The present disclosure generally relates to the field of clear icemakers. In particular, the present disclosure is directed to methods of producing clear ice shapes using suction, and apparatuses for performing same.
Shaped clear water ice, i.e., water ice that is optically clear and without cloudiness caused by air bubbles trapped within the ice, is popular for many uses, including for chilling drinks containing top-shelf liquor, such as bourbon, scotch, rye, vodka, and tequila, among others. Using clear ice provides the drinks with a pleasing visual aesthetic that enhances the overall experience of the drinkers of such liquors.
A number of devices have been developed in recent years for making clear water ice, particularly clear water ice in relatively large shapes, such as 2.5-inch (64 mm) diameter spheres, 2-inch (50.8 mm)×2-inch (50.8 mm) 2-inch (50.8 mm) cubes, and 1.25-inch (31.75 mm)×1.25-inch (31.75 mm)×5-inch (127 mm) rectangular spears, among others. These larger sizes are particularly desirable to minimize the surface area of ice that the drink is exposed to in order to minimize melting and the resulting dilution of the drink being chilled. One such device is the Ice Chest clear icemaker available from Wintersmiths, LLC, Waterbury, Vt.
The Ice Chest clear icemaker is specially designed to force water with a mold to freeze directionally toward an outlet that is in fluid communication with a thermally insulated space outside the mold. As the water progressively freezes toward the outlet, the impurities, including air bubbles that would cause the ice within the mold to be cloudy, are forced into the thermally insulated space outside the mold, leaving the ice within the mold impurity free and therefore clear. See, for example, U.S. Pat. No. 10,443,915 issued to the present inventors on Oct. 15, 2019, and titled “DEVICES FOR MAKING SHAPED CLEAR ICE”, for a more detailed description of how the Ice Chest clear icemaker and similar clear icemakers work. Such directional-freezing-type clear icemakers require a significant amount of thermal insulation to control freezing, and this thermal insulation can increase the time needed to form the finished ice shape.
In one implementation, the present disclosure is directed to an icemaker for making a body of ice having a shape and a size. The icemaker includes a mold having a closed mold cavity designed and configured to provide the shape and size of the body of ice when the mold is filled with a freezable liquid and the freezable liquid is frozen to form the body of ice; a suction device in fluid communication with the closed mold cavity and designed and configured to, during operation of the icemaker, draw a first portion of the freezable liquid out of the closed mold cavity during freezing of the freezable liquid; and a replenishment system in fluid communication with the closed mold cavity and designed and configured to, during operation of the icemaker, replenish the first portion of the freezable liquid into the closed mold cavity as the suction device draws the first portion from the closed mold cavity.
In another implementation, the present disclosure is directed to a method of making a body of ice having a size and a shape. The method includes filling a closed mold cavity with a freezable liquid, wherein the closed mold cavity has the size and shape of the body of ice; causing the freezable liquid in the closed mold cavity to freeze in an inwardly direction relative to the closed mold cavity; and while causing the freezable liquid to freeze within the closed mold cavity, simultaneously drawing a first portion of the freezable liquid out of the closed mold cavity and replenishing the first portion of the freezable liquid.
For the purpose of illustration, the drawings show aspects of example embodiments. However, it should be understood that the present disclosure is not limited to the precise arrangements and instrumentalities shown in the drawings, wherein:
In some aspects, the present disclosure is directed to methods of making, from freezable liquids such as water, bodies of ice that are “clear”, i.e., that do not contain air bubbles entrapped in the ice that would make the ice cloudy. When the freezable liquid is optically clear and colorless, such as with clean water, the resulting clear ice made in accordance with the present disclosure is also optically clear and colorless. However, in some embodiments neither the freezable liquid, nor the resulting ice, need to be optically clear or colorless. For example, the freezable liquid may be optically transparent but colored so as to provide an optically transparent colored ice. Examples of optically transparent and colored freezable liquids include, but are not limited to, artificially colored water and filtered fruit juices, such as white grape juice, purple grape juice, and cranberry juice, among others. Fundamentally, there is no limitation on the freezable liquid other than it freeze at the requisite temperature. It is also typically desirable, though not necessary, that viewers can visually discern the absence of trapped air bubbles in the ice after freezing.
In some embodiments, the term “clear ice” shall mean that the ice shapes made in accordance with the present disclosure are substantially to completely free of trapped air bubbles frozen into the ice that, if present, would make the ice shapes cloudy in the manner of ice shapes made using conventional uninsulated open-top ice trays and automatic icemakers that use uninsulated open-top molds located in freezer cavities of domestic refrigerator-freezers, as is well known in the art. The term “clear ice” does not exclusively mean optically clear, though in many cases the clear ice shapes made in accordance with the present disclosure will be optically clear. Relative to the term “clear ice”, the modifier “substantially” shall mean to a degree that any cloudiness from trapped air bubbles that may be present in an ice shape is not visible with the naked eye from a distance of 12 inches (30.5 cm) after the ice shape has been removed from initially clean room-temperature water after having been immersed in such water for 5 seconds. In the context of clean water ice placed in clean water, “substantially clear” ice may mean that one can see only the outline of the ice shape. In contrast, an ice shape that is not substantially clear will have more of its form visible. Also in the context of ice made from clean water, “substantially clear ice” may include extremely little (e.g., only a spot at the location of an inlet-outlet structure that is the last to freeze) to no cloudiness. In contrast, an ice shape that is not substantially clear will typically have more extensive cloudiness, typically at least at the center of the ice shape.
In some aspects of the present disclosure, clear ice is formed from a freezable liquid by providing, during freezing of the freezable liquid, a suction to one or more ice molds that is constantly pulling a portion of the freezable liquid, and air bubbles and/or other impurities (e.g., any one or more of a variety of minerals present in some water sources) contained therein, out of each mold cavity, as another portion of the freezable liquid remaining in the mold cavity(ies) freezes. In some embodiments, freezable liquid drawn out of each mold by the suction may be circulated back into the ice mold cavity, while in some embodiments the freezable liquid drawn out of the mold may be directed away from the mold and replaced by additional freezable liquid.
Generally, the direction of freezing of the freezable liquid is controlled so that the freezable liquid remaining in the mold cavity freezes in a direction toward the location(s) from which the portion of freezable liquid is drawn from the cavity. As a freezable liquid, containing air bubbles and/or other impurities, freezes and advances a solid-liquid interface between the frozen freezable liquid and the liquid freezable liquid, the advancing solid-liquid interface pushes the impurities in the liquid. As long as a portion of the freezable liquid remains liquid and that portion does not become oversaturated with the impurities, the advancing solid ice remains substantially impurity free. In the context of a sealed ice mold, the impurity-laden liquid portion of the freezable liquid will eventually freeze, thereby entrapping the impurities in the ice and making the completely frozen ice shape cloudy.
As disclosed herein, the direction of freezing is controlled to be in the direction of the suction location(s). By drawing at least a portion of the liquid freezable liquid in front of the advancing solid-liquid interface out of the mold cavity during freezing, the increasing amount of impurities pushed by the advancing ice in the remaining liquid are drawn out of the mold cavity, with the drawn-off liquid being replenished in order to keep the mold cavity completely full. As the advancing solid-liquid interface continues to advance, the portion of the freezable liquid in the mold cavity becomes smaller and smaller, and at some point, all of the freezable liquid within the mold cavity freezes. Since the vast majority of the impurities pushed along by the advancing solid-liquid interface are removed by the suction/replenishment scheme, there are few if any impurities in the small volume of liquid in the mold cavity that eventually freezes. The result is an ice substantially or completely free of impurities and associated cloudiness.
In some embodiments, the freezable liquid in each ice mold cavity may be forced to increasingly freeze from the bottom and all sides inwardly and upwardly, and the very top where the suction is applied is the last portion to freeze. In some embodiments, the suction need not be applied at the top of the mold cavity and, correspondingly, the direction of the freezing need not be toward the top of the mold cavity. In some embodiments, thermal insulation, i.e., one or more materials provided intentionally to thermally insulate one or more portions of the ice mold(s) so as to control the freezing of the freezable liquid within the ice mold cavity, is not needed to control freezing. However, care may need to be taken when locating an ice mold close to a thermally insulated wall of a freezer unit in certain embodiments. Additionally, when a freezable-liquid reservoir (see below) containing freezable liquid for replenishing the portion of freezable liquid drawn from a mold cavity by the suction is provided above the ice mold, circulating freezable liquid constantly in the freezable liquid reservoir above the mold cavity (or cavities), and/or using a heating element in the reservoir, may be used to prevent the freezable liquid in that reservoir from freezing solid; a heating element may also be used to thaw the reservoir if it freezes. In some embodiments, it may be necessary to thermally insulate the outlet and/or outlet structures proximate the top of each mold and/or any conduit(s) (tube(s)) connected thereto.
In some aspects, the present disclosure is directed to icemakers that can create solid clear ice shapes in accordance with one or more aspects of the methodologies described above. The ice-shape embodiments of the present disclosure are able to be created as crystal clear, solid, and dense and can be any geometric or other shape. In some embodiments, an icemaker may be configured to use interchangeable ice molds of differing shapes and sizes. In some embodiments, an icemaker may be configured for making one or more ice shapes in a manual manner or an automated manner. For example, a manual icemaker of the present disclosure may require manual filling, manual placement into and removal from a freezer compartment of a domestic or commercial freezer, and manual removal of the ice shape(s) from the mold cavity(ies). In some embodiments, a manual icemaker may be battery powered, for example, by one or more batteries. An automatic icemaker of the present disclosure may include one or more automated features, such as automated filling of the mold cavity(ies) with a freezable liquid, automated control of the suction device(s) used to draw necessary suction and/or replenishment system for replenishing freezable liquid drawn out of the mold cavity(ies), and automated removal of the finished ice shape(s) from the mold cavity(ies). These foregoing and other aspects are described below in detail.
The icemaker 100 also includes a suction device 108 that is in fluid communication with the mold cavity 104A so as to draw a portion of the freezable liquid out of the mold cavity during the process of forming an ice shape (not shown) within the cavity. Although a single suction device 108 is illustrated, more than one suction device may be used. Accompanying the suction device 108 is a suitable replenishment system 112 that replenishes the portion of the freezable liquid drawn out of the mold cavity 104A. Each of the suction device 108 and replenishment system 112 are in fluid communication with the mold cavity 104A in any manner suitable to effect the goal of eliminating the formation of cloudy regions within the final clear ice shape caused by trapped air bubbles and any other impurities.
In some embodiments, the mold cavity 104A has an upper end and a lower end, and each of the suction device 108 and the replenishment system 112 is in fluid communication with the mold cavity at or proximate to its upper end. However, in some embodiments, one or both of the suction device 108 and the replenishment system 112 may be in fluid communication with the mold cavity 104A in another location, such as at the bottom of the mold cavity or on one or more lateral sides of the mold cavity. As long as the location(s) at which each of the suction device 108 and the replenishment system 112 allow them to provide the necessary functionalities, their location(s) may vary. Examples of manners in which each of the suction device 108 and the replenishment system 112 may be in fluid communication with the mold cavity 104A are described below in connection with
The suction device 108 may be any suction device capable of performing the function of drawing a portion of the freezable liquid out of the mold cavity 104A during the freezing process. Examples of suction devices suitable for use as suction device 108 includes centrifugal pumps, axial flow pumps, and positive-displacement pumps, among others. Fundamentally, there is no limitation on the type(s) of suction device 108 provided as long as it/they provide the requisite amount of suction.
The replenishment system 112 may be any replenishment system capable of performing the function of replacing the portion of the freezable liquid that the suction device 108 draws out of the mold cavity 104A. In some embodiments, the replenishment system 112 is configured to recirculate, back to the mold cavity 104A, the freezable liquid that the suction device 108 draws out of the mold cavity. Such recirculation can take any of a variety of forms, including the suction device 108 discharging the drawn-out freezable liquid into an optional freezable-liquid reservoir 112A and allowing the freezable liquid to flow from the freezable-liquid reservoir into the mold cavity. In some instantiations and when provided, the freezable-liquid reservoir 112A may be located at an elevation relative to the mold cavity 104A above the mold cavity. In this case, the freezable liquid may flow from the freezable-liquid reservoir 112A largely under the force of gravity. In some instantiations, such as when the highest point of the freezable liquid in the freezable-liquid reservoir is located lower than the elevation of the top of the mold cavity 104A, the replenishment system 112 may include a pump (not shown) for assisting with moving freezable liquid from the freezable-liquid reservoir 112A to the mold cavity. In some embodiments, the freezable-liquid reservoir 112A may include a heater 112A(1) to inhibit the freezable liquid from freezing. In some embodiments in which the ice mold is located in a freezer cavity (not shown), the freezable-liquid reservoir 112A may be located either inside or outside of the freezer cavity. As another example, recirculation may take the form of a closed conduit (not shown) that directs effluent of the suction device 108 back to the mold cavity 104A. In some embodiments, the portion of the freezable liquid that the suction device 108 draws out of the mold cavity 104A is not recirculated. For example, the suction device 108 may discharge the freezable liquid it draws out of the mold cavity 104A to a drain line or other location. If the freezable liquid is not recirculated, the freezable liquid within the mold cavity 104A may be replenished from an external source. In the example of the freezable liquid being water, the icemaker 100 may include a makeup water line (not shown) connected to a suitable source of makeup (i.e., replenishment) water.
Referring now to
In the embodiment of
With continued reference to
In the embodiment of
As those skilled in the art will readily appreciate, a feature of the design of the suction device 108 and/or the replenishment system 112 (
A number of variables, including the size and shape of the desired clear ice shape, the type of freezable liquid, the temperature to which the freezable liquid inside the mold cavity is exposed, and the extent to which the mold cavity is exposed to freezing temperature, may need to be considered when determining how to strike the necessary balance of allowing thickening of the ice shell (e.g., ice shell 200A, 200A′, 200A″ (
The outlet-inlet structure 404′ of
Referring again to
In some embodiments, the icemaker 100 may be configured to be integrated into a freezer compartment 122A, such as a freezer compartment of a freezer 122 of either a domestic type or a commercial type. In such embodiments, the suction device 108 may be hardwired to power circuitry within the freezer or refrigerator-freezer unit, and the icemaker 100 may optionally include one or more systems for automating the operation of the icemaker. For example, in such integrated embodiments, the icemaker may include an autofill system 124 designed and configured to automatically fill the mold cavity 104A and/or the freezable-liquid reservoir 112A (if provided) with a freezable liquid after the complete formation and removal of a clear ice shape from the mold cavity. If the freezable liquid is water, in some embodiments the autofill system 124 may be fluidly connected to a pressurized source of water and include an electronically controlled valve (not shown) and one or more sensors and/or timers for controlling the operation of the electronically controlled valve. The autofill system 124 may include its own controller (not shown) for controlling the autofill system, and/or the icemaker 100 may have a master controller 128 for controlling the autofill system and other automated aspects of the icemaker.
In some embodiments, the icemaker 100 may include an auto-release system 132 that automatically unloads a finished clear ice shape from the mold cavity 104A. If provided, the auto-release system 132 may include a heater 132A that heats the ice mold 104 adjacent to the mold cavity 104A to free the clear ice shape from the ice mold. The auto-release system 132 may also or alternatively include an opening-closing system 132B that opens the ice mold 104 for the unloading process and closes the ice mold for making another clear ice shape. The auto-release system 132 may include its own controller (not shown) for controlling the auto-release system, and/or, as noted above, the icemaker 100 may have the master controller 128 for controlling the auto-release system and other automated aspects of the icemaker.
In some embodiments, the ice mold 104 may be interchangeable with another ice mold (not shown), such as an ice mold having a mold cavity having a shape different from the shape of the mold cavity of the ice mold 104. In some embodiments, the icemaker 100 may include an ice bin 144 for holding finished clear ice shapes unloaded from the ice mold. Depending on the design, the ice bin 144 may be integral with, removably engaged with, or separate from other components of the icemaker 100. It is noted that while many of the components of the example icemaker 100 are described and shown in the singular, in other embodiments more than one of each type of component may be provided. For example, instead of a single mold cavity 104A, multiple mold cavities may be provided. Similarly, multiple ice molds and/or multiple suction devices may be provided. In addition, multiple suction outlets and/or multiple replenishment inlets may be provided for each mold cavity. Those skilled in the art will readily understand the many variations of the icemaker 100 that are possible and that are within the capability of someone of ordinary skill in the art to make.
In some embodiments, the icemaker 100 may optionally include its own freezing system 136, which may include any suitable device(s) 136A needed to apply freezing temperatures to the freezable liquid within the mold cavity 104A, such as a compressor, a condenser, a thermal expansion valve, an evaporator, and/or one or more thermoelectric coolers, among others. In some embodiments, the ice mold 104 may include internal cooling passageways (not shown) that eliminate the need to place the ice mold in a freezer compartment. In some embodiments that include the freezing system 136, the icemaker 100 may be embodied as a standalone unit. The freezing system 136 may include a dedicated controller (not shown), and/or the freezing system may be under at least partial control of the master controller 128, if provided.
If included, the master controller 128 may be in operative communication with one or more sensors 140 and/or include one or more timers (not shown) for controlling one or more operations of the icemaker 100. The one or more sensors 140 may include one or more temperature sensors for sensing one or more temperatures within the icemaker 100, such as the temperature of the freezable liquid at one or more locations, one or more liquid-level sensors, for example, to sense the level of the freezable liquid in the freezable-liquid reservoir 112A (if present), one or more fullness sensors to sense the fullness of the ice bin 144 (if present), and/or one or more other types of sensors. Those skilled in the art will understand how to deploy and use any sensors implemented for a particular design.
The master controller 128 may also or alternatively be in operative communication with one or more components of each of any other systems provided, such as the autofill system 124 and/or the auto-release system 132, so as to control such component(s). For example, the master controller 128 may be in operative communication with a valve, pump, or other device of the autofill system 124 and/or in operative communication with one or more actuators of the opening-closing system 132B, among others. In some embodiments, the master controller 128 may be implemented digitally via one or more microprocessors and associated physical memory(ies), which may be implemented using any suitable architecture, such as a system on chip or a motherboard architecture. The master controller 128 may be controlled by suitable software (i.e., machine-executable instructions) stored in the physical memory(ies). In some embodiments, the master controller 128 may include one or more user interfaces 128A that allow a user to control the operation of the icemaker 100, in some embodiments including selecting one or more operating parameters of the icemaker, such as operating conditions and/or production output, among others. Such user interface(s) 128A may be accessible to a user in any suitable manner, such as one or more input/output devices, including hard buttons, touch-screen devices, laptop computers, tablet computers, smartphones, etc.
If automatic release and storage of ice shapes is desired, one or more of a number of features may be provided. For example, before extraction, action may be taken to prevent liquid water from escaping through the ice mold 104 when it is opened, for example, by either sealing off the water reservoir 112A (if present) from the ice mold with a valve (not shown) or similar device, by allowing freezable liquid in the inlet flow passageway 316 (
Referring to
Referring to
1) A freezing device (e.g., a domestic or commercial freezer) is turned on and set to, for example, −10 degrees Fahrenheit.
2) Once −10 degrees is reached, the ice mold cavity/cavities 104A are filled with water from above water reservoir 112A.
3) The suction pump (suction device 108) is turned on and continuously pulls water from the top of each cavity 104A via the suction tube(s) (see, e.g., the suction conduit 324 of
4) Water freezes for some amount of time (in one example ˜6 hours, but this will vary with application, including but not limited to icemaker configuration, size and shape of ice being created, and freezing environment). The conclusion of the freezing process may be determined by a countdown timer (see, e.g., the Timer of
5) After a set time, a mechanical system (not shown) is activated to seal off the reservoir from the mold cavities, then open the ice mold cavity(ies) 104A in two halves and release the finished ice shapes into the ice bin 144, funnel device, or other device, such as a tapered mesh tube, to carefully lower the finished ice shapes into the ice bin.
5A) Another way that the reservoir 112A can be sealed off from the mold cavity(ies) 104A without a mechanical system is to ensure the inlet tube is filled with solid ice above the mold cavity prior to releasing the finished ice shapes into the ice bin 144. The ice in the inlet tube serves as a “natural plug” to prevent water from leaking out of the reservoir 112A. As noted below, for the next cycle, any ice plug so formed can be melted to allow liquid water to flow again.
6) Mechanical system (see, e.g., the Mechanical Motor of
7) Then a heater 112A(1) is turned on in the water reservoir 112A to ensure that any ice build-up in the reservoir (and in the inlet tube as described in 5A, above) is melted prior to the next batch.
8) After a predetermined amount of time when it is known that the water reservoir 112A has returned to liquid, non-frozen form, the heating element 112A(1) is turned off. This can be determined by time, a temperature sensor, or another type of sensor 140.
9) The process starts over again at step 2, above, unless a sensor (see, e.g., the Finished ice hold tank capacity sensor of
Components and features of icemaker 800 include:
Although not illustrated, in one functioning embodiment, the pump compartment 820 holds a small 6V water pump that is wired to the illuminated on/off button switch 812 and a rechargeable 18650 3.7V lithium ion battery residing in the battery compartment 828. In an example instantiation, the pump used is model ZL25-02 made by by Dongguan Zhonglong Pump Technology Co. Ltd., Dongguan City, Guangdong Province, China. The head unit 804 is closed/assembled by affixing the lid 804A and securing the closures 828B and 824B, respectively, to the side battery compartment 828 and the fill hole 824. The head unit 804 is then attached to the 2-piece mold unit 808. In this embodiment, when the pump is installed, a pump inlet (not shown) of the pump, in conjunction with the outlet-inlet structure opening 832A, form the outlet-inlet structure (not shown) in a manner similar to outlet-inlet structure 312 of
To use the icemaker 800, a user opens the fill hole closure 824A and fills the spherical mold (2.5 inches in diameter in the example instantiation) of the mold unit 808 and the reservoir 816 in the head unit 804 with freezable liquid (e.g., water) (not shown). Then, the user presses the on/off button switch 812 to turn on the pump (not shown), which, in this example, operates at approximately 0.8-1.0 liters per minute (L/M) at 3.7V/1.6 A using the pump noted above. The pump continuously pumps the freezable liquid out of the spherical mold via the central freezable-liquid outlet 832A and into the reservoir 816, and then the water naturally flows back into the spherical mold from the reservoir via the annular freezable-liquid inlet. Once full of water and turned on, the entire icemaker 800 is placed into a freezer or any environment (not shown) at a suitable temperature, such as a temperature at or below +10 degrees Fahrenheit. After the freezable liquid in the sphere mold has frozen solid (e.g., 5-12 hours depending on freezing conditions/temperature), the 2-piece mold unit 808 can be twisted off of the head unit 804 and the upper and lower components 808A and 808B of the mold unit 808 can be separated to reveal a substantially clear ice sphere.
Experimentally, the above pump has been tested in the icemaker 800 at a voltage from 2V to 6V and flow rates from 0.7 L/M-1.6 L/M with successful results. The specific power input and flow rate can be adjusted to achieve specific ice sizes/shapes and freeze duration and could be outside of these ranges for larger ice shapes or a higher quantity of ice. Other pumps with higher voltage and/or flow rates can also be substituted but the layout/design would need to be adjusted accordingly to ensure the consistent freezing of substantially clear ice shapes in the least amount of time.
The foregoing has been a detailed description of illustrative embodiments of the disclosure. It is noted that in the present specification and claims appended hereto, conjunctive language such as is used in the phrases “at least one of X, Y and Z” and “one or more of X, Y, and Z,” unless specifically stated or indicated otherwise, shall be taken to mean that each item in the conjunctive list can be present in any number exclusive of every other item in the list or in any number in combination with any or all other item(s) in the conjunctive list, each of which may also be present in any number. Applying this general rule, the conjunctive phrases in the foregoing examples in which the conjunctive list consists of X, Y, and Z shall each encompass: one or more of X; one or more of Y; one or more of Z; one or more of X and one or more of Y; one or more of Y and one or more of Z; one or more of X and one or more of Z; and one or more of X, one or more of Y and one or more of Z.
Various modifications and additions can be made without departing from the spirit and scope of this disclosure. Features of each of the various embodiments described above may be combined with features of other described embodiments as appropriate in order to provide a multiplicity of feature combinations in associated new embodiments. Furthermore, while the foregoing describes a number of separate embodiments, what has been described herein is merely illustrative of the application of the principles of the present disclosure. Additionally, although particular methods herein may be illustrated and/or described as being performed in a specific order, the ordering is highly variable within ordinary skill to achieve aspects of the present disclosure. Accordingly, this description is meant to be taken only by way of example, and not to otherwise limit the scope of this disclosure.
Exemplary embodiments have been disclosed above and illustrated in the accompanying drawings. It will be understood by those skilled in the art that various changes, omissions and additions may be made to that which is specifically disclosed herein without departing from the spirit and scope of the present disclosure.
This application claims the benefit of priority of U.S. Provisional Patent Application Ser. No. 62/850,144, filed on May 20, 2019, and titled “METHODS OF PRODUCING CLEAR ICE SHAPES USING SUCTION, AND APPARATUSES FOR PERFORMING SAME”, which is incorporated by reference herein in its entirety.
Number | Date | Country | |
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62850144 | May 2019 | US |