Methods of forming earth-boring tools including sinterbonded components

Information

  • Patent Grant
  • 10144113
  • Patent Number
    10,144,113
  • Date Filed
    Friday, June 23, 2017
    7 years ago
  • Date Issued
    Tuesday, December 4, 2018
    5 years ago
Abstract
Partially formed earth-boring rotary drill bits comprise a first less than fully sintered particle-matrix component having at least one recess, and at least a second less than fully sintered particle-matrix component disposed at least partially within the at least one recess. Each less than fully sintered particle-matrix component comprises a green or brown structure including compacted hard particles, particles comprising a metal alloy matrix material, and an organic binder material. The at least a second less than fully sintered particle-matrix component is configured to shrink at a slower rate than the first less than fully sintered particle-matrix component due to removal of organic binder material from the less than fully sintered particle-matrix components in a sintering process to be used to sinterbond the first less than fully sintered particle-matrix component to the at least a second less than fully sintered particle-matrix component. Earth-boring rotary drill bits comprise such components sinterbonded together.
Description
FIELD

The present invention generally relates to earth-boring drill bits and other earth-boring tools that may be used to drill subterranean formations, and to methods of manufacturing such drill bits and tools. More particularly, the present invention relates to methods of sinterbonding components together to form at least a portion of an earth-boring tool and to tools formed using such methods.


BACKGROUND

The depth of well bores being drilled continues to increase as the number of shallow depth hydrocarbon-bearing earth formations continues to decrease. These increasing well bore depths are pressing conventional drill bits to their limits in terms of performance and durability. Several drill bits are often required to drill a single well bore, and changing a drill bit on a drill string can be both time consuming and expensive.


In efforts to improve drill bit performance and durability, new materials and methods for forming drill bits and their various components are being investigated. For example, methods other than conventional infiltration processes are being investigated to form bit bodies comprising particle-matrix composite materials. Such methods include forming bit bodies using powder compaction and sintering techniques. The term “sintering,” as used herein, means the densification of a particulate component and involves removal of at least a portion of the pores between the starting particles, accompanied by shrinkage, combined with coalescence and bonding between adjacent particles. Such techniques are disclosed in U.S. Pat. No. 7,802,495, issued Sep. 28, 2010, and U.S. Pat. No. 7,776,256, issued Aug. 17, 2010, both of which are assigned to the assignee of the present invention, and the entire disclosure of each of which is incorporated herein by this reference.


An example of a bit body 50 that may be formed using such powder compaction and sintering techniques is illustrated in FIG. 1. The bit body 50 may be predominantly comprised of a particle-matrix composite material 54. As shown in FIG. 1, the bit body 50 may include wings or blades 58 that are separated by junk slots 60, and a plurality of PDC cutting elements 62 (or any other type of cutting element) may be secured within cutting element pockets 64 on a face 52 of the bit body 50. The PDC cutting elements 62 may be supported from behind by buttresses 66, which may be integrally formed with the bit body 50. The bit body 50 may include internal fluid passageways (not shown) that extend between the face 52 of the bit body 50 and a longitudinal bore 56, which extends through the bit body 50. Nozzle inserts (not shown) also may be provided at the face 52 of the bit body 50 within the internal fluid passageways.


An example of a manner in which the bit body 50 may be formed using powder compaction and sintering techniques is described briefly below.


Referring to FIG. 2A, a powder mixture 68 may be pressed (e.g., with substantially isostatic pressure) within a mold or container 74. The powder mixture 68 may include a plurality of hard particles and a plurality of particles comprising a matrix material. Optionally, the powder mixture 68 may further include additives commonly used when pressing powder mixtures such as, for example, organic binders for providing structural strength to the pressed powder component, plasticizers for making the organic binder more pliable, and lubricants or compaction aids for reducing inter-particle friction and otherwise providing lubrication during pressing.


The container 74 may include a fluid-tight deformable member 76 such as, for example, a deformable polymeric bag and a substantially rigid sealing plate 78. Inserts or displacement members 79 may be provided within the container 74 for defining features of the bit body 50 such as, for example, a longitudinal bore 56 (FIG. 1) of the bit body 50. The sealing plate 78 may be attached or bonded to the deformable member 76 in such a manner as to provide a fluid-tight seal therebetween.


The container 74 (with the powder mixture 68 and any desired displacement members 79 contained therein) may be pressurized within a pressure chamber 70. A removable cover 71 may be used to provide access to the interior of the pressure chamber 70. A fluid (which may be substantially incompressible) such as, for example, water, oil, or gas (such as, for example, air or nitrogen) is pumped into the pressure chamber 70 through an opening 72 at high pressures using a pump (not shown). The high pressure of the fluid causes the walls of the deformable member 76 to deform, and the fluid pressure may be transmitted substantially uniformly to the powder mixture 68.


Pressing of the powder mixture 68 may form a green (or unsintered) body 80 shown in FIG. 2B, which can be removed from the pressure chamber 70 and container 74 after pressing.


The green body 80 shown in FIG. 2B may include a plurality of particles (hard particles and particles of matrix material) held together by interparticle friction forces and an organic binder material provided in the powder mixture 68 (FIG. 2A). Certain structural features may be machined in the green body 80 using conventional machining techniques including, for example, turning techniques, milling techniques, and drilling techniques. Hand held tools also may be used to manually form or shape features in or on the green body 80. By way of example and not limitation, blades 58, junk slots 60 (FIG. 1), and other features may be machined or otherwise formed in the green body 80 to form a partially shaped green body 84 shown in FIG. 2C.


The partially shaped green body 84 shown in FIG. 2C may be at least partially sintered to provide a brown (partially sintered) body 90 shown in FIG. 2D, which has less than a desired final density. Partially sintering the green body 84 to form the brown body 90 may cause at least some of the plurality of particles to have at least partially grown together to provide at least partial bonding between adjacent particles. The brown body 90 may be machinable due to the remaining porosity therein. Certain structural features also may be machined in the brown body 90 using conventional machining techniques.


By way of example and not limitation, internal fluid passageways (not shown), cutting element pockets 64, and buttresses 66 (FIG. 1) may be machined or otherwise formed in the brown body 90 to form a brown body 96 shown in FIG. 2E. The brown body 96 shown in FIG. 2E then may be fully sintered to a desired final density, and the cutting elements 62 may be secured within the cutting element pockets 64 to provide the bit body 50 shown in FIG. 1.


In other methods, the green body 80 shown in FIG. 2B may be partially sintered to form a brown body without prior machining, and all necessary machining may be performed on the brown body prior to fully sintering the brown body to a desired final density. Alternatively, all necessary machining may be performed on the green body 80 shown in FIG. 2B, which then may be fully sintered to a desired final density.


BRIEF SUMMARY

In some embodiments, the present invention includes methods of forming earth-boring rotary drill bits by forming and joining two less than fully sintered components, by forming and joining a first fully sintered component with a first shrink rate and forming a second less than fully sintered component with a second sinter-shrink rate greater than that of the first shrink rate of the first fully sintered component, by forming and joining a first less than fully sintered component with a first sinter-shrink rate and by forming and joining at least a second less than fully sintered component with a second sinter-shrink rate less than the first sinter-shrink rate. The methods include co-sintering a first less than fully sintered component and a second less than fully sintered component to a desired final density to form at least a portion of an earth-boring rotary drill bit, which may either cause the first less than fully sintered component and the second less than fully sintered component to join or may cause one of the first less than fully sintered component and the second less than fully sintered component to shrink around and at least partially capture the other less than fully sintered component.


In additional embodiments, the present invention includes methods of forming earth-boring rotary drill bits by providing a first component with a first sinter-shrink rate, placing at least a second component with a second sinter-shrink rate less than the first sinter-shrink rate at least partially within at least a first recess of the first component, and causing the first component to shrink at least partially around and bond to the at least a second component by co-sintering the first component and the at least a second component.


In yet additional embodiments, the present invention includes methods of forming earth-boring rotary drill bits by tailoring the sinter-shrink rate of a first component to be greater than the sinter-shrink rate of at least a second component and co-sintering the first component and the at least a second component to cause the first component to at least partially contract upon and bond to the at least a second component.


In other embodiments, the present invention includes earth-boring rotary drill bits including a first particle-matrix component and at least a second particle-matrix component at least partially surrounded by and sinterbonded to the first particle-matrix component.


In additional embodiments, the present invention includes earth-boring rotary drill bits including a bit body comprising a particle-matrix composite material and at least one cutting structure comprising a particle-matrix composite material sinterbonded at least partially within at least one recess of the bit body.





BRIEF DESCRIPTION OF THE DRAWINGS

While the specification concludes with claims particularly pointing out and distinctly claiming that which is regarded as the present invention, the advantages of this invention may be more readily ascertained from the description of the invention when read in conjunction with the accompanying drawings, in which:



FIG. 1 is a partial longitudinal cross-sectional view of a bit body of an earth-boring rotary drill bit that may be formed using powder compaction and sintering processes;



FIGS. 2A-2E illustrate an example of a particle compaction and sintering process that may be used to form the bit body shown in FIG. 1;



FIG. 3 is a perspective view of one embodiment of an earth-boring rotary drill bit of the present invention that includes two or more sinterbonded components;



FIG. 4 is a plan view of the face of the earth-boring rotary drill bit shown in FIG. 3;



FIG. 5 is a side, partial cross-sectional view of the earth-boring rotary drill bit shown in FIG. 3 taken along the section line 5-5 shown therein, which includes a plug sinterbonded within a recess of a cutting element pocket;



FIG. 6 is a side, partial cross-sectional view like that of FIG. 5 illustrating a less than fully sintered bit body and a less than fully sintered plug that may be co-sintered to a desired final density to form the earth-boring rotary drill bit shown in FIG. 5;



FIG. 7A is a cross-sectional view of the bit body and plug shown in FIG. 6 taken along section line 7A-7A shown therein;



FIG. 7B is a cross-sectional view of the bit body shown in FIG. 5 taken along the section line 7B-7B shown therein that may be formed by sintering the bit body and the plug shown in FIG. 7A to a final desired density;



FIG. 8 is a longitudinal cross-sectional view of the earth-boring rotary drill bit shown in FIGS. 3 and 4 taken along the section line 8-8 shown in FIG. 4 that includes several particle-matrix components that have been sinterbonded together according to teachings of the present invention;



FIG. 8A is a longitudinal cross-sectional view of the earth-boring rotary drill bit shown in FIGS. 3 and 4 taken along the section line 8-8 shown in FIG. 4 that includes several particle-matrix components that have been sinterbonded together according to teachings of the present invention;



FIG. 8B is a cross-sectional view of the earth-boring rotary drill bit shown in FIG. 8A taken along section line 9A-9A shown therein that includes a less than fully sintered extension to be sinterbonded to a fully sintered bit body;



FIG. 8C is a cross-sectional view, similar to the cross-sectional view shown in FIG. 8B, illustrating a fully sintered bit body and a less than fully sintered extension that may be sintered to a desired final density to form the earth-boring rotary drill bit shown in FIG. 8B;



FIG. 9A is a cross-sectional view of the earth-boring rotary drill bit shown in FIG. 8 taken along section line 9A-9A shown therein that includes an extension sinterbonded to a bit body;



FIG. 9B is a cross-sectional view, similar to the cross-sectional view shown in FIG. 9A, illustrating a less than fully sintered bit body and a less than fully sintered extension that may be co-sintered to a desired final density to form the earth-boring rotary drill bit shown in FIG. 9A;



FIG. 10A is a cross-sectional view of the earth-boring rotary drill bit shown in FIG. 8 taken along section line 10A-10A shown therein that includes a blade sinterbonded to a bit body;



FIG. 10B is a cross-sectional view, similar to the cross-sectional view shown in FIG. 10A, illustrating a less than fully sintered bit body and a less than fully sintered blade that may be co-sintered to a desired final density to form the earth-boring rotary drill bit shown in FIG. 10A;



FIG. 11A is a partial cross-sectional view of a blade of an earth-boring rotary drill bit with a cutting structure sinterbonded thereto using methods of the present invention;



FIG. 11B is a partial cross-sectional view, similar to the partial cross-sectional view shown in FIG. 11A, illustrating a less than fully sintered blade of an earth-boring rotary drill bit and a less than fully sintered cutting structure that may be co-sintered to a desired final density to form the blade of the earth-boring rotary drill bit shown in FIG. 11A;



FIG. 12A is an enlarged partial cross-sectional view of the earth-boring rotary drill bit shown in FIG. 8 that includes a nozzle exit ring sinterbonded to a bit body;



FIG. 12B is a cross-sectional view, similar to the cross-sectional view shown in FIG. 12A, of a less than full sintered earth-boring rotary drill bit that may be sintered to a final desired density to form the earth-boring rotary drill bit shown in FIG. 12A;



FIG. 13 is a partial perspective view of a bit body of another embodiment of an earth-boring rotary drill bit of the present invention, and more particularly of a blade of the bit body of an earth-boring rotary drill bit that includes buttresses that may be sinterbonded to the bit body;



FIG. 14A is a partial cross-sectional view of the bit body shown in FIG. 13 taken along the section line 14A-14A shown therein that does not illustrate a cutting element 210; and



FIG. 14B is partial cross-sectional view, similar to the partial cross-sectional view shown in FIG. 14A, of a less than fully sintered bit body that may be sintered to a desired final density to form the bit body shown in FIG. 14A.





DETAILED DESCRIPTION

The illustrations presented herein are not meant to be actual views of any particular material, apparatus, system, or method, but are merely idealized representations which are employed to describe the present invention. Additionally, elements common between figures may retain the same numerical designation.


An embodiment of an earth-boring rotary drill bit 100 of the present invention is shown in perspective in FIG. 3. FIG. 4 is a top plan view of the face of the earth-boring rotary drill bit 100 shown in FIG. 3. The earth-boring rotary drill bit 100 may comprise a bit body 102 that is secured to a shank 104 having a threaded connection portion 106 (e.g., an American Petroleum Institute (API) threaded connection portion) for attaching the drill bit 100 to a drill string (not shown). In some embodiments, such as that shown in FIG. 3, the bit body 102 may be secured to the shank 104 using an extension 108. In other embodiments, the bit body 102 may be secured directly to the shank 104.


The bit body 102 may include internal fluid passageways (not shown) that extend between a face 103 of the bit body 102 and a longitudinal bore (not shown), which extends through the shank 104, the extension 108, and partially through the bit body 102, similar to the longitudinal bore 56 shown in FIG. 1. Nozzle inserts 124 also may be provided at the face 103 of the bit body 102 within the internal fluid passageways. The bit body 102 may further include a plurality of blades 116 that are separated by junk slots 118. In some embodiments, the bit body 102 may include gage wear plugs 122 and wear knots 128. A plurality of cutting elements 110 (which may include, for example, PDC cutting elements) may be mounted on the face 103 of the bit body 102 in cutting element pockets 112 that are located along each of the blades 116.


The earth-boring rotary drill bit 100 shown in FIG. 3 may comprise a particle-matrix composite material 120 and may be formed using powder compaction and sintering processes, such as those described in previously mentioned U.S. Pat. No. 7,802,495, and U.S. Pat. No. 7,776,256. By way of example and not limitation, the particle-matrix composite material 120 may comprise a plurality of hard particles dispersed throughout a matrix material. In some embodiments, the hard particles may comprise a material selected from diamond, boron carbide, boron nitride, aluminum nitride, and carbides or borides of the group consisting of W, Ti, Mo, Nb, V, Hf, Zr, Si, Ta, and Cr, and the matrix material may be selected from the group consisting of iron-based alloys, nickel-based alloys, cobalt-based alloys, titanium-based alloys, aluminum-based alloys, iron- and nickel-based alloys, iron- and cobalt-based alloys, and nickel- and cobalt-based alloys. As used herein, the term “[metal]-based alloy” (where [metal] is any metal) means commercially pure [metal] in addition to metal alloys wherein the weight percentage of [metal] in the alloy is greater than or equal to the weight percentage of all other components of the alloy individually.


Furthermore, the earth-boring rotary drill bit 100 may be formed from two or more, less than fully sintered components (i.e., green or brown components) that may be sinterbonded together to form at least a portion of the drill bit 100. During sintering of two or more less than fully sintered components (i.e., green or brown components), the two or more components will bond together. Additionally, when sintering the two or more less than fully sintered components together, the relative shrinkage rates of the two or more components may be tailored such that during sintering a first component and at least a second component will shrink essentially the same or a first component will shrink more than at least a second component. By tailoring the sinter-shrink rates such that a first component will have a greater shrinkage rate than the at least a second component, the components may be configured such that during sintering the at least a second component is at least partially surrounded and captured as the first component contracts upon it, thereby facilitating a complete sinterbond between the first and at least second components. The sinter-shrink rates of the two or more components may be tailored by controlling the porosity of the less than fully sintered components. Thus, forming a first component with more porosity than at least a second component may cause the first component to have a greater sinter-shrink rate than the at least a second component having less porosity.


The porosity of the components may be tailored by modifying one or more of the following non-limiting variables: particle size and size distribution, particle shape, pressing method, compaction pressure, and the amount of binder used when forming the less than fully sintered components.


Particles that are all the same size may be difficult to pack efficiently. Components formed from particles of the same size may include large pores and a high volume percentage of porosity. On the other hand, components formed from particles with a broad range of sizes may pack efficiently and minimize pore space between adjacent particles. Thus, porosity and therefore the sinter-shrink rates of a component may be controlled by the particle size and size distribution of the hard particles and matrix material used to form the component.


The pressing method may also be used to tailor the porosity of a component. Specifically, one pressing method may lead to tighter packing and therefore less porosity. As a non-limiting example, substantially isostatic pressing methods may produce tighter packed particles in a less than fully sintered component than uniaxial pressing methods and therefore less porosity. Therefore, porosity and the sinter-shrink rates of a component may be controlled by the pressing method used to form the less than full sintered component.


Additionally, compaction pressure may be used to control the porosity of a component. The greater the compaction pressure used to form the component the lesser amount of porosity the component may exhibit.


Finally, the amount of binder used in the components relative to the powder mixture may vary which affects the porosity of the powder mixture when the binder is burned from the powder mixture. The binder used in any powder mixture includes commonly used additives when pressing powder mixtures such as, for example, binders for providing lubrication during pressing and for providing structural strength to the pressed powder component, plasticizers for making the binder more pliable, and lubricants or compaction aids for reducing inter-particle friction.


The shrink rate of a particle-matrix material component is independent of composition. Therefore, varying the composition of the first component and the at least second components may not cause a difference in relative sinter-shrink rates. However, the composition of the first and the at least second components may be varied. In particular, the composition of the components may be varied to provide a difference in wear resistance or fracture toughness between the components. As a non-limiting example, a different grade of carbide may be used to form one component so that it exhibits greater wear resistance and/or fracture toughness relative to the component to which it is sinterbonded.


In some embodiments, the first component and at least a second component may comprise green body structures. In other embodiments, the first component and the at least a second component may comprise brown components. In yet additional embodiments, one of the first component and the at least a second component may comprise a green body component and the other a brown body component.


Recently, new methods of forming cutting element pockets by using a rotating cutter to machine a cutting element pocket in such a way as to avoid mechanical tool interference problems and forming the pocket so as to sufficiently support a cutting element therein have been investigated. Such methods are disclosed in U.S. Pat. No. 7,836,980, issued Nov. 23, 2010, the entire disclosure of which is incorporated by reference herein. Such methods may include machining a first recess in a bit body of an earth-boring tool to define a lateral sidewall surface of a cutting element pocket, machining a second recess to define at least a portion of a shoulder at an intersection with the first recess, and disposing a plug within the second recess to define at least a portion of an end surface of the cutting element pocket.


According to some embodiments of the present invention, the plug as disclosed by the previously referenced U.S. Pat. No. 7,836,980, may be sinterbonded within the second recess to form a unitary bit body. More particularly, the sinter-shrink rates of the plug and the bit body surrounding it may be tailored so the bit body at least partially surrounds and captures the plug during co-sintering to facilitate a complete sinterbond.



FIG. 5 is a side, partial cross-sectional view of the bit body 102 shown in FIG. 3 taken along the section line 5-5 shown therein. FIG. 6 is side, partial cross-sectional view of a less than fully sintered bit body 101 (i.e., a green or brown bit body) that may be sintered to a desired final density to form the bit body 102 shown in FIG. 5. As shown in FIG. 6, the bit body 101 may comprise a cutting element pocket 112 as defined by first and second recesses 130, 132 formed according to the methods of the previously mentioned U.S. Pat. No. 7,836,980. A plug 134 may be disposed in the second recess 132 and may be placed so that at least a portion of a leading face 136 of the plug 134 may abut against a shoulder 138 between the first and second recesses 130, 132. At least a portion of the leading face 136 of the plug 134 may be configured to define the back surface (e.g., rear wall) of the cutting element pocket 112 against which a cutting element 110 may abut and rest. The plug 134 may be used to replace the excess material removed from the bit body 101 when forming the first recess 130 and the second recess 132, and to fill any portion or portions of the first recess 130 and the second recess 132 that are not comprised by the cutting element pocket 112.


Both the plug 134 and the bit body 102 may comprise particle-matrix composite components formed from any of the materials described hereinabove in relation to particle-matrix composite material 120. In some embodiments, the plug 134 and the bit body 101 may both comprise green powder components. In other embodiments, the plug 134 and the bit body 101 may both comprise brown components. In yet additional embodiments, one of the plug 134 and the bit body 101 may comprise a green body and the other a brown body. The sinter-shrink rate of the plug 134 and the bit body 101 may be tailored as desired as discussed herein. For instance, the sinter-shrink rate of the plug 134 and the bit body 101 may be tailored so the bit body 101 has a greater sinter-shrink rate than the plug 134. The plug 134 may be disposed within the second recess 132 as shown in FIG. 6, and the plug 134 and the bit body 101 may be co-sintered to a final desired density to sinterbond the less than full sintered bit body 101 to the plug 134 to form the unitary bit body 102 shown in FIG. 5. As mentioned previously, the sinter-shrink rates of the plug 134 and the bit body 101 may be tailored by controlling the porosity of each so the bit body 101 has a greater porosity than the plug 134 such that during sintering the bit body 101 will shrink more than the plug 134. The porosity of the bit body 101 and the plug 134 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.



FIG. 7A is a cross-sectional view of the bit body 101 shown in FIG. 6 taken along section line 7A-7A shown therein. In some embodiments, as shown in FIG. 7A, a diameter D132 of the second recess 132 of the cutting element pocket 112 may be larger than a diameter D134 of the plug 134. The difference in the diameters of the second recess 132 and the plug 134 may allow the plug 134 to be easily placed within the second recess 132. FIG. 7B is a cross-sectional view of the bit body 102 shown in FIG. 5 taken along the section line 7B-7B shown therein and may be formed by sintering the bit body 101 and the plug 134 as shown in FIG. 7A to a final desired density. As shown in FIG. 7B, after sintering the bit body 101 and the plug 134 to a final desired density, any gap between the second recess 132 and the plug 134 created by the difference between the diameters D132, D134 of the second recess 132 and the plug 134 may be eliminated as the bit body 101 shrinks around and captures the plug 134 during co-sintering. Thus, because the bit body 101 has a greater sinter-shrink rate than the plug 134 and shrinks around and captures the plug 134 during sintering, a complete sinterbond along the entire interface between the plug 134 and the bit body 101 may be formed despite any gap between the second recess 132 and the plug 134 prior to co-sintering.


After co-sintering the plug 134 and the bit body 101 to a final desired density as shown in FIGS. 6 and 7B, the bit body 102 and the plug 134 may form a unitary structure. In other words, coalescence and bonding may occur between adjacent particles of the particle-matrix composite materials of the plug 134 and the bit body 101 during co-sintering. By co-sintering the plug 134 and the bit body 101 and forming a sinterbond therebetween, the bit body 102 may exhibit greater strength than a bit body formed from a plug that has been welded or brazed therein using conventional bonding methods.



FIG. 8 is a longitudinal cross-sectional view of the earth-boring rotary drill bit 100 shown in FIGS. 3 and 4 taken along the section line 8-8 shown in FIG. 4. The earth-boring rotary drill bit 100 shown in FIG. 8 does not include cutting elements 110, nozzle inserts 124, or a shank 104. As shown in FIG. 8, the earth-boring rotary drill bit 100 may comprise one or more particle-matrix components that have been sinterbonded together to form the earth-boring rotary drill bit 100. In particular, the earth-boring rotary drill bit 100 may comprise an extension 108 that will be sinterbonded to the bit body 102, a blade 116 that may be sinterbonded to the bit body 102, cutting structures 146 that may be sinterbonded to the blade 116, and nozzle exit rings 127 that may be sinterbonded to the bit body 102 all using methods of the present invention in a manner similar to those described above in relation to the plug 134 and the bit body 102. The sinterbonding of the extension 108 and the bit body 102 is described hereinbelow in relation to FIGS. 9A and 9B; the sinterbonding of the blade 116 to the bit body 102 is described hereinbelow in relation to FIGS. 10A and 10B; the sinterbonding of the cutting structures 146 to the blade 116 is described hereinbelow in relation to FIGS. 11A and 11B; and the sinterbonding of the nozzle exit ring 127 to the bit body 102 is described herein below in relation to FIGS. 12A and 12B.



FIG. 8A is another longitudinal cross-sectional view of the earth-boring rotary drill bit 100 shown in FIGS. 3 and 4 taken along the section line 8-8 shown in FIG. 4. The earth-boring rotary drill bit 100 shown in FIG. 8 does not include cutting elements 110, nozzle inserts 124, or a shank 104. As shown in FIG. 8A, the earth-boring rotary drill bit 100 may comprise one or more particle-matrix components that will be or are sinterbonded together to form the earth-boring rotary drill bit 100. In particular, the earth-boring rotary drill bit 100 may comprise an extension 108 that will be sinterbonded to the previously finally sintered bit body 102, a blade 116 that has been sinterbonded to the bit body 102, cutting structures 146 that have been sinterbonded to the blade 116, and nozzle exit rings 127 that have been sinterbonded to the bit body 102 all using methods of the present invention in a manner similar to those described above in relation to the plug 134 and the bit body 102. The sinterbonding of the extension 108 and the bit body 102 occurs after the final sintering of the bit body 102 such as described herein when it is desired to have the shrinking of the extension to attach the extension 108 to the bit body 102. In general, after sinterbonding, the bit body 102 and the extension 108 are illustrated in relation to FIGS. 8B-8C. The extension 108 may be formed having a taper of approximately ½° to approximately 2°, as illustrated, while the bit body 102 may be formed having a mating taper of approximately ½° to approximately 2°, as illustrated, so that after the sinterbonding of the extension 108 to the bit body 102 the mating tapers of the extension 108 and the bit body 102 have formed an interference fit therebetween.



FIG. 8B is a cross-sectional view of the earth-boring rotary drill bit 100 shown in FIG. 8 taken along the section line 9A-9A shown therein. FIG. 8C is a cross-sectional view of a fully sintered bit body 102, similar to the cross-sectional view shown in FIG. 8B, that has been sintered to a final desired density to form the earth-boring rotary drill bit body 102 shown in FIG. 8A. As shown in FIG. 8B, the earth-boring rotary drill bit 100 comprises a fully sintered bit body 102 and a less than fully sintered extension 108. The fully sintered bit body 102 and the less than fully sintered extension 108 may both comprise particle-matrix composite components. In some embodiments, both the fully sintered bit body 102 and the less than fully sintered extension 108 may comprise particle-matrix composite components formed from a plurality of tungsten carbide particles dispersed throughout a cobalt matrix material. In other embodiments, the less than fully sintered extension 108 and the fully sintered bit body 102 may comprise any of the materials described hereinabove in relation to particle-matrix composite material 120.


Furthermore, in some embodiments the fully sintered bit body 102 and less than fully sintered extension 108 may exhibit different material properties. As non-limiting examples, the fully sintered bit body 102 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered extension 108.


The sinter-shrink rates of the fully sintered bit body 102, although a fully sintered bit body 102 essentially has no sinter-shrink rate after being fully sintered, and the less than fully sintered extension 108 may be tailored by controlling the porosity of each so the extension 108 has a greater porosity than the bit body 102 such that during sintering the extension 108 will shrink more than the fully sintered bit body 102. The porosity of the bit body 102 and the extension 108 may be tailored by modifying one or more of the particle size and size distribution, particle shape, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove. Suitable types of connectors, such as lugs and recesses 108′ or keys and recesses 108″ (illustrated in dashed lines in FIGS. 8B, 8C) may be used as desired between the bit body 102 and extension 108.



FIG. 9A is a cross-sectional view of the earth-boring rotary drill bit 100 shown in FIG. 8 taken along the section line 9A-9A shown therein. FIG. 9B is a cross-sectional view of a less than full sintered (i.e., a green or brown bit body) earth-boring rotary drill bit 105, similar to the cross-sectional view shown in FIG. 9A, that may be sintered to a final desired density to form the earth-boring rotary drill bit 100 shown in FIG. 9A. As shown in FIG. 9B, the earth-boring rotary drill bit 105 may comprise a less than fully sintered bit body 101 and a less than fully sintered extension 107. The less than fully sintered bit body 101 and the less than fully sintered extension 107 may both comprise particle-matrix composite components. In some embodiments, both the less than fully sintered bit body 101 and the less than fully sintered extension 107 may comprise particle-matrix composite components formed from a plurality of tungsten carbide particles dispersed throughout a cobalt matrix material. In other embodiments, the less than fully sintered extension 107 and the less than fully sintered bit body 101 may comprise any of the materials described hereinabove in relation to particle-matrix composite material 120.


Furthermore, in some embodiments the less than fully sintered bit body 101 and less than fully sintered extension 107 may exhibit different material properties. As non-limiting examples, the less than fully sintered bit body 101 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered extension 107.


The sinter-shrink rates of the less than fully sintered bit body 101 and the less than fully sintered extension 107 may be tailored by controlling the porosity of each so the extension 107 has a greater porosity than the bit body 101 such that during sintering the extension 107 will shrink more than the bit body 101. The porosity of the bit body 101 and the extension 107 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.


As mentioned previously, the extension 107 and the bit body 101, as shown in FIG. 9B, may be co-sintered to a final desired density to form the earth-boring rotary drill bit 100 shown in FIG. 9A. In particular, a portion 140 (FIG. 8) of the bit body 101 may be disposed at least partially within a recess 142 (FIG. 8) of the extension 107 and the extension 107 and the bit body 101 may be co-sintered. Because the extension 107 has a greater sinter-shrink rate than the bit body 101, the extension 107 may contract around the bit body 101 facilitating a complete sinterbond along an interface 144 therebetween, as shown in FIG. 9A.



FIG. 10A is a cross-sectional view of the earth-boring rotary drill bit 100 shown in FIG. 8 taken along the section line 10A-10A shown therein. FIG. 10B is a cross-sectional view of a less than fully sintered (i.e., a green or brown bit body) earth-boring rotary drill bit 105, similar to the cross-sectional view shown in FIG. 10A, that may be sintered to a final desired density to form the earth-boring rotary drill bit 100 shown in FIG. 10A. As shown in FIG. 10B, the earth-boring rotary drill bit 105 may comprise a less than fully sintered bit body 101 and a less than fully sintered blade 150. The less than fully sintered bit body 101 and the less than fully sintered blade 150 may both comprise particle-matrix composite components. In some embodiments, both the less than fully sintered bit body 101 and the less than fully sintered blade 150 may comprise particle-matrix composite components formed from a plurality of tungsten carbide particles dispersed throughout a cobalt matrix material. In other embodiments, the less than fully sintered blade 150 and the less than fully sintered bit body 101 may comprise any of the materials described hereinabove in relation to particle-matrix composite material 120.


Furthermore, in some embodiments the less than fully sintered bit body 101 and less than fully sintered blade 150 may exhibit different material properties. As non-limiting examples, the less than fully sintered blade 150 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered bit body 101. As non-limiting examples, the binder content may be lowered or a different grade of carbide may be used to form the blade 150 so that it exhibits greater wear resistance and/or fracture toughness relative to the bit body 101. In other embodiments, the less than fully sintered bit body 101 and less than fully sintered blade 150 may exhibit similar material properties.


The sinter-shrink rates of the less than fully sintered bit body 101 and the less than fully sintered blade 150 may be tailored by controlling the porosity of each so the bit body 101 has a greater porosity than the blade 150 such that during sintering the bit body 101 will shrink more than the blade 150. The porosity of the bit body 101 and the blade 150 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.


As mentioned previously, the blade 150 and the bit body 101, as shown in FIG. 10B, may be co-sintered to a final desired density to form the earth-boring rotary drill bit 100 shown in FIG. 10A. In particular, the blade 150 may be at least partially disposed within a recess 154 of the bit body 101 and the blade 150 and the bit body 101 may be co-sintered. Because the bit body 101 has a greater sinter-shrink rate than the blade 150, the bit body 101 may contract around the blade 150 facilitating a complete sinterbond along an interface 155 therebetween as shown in FIG. 10A.


Additionally as seen in FIG. 8, the earth-boring rotary drill bit 100 may include cutting structures 146 that may be sinterbonded to the bit body 102 and more particularly to the blades 116 using methods of the present invention. “Cutting structures” as used herein mean any structure of an earth-boring rotary drill bit configured to engage earth formations in a bore hole. For example, cutting structures may comprise wear knots 128, gage wear plugs 122, cutting elements 110 (FIG. 3), and BRUTE™ cutters 260 (Backup cutters that are Radially Unaggressive and Tangentially Efficient, illustrated in (FIG. 13).



FIG. 11A is a partial cross-sectional view of a blade 116 of an earth-boring rotary drill bit with a cutting structure 146 sinterbonded thereto using methods of the present invention. FIG. 11B is a partial cross-sectional view of a less than fully sintered blade 160 of an earth-boring rotary drill bit, similar to the cross-sectional view shown in FIG. 11A, that may be sintered to a final desired density to form the blade 116 shown in FIG. 11A. As shown in FIG. 11B, a less than fully sintered cutting structure 147 may be disposed at least partially within a recess 148 of the less than fully sintered blade 160. The less than fully sintered cutting structure 147 and the less than fully sintered blade 160 may both comprise particle-matrix composite components. In some embodiments, both the less than fully sintered cutting structure 147 and the less than fully sintered blade 160 may comprise particle-matrix composite components formed from a plurality of tungsten carbide particles dispersed throughout a cobalt matrix material. In other embodiments, the less than fully sintered blade 160 and the less than fully sintered cutting structure 147 may comprise any of the materials described hereinabove in relation to particle-matrix composite material 120.


Furthermore, in some embodiments the less than fully sintered cutting structure 147 and less than fully sintered blade 160 may exhibit different material properties. As non-limiting examples, the less than fully sintered cutting structure 147 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered blade 160. As non-limiting examples, the binder content may be lowered or a different grade of carbide may be used to form the less than fully sintered cutting structure 147 so that it exhibits greater wear resistance and/or fracture toughness relative to the blade 160. In other embodiments, the less than fully sintered cutting structure 147 and less than fully sintered blade 160 may exhibit similar material properties.


The sinter-shrink rates of the less than fully sintered cutting structure 147 and the less than fully sintered blade 160 may be tailored by controlling the porosity of each so the blade 160 has a greater porosity than the cutting structure 147 such that during sintering the blade 160 will shrink more than the cutting structure 147. The porosity of the cutting structure 147 and the blade 160 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.


As mentioned previously, the blade 160 and the cutting structure 147, as shown in FIG. 11B, may be co-sintered to a final desired density to form the blade 116 shown in FIG. 11A. Because the blade 160 has a greater sinter-shrink rate than the cutting structure 147, the blade 160 may contract around the cutting structure 147 facilitating a complete sinterbond along an interface 162 therebetween as shown in FIG. 11A.



FIG. 12A is an enlarged partial cross-sectional view of the earth-boring rotary drill bit 100 shown in FIG. 8. FIG. 12B is a cross-sectional view of a less than fully sintered earth-boring rotary drill bit 105, similar to the cross-sectional view shown in FIG. 12A, that may be sintered to a final desired density to form the earth-boring rotary drill bit 100 shown in FIG. 12A. As shown in FIG. 12B, the earth-boring rotary drill bit 105 may comprise a less than fully sintered bit body 101 and a less than fully sintered nozzle exit ring 129. The less than fully sintered bit body 101 and the less than fully sintered nozzle exit ring 129 may both comprise particle-matrix composite components. In some embodiments, both the less than fully sintered bit body 101 and the less than fully sintered nozzle exit ring 129 may comprise particle-matrix composite components formed from a plurality of tungsten carbide particles dispersed throughout a cobalt matrix material. In other embodiments, the less than fully sintered nozzle exit ring 129 and the less than fully sintered bit body 101 may comprise any of the materials described hereinabove in relation to particle-matrix composite material 120.


Furthermore, in some embodiments the less than fully sintered bit body 101 and less than fully sintered nozzle exit ring 129 may exhibit different material properties. As non-limiting examples, the less than fully sintered nozzle exit ring 129 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered bit body 101. As non-limiting examples, the binder content may be lowered or a different grade of carbide may be used to form the nozzle exit ring 129 so that it exhibits greater wear resistance and/or fracture toughness relative to the bit body 101. In other embodiments, the less than fully sintered bit body 101 and less than fully sintered nozzle exit ring 129 may exhibit similar material properties.


The sinter-shrink rates of the less than fully sintered bit body 101 and the less than fully sintered nozzle exit ring 129 may be tailored by controlling the porosity of each so the bit body 101 has a greater porosity than the nozzle exit ring 129 such that during sintering the bit body 101 will shrink more than the nozzle exit ring 129. The porosity of the bit body 101 and the nozzle exit ring 129 may be tailored by modifying one or more of the particle size and size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.


As mentioned previously, the nozzle exit ring 129 and the bit body 101, as shown in FIG. 12B, may be co-sintered to a final desired density to form the earth-boring rotary drill bit 100 shown in FIG. 11A. In particular, the nozzle exit ring 129 may be at least partially disposed within a recess 163 of the bit body 101 and the nozzle exit ring 129 and the bit body 101 may be co-sintered. Because the bit body 101 has a greater sinter-shrink rate than the nozzle exit ring 129, the bit body 101 may contract around the nozzle exit ring 129 facilitating a complete sinterbond along an interface 173 therebetween, as shown in FIG. 12A.



FIG. 13 is a partial perspective view of a bit body 202 of an earth-boring rotary drill bit, and more particularly of a blade 216 of the bit body 202, similar to the bit body 102 shown in FIG. 3. The bit body 202 may comprise a particle-matrix composite material 120 and may be formed using powder compaction and sintering processes, such as those previously described. As shown in FIG. 13, the bit body 202 may include a plurality of cutting elements 210 supported by buttresses 207. The bit body 202 may also include a plurality of BRUTE™ cutters 260.


According to some embodiments of the present invention, the buttresses 207 may be sinterbonded to the bit body 202. FIG. 14A is a partial cross-sectional view of the bit body 202 shown in FIG. 13 taken along the section line 14A-14A shown therein. FIG. 14A, however, does not illustrate the cutting element 210. FIG. 14B is a less than fully sintered bit body 201 (i.e., a green or brown bit body) that may be sintered to a desired final density to form the bit body 202 shown in FIG. 14A. As shown in FIG. 14B, the less than fully sintered bit body 201 may comprise a cutting element pocket 212 and a recess 214 configured to receive a less than fully sintered buttress 208.


The less than fully sintered buttress 208 and the less than fully sintered bit body 201 may both comprise particle-matrix composite components. In some embodiments, both the less than fully sintered buttress 208 and the less than fully sintered bit body 201 may comprise particle-matrix composite components formed from a plurality of tungsten carbide particles dispersed throughout a cobalt matrix material. In other embodiments, the less than fully sintered bit body 201 and the less than fully sintered buttress 208 may comprise any of the materials described hereinabove in relation to particle-matrix composite material 120.


Furthermore, in some embodiments the less than fully sintered buttress 208 and less than fully sintered bit body 201 may exhibit different material properties. As non-limiting examples, the less than fully sintered buttress 208 may comprise a tungsten carbide material with greater fracture toughness or wear resistance than a tungsten carbide material used to form the less than fully sintered bit body 201. As non-limiting examples, the binder content may be lowered or a different grade of carbide may be used to form the less than fully sintered buttress 208 so that it exhibits greater wear resistance and/or fracture toughness relative to the bit body 201. In other embodiments, the less than fully sintered buttress 208 and less than fully sintered bit body 201 may exhibit similar material properties.


The sinter-shrink rates of the less than fully sintered buttress 208 and the less than fully sintered bit body 201 may be tailored by controlling the porosity of each so the bit body 201 has a greater porosity than the buttress 208 such that during sintering the bit body 201 will shrink more than the buttress 208. The porosity of the buttress 208 and the bit body 201 may be tailored by modifying one or more of the particle size, particle shape, and particle size distribution, pressing method, compaction pressure, and the amount of the binder used in a component when forming the less than fully sintered components as described hereinabove.


As mentioned previously, the bit body 201 and the buttress 208, as shown in FIG. 14B, may be co-sintered to a final desired density to form the bit body 202 shown in FIG. 14A. Because the bit body 201 has a greater sinter-shrink rate than the buttress 208, the bit body 201 may contract around the buttress 208 facilitating a complete sinterbond along an interface 220 therebetween as shown in FIG. 14A.


Although the methods of the present invention have been described in relation to fixed-cutter rotary drill bits, they are equally applicable to any bit body that is formed by sintering a less than fully sintered bit body to a desired final density. For example, the methods of the present invention may be used to form subterranean tools other than fixed-cutter rotary drill bits including, for example, core bits, eccentric bits, bicenter bits, reamers, mills, drag bits, roller cone bits, and other such structures known in the art.


While the present invention has been described herein with respect to certain preferred embodiments, those of ordinary skill in the art will recognize and appreciate that it is not so limited. Rather, many additions, deletions and modifications to the preferred embodiments may be made without departing from the scope of the invention as hereinafter claimed. In addition, features from one embodiment may be combined with features of another embodiment while still being encompassed within the scope of the invention as contemplated by the inventors.

Claims
  • 1. An earth-boring rotary drill bit, comprising: a bit body comprising a first component and a second component sinterbonded together, wherein the first component comprises a surface defining a recess in the first component and a shoulder adjacent the recess, wherein at least a portion of the second component is disposed within the recess and adjacent the shoulder, and wherein the first component and the second component have an interfering fit with one another;wherein at least one of the first component or the second component has a surface tapered between about ½° and about 2° with respect to a longitudinal axis of the first component or the second component.
  • 2. The earth-boring rotary drill bit of claim 1, wherein the first component has a composition different from a composition of the second component.
  • 3. The earth-boring rotary drill bit of claim 1, wherein both the first component and the second component have a surface tapered with respect to a longitudinal axis thereof.
  • 4. The earth-boring rotary drill bit of claim 3, wherein the surfaces each have complementary tapers between approximately ½° and approximately 2° with respect to the longitudinal axis.
  • 5. The earth-boring rotary drill bit of claim 1, wherein at least one of the first component and the second component comprises a particle-matrix composite.
  • 6. The earth-boring rotary drill bit of claim 5, wherein the particle-matrix composite comprises hard particles selected from the group consisting of diamond, boron carbide, boron nitride, aluminum nitride, and carbides and borides of the group consisting of W, Ti, Mo, Nb, V, Hf, Zr, Si, Ta, and Cr.
  • 7. The earth-boring rotary drill bit of claim 5, wherein the particle-matrix composite comprises a material selected from the group consisting of iron-based alloys, nickel-based alloys, cobalt-based alloys, titanium-based alloys, aluminum-based alloys, iron- and nickel-based alloys, iron- and cobalt-based alloys, and nickel- and cobalt-based alloys.
  • 8. The earth-boring rotary drill bit of claim 1, wherein at least one of the first component or the second component comprises a plurality of tungsten carbide particles dispersed within a matrix comprising cobalt.
  • 9. The earth-boring rotary drill bit of claim 1, wherein the first component comprises a bit body, and wherein the second component comprises an extension sinterbonded to the bit body.
  • 10. The earth-boring rotary drill bit of claim 9, wherein the extension comprises a surface defining a threaded fitting.
  • 11. The earth-boring rotary drill bit of claim 1, wherein the first component comprises a bit body, and wherein the second component comprises a blade sinterbonded to the bit body.
  • 12. The earth-boring rotary drill bit of claim 1, wherein the first component comprises a blade, and wherein the second component comprises a cutting structure sinterbonded to the blade.
  • 13. The earth-boring rotary drill bit of claim 1, wherein the first component comprises a blade, and wherein the second component comprises a buttress configured to support a cutting element.
  • 14. The earth-boring rotary drill bit of claim 13, wherein the buttress is secured at least partially within a recess defined by a surface of the blade.
  • 15. The earth-boring rotary drill bit of claim 13, further comprising a cutting element secured to the blade in contact with the buttress.
  • 16. The earth-boring rotary drill bit of claim 1, wherein at least one of the first component or the second component comprises a threaded connection configured to secure the bit to a drill string.
  • 17. The earth-boring rotary drill bit of claim 1, wherein at least one of the first component or the second component comprises a surface defining at least one internal fluid passageway.
  • 18. The earth-boring rotary drill bit of claim 1, wherein the first component and the second component each comprise hard particles, wherein the hard particles of the first component have a first average diameter, and wherein the hard particles of the second component have a second average diameter different from the first average diameter.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No. 14/874,639, filed Oct. 5, 2015, now U.S. Pat. No. 9,700,991, issued Jul. 11, 2017, which is a divisional of U.S. patent application Ser. No. 14/325,056, filed Jul. 7, 2014, now U.S. Pat. No. 9,192,989, issued Nov. 24, 2015; which is a divisional of U.S. patent application Ser. No. 12/136,703, filed Jun. 10, 2008, now U.S. Pat. No. 8,770,324, issued Jul. 8, 2014, the disclosure of each of which is hereby incorporated herein in its entirety by this reference. The subject matter of this application is related to the subject matter of U.S. application Ser. No. 11/272,439, filed Nov. 10, 2005, now U.S. Pat. No. 7,776,256, issued Aug. 17, 2010 and U.S. application Ser. No. 11/271,153, filed Nov. 10, 2005, now U.S. Pat. No. 7,802,495, issued Sep. 28, 2010, the disclosure of each of which is hereby incorporated herein in its entirety by this reference. The subject matter of this application is also related to U.S. application Ser. No. 12/831,608, filed Jul. 7, 2010, and U.S. application Ser. No. 12/827,968, filed Jun. 30, 2010, now U.S. Pat. No. 8,309,018, issued Nov. 13, 2012, the disclosure of each of which is hereby incorporated herein in its entirety by this reference.

US Referenced Citations (240)
Number Name Date Kind
1954166 Campbell Apr 1934 A
2299207 Bevillard Oct 1942 A
2507439 Goolsbee May 1950 A
2819958 Abkowitz et al. Jan 1958 A
2819959 Abkowitz et al. Jan 1958 A
2906654 Abkowitz Sep 1959 A
3368881 Abkowitz et al. Feb 1968 A
3471921 Feenstra Oct 1969 A
3660050 Iler et al. May 1972 A
3757879 Wilder et al. Sep 1973 A
3859016 McGee et al. Jan 1975 A
3880971 Pantanelli Apr 1975 A
3987859 Lichte Oct 1976 A
4017480 Baum Apr 1977 A
4047828 Makely Sep 1977 A
4094709 Rozmus Jun 1978 A
4128136 Generoux Dec 1978 A
4134759 Yajima et al. Jan 1979 A
4157122 Morris Jun 1979 A
4198233 Frehn Apr 1980 A
4221270 Vezirian Sep 1980 A
4229638 Lichte Oct 1980 A
4233720 Rozmus Nov 1980 A
4252202 Purser, Sr. Feb 1981 A
4255165 Dennis et al. Mar 1981 A
4306139 Shinozaki et al. Dec 1981 A
4341557 Lizenby Jul 1982 A
4389952 Dreier et al. Jun 1983 A
4398952 Drake Aug 1983 A
4453605 Short, Jr. Jun 1984 A
4499048 Hanejko Feb 1985 A
4499795 Radtke Feb 1985 A
4499958 Radtke et al. Feb 1985 A
4503009 Asaka Mar 1985 A
4526748 Rozmus Jul 1985 A
4547337 Rozmus Oct 1985 A
4552232 Frear Nov 1985 A
4554130 Ecer Nov 1985 A
4562990 Rose Jan 1986 A
4596694 Rozmus Jun 1986 A
4597730 Rozmus Jul 1986 A
4620600 Persson Nov 1986 A
4630693 Goodfellow Dec 1986 A
4656002 Lizenby et al. Apr 1987 A
4667756 King et al. May 1987 A
4686080 Hara et al. Aug 1987 A
4694919 Barr Sep 1987 A
4738322 Hall et al. Apr 1988 A
4743515 Fischer et al. May 1988 A
4744943 Timm May 1988 A
4774211 Hamilton et al. Sep 1988 A
4809903 Eylon et al. Mar 1989 A
4838366 Jones Jun 1989 A
4871377 Frushour Oct 1989 A
4881431 Bieneck Nov 1989 A
4884477 Smith et al. Dec 1989 A
4889017 Fuller et al. Dec 1989 A
4919013 Smith et al. Apr 1990 A
4923512 Timm et al. May 1990 A
4956012 Jacobs et al. Sep 1990 A
4968348 Abkowitz et al. Nov 1990 A
4981665 Boecker et al. Jan 1991 A
5000273 Horton et al. Mar 1991 A
5030598 Hsieh Jul 1991 A
5032352 Meeks et al. Jul 1991 A
5049450 Dorfman et al. Sep 1991 A
5090491 Tibbits et al. Feb 1992 A
5101692 Simpson Apr 1992 A
5150636 Hill Sep 1992 A
5161898 Drake Nov 1992 A
5232522 Doktycz et al. Aug 1993 A
5281260 Kumar et al. Jan 1994 A
5286685 Schoennahl et al. Feb 1994 A
5311958 Isbell et al. May 1994 A
5322139 Rose et al. Jun 1994 A
5333699 Thigpen et al. Aug 1994 A
5348806 Kojo et al. Sep 1994 A
5372777 Yang Dec 1994 A
5373907 Weaver Dec 1994 A
5433280 Smith Jul 1995 A
5439068 Huffstutler et al. Aug 1995 A
5443337 Katayama Aug 1995 A
5455000 Seyferth et al. Oct 1995 A
5467669 Stroud Nov 1995 A
5479997 Scott et al. Jan 1996 A
5482670 Hong Jan 1996 A
5484468 Ostlund et al. Jan 1996 A
5506055 Dorfman et al. Apr 1996 A
5541006 Conley Jul 1996 A
5543235 Mirchandani et al. Aug 1996 A
5544550 Smith Aug 1996 A
5560440 Tibbitts Oct 1996 A
5586612 Isbell et al. Dec 1996 A
5593474 Keshavan et al. Jan 1997 A
5611251 Katayama Mar 1997 A
5612264 Nilsson et al. Mar 1997 A
5624002 Huffstutler Apr 1997 A
5641029 Beaton et al. Jun 1997 A
5641251 Leins et al. Jun 1997 A
5641921 Dennis et al. Jun 1997 A
5662183 Fang Sep 1997 A
5666864 Tibbitts Sep 1997 A
5677042 Massa et al. Oct 1997 A
5679445 Massa et al. Oct 1997 A
5696694 Khouja et al. Dec 1997 A
5697046 Conley Dec 1997 A
5697462 Grimes et al. Dec 1997 A
5710969 Newman Jan 1998 A
5725827 Rhodes et al. Mar 1998 A
5732783 Truax et al. Mar 1998 A
5733649 Kelley et al. Mar 1998 A
5733664 Kelley et al. Mar 1998 A
5740872 Smith Apr 1998 A
5753160 Takeuchi et al. May 1998 A
5765095 Flak et al. Jun 1998 A
5776593 Massa et al. Jul 1998 A
5778301 Hong Jul 1998 A
5789686 Massa et al. Aug 1998 A
5792403 Massa et al. Aug 1998 A
5806934 Massa et al. Sep 1998 A
5829539 Newton et al. Nov 1998 A
5830256 Northrop et al. Nov 1998 A
5856626 Fischer et al. Jan 1999 A
5865571 Tankala et al. Feb 1999 A
5878634 Tibbitts Mar 1999 A
5880382 Fang et al. Mar 1999 A
5897830 Abkowitz et al. Apr 1999 A
5904212 Arfele May 1999 A
5947214 Tibbitts Sep 1999 A
5957006 Smith Sep 1999 A
5963775 Fang Oct 1999 A
5967248 Drake et al. Oct 1999 A
5980602 Carden Nov 1999 A
6029544 Katayama Feb 2000 A
6045750 Drake et al. Apr 2000 A
6051171 Takeuchi et al. Apr 2000 A
6063333 Dennis May 2000 A
6068070 Scott May 2000 A
6073518 Chow Jun 2000 A
6086980 Foster et al. Jul 2000 A
6089123 Chow et al. Jul 2000 A
6099664 Davies et al. Aug 2000 A
6135218 Deane et al. Oct 2000 A
6148936 Evans et al. Nov 2000 A
6200514 Meister Mar 2001 B1
6209420 Butcher et al. Apr 2001 B1
6214134 Eylon et al. Apr 2001 B1
6214287 Waldenstrom Apr 2001 B1
6220117 Butcher Apr 2001 B1
6227188 Tankala et al. May 2001 B1
6228139 Oskarsson May 2001 B1
6241036 Lovato et al. Jun 2001 B1
6254658 Taniuchi et al. Jul 2001 B1
6284014 Carden Sep 2001 B1
6287360 Kembaiyan et al. Sep 2001 B1
6290438 Papajewski Sep 2001 B1
6293986 Rodiger et al. Sep 2001 B1
6322746 LaSalle et al. Nov 2001 B1
6338390 Tibbitts Jan 2002 B1
6348110 Evans Feb 2002 B1
6375706 Kembaiyan et al. Apr 2002 B2
6408958 Isbell et al. Jun 2002 B1
6453899 Tselesin Sep 2002 B1
6454025 Runquist et al. Sep 2002 B1
6454028 Evans Sep 2002 B1
6454030 Findley et al. Sep 2002 B1
6458471 Lovato et al. Oct 2002 B2
6474424 Saxman Nov 2002 B1
6474425 Truax et al. Nov 2002 B1
6500226 Dennis Dec 2002 B1
6511265 Mirchandani et al. Jan 2003 B1
6576182 Ravagni et al. Jun 2003 B1
6589640 Griffin et al. Jul 2003 B2
6599467 Yamaguchi et al. Jul 2003 B1
6607693 Saito et al. Aug 2003 B1
6615935 Fang et al. Sep 2003 B2
6651481 Youngquist Nov 2003 B1
6651756 Costo, Jr. et al. Nov 2003 B1
6655481 Findley et al. Dec 2003 B2
6685880 Engstrom et al. Feb 2004 B2
6742608 Murdoch Jun 2004 B2
6742611 Illerhaus et al. Jun 2004 B1
6756009 Sim et al. Jun 2004 B2
6766870 Overstreet Jul 2004 B2
6849231 Kojima et al. Feb 2005 B2
6908688 Majagi et al. Jun 2005 B1
6918942 Hatta et al. Jul 2005 B2
7044243 Kembaiyan et al. May 2006 B2
7048081 Smith et al. May 2006 B2
7395882 Oldham et al. Jul 2008 B2
7513320 Mirchandani et al. Apr 2009 B2
7776256 Smith et al. Aug 2010 B2
7802495 Oxford et al. Sep 2010 B2
7807099 Choe et al. Oct 2010 B2
7954569 Mirchandani et al. Jun 2011 B2
8309018 Smith et al. Nov 2012 B2
20010000591 Tibbitts May 2001 A1
20010008190 Scott et al. Jul 2001 A1
20020004105 Kunze et al. Jan 2002 A1
20030010409 Kunze et al. Jan 2003 A1
20030079916 Oldham et al. May 2003 A1
20040007393 Griffin Jan 2004 A1
20040013558 Kondoh et al. Jan 2004 A1
20040040750 Griffo et al. Mar 2004 A1
20040060742 Kembaiyan et al. Apr 2004 A1
20040065481 Murdoch Apr 2004 A1
20040141865 Keshavan Jul 2004 A1
20040196638 Lee et al. Oct 2004 A1
20040243241 Istephanous et al. Dec 2004 A1
20040245022 Izaguirre et al. Dec 2004 A1
20040245024 Kembaiyan Dec 2004 A1
20050008524 Testani Jan 2005 A1
20050072496 Hwang et al. Apr 2005 A1
20050072601 Griffo et al. Apr 2005 A1
20050084407 Myrick Apr 2005 A1
20050117984 Eason et al. Jun 2005 A1
20050126334 Mirchandani Jun 2005 A1
20050211474 Nguyen et al. Sep 2005 A1
20050211475 Mirchandani et al. Sep 2005 A1
20050220658 Olsson et al. Oct 2005 A1
20050247491 Mirchandani et al. Nov 2005 A1
20050268746 Abkowitz et al. Dec 2005 A1
20060016521 Hanusiak et al. Jan 2006 A1
20060032677 Azar et al. Feb 2006 A1
20060043648 Takeuchi et al. Mar 2006 A1
20060057017 Woodfield et al. Mar 2006 A1
20060131081 Mirchandani et al. Jun 2006 A1
20060185908 Kembaiyan et al. Aug 2006 A1
20060231293 Ladi et al. Oct 2006 A1
20070042217 Fang et al. Feb 2007 A1
20070102198 Oxford et al. May 2007 A1
20070102199 Smith et al. May 2007 A1
20070102200 Choe May 2007 A1
20070202000 Andrees et al. Aug 2007 A1
20070227782 Kirk et al. Oct 2007 A1
20080053709 Lockstedt et al. Mar 2008 A1
20080101977 Eason et al. May 2008 A1
20080202814 Lyons et al. Aug 2008 A1
20090031863 Lyons et al. Feb 2009 A1
20090044663 Stevens et al. Feb 2009 A1
Foreign Referenced Citations (17)
Number Date Country
695583 Aug 1998 AU
2212197 Feb 1998 CA
264674 Apr 1988 EP
453428 Oct 1991 EP
995876 Apr 2000 EP
1244531 Oct 2002 EP
945227 Dec 1963 GB
2017153 Oct 1979 GB
2075554 Nov 1981 GB
2017153 Oct 1982 GB
2203774 Oct 1988 GB
2345930 Jul 2000 GB
2385350 Aug 2003 GB
2393449 Mar 2004 GB
10219385 Aug 1998 JP
03049889 Jun 2003 WO
2004053197 Jun 2004 WO
Non-Patent Literature Citations (17)
Entry
US 4,966,627, 10/1990, Keshavan et al. (withdrawn)
Alman D.E. et al. “The Abrasive Wear of Sintered Titanium Matrix-Ceramic Particle Reinforced Composites” WEAR 225-229 (1999) pp. 629-639.
Choe Heeman et al. “Effect of Tungsten Additions on the Mechanical Properties of Ti-6A1-4V” Material Science and Engineering A 396 (2005) pp. 99-106 Elsevier.
Diamond Innovations “Composite Diamond Coatings Superhard Protection of Wear Parts New Coating and Service Parts from Diamond Innovations” brochure 2004.
Supplemental European Search Report for European Application No. 09763485 completion date Jul. 12, 2013, 6 pages.
Gale W.F. et al. Smithells Metals Reference Book Eighth Edition 2003 p. 2117 Elsevier Butterworth Heinemann.
International Preliminary Report on Patentability for International Application No. PCT/US2009/046812 dated Dec. 13, 2010, 8 pages.
International Search Report for International Application No. PCT/US2009/046812 dated Jan. 26, 2010 5 pages.
Written Opinion for International Application No. PCT/US2009/046812 dated Jan. 26, 2010, 5 pages.
Miserez A. et al. “Particle Reinforced Metals of High Ceramic Content” Material Science and Engineering A 387-389 (2004) pp. 822-831 Elsevier.
Reed James S. “Chapter 13: Particle Packing Characteristics” Principles of Ceramics Processing Second Edition John Wiley & Sons Inc. (1995) pp. 215-227.
Serway Raymond A. Principles of Physics p. 445 (2d Ed. 1998).
U.S. Appl. No. 60/566,063, filed Apr. 28 2004 entitled “Body Materials for Earth Boring Bits” to Mirchandani et al.
Warrier S.G. et al. “Infiltration of Titanium Alloy-Matrix Composites” Journal of Materials Science Letters 12 (1993) pp. 865-868 Chapman & Hall.
“Boron Carbide Nozzles and Inserts” Seven Stars International webpage http://www.concentric.net/˜ctkang/nozzle.shtml printed Sep. 7, 2006.
“Heat Treating of Titanium and Titanium Alloys” Key to Metals website article www.key-to-metals.com, visited Sep. 21, 2006).
European Office Action for European Application No. 09763485, dated May 3, 2016, 5 pages.
Related Publications (1)
Number Date Country
20170321488 A1 Nov 2017 US
Divisions (2)
Number Date Country
Parent 14325056 Jul 2014 US
Child 14874639 US
Parent 12136703 Jun 2008 US
Child 14325056 US
Continuations (1)
Number Date Country
Parent 14874639 Oct 2015 US
Child 15631738 US