenenaphalate, polyimides, polyethers, polysulphones, polyvinylacetylenes, transparent thermoplastics, transparent polybutadienes, polycyanoacrylates, cellulose-based polymers, polyacrylates and polymethacrylates, polyvinylalcohol, polysulphides, polyvinyl butyral, polymethyl methacrylate and polysiloxanes. It is also possible to use polymers which can be deposited/coated as pre-polymers or pre-compounds and then converted, such as epoxy-resins, polyurethanes, phenol-formaldehyde resins, and melamine-formaldehyde resins. Many display and electrical applications may prefer acrylic based polymers, silicones and such structural aiding layers, for example, commercially available SentryGlas® from DuPont. The polymer layers may be transparent for some applications, but need not be for other applications.
An adhesive layer 20 may be formed of an adhesive material 22 that may be used to laminate the flexible glass layer 12 to the non-glass substrate layer 16 at the interfaces between their respective broad surfaces 24 and 26. The adhesive material 22 may be a non-adhesive interlayer, an adhesive, a sheet or film of adhesive, a liquid adhesive, a powder adhesive, a pressure sensitive adhesive, an ultraviolet-light curable adhesive, a thermally curable adhesive, or other similar adhesive or combination thereof. The adhesive material 22 may assist in attaching the flexible glass 14 to the non-glass substrate 18 during lamination. Some examples of low temperature adhesive materials include Norland 68 cured by UV, Flexcon V29TT, 3M OCA 8211, 8212, 8146, and 8172 (bonded by pressure at room temperature or above), 3M 4905, OptiClear® adhesive, silicones, acrylates, optically clear adhesives, encaptulant material, polyurethane polyvinylbutyrates, ethylenevinylacetates, ionomers, and wood glues. Typical graphic adhesives such as Graphicmount and Facemount may also be used (as available from LexJet Corporation, located in Sarasota Fla., for example). Some examples of higher temperature adhesive materials include DuPont SentryGlas, DuPont PV 5411, Japan World Corporation material FAS and polyvinyl butyral resin. The adhesive layer 20 may be thin, having a thickness less than or equal to about 1000 μm, including less than or equal to about 500 μm, about 250 μm, less than or equal to about 50 μm, less than or equal to 40 μm, less than or equal to about 25 μm, or between about 0.1 mm and about 5 mm. The adhesives may also contain other functional components such as color, decoration, heat or UV resistance, AR filtration etc. The adhesive material 22 may be optically clear on cure, or may otherwise be opaque. In embodiments where the adhesive material 22 is a sheet or film of adhesive, the adhesive material 22 may have a decorative pattern or design visible through the thickness of the flexible glass, as shown in
In
The flexible glass sheet 14 may have a thickness 34 of about 0.3 mm or less including but not limited to thicknesses of, for example, about 0.01-0.05 mm, about 0.05-0.1 mm, about 0.1-0.15 mm, about 0.15-0.3 mm, about 0.100 to about 0.200 mm, 0.3, 0.275, 0.25, 0.225, 0.2, 0.19, 0.18, 0.17, 0.16, 0.15, 0.14, 0.13, 0.12, 0.11, 0.10, 0.09, 0.08 0.07, 0.06, 0.05, 0.04, 0.03, 0.02, or 0.01 mm. The flexible glass sheet 14 may be formed of glass, a glass ceramic, a ceramic material or composites thereof. A fusion process (e.g., downdraw process) that forms high quality flexible glass sheets can be used in a variety of devices and one such application is flat panel displays. Glass sheets produced in a fusion process have surfaces with superior flatness and smoothness when compared to glass sheets produced by other methods. The fusion process is described in U.S. Pat. Nos. 3,338,696 and 3,682,609. Other suitable glass sheet forming methods include a float process, updraw and slot draw methods. Additionally, the flexible glass sheet 14 may also contain anti-microbial properties by using a chemical composition for the glass including an Ag ion concentration on the surface in the range greater than 0 to 0.047 μg/cm2, further described in U.S. Patent Application Publication No. 2012/0034435 A1. The flexible glass 14 may also be coated with a glaze composed of silver, or otherwise doped with silver ions, to gain the desired anti-microbial properties, as further described in U.S. Patent Application Publication No. 2011/0081542 A1. Additionally, the flexible glass 14 may have a molar composition of 50% SiO2, 25% CaO, and 25% Na2O to achieve the desired anti-microbial effects.
Once the flexible glass sheet 14 is formed, it may be laminated to the non-glass substrate 18 using a variety of apparatus and processes. Some examples include sheet-to-sheet lamination where pressure and/or heat are used to bond the flexible glass sheet 14 to the non-glass substrate 18, for example, using the adhesive material 22. As another example, a roll-to-sheet or roll-to-roll lamination method may be used where; again, pressure is used to bond a continuous ribbon of flexible glass sheet 14 from a supply roll to a non-glass substrate 18 either as a continuous substrate from a supply roll or a plurality of individual substrates. While it may be possible to form the laminated glass structure to a final, desired dimension, it may be the case that some type of shaping (e.g., cutting) of the laminated glass structure will be needed after the laminated glass structure is formed. In these instances, the laminated glass structure may be referred to as a preform laminated glass structure in that the preform laminated glass structure will undergo final processing in the field, for example, at an installation site to desired dimensions.
Without wishing to be bound by theory, one difficulty that may be encountered during cutting of the laminated glass structures to a predetermined dimension is maintaining an acceptable edge quality of the flexible glass sheet 14. Edge quality of the flexible glass sheet 14 is related to edge strength and the possibility of initiation/formation of undesirable or unintended cracks and fractures in the flexible glass sheet 14. As used herein, “edge strength” refers to the strength of a flexible glass sheet of a laminated glass structure determined using a modified procedure based on the procedure described in ASTM C-158 “Standard Test Methods for Strength of Glass by Flexure (Determination of Modulus of Rupture),” which is incorporated herein by reference in its entirety. The modified procedure is generally the same as the procedure described in ASTM C-158, except for an additional calculation performed to determine the glass strength. The modified procedure includes determining a load vs. glass stress calibration curve for the laminated glass structure using one of the following methods: 1) directly measuring the strain in the flexible glass sheet (e.g., by a strain gauge) at multiple loads and then calculating stress in the flexible glass sheet at the multiple loads using its elastic modulus, 2) directly measuring the stress in the flexible glass sheet (e.g., by a stress optical method) at multiple loads, or 3) beam theory analysis of the laminated glass structure, which may be difficult due to uncertainties in the adhesive properties. The laminated glass structure is tested using the procedure described in ASTM C-158 to determine the load at which the flexible glass sheet (as opposed to the complete laminated glass structure) fails, and the calibration curve is used to translate the determined failure load into a glass stress value, which is reported as the glass strength. In some embodiments, it may be desirable to maintain a predetermined edge strength in the flexible glass sheet 14 after cutting and an even higher predetermined edge strength after edge finishing the flexible glass sheet 14. For example, maintaining an edge strength in the flexible glass sheet 14 of at least about 50 MPa can allow the flexible glass sheet 14 of the laminated glass structure 10 to survive end use conditions, such as handling and installation, without forming cracks and fractures in the flexible glass sheet 14. However, specialized tools for cutting and finishing the flexible glass sheet 14 are generally not available in manufacturing and installation environments. It has been found that, under predetermined conditions, finishing methods and equipment that are not typically used for at least one of the materials in the laminated glass structure can be used to finish the laminated glass structures 10 (e.g., flexible glass sheet 14, adhesive material 22 and non-glass substrate 18), and, in some embodiments, can maintain or provide a predetermined edge strength of at least about 50 MPa, such as at least about 70 MPa in the flexible glass sheets 14.
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The systems and methods of finishing laminated glass structures described above allow for use of manufacturing-based finishing methods and machines, such as rotary tools and compliant finishing equipment, while maintaining edge strengths of the flexible glass sheets of at least about 50 MPa, such as about 70 MPa. While manual finishing is described primarily above, other automated tools may be used such as a computerized numerical control (CNC) machine, which can utilize one or more of the sanding structures or variations thereon suitable for use with a CNC machine. The flexible glass sheets can be maintained in compression throughout the finishing process and a finishing angle can be maintained to achieve acceptable edge strength. The finishing systems and methods facilitate repair of any damage flexible glass sheets and maintain life expectance of the flexible glass laminate. Finishing operations can be conducted in the field or manufacturing environment where cutting of the flexible glass laminates may take place.
Although the laminated glass structure 10 is described herein as comprising a single flexible glass sheet 14 laminated to the non-glass substrate 18, other embodiments are included in this disclosure. In some embodiments, the laminated glass structure comprises a second flexible glass sheet laminated to the non-glass substrate. For example, the second flexible glass sheet can be laminated to a second broad surface of the non-glass substrate opposite the first flexible glass sheet. The second flexible glass sheet can be laminated to the non-glass substrate as described herein with respect to the first flexible glass sheet, and one or more edges of the second flexible glass sheet can be finished using the processes described herein with respect to the first flexible glass sheet.
It should be emphasized that the above-described embodiments of the present disclosure, including any embodiments, are merely possible examples of implementations, merely set forth for a clear understanding of various principles of the disclosure. Many variations and modifications may be made to the above-described embodiments of the disclosure without departing substantially from the spirit and various principles of the disclosure. All such modifications and variations are intended to be included herein within the scope of this disclosure and the present disclosure and protected by the following claims.
This application claims the benefit of priority to U.S. Application No. 62/151,167 filed on Apr. 22, 2015 the content of which is incorporated herein by reference in its entirety.
Filing Document | Filing Date | Country | Kind |
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PCT/US16/28851 | 4/22/2016 | WO | 00 |
Number | Date | Country | |
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62151167 | Apr 2015 | US |