Patent Application
20200378228
This invention relates generally to the field of hydrocarbon extraction and most particularly to EOR (Enhanced Oil Recovery) as applied to unconventional resources such as the Canadian oil sands. One type of EOR is a solvent based in situ gravity drainage extraction process. In particular, this invention relates to methods for managing a condensing solvent in situ gravity drainage extraction process. Most particularly this invention relates to methods and apparatuses which may be used to manage or optimize the amount of solvent required in a formed extraction chamber.
Many attempts have been made to extract in situ hydrocarbons from deposits which do not readily flow at reservoir conditions, such as the Canadian oil sands, by using various EOR processes. One such process is SAGD which requires the injection of large volumes of super heated steam to try to mobilize in situ hydrocarbons. Although SAGD has been made to work, it has some undesirable characteristics because it requires water/steam heated to high temperatures (often more than 200 C) which in turn requires burning a lot of fuel to generate the heat to get to the steam temperatures required to make SAGD work. Extraction can be achieved, but at a high greenhouse gas emissions cost. Another process is called VAPEX which involves the injection of a mixed gas comprising a solvent and a carrier gas, such as methane. A problem with VAPEX is that it is too slow to be commercially viable. Another process is called SAVEX which starts as a SAGD process and later transitions to VAPEX in a form of hybrid process. This process requires both a sizeable steam plant and a solvent plant which increases the capital costs of the facility.
In CA 2,351,148, directed to the Nsolv® condensing solvent extraction process, Nenniger taught injecting solvent into the extraction chamber at a temperature and pressure sufficient for the solvent to be a vapour in the chamber and to condense to a liquid on the extraction surface, and to control the extraction temperature and pressure to achieve bubble point conditions to permit continued solvent condensation at the extraction surface. The bubble point conditions are achieved at least in part by limiting the presence of non-condensable gases within the chamber in general and in particular adjacent to the extraction interface where condensation of the solvent onto the bitumen is to occur. Solvent condensation releases the latent heat of condensation. When this occurs in the chamber at the extraction surface, the heat flux from condensing solvent to the bitumen heats the bitumen, causing the bitumen viscosity to decrease. As well, the solvent dissolves into the bitumen for a further viscosity reduction. Under the right conditions a solvent/hydrocarbon blend will have a low enough viscosity to drain by gravity into a lower producer well, simply through the combined solvent/thermal effects on viscosity. From there, the blend can be produced to surface and separated, in a surface facility, into sales oil and recovered solvent. The recovered solvent can then be recirculated back down into the extraction chamber to condense again. CA 2,351,148 teaches the heat flux due to solvent condensation is constant per unit of solvent injected, therefore, as the extracted chamber grows and the extraction surface area increases, higher solvent injection rates will be required.
In CA 2,639,851, Nenniger also comprehended that as the chamber grows in size, the heat losses to the overburden will increase and this has the effect of increasing the solvent to oil ratio. In oil sands deposits the pay zone is typically in a thin layer which covers a large geographic area. As a gravity drainage process creates an in situ extraction chamber the extracted zone may first rise above the horizontal well pair towards the over burden and then further extraction takes place laterally away from the source of the solvent, namely the injection well in the horizontal well pair. This lateral chamber growth exposes more and more of the overburden to the condensing solvent conditions. Basically, any solvent condensing on the overburden is condensing in a non-productive way as it is condensing not at the extraction interface where it can transfer heat to mobilize and extract bitumen, but instead on the unyielding overburden. Solvent condensing due to overburden heat losses must drain down as a liquid through the solvent chamber, thereby contributing to the total amount of liquid solvent in the chamber, but as noted above this liquid solvent is not directly assisting in further bitumen extraction. Essentially any condensation that occurs not on the extraction interface is unproductive, in the sense that it is not helping to mobilize any fresh bitumen for extraction. An increase in solvent to oil ratio means a bigger surface plant is required with larger capital costs to recirculate the larger solvent volumes. As well if more of the extraction chamber is filled with liquid rather than vapour solvent, more total solvent mass is required due to the lower specific volume of the liquid form. The solvent can be recovered and reused, but the solvent also has an inherent cost. If more solvent is caught up as liquid in the chamber and more solvent is required, then the costs of supplying the extra solvent will have to be met by the operator. So, reducing the non-productive portions of solvent to oil ratio and solvent inventory would also help reduce the operating costs and the total amount of solvent required and therefore the total solvent cost during solvent injection and before solvent recovery during chamber blowdown.
One possible solution for this problem was provided in CA 2,281,276 to Suncor directed to a so called “Thermal Solvent” process. In this process a local heat source is provided in the reservoir along the lower production well to create a hot zone which in theory allows the solvent to reflux up to the extraction interface at the edge of the chamber, condense, and then return to the hot zone where it flashes to reflux up again. The heat source described is a closed steam loop which creates a hot zone in the areas of the reservoir around the heat source. The draining liquid solvent simply comes into contact with the hot zone and then flashes off as a vapour. It is believed that this Thermal Solvent process was piloted in the field but without much success. One problem may have been although in concept this process is theoretically frugal in terms of total solvent required, the solvent has no way to get to the production well without crossing the hot zone at the lower production well. This means that non-condensable gases such as formation gas from the reservoir cannot get past the hot zone either. As taught by Nenniger this will trap the non-condensable gases in the chamber leading to less and less direct contact between the solvent vapour and the bitumen leading to ever declining bitumen mobilization, until the material balance means that extraction will effectively stop. This will occur at the point when the solvent simply refluxes between the hot zone and a non-condensable gas cloud that has built up above the hot zone, without coming into contact with the extraction interface.
Another possible problem lies with the reflux step. As the solvent flashes off the draining solvent bitumen blend there will be a rapid decrease in mobility of the bitumen. It is possible that the diluted bitumen will be transported to a specific location within the extraction chamber, then the hot zone will cause a flash off of solvent thereby greatly increasing the viscosity of the bitumen and the counter current vapour flux reducing the effective permeability of oil. This may lead to a build up of a slow draining region just at the periphery of the hot zone, where the solvent flashes. Such an immobile region can interfere with draining fluids preventing them from reaching the production well. So, although the “Thermal Solvent” approach has been suggested it does not appear to be an attractive alternative.
Another method of decreasing the solvent to oil ratio was briefly mentioned in “A Numerical Simulation Study of the N-Solv™ Process” by K. Cao. K. Cao's simulations predicted that injecting superheated propane would result in an improved (reduced) solvent to oil ratio, with a slightly reduced cumulative oil production.
What is desired is a method or process that can address the need to be efficient in terms of the amount of solvent used in situ, one which allows the draining fluids to drain and the non-condensable off gases and impurities to be removed as taught by Nenniger, and does not adversely affect cumulative oil production.
What is desired therefore are methods to reduce the amount of liquid solvent which may be present in the extraction chamber and to reduce the solvent to oil ratio of the process. Preventing solvent from condensing in unproductive areas such as in the internal casing of the well bore, the already extracted zone in the chamber or even parts of the overburden, may also be desirable to reduce operating and capital costs. It may further be desirable to have methods to mitigate the increased solvent demand due to heat loss to unproductive areas and short-circuiting as the chamber grows in size, as with a larger size such effects may become ever more dominant. It may be desirable to allow non-condensable gasses to be removed from the chamber during such a process as well as limiting the demobilization of bitumen in inopportune locations by flashing off the solvent in situ from a mixed draining fluid. The present invention may address some of the issues of the prior processes through careful attention to process parameters and extraction chamber dynamics.
According to the present invention one method by which these problems may be addressed is to, in conjunction with a formed extraction chamber, increase the bottom hole temperature at or above the injector elevation so that it is above the dew point of the injected solvent, such that the solvent will remain as mostly vapour in the hot zone of the chamber and only reach its bubble point at the extraction surface. The higher temperature of the injected solvent provides sensible heat that is used to vapourize condensed or liquid solvent within the chamber, thus reduces the liquid solvent within the chamber that is not being productive. This may reduce the solvent volume used in the Nsolv® condensing solvent process. What is desired is to do so without creating any in situ barriers for draining fluids or for non-condensable gas removal. In this sense, the present invention may provide a heated zone locally around the injector which extends into the extracted portion of the chamber. A heated zone in this sense means that the temperature of the heated zone is above the condensation temperature of the solvent at the extraction interface, to promote vaporization of any liquid solvent passing through the heated zone.
Therefore, according to one aspect the present invention may provide a method of reducing an in situ liquid solvent inventory in a condensing solvent gravity drainage extraction process which includes a pair of generally horizontal wells, including an upper injection well and a lower production well, the method comprising the steps of:
The application of the temperature increase to the extracted volume may be beneficial after the extraction chamber has grown enough that it has reached top of pay when the heat losses to the overburden are much higher than a young chamber. At this time, the draining liquids above the heated zone will be hydrocarbon lean. If the increased injector bottom hole temperature is applied too early or is set too high, when the chamber is too small, the drainage fluids may be affected by the elevated temperature. This may cause the dissolved solvent and non-condensables in the drainage fluids to vapourize from the drainage fluid, rendering the heavy oil in the drainage fluid relatively immobile at certain conditions thereby creating a drainage barrier as was postulated in conjunction with the Thermal Solvent process described above. The present invention comprehends a balance between increasing the heat deposited to the extracted volume and simply increasing the amount of solvent being injected to satisfy the growing demand for solvent in a growing chamber with an expanding extraction surface.
In another aspect, the present invention may limit or not apply an increase in temperature to the extracted volume until there is sufficient extracted volume adjacent to the heated zone to permit mixed fluids (solvent and hydrocarbons being recovered) to drain to the production well without passing through the heated zone and therefore without flashing off the solvent.
In another aspect, the present invention may place additional heaters above the elevation of the injector to create a larger solvent liquid depleted zone, provided that it adheres to the same principles of injector heating and the hot zone does not significantly overlap with the overburden to cause excessive heat loss to the overburden.
The present invention comprehends the bottom hole temperature of the extracted zone may be increased by a variety of methods, separate or in combination, for example, but not limited to:
In some cases, the central process facility may be located a significant distance from the individual well pads, which may lead to appreciable heat losses to superheated solvent or other heated injection fluids before it can reach the injector bottom hole. Therefore, the present invention may also contemplate vapourizing and/or heating the solvent or other heating injection fluids at the well pad, rather than solely at the central process facility to achieve the bottom hole temperature target. Heating at the well pad may provide cost efficiencies for injecting larger volumes of vapour due to superheat. Furthermore, bottom hole electric heaters or hot tubing containing a circulating heat transfer fluid may be employed to similar effect. Hot tube surfaces primarily relying on conductive heat transfer tend to deliver a lower heat intensity per unit length, due to the relatively low heat transfer coefficient to a convective gas, therefore it may be necessary to equip the tubes with heat transfer enhancing fins or to deploy the tubes directly into the sand matrix.
The present invention may also contemplate various methods as known by those skilled in the art to prevent excessive heat loss from the intermediate sections of the injector. These may include but are not limited to;
The present invention may also contemplate using various measurements such as real time monitoring of the temperature contours of the extraction chamber by observation well temperatures, tracking solvent to oil ratio changes, tracking solvent retention changes, well temperature tracking and long term analysis such as seismic analysis. Some or all of these measurements may be used to assist in establishing an appropriate hot zone adjacent to the injection well.
According to another aspect the present invention may also provide a method of reducing a solvent to oil ratio in a condensing solvent extraction process comprising the steps of:
Reference will now be made by way of example only to preferred embodiments of the invention by reference to the following drawing in which:
As shown in
Certain aspects of the present invention may be illustrated by way of example. A demonstration plant for the Nsolv® extraction process has been operating near Fort McMurray, Alberta, for several years and various qualities have been measured over that time. In this demonstration plant it was found that the solvent inventory in the reservoir at any given degree of extraction could be estimated by a volumetric balance, which is the total solvent make-up injected minus facility losses, and could be reported as a ratio to the volume of product oil. Both daily and cumulative inventory ratios could be tracked. This inventory of solvent may represent a combination of solvent in the drainage layer that has not yet been produced to surface, uncondensed solvent vapour, and solvent that has condensed in the swept zone away from the drainage layer so that it is not extracting oil. Such solvent may be thought of as short circuiting in the chamber. In other cases non-conformities may be present which impede drainage and can cause liquid pools of solvent to accumulate thereby contributing to solvent retention.
Another metric that could be tracked at the demonstration plant is the solvent to oil ratio (SvOR), which may be calculated as the volume of injected solvent divided by the volume of produced oil. As with the solvent inventory, daily and cumulative ratios could be tracked.
A large inventory of solvent in the reservoir is undesirable because it increases the make-up solvent requirements (operating costs) and may require a longer solvent recovery period during chamber blowdown. A large inventory of solvent, particularly due to solvent short-circuiting, contributes to increasing the SvOR. This solvent is condensing away from the solvent-oil interface and in some cases may be accumulating in the reservoir instead of being produced to surface. The demonstration plant has found that the change in daily solvent inventory ratio generally follows in trend to the change in daily SvOR.
Overall, using the first temperature conditions as the baseline, the results of the two tests showed that while the produced oil rate was approximately the same and energy applied per volume of oil produced did not increase significantly, the daily solvent inventory decreased by nearly 70%, while the daily SvOR decreased about 10%. Without being restricted to a specific mechanism, the decrease in solvent inventory may be due to the extra sensible heat of the injected solvent, which reduces solvent short-circuiting, and possible vaporization of liquid solvent that previously condensed in the swept region away from the drainage layer, allowing the solvent to now move laterally to the drainage layer where it may condense, drain and be produced to surface. In other words, the extracted zone may include more vapour than without the increased temperature zone and the extraction surface may include more liquid solvent. To ensure the bottom hole pressure does not increase, the operation is thus required to reduce the amount of solvent injected into the reservoir.
In this example, the injector bottom hole temperature increase from 63° C. to 83° C. was achieved by superheating the solvent. This temperature increase was by way of example only and is not intended to be limiting. The bottom hole temperature of the extraction zone may be heated between the dew point of the injected solvent up to for example 250° C., which is a practical operating temperature constraint for some surveillance instrumentation employed in the injector well, although the optimum temperature profile will be determined based on establishing an appropriate reach of the hot zone adjacent to the injection well. While higher temperatures extend the reach of the liquid solvent depleted hot zone, it can lower the solvent concentration in the produced fluid such that there is insufficient solvent to maintain fluid mobility and/or remove the non-condensable solution gas from the reservoir. The removal of non-condensables from the chamber by solvent in the produced fluids has been previously taught by Nenniger to avoid the adverse effects non-condensable gases have on solvent-bitumen interface. The higher the operating temperature the greater the energy required and so the more greenhouse gasses will be produced. Thus, while the higher temperatures noted above are comprehended, lower temperatures are generally preferred. The present invention may deliver reasonable results across a wide range of temperatures depending upon in situ characteristics and the maturity of the extraction chamber. The present invention is also not limited to increasing the injector bottom hole temperature by superheating the injected solvent. The same effect may be achieved using other methods to deliver heat to the extracted portion of the chamber, including downhole electrical resistance heaters as will be understood by those skilled in the art. Downhole heaters may offer the advantage of more uniform heat distribution across the entire length of a horizontal well (and chamber). What matters is that the injector bottom hole temperature is increased such that the SvOR and solvent inventory in the extracted region may decrease, without affecting the oil production rate or significantly increasing the energy consumption.
Vapour short-circuiting from the injector directly to the producer is anticipated and may even be exacerbated by increasing the bottom hole injector temperature, therefore, the present invention may also contemplate various methods to prevent or limit the amount of vapour short-circuiting to the producer, including, but not limited to:
The present invention increases the temperature in the region near the injector well rather than in or near the producer. This permits continued drainage of the drainage layer with concomitant non-condensable gas removal through the production well. This may be illustrated by the following example.
Consider a volume of reservoir in the Athabasca oil sands of Alberta with a porosity of 30% and oil saturation of 80% and native reservoir temperature of 10° C. The sand has the same properties as silica sand, that is a density of 2700 kg/m3 and specific heat of 830 J/kg° C., the oil has a density of 1030 kg/m3 and specific heat of 1023 J/kg° C., and the water has a density of 1000 kg/m3 and specific heat of 4186 J/kg° C. Due to the high volume of sand, the sand fraction accounts for over 75% of the total heat capacity of the reservoir even though the specific heat of oil and water are higher than the sand. This means that over 75% of the heat delivered to the reservoir will be used to raise the temperature of the sand from native reservoir temperature.
Now, consider that the reservoir has an injector well placed some distance below the top of the pay zone, with a producer well placed some distance below the injector, typically between 3 and 5 meters although this can vary. Consider the circumstance of
Note that for all three profiles, the temperature increases radially around the injector but the temperature along the drainage layers 42 (
Without being restricted by the temperature ranges given in the above examples, it can now be understood that increasing the injector bottom hole temperature such that it does not have a significant effect on the drainage layer temperature, can reduce the solvent inventory and the solvent to oil ratio. The injector bottom hole temperature increase may be applied at a mid-point in the well life or it even may be applied at the start of production as long as there is a drainage path that is unaffected. The injector bottom hole temperature increase may be achieved by superheating the injected solvent, co-injecting with steam, and/or by a downhole heater or other means of supplying heat. The optimum injector bottom hole temperature set point(s) for a particular reservoir will depend on the reservoir properties and well design, and will be a trade-off between its impact on equipment size and cost, and the effect on the drainage layer, while maintaining condensing conditions at the solvent-oil interface, namely the bubble point temperature corresponding to the bottom hole pressure and preventing accumulation of non-condensable gas in the chamber by solvent concentration, as taught in prior art. As non-condensable gases accumulate within the chamber and at the interface the bubble point temperature of the solvent gas mixture is depressed, which in turn lowers the extraction temperature and creates resistance for solvent condensation mass transfer. With these considerations, the maximum injector bottom hole temperature can be calculated for the estimated minimum solvent to oil ratio required to extract oil, as taught by Nenniger. The maximum injector bottom hole temperature temperature and its effect on the drainage layer may be determined by computational modeling during the design phase of the wells and/or by estimating the extent of bubble point depression in comparison to sand pack and filed trial reference values and/or may be monitored during operation by observation well readings, the producer temperature readings, and by chamber classification through seismic analysis.
As the wells are depleted of extractable oil, it may be necessary to gradually decrease the elevation of injector bottom hole temperature to transition the chamber from the production phase to wind-down phase and eventually blowdown phase to recover solvent. Reducing the injector bottom hole temperature at the right time may be important to avoid leaving excessive energy stored in the reservoir once it has been depleted of solvent.
The present invention comprehends that while increasing the temperature of the injector bottom hole above solvent saturation may not significantly impact the oil production rate for the same bottom hole pressure, the means of supplying that extra heat may impact the overall solvent usage and thus the SvOR and solvent inventory.
There may also be a difference in the in situ energy intensity between heating methods. In situ energy intensity is the energy delivered to the reservoir to produce a barrel of oil and includes the enthalpy and/or electrical energy of the heating medium.
A combination of heating methods may also be utilized. For example, electric heating may be the predominant source initially, adding solvent superheating later as the chamber grows and the solvent to oil ratio increases. Vice versa, solvent superheating may be utilized initially, supplementing electrical heating later to offset the increase in SvOR as the chamber grows. The method and combination of heating may be a trade-off between equipment size, cost, and energy efficiency, as long as there is sufficient solvent injected in situ to achieve condensing conditions at the solvent-oil interface, including withdrawal of non-condensable gases.
The present invention may also be used in conjunction with other methods that help to retain heat in the extracted chamber, such as establishing a buoyant gas blanket of non-condensable gases to prevent heat loss from the chamber to the overburden, as taught by Nenniger. This may reduce SvOR and/or solvent inventory by reducing the heat loss to the overburden, the amount short circuit solvent condensation required to service said heat loss, and the amount of liquid solvent draining through the extracted zone.
When solvent is injected dry then it may pick up a small amount moisture from the formation water up to the water saturation limit of the solvent gas. This in turn may slowly dessicate the region of the chamber that extends from the injector. Under elevated bottom hole conditions, the solvent gas will have a higher propensity to evaporate water in the hot zone. This water is expected to partially condense towards the edge of the hot zone, somewhat analogous to the steam co-injection system. Under certain conditions this may dessicate a portion of the sand matrix to the extent that, when cooled, this dessicated region may no longer behave as a water-wet sand system, and it may have somewhat reduced permeability to hydrocarbon liquids. This potentially negative effect on recovery performance may be avoided by ensuring the gas is injected under water saturated conditions.
In another embodiment of the present invention, the injector bottom hole temperature may be increased by co-injection of a vapour energy carrier with the solvent. The ideal energy carrier should be less volatile than the solvent so that it may condense and release its latent heat to the reservoir before the solvent. It would be most beneficial if the energy carrier had a higher specific enthalpy (i.e. kJ/kg) than the solvent so that it can deliver more energy to the formation per unit mass than the solvent. Finally, it should also be less expensive than solvent to inject in situ since it may serve to reduce the solvent inventory. Steam is a promising energy carrier because it has a higher specific heat capacity and specific latent heat of condensation than many of the solvents envisioned for a condensing solvent EOR, such as propane, butane and the like. Steam co-injection may also prevent the aforementioned potentially negative effect of dessication of sand regions extending from the injection well.
Some of the condensed water from the injected steam may preferentially occupy pore space that has been vacated by extracted bitumen and connate water. This pore space would otherwise be occupied by condensed solvent. This may reduce the overall solvent inventory in the chambers as well as the SvOR. The amount of energy carrier to inject with the solvent will be limited by a minimum SvOR that is required to achieve condensing conditions at the solvent-bitumen interface, providing sufficient withdrawal of non-condensable solution gas to surface, and there will also be a trade-off between cost of the energy carrier and energy efficiency of the system for each particular reservoir.
A benefit of using steam as the energy carrier is the main source water for steam generation may be the produced connate water from the reservoir. Many reservoirs have mobile water that may be produced to surface with the solvent and oil. This water may be separated from the hydrocarbons by a number of means as will be understood by those skilled in the art and must be treated and disposed of. For 20% steam co-injection into a reservoir containing about 15% mobile water (typical for Athabasca oil sands), the mass and energy balance shows that 80% of the injected steam may be recycled, with the balance as fresh steam make-up taken from a minor fraction of the connate water, which would allow for bleed of connate water impurities such as salt and other minerals and without the need for fresh water consumption by using evaporative technologies for brackish water, such as mechanical vapour recompression evaporation, steam compression distillation, or multiple effect evaporation, or membrane technologies, such as reverse osmosis, where the permeate may be directed to a boiler. As will be understood by those skilled in the art, the selection of technology is dependent on connate water quality, expected production water cut, co-injection steam requirement, injected steam recycle ratio, availability and cost of energy sources, as well as capital and operating cost tradeoffs for project optimization.
Comparing lines 302, 304 and 306 in
The in situ energy intensity 340 is shown with line 342 for prior art, line 344 for superheated solvent and line 346 for co-injection with steam. Lines 342 and 344 are very similar while more energy is required for co-injection of solvent with steam line 346. This is due to the higher heat capacity of the water compared to solvent. As the chambers grow, the inventory of water in situ increases, largely off-setting the solvent inventory. Because water has a higher heat capacity than solvent, more energy is required to maintain the water vapour chamber temperature than a solvent chamber. However, if there is a readily available source of steam to the well pad, this may still prove to be an economical way to reduce the SvOR and solvent inventory.
It will now be understood by those skilled in the art that various modifications and alterations can be made to the present invention without departing from the scope of the invention as defined in the appended claims. Some of these have been discussed above. For example, there are a number of ways that the extra heat to create a local hot zone in the extraction chamber to reduce a liquid solvent volume within the chamber can be supplied and the present invention comprehends all such heating methods. Further, while reference has been made to a pair of horizontal wells, the wells could be of any suitable configuration, including one or more horizontal wells, one or more vertical wells or any combination of vertical and horizontal wells.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2973710 | Jul 2017 | CA | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/CA2018/000142 | 7/17/2018 | WO | 00 |
