The present invention generally relates to earth-boring drill bits and other earth-boring tools that may be used to drill subterranean formations, and to methods of manufacturing such drill bits and tools. More particularly, the present invention relates to methods of sinterbonding components together to form at least a portion of an earth-boring tool and to tools formed using such methods.
The depth of well bores being drilled continues to increase as the number of shallow depth hydrocarbon-bearing earth formations continues to decrease. These increasing well bore depths are pressing conventional drill bits to their limits in terms of performance and durability. Several drill bits are often required to drill a single well bore, and changing a drill bit on a drill string can be both time consuming and expensive.
In efforts to improve drill bit performance and durability, new materials and methods for forming drill bits and their various components are being investigated. For example, methods other than conventional infiltration processes are being investigated to form bit bodies comprising particle-matrix composite materials. Such methods include forming bit bodies using powder compaction and sintering techniques. The term “sintering,” as used herein, means the densification of a particulate component and involves removal of at least a portion of the pores between the starting particles, accompanied by shrinkage, combined with coalescence and bonding between adjacent particles. Such techniques are disclosed in U.S. Pat. No. 7,802,495, issued Sep. 28, 2010, and U.S. Pat. No. 7,776,256, issued Aug. 17, 2010, both of which are assigned to the assignee of the present invention, and the entire disclosure of each of which is incorporated herein by this reference.
An example of a bit body 50 that may be formed using such powder compaction and sintering techniques is illustrated in
An example of a manner in which the bit body 50 may be formed using powder compaction and sintering techniques is described briefly below.
Referring to
The container 74 may include a fluid-tight deformable member 76 such as, for example, a deformable polymeric bag and a substantially rigid sealing plate 78. Inserts or displacement members 79 may be provided within the container 74 for defining features of the bit body 50 such as, for example, a longitudinal bore 56 (
The container 74 (with the powder mixture 68 and any desired displacement members 79 contained therein) may be pressurized within a pressure chamber 70. A removable cover 71 may be used to provide access to the interior of the pressure chamber 70. A fluid (which may be substantially incompressible) such as, for example, water, oil, or gas (such as, for example, air or nitrogen) is pumped into the pressure chamber 70 through an opening 72 at high pressures using a pump (not shown). The high pressure of the fluid causes the walls of the deformable member 76 to deform, and the fluid pressure may be transmitted substantially uniformly to the powder mixture 68.
Pressing of the powder mixture 68 may form a green (or unsintered) body 80 shown in
The green body 80 shown in
The partially shaped green body 84 shown in
By way of example and not limitation, internal fluid passageways (not shown), cutting element pockets 64, and buttresses 66 (
In other methods, the green body 80 shown in
In some embodiments, the present invention includes methods of forming earth-boring rotary drill bits by forming and joining two less than fully sintered components, by forming and joining a first fully sintered component with a first shrink rate and forming a second less than fully sintered component with a second sinter-shrink rate greater than that of the first shrink rate of the first fully sintered component, by forming and joining a first less than fully sintered component with a first sinter-shrink rate and by forming and joining at least a second less than fully sintered component with a second sinter-shrink rate less than the first sinter-shrink rate. The methods include co-sintering a first less than fully sintered component and a second less than fully sintered component to a desired final density to form at least a portion of an earth-boring rotary drill bit, which may either cause the first less than fully sintered component and the second less than fully sintered component to join or may cause one of the first less than fully sintered component and the second less than fully sintered component to shrink around and at least partially capture the other less than fully sintered component.
In additional embodiments, the present invention includes methods of forming earth-boring rotary drill bits by providing a first component with a first sinter-shrink rate, placing at least a second component with a second sinter-shrink rate less than the first sinter-shrink rate at least partially within at least a first recess of the first component, and causing the first component to shrink at least partially around and bond to the at least a second component by co-sintering the first component and the at least a second component.
In yet additional embodiments, the present invention includes methods of forming earth-boring rotary drill bits by tailoring the sinter-shrink rate of a first component to be greater than the sinter-shrink rate of at least a second component and co-sintering the first component and the at least a second component to cause the first component to at least partially contract upon and bond to the at least a second component.
In other embodiments, the present invention includes earth-boring rotary drill bits including a first particle-matrix component and at least a second particle-matrix component at least partially surrounded by and sinterbonded to the first particle-matrix component.
In additional embodiments, the present invention includes earth-boring rotary drill bits including a bit body comprising a particle-matrix composite material and at least one cutting structure comprising a particle-matrix composite material sinterbonded at least partially within at least one recess of the bit body.
While the specification concludes with claims particularly pointing out and distinctly claiming that which is regarded as the present invention, the advantages of this invention may be more readily ascertained from the description of the invention when read in conjunction with the accompanying drawings, in which:
The illustrations presented herein are not meant to be actual views of any particular material, apparatus, system, or method, but are merely idealized representations which are employed to describe the present invention. Additionally, elements common between figures may retain the same numerical designation.
An embodiment of an earth-boring rotary drill bit 100 of the present invention is shown in perspective in
The bit body 102 may include internal fluid passageways (not shown) that extend between a face 103 of the bit body 102 and a longitudinal bore (not shown), which extends through the shank 104, the extension 108, and partially through the bit body 102, similar to the longitudinal bore 56 shown in
The earth-boring rotary drill bit 100 shown in
Furthermore, the earth-boring rotary drill bit 100 may be formed from two or more, less than fully sintered components (i.e., green or brown components) that may be sinterbonded together to form at least a portion of the drill bit 100. During sintering of two or more less than fully sintered components (i.e., green or brown components), the two or more components will bond together. Additionally, when sintering the two or more less than fully sintered components together, the relative shrinkage rates of the two or more components may be tailored such that during sintering a first component and at least a second component will shrink essentially the same or a first component will shrink more than at least a second component. By tailoring the sinter-shrink rates such that a first component will have a greater shrinkage rate than the at least a second component, the components may be configured such that during sintering the at least a second component is at least partially surrounded and captured as the first component contracts upon it, thereby facilitating a complete sinterbond between the first and at least second components. The sinter-shrink rates of the two or more components may be tailored by controlling the porosity of the less than fully sintered components. Thus, forming a first component with more porosity than at least a second component may cause the first component to have a greater sinter-shrink rate than the at least a second component having less porosity.
The porosity of the components may be tailored by modifying one or more of the following non-limiting variables: particle size and size distribution, particle shape, pressing method, compaction pressure, and the amount of binder used when forming the less than fully sintered components.
Particles that are all the same size may be difficult to pack efficiently. Components formed from particles of the same size may include large pores and a high volume percentage of porosity. On the other hand, components formed from particles with a broad range of sizes may pack efficiently and minimize pore space between adjacent particles. Thus, porosity and therefore the sinter-shrink rates of a component may be controlled by the particle size and size distribution of the hard particles and matrix material used to form the component.
The pressing method may also be used to tailor the porosity of a component. Specifically, one pressing method may lead to tighter packing and therefore less porosity. As a non-limiting example, substantially isostatic pressing methods may produce tighter packed particles in a less than fully sintered component than uniaxial pressing methods and therefore less porosity. Therefore, porosity and the sinter-shrink rates of a component may be controlled by the pressing method used to form the less than full sintered component.
Additionally, compaction pressure may be used to control the porosity of a component. The greater the compaction pressure used to form the component the lesser amount of porosity the component may exhibit.
Finally, the amount of binder used in the components relative to the powder mixture may vary which affects the porosity of the powder mixture when the binder is burned from the powder mixture. The binder used in any powder mixture includes commonly used additives when pressing powder mixtures such as, for example, binders for providing lubrication during pressing and for providing structural strength to the pressed powder component, plasticizers for making the binder more pliable, and lubricants or compaction aids for reducing inter-particle friction.
The shrink rate of a particle-matrix material component is independent of composition. Therefore, varying the composition of the first component and the at least second components may not cause a difference in relative sinter-shrink rates. However, the composition of the first and the at least second components may be varied. In particular, the composition of the components may be varied to provide a difference in wear resistance or fracture toughness between the components. As a non-limiting example, a different grade of carbide may be used to form one component so that it exhibits greater wear resistance and/or fracture toughness relative to the component to which it is sinterbonded.
In some embodiments, the first component and at least a second component may comprise green body structures. In other embodiments, the first component and the at least a second component may comprise brown components. In yet additional embodiments, one of the first component and the at least a second component may comprise a green body component and the other a brown body component.
Recently, new methods of forming cutting element pockets by using a rotating cutter to machine a cutting element pocket in such a way as to avoid mechanical tool interference problems and forming the pocket so as to sufficiently support a cutting element therein have been investigated. Such methods are disclosed in U.S. Pat. No. 7,836,980, issued Nov. 23, 2010, the entire disclosure of which is incorporated by reference herein. Such methods may include machining a first recess in a bit body of an earth-boring tool to define a lateral sidewall surface of a cutting element pocket, machining a second recess to define at least a portion of a shoulder at an intersection with the first recess, and disposing a plug within the second recess to define at least a portion of an end surface of the cutting element pocket.
According to some embodiments of the present invention, the plug as disclosed by the previously referenced U.S. Pat. No. 7,836,980, may be sinterbonded within the second recess to form a unitary bit body. More particularly, the sinter-shrink rates of the plug and the bit body surrounding it may be tailored so the bit body at least partially surrounds and captures the plug during co-sintering to facilitate a complete sinterbond.
Both the plug 134 and the bit body 102 may comprise particle-matrix composite components formed from any of the materials described hereinabove in relation to particle-matrix composite material 120. In some embodiments, the plug 134 and the bit body 101 may both comprise green powder components. In other embodiments, the plug 134 and the bit body 101 may both comprise brown components. In yet additional embodiments, one of the plug 134 and the bit body 101 may comprise a green body and the other a brown body. The sinter-shrink rate of the plug 134 and the bit body 101 may be tailored as desired as discussed herein. For instance, the sinter-shrink rate of the plug 134 and the bit body 101 may be tailored so the bit body 101 has a greater sinter-shrink rate than the plug 134. The plug 134 may be disposed within the second recess 132 as shown in
After co-sintering the plug 134 and the bit body 101 to a final desired density as shown in
Furthermore, in some embodiments the fully sintered bit body 102 and less than fully sintered extension 108 may exhibit different material properties. As non-limiting examples, the fully sintered bit body 102 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered extension 108.
The sinter-shrink rates of the fully sintered bit body 102, although a fully sintered bit body 102 essentially has no sinter-shrink rate after being fully sintered, and the less than fully sintered extension 108 may be tailored by controlling the porosity of each so the extension 108 has a greater porosity than the bit body 102 such that during sintering the extension 108 will shrink more than the fully sintered bit body 102. The porosity of the bit body 102 and the extension 108 may be tailored by modifying one or more of the particle size and size distribution, particle shape, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove. Suitable types of connectors, such as lugs and recesses 108′ or keys and recesses 108″ (illustrated in dashed lines in
Furthermore, in some embodiments the less than fully sintered bit body 101 and less than fully sintered extension 107 may exhibit different material properties. As non-limiting examples, the less than fully sintered bit body 101 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered extension 107.
The sinter-shrink rates of the less than fully sintered bit body 101 and the less than fully sintered extension 107 may be tailored by controlling the porosity of each so the extension 107 has a greater porosity than the bit body 101 such that during sintering the extension 107 will shrink more than the bit body 101. The porosity of the bit body 101 and the extension 107 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.
As mentioned previously, the extension 107 and the bit body 101, as shown in
Furthermore, in some embodiments the less than fully sintered bit body 101 and less than fully sintered blade 150 may exhibit different material properties. As non-limiting examples, the less than fully sintered blade 150 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered bit body 101. As non-limiting examples, the binder content may be lowered or a different grade of carbide may be used to form the blade 150 so that it exhibits greater wear resistance and/or fracture toughness relative to the bit body 101. In other embodiments, the less than fully sintered bit body 101 and less than fully sintered blade 150 may exhibit similar material properties.
The sinter-shrink rates of the less than fully sintered bit body 101 and the less than fully sintered blade 150 may be tailored by controlling the porosity of each so the bit body 101 has a greater porosity than the blade 150 such that during sintering the bit body 101 will shrink more than the blade 150. The porosity of the bit body 101 and the blade 150 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.
As mentioned previously, the blade 150 and the bit body 101, as shown in
Additionally as seen in
Furthermore, in some embodiments the less than fully sintered cutting structure 147 and less than fully sintered blade 160 may exhibit different material properties. As non-limiting examples, the less than fully sintered cutting structure 147 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered blade 160. As non-limiting examples, the binder content may be lowered or a different grade of carbide may be used to form the less than fully sintered cutting structure 147 so that it exhibits greater wear resistance and/or fracture toughness relative to the blade 160. In other embodiments, the less than fully sintered cutting structure 147 and less than fully sintered blade 160 may exhibit similar material properties.
The sinter-shrink rates of the less than fully sintered cutting structure 147 and the less than fully sintered blade 160 may be tailored by controlling the porosity of each so the blade 160 has a greater porosity than the cutting structure 147 such that during sintering the blade 160 will shrink more than the cutting structure 147. The porosity of the cutting structure 147 and the blade 160 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.
As mentioned previously, the blade 160 and the cutting structure 147, as shown in
Furthermore, in some embodiments the less than fully sintered bit body 101 and less than fully sintered nozzle exit ring 129 may exhibit different material properties. As non-limiting examples, the less than fully sintered nozzle exit ring 129 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered bit body 101. As non-limiting examples, the binder content may be lowered or a different grade of carbide may be used to form the nozzle exit ring 129 so that it exhibits greater wear resistance and/or fracture toughness relative to the bit body 101. In other embodiments, the less than fully sintered bit body 101 and less than fully sintered nozzle exit ring 129 may exhibit similar material properties.
The sinter-shrink rates of the less than fully sintered bit body 101 and the less than fully sintered nozzle exit ring 129 may be tailored by controlling the porosity of each so the bit body 101 has a greater porosity than the nozzle exit ring 129 such that during sintering the bit body 101 will shrink more than the nozzle exit ring 129. The porosity of the bit body 101 and the nozzle exit ring 129 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.
As mentioned previously, the nozzle exit ring 129 and the bit body 101, as shown in
According to some embodiments of the present invention, the buttresses 207 may be sinterbonded to the bit body 202.
The less than fully sintered buttress 208 and the less than fully sintered bit body 201 may both comprise particle-matrix composite components. In some embodiments, both the less than fully sintered buttress 208 and the less than fully sintered bit body 201 may comprise particle-matrix composite components formed from a plurality of tungsten carbide particles dispersed throughout a cobalt matrix material. In other embodiments, the less than fully sintered bit body 201 and the less than fully sintered buttress 208 may comprise any of the materials described hereinabove in relation to particle-matrix composite material 120.
Furthermore, in some embodiments the less than fully sintered buttress 208 and less than fully sintered bit body 201 may exhibit different material properties. As non-limiting examples, the less than fully sintered buttress 208 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered bit body 201. As non-limiting examples, the binder content may be lowered or a different grade of carbide may be used to form the less than fully sintered buttress 208 so that it exhibits greater wear resistance and/or fracture toughness relative to the bit body 201. In other embodiments, the less than fully sintered buttress 208 and less than fully sintered bit body 201 may exhibit similar material properties.
The sinter-shrink rates of the less than fully sintered buttress 208 and the less than fully sintered bit body 201 may be tailored by controlling the porosity of each so the bit body 201 has a greater porosity than the buttress 208 such that during sintering the bit body 201 will shrink more than the buttress 208. The porosity of the buttress 208 and the bit body 201 may be tailored by modifying one or more of the particle size, particle shape, and particle size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.
As mentioned previously, the bit body 201 and the buttress 208, as shown in
Although the methods of the present invention have been described in relation to fixed-cutter rotary drill bits, they are equally applicable to any bit body that is formed by sintering a less than fully sintered bit body to a desired final density. For example, the methods of the present invention may be used to form subterranean tools other than fixed-cutter rotary drill bits including, for example, core bits, eccentric bits, bicenter bits, reamers, mills, drag bits, roller cone bits, and other such structures known in the art.
While the present invention has been described herein with respect to certain preferred embodiments, those of ordinary skill in the art will recognize and appreciate that it is not so limited. Rather, many additions, deletions and modifications to the preferred embodiments may be made without departing from the scope of the invention as hereinafter claimed. In addition, features from one embodiment may be combined with features of another embodiment while still being encompassed within the scope of the invention as contemplated by the inventors.
This application is a continuation of U.S. patent application Ser. No. 14/874,639, filed Oct. 5, 2015, now U.S. Pat. No. 9,700,991, issued Jul. 11, 2017, which is a divisional of U.S. patent application Ser. No. 14/325,056, filed Jul. 7, 2014, now U.S. Pat. No. 9,192,989, issued Nov. 24, 2015; which is a divisional of U.S. patent application Ser. No. 12/136,703, filed Jun. 10, 2008, now U.S. Pat. No. 8,770,324, issued Jul. 8, 2014, the disclosure of each of which is hereby incorporated herein in its entirety by this reference. The subject matter of this application is related to the subject matter of U.S. application Ser. No. 11/272,439, filed Nov. 10, 2005, now U.S. Pat. No. 7,776,256, issued Aug. 17, 2010 and U.S. application Ser. No. 11/271,153, filed Nov. 10, 2005, now U.S. Pat. No. 7,802,495, issued Sep. 28, 2010, the disclosure of each of which is hereby incorporated herein in its entirety by this reference. The subject matter of this application is also related to U.S. application Ser. No. 12/831,608, filed Jul. 7, 2010, and U.S. application Ser. No. 12/827,968, filed Jun. 30, 2010, now U.S. Pat. No. 8,309,018, issued Nov. 13, 2012, the disclosure of each of which is hereby incorporated herein in its entirety by this reference.
Number | Name | Date | Kind |
---|---|---|---|
1954166 | Campbell | Apr 1934 | A |
2299207 | Bevillard | Oct 1942 | A |
2507439 | Goolsbee | May 1950 | A |
2819958 | Abkowitz et al. | Jan 1958 | A |
2819959 | Abkowitz et al. | Jan 1958 | A |
2906654 | Abkowitz | Sep 1959 | A |
3368881 | Abkowitz et al. | Feb 1968 | A |
3471921 | Feenstra | Oct 1969 | A |
3660050 | Iler et al. | May 1972 | A |
3757879 | Wilder et al. | Sep 1973 | A |
3859016 | McGee et al. | Jan 1975 | A |
3880971 | Pantanelli | Apr 1975 | A |
3987859 | Lichte | Oct 1976 | A |
4017480 | Baum | Apr 1977 | A |
4047828 | Makely | Sep 1977 | A |
4094709 | Rozmus | Jun 1978 | A |
4128136 | Generoux | Dec 1978 | A |
4134759 | Yajima et al. | Jan 1979 | A |
4157122 | Morris | Jun 1979 | A |
4198233 | Frehn | Apr 1980 | A |
4221270 | Vezirian | Sep 1980 | A |
4229638 | Lichte | Oct 1980 | A |
4233720 | Rozmus | Nov 1980 | A |
4252202 | Purser, Sr. | Feb 1981 | A |
4255165 | Dennis et al. | Mar 1981 | A |
4306139 | Shinozaki et al. | Dec 1981 | A |
4341557 | Lizenby | Jul 1982 | A |
4389952 | Dreier et al. | Jun 1983 | A |
4398952 | Drake | Aug 1983 | A |
4453605 | Short, Jr. | Jun 1984 | A |
4499048 | Hanejko | Feb 1985 | A |
4499795 | Radtke | Feb 1985 | A |
4499958 | Radtke et al. | Feb 1985 | A |
4503009 | Asaka | Mar 1985 | A |
4526748 | Rozmus | Jul 1985 | A |
4547337 | Rozmus | Oct 1985 | A |
4552232 | Frear | Nov 1985 | A |
4554130 | Ecer | Nov 1985 | A |
4562990 | Rose | Jan 1986 | A |
4596694 | Rozmus | Jun 1986 | A |
4597730 | Rozmus | Jul 1986 | A |
4620600 | Persson | Nov 1986 | A |
4630693 | Goodfellow | Dec 1986 | A |
4656002 | Lizenby et al. | Apr 1987 | A |
4667756 | King et al. | May 1987 | A |
4686080 | Hara et al. | Aug 1987 | A |
4694919 | Barr | Sep 1987 | A |
4738322 | Hall et al. | Apr 1988 | A |
4743515 | Fischer et al. | May 1988 | A |
4744943 | Timm | May 1988 | A |
4774211 | Hamilton et al. | Sep 1988 | A |
4809903 | Eylon et al. | Mar 1989 | A |
4838366 | Jones | Jun 1989 | A |
4871377 | Frushour | Oct 1989 | A |
4881431 | Bieneck | Nov 1989 | A |
4884477 | Smith et al. | Dec 1989 | A |
4889017 | Fuller et al. | Dec 1989 | A |
4919013 | Smith et al. | Apr 1990 | A |
4923512 | Timm et al. | May 1990 | A |
4956012 | Jacobs et al. | Sep 1990 | A |
4968348 | Abkowitz et al. | Nov 1990 | A |
4981665 | Boecker et al. | Jan 1991 | A |
5000273 | Horton et al. | Mar 1991 | A |
5030598 | Hsieh | Jul 1991 | A |
5032352 | Meeks et al. | Jul 1991 | A |
5049450 | Dorfman et al. | Sep 1991 | A |
5090491 | Tibbits et al. | Feb 1992 | A |
5101692 | Simpson | Apr 1992 | A |
5150636 | Hill | Sep 1992 | A |
5161898 | Drake | Nov 1992 | A |
5232522 | Doktycz et al. | Aug 1993 | A |
5281260 | Kumar et al. | Jan 1994 | A |
5286685 | Schoennahl et al. | Feb 1994 | A |
5311958 | Isbell et al. | May 1994 | A |
5322139 | Rose et al. | Jun 1994 | A |
5333699 | Thigpen et al. | Aug 1994 | A |
5348806 | Kojo et al. | Sep 1994 | A |
5372777 | Yang | Dec 1994 | A |
5373907 | Weaver | Dec 1994 | A |
5433280 | Smith | Jul 1995 | A |
5439068 | Huffstutler et al. | Aug 1995 | A |
5443337 | Katayama | Aug 1995 | A |
5455000 | Seyferth et al. | Oct 1995 | A |
5467669 | Stroud | Nov 1995 | A |
5479997 | Scott et al. | Jan 1996 | A |
5482670 | Hong | Jan 1996 | A |
5484468 | Ostlund et al. | Jan 1996 | A |
5506055 | Dorfman et al. | Apr 1996 | A |
5541006 | Conley | Jul 1996 | A |
5543235 | Mirchandani et al. | Aug 1996 | A |
5544550 | Smith | Aug 1996 | A |
5560440 | Tibbitts | Oct 1996 | A |
5586612 | Isbell et al. | Dec 1996 | A |
5593474 | Keshavan et al. | Jan 1997 | A |
5611251 | Katayama | Mar 1997 | A |
5612264 | Nilsson et al. | Mar 1997 | A |
5624002 | Huffstutler | Apr 1997 | A |
5641029 | Beaton et al. | Jun 1997 | A |
5641251 | Leins et al. | Jun 1997 | A |
5641921 | Dennis et al. | Jun 1997 | A |
5662183 | Fang | Sep 1997 | A |
5666864 | Tibbitts | Sep 1997 | A |
5677042 | Massa et al. | Oct 1997 | A |
5679445 | Massa et al. | Oct 1997 | A |
5696694 | Khouja et al. | Dec 1997 | A |
5697046 | Conley | Dec 1997 | A |
5697462 | Grimes et al. | Dec 1997 | A |
5710969 | Newman | Jan 1998 | A |
5725827 | Rhodes et al. | Mar 1998 | A |
5732783 | Truax et al. | Mar 1998 | A |
5733649 | Kelley et al. | Mar 1998 | A |
5733664 | Kelley et al. | Mar 1998 | A |
5740872 | Smith | Apr 1998 | A |
5753160 | Takeuchi et al. | May 1998 | A |
5765095 | Flak et al. | Jun 1998 | A |
5776593 | Massa et al. | Jul 1998 | A |
5778301 | Hong | Jul 1998 | A |
5789686 | Massa et al. | Aug 1998 | A |
5792403 | Massa et al. | Aug 1998 | A |
5806934 | Massa et al. | Sep 1998 | A |
5829539 | Newton et al. | Nov 1998 | A |
5830256 | Northrop et al. | Nov 1998 | A |
5856626 | Fischer et al. | Jan 1999 | A |
5865571 | Tankala et al. | Feb 1999 | A |
5878634 | Tibbitts | Mar 1999 | A |
5880382 | Fang et al. | Mar 1999 | A |
5897830 | Abkowitz et al. | Apr 1999 | A |
5904212 | Arfele | May 1999 | A |
5947214 | Tibbitts | Sep 1999 | A |
5957006 | Smith | Sep 1999 | A |
5963775 | Fang | Oct 1999 | A |
5967248 | Drake et al. | Oct 1999 | A |
5980602 | Carden | Nov 1999 | A |
6029544 | Katayama | Feb 2000 | A |
6045750 | Drake et al. | Apr 2000 | A |
6051171 | Takeuchi et al. | Apr 2000 | A |
6063333 | Dennis | May 2000 | A |
6068070 | Scott | May 2000 | A |
6073518 | Chow | Jun 2000 | A |
6086980 | Foster et al. | Jul 2000 | A |
6089123 | Chow et al. | Jul 2000 | A |
6099664 | Davies et al. | Aug 2000 | A |
6135218 | Deane et al. | Oct 2000 | A |
6148936 | Evans et al. | Nov 2000 | A |
6200514 | Meister | Mar 2001 | B1 |
6209420 | Butcher et al. | Apr 2001 | B1 |
6214134 | Eylon et al. | Apr 2001 | B1 |
6214287 | Waldenstrom | Apr 2001 | B1 |
6220117 | Butcher | Apr 2001 | B1 |
6227188 | Tankala et al. | May 2001 | B1 |
6228139 | Oskarsson | May 2001 | B1 |
6241036 | Lovato et al. | Jun 2001 | B1 |
6254658 | Taniuchi et al. | Jul 2001 | B1 |
6284014 | Carden | Sep 2001 | B1 |
6287360 | Kembaiyan et al. | Sep 2001 | B1 |
6290438 | Papajewski | Sep 2001 | B1 |
6293986 | Rodiger et al. | Sep 2001 | B1 |
6322746 | LaSalle et al. | Nov 2001 | B1 |
6338390 | Tibbitts | Jan 2002 | B1 |
6348110 | Evans | Feb 2002 | B1 |
6375706 | Kembaiyan et al. | Apr 2002 | B2 |
6408958 | Isbell et al. | Jun 2002 | B1 |
6453899 | Tselesin | Sep 2002 | B1 |
6454025 | Runquist et al. | Sep 2002 | B1 |
6454028 | Evans | Sep 2002 | B1 |
6454030 | Findley et al. | Sep 2002 | B1 |
6458471 | Lovato et al. | Oct 2002 | B2 |
6474424 | Saxman | Nov 2002 | B1 |
6474425 | Truax et al. | Nov 2002 | B1 |
6500226 | Dennis | Dec 2002 | B1 |
6511265 | Mirchandani et al. | Jan 2003 | B1 |
6576182 | Ravagni et al. | Jun 2003 | B1 |
6589640 | Griffin et al. | Jul 2003 | B2 |
6599467 | Yamaguchi et al. | Jul 2003 | B1 |
6607693 | Saito et al. | Aug 2003 | B1 |
6615935 | Fang et al. | Sep 2003 | B2 |
6651481 | Youngquist | Nov 2003 | B1 |
6651756 | Costo, Jr. et al. | Nov 2003 | B1 |
6655481 | Findley et al. | Dec 2003 | B2 |
6685880 | Engstrom et al. | Feb 2004 | B2 |
6742608 | Murdoch | Jun 2004 | B2 |
6742611 | Illerhaus et al. | Jun 2004 | B1 |
6756009 | Sim et al. | Jun 2004 | B2 |
6766870 | Overstreet | Jul 2004 | B2 |
6849231 | Kojima et al. | Feb 2005 | B2 |
6908688 | Majagi et al. | Jun 2005 | B1 |
6918942 | Hatta et al. | Jul 2005 | B2 |
7044243 | Kembaiyan et al. | May 2006 | B2 |
7048081 | Smith et al. | May 2006 | B2 |
7395882 | Oldham et al. | Jul 2008 | B2 |
7513320 | Mirchandani et al. | Apr 2009 | B2 |
7776256 | Smith et al. | Aug 2010 | B2 |
7802495 | Oxford et al. | Sep 2010 | B2 |
7807099 | Choe et al. | Oct 2010 | B2 |
7954569 | Mirchandani et al. | Jun 2011 | B2 |
8309018 | Smith et al. | Nov 2012 | B2 |
20010000591 | Tibbitts | May 2001 | A1 |
20010008190 | Scott et al. | Jul 2001 | A1 |
20020004105 | Kunze et al. | Jan 2002 | A1 |
20030010409 | Kunze et al. | Jan 2003 | A1 |
20030079916 | Oldham et al. | May 2003 | A1 |
20040007393 | Griffin | Jan 2004 | A1 |
20040013558 | Kondoh et al. | Jan 2004 | A1 |
20040040750 | Griffo et al. | Mar 2004 | A1 |
20040060742 | Kembaiyan et al. | Apr 2004 | A1 |
20040065481 | Murdoch | Apr 2004 | A1 |
20040141865 | Keshavan | Jul 2004 | A1 |
20040196638 | Lee et al. | Oct 2004 | A1 |
20040243241 | Istephanous et al. | Dec 2004 | A1 |
20040245022 | Izaguirre et al. | Dec 2004 | A1 |
20040245024 | Kembaiyan | Dec 2004 | A1 |
20050008524 | Testani | Jan 2005 | A1 |
20050072496 | Hwang et al. | Apr 2005 | A1 |
20050072601 | Griffo et al. | Apr 2005 | A1 |
20050084407 | Myrick | Apr 2005 | A1 |
20050117984 | Eason et al. | Jun 2005 | A1 |
20050126334 | Mirchandani | Jun 2005 | A1 |
20050211474 | Nguyen et al. | Sep 2005 | A1 |
20050211475 | Mirchandani et al. | Sep 2005 | A1 |
20050220658 | Olsson et al. | Oct 2005 | A1 |
20050247491 | Mirchandani et al. | Nov 2005 | A1 |
20050268746 | Abkowitz et al. | Dec 2005 | A1 |
20060016521 | Hanusiak et al. | Jan 2006 | A1 |
20060032677 | Azar et al. | Feb 2006 | A1 |
20060043648 | Takeuchi et al. | Mar 2006 | A1 |
20060057017 | Woodfield et al. | Mar 2006 | A1 |
20060131081 | Mirchandani et al. | Jun 2006 | A1 |
20060185908 | Kembaiyan et al. | Aug 2006 | A1 |
20060231293 | Ladi et al. | Oct 2006 | A1 |
20070042217 | Fang et al. | Feb 2007 | A1 |
20070102198 | Oxford et al. | May 2007 | A1 |
20070102199 | Smith et al. | May 2007 | A1 |
20070102200 | Choe | May 2007 | A1 |
20070202000 | Andrees et al. | Aug 2007 | A1 |
20070227782 | Kirk et al. | Oct 2007 | A1 |
20080053709 | Lockstedt et al. | Mar 2008 | A1 |
20080101977 | Eason et al. | May 2008 | A1 |
20080202814 | Lyons et al. | Aug 2008 | A1 |
20090031863 | Lyons et al. | Feb 2009 | A1 |
20090044663 | Stevens et al. | Feb 2009 | A1 |
Number | Date | Country |
---|---|---|
695583 | Aug 1998 | AU |
2212197 | Feb 1998 | CA |
264674 | Apr 1988 | EP |
453428 | Oct 1991 | EP |
995876 | Apr 2000 | EP |
1244531 | Oct 2002 | EP |
945227 | Dec 1963 | GB |
2017153 | Oct 1979 | GB |
2075554 | Nov 1981 | GB |
2017153 | Oct 1982 | GB |
2203774 | Oct 1988 | GB |
2345930 | Jul 2000 | GB |
2385350 | Aug 2003 | GB |
2393449 | Mar 2004 | GB |
10219385 | Aug 1998 | JP |
03049889 | Jun 2003 | WO |
2004053197 | Jun 2004 | WO |
Entry |
---|
US 4,966,627, 10/1990, Keshavan et al. (withdrawn) |
Alman D.E. et al. “The Abrasive Wear of Sintered Titanium Matrix-Ceramic Particle Reinforced Composites” WEAR 225-229 (1999) pp. 629-639. |
Choe Heeman et al. “Effect of Tungsten Additions on the Mechanical Properties of Ti-6A1-4V” Material Science and Engineering A 396 (2005) pp. 99-106 Elsevier. |
Diamond Innovations “Composite Diamond Coatings Superhard Protection of Wear Parts New Coating and Service Parts from Diamond Innovations” brochure 2004. |
Supplemental European Search Report for European Application No. 09763485 completion date Jul. 12, 2013, 6 pages. |
Gale W.F. et al. Smithells Metals Reference Book Eighth Edition 2003 p. 2117 Elsevier Butterworth Heinemann. |
International Preliminary Report on Patentability for International Application No. PCT/US2009/046812 dated Dec. 13, 2010, 8 pages. |
International Search Report for International Application No. PCT/US2009/046812 dated Jan. 26, 2010 5 pages. |
Written Opinion for International Application No. PCT/US2009/046812 dated Jan. 26, 2010, 5 pages. |
Miserez A. et al. “Particle Reinforced Metals of High Ceramic Content” Material Science and Engineering A 387-389 (2004) pp. 822-831 Elsevier. |
Reed James S. “Chapter 13: Particle Packing Characteristics” Principles of Ceramics Processing Second Edition John Wiley & Sons Inc. (1995) pp. 215-227. |
Serway Raymond A. Principles of Physics p. 445 (2d Ed. 1998). |
U.S. Appl. No. 60/566,063, filed Apr. 28 2004 entitled “Body Materials for Earth Boring Bits” to Mirchandani et al. |
Warrier S.G. et al. “Infiltration of Titanium Alloy-Matrix Composites” Journal of Materials Science Letters 12 (1993) pp. 865-868 Chapman & Hall. |
“Boron Carbide Nozzles and Inserts” Seven Stars International webpage http://www.concentric.net/˜ctkang/nozzle.shtml printed Sep. 7, 2006. |
“Heat Treating of Titanium and Titanium Alloys” Key to Metals website article www.key-to-metals.com, visited Sep. 21, 2006). |
European Office Action for European Application No. 09763485, dated May 3, 2016, 5 pages. |
Number | Date | Country | |
---|---|---|---|
20170321488 A1 | Nov 2017 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 14325056 | Jul 2014 | US |
Child | 14874639 | US | |
Parent | 12136703 | Jun 2008 | US |
Child | 14325056 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 14874639 | Oct 2015 | US |
Child | 15631738 | US |