Wear-resistant, polycrystalline diamond compacts (“PDCs”) are utilized in a variety of mechanical applications. For example, PDCs are used in drilling tools (e.g., cutting elements, gage trimmers, etc.), machining equipment, bearing apparatuses, wire-drawing machinery, and in other mechanical apparatuses.
PDCs have found particular utility as superabrasive cutting elements in rotary drill bits, such as roller-cone drill bits and fixed-cutter drill bits. A PDC cutting element typically includes a superabrasive diamond layer commonly known as a diamond table. The diamond table is formed and bonded to a substrate using a high-pressure/high-temperature (“HPHT”) process. The PDC cutting element may be brazed directly into a preformed pocket, socket, or other receptacle formed in a bit body. The substrate may often be brazed or otherwise joined to an attachment member, such as a cylindrical backing. A rotary drill bit typically includes a number of PDC cutting elements affixed to the bit body. It is also known that a stud carrying the PDC may be used as a PDC cutting element when mounted to a bit body of a rotary drill bit by press-fitting, brazing, or otherwise securing the stud into a receptacle formed in the bit body.
Conventional PDCs are normally fabricated by placing a cemented carbide substrate into a container or cartridge with a volume of diamond particles positioned on a surface of the cemented carbide substrate. A number of such cartridges may be loaded into an HPHT press. The substrate(s) and volume(s) of diamond particles are then processed under HPHT conditions in the presence of a catalyst material that causes the diamond particles to bond to one another to form a matrix of bonded diamond grains defining a polycrystalline diamond (“PCD”) table. The catalyst material is often a metal-solvent catalyst (e.g., cobalt, nickel, iron, or alloys thereof) that is used for promoting intergrowth of the diamond particles.
In one conventional approach, a constituent of the cemented carbide substrate, such as cobalt from a cobalt-cemented tungsten carbide substrate, liquefies and sweeps from a region adjacent to the volume of diamond particles into interstitial regions between the diamond particles during the HPHT process. The cobalt acts as a catalyst to promote intergrowth between the diamond particles, which results in formation of a matrix of bonded diamond grains having diamond-to-diamond bonding therebetween, with interstitial regions between the bonded diamond grains being occupied by the solvent catalyst.
Despite the availability of a number of different PDCs, manufacturers and users of PDCs continue to seek PDCs that exhibit improved toughness, wear resistance, thermal stability, and/or increased operational lifetime.
Embodiments of the invention relate to superabrasive compacts including multiple superabrasive cutting portions and methods of fabricating such superabrasive compacts. In an embodiment, a superabrasive compact comprises a cemented carbide substrate including a first interfacial surface and a second interfacial surface spaced from the first interfacial surface. A first superabrasive cutting portion may be bonded to the first interfacial surface of the cemented carbide substrate. The first superabrasive cutting portion includes a first working surface. A second superabrasive cutting portion may be bonded to the second interfacial surface of the cemented carbide substrate and spaced from the first superabrasive cutting portion. The second superabrasive cutting portion includes a second working surface that generally opposes the first working surface of the first superabrasive cutting portion.
Embodiments also include applications utilizing the disclosed superabrasive compacts in various articles and apparatuses, such as rotary drill bits, machining equipment, and other articles and apparatuses.
Features from any of the disclosed embodiments may be used in combination with one another, without limitation. In addition, other features and advantages of the present disclosure will become apparent to those of ordinary skill in the art through consideration of the following detailed description and the accompanying drawings.
The drawings illustrate several embodiments of the invention, wherein identical reference numerals refer to identical elements or features in different views or embodiments shown in the drawings.
Embodiments of the invention relate to superabrasive compacts including multiple superabrasive cutting portions and methods of fabricating such superabrasive compacts. The operational lifetime of such superabrasive compacts may be enhanced because when one superabrasive cutting portion is worn, the other non-worn superabrasive cutting portion may be employed. The disclosed superabrasive compacts may be used in a variety of applications, such as rotary drill bits, machining equipment, and other articles and apparatuses.
The superabrasive compact 100 includes a first superabrasive cutting portion 108 that is bonded to and may extend laterally over substantially all of the first interfacial surface 104, and a second superabrasive cutting portion 110 that is bonded to and may extend laterally over substantially all of the second interfacial surface 106. In the illustrated embodiment, each of the first and second interfacial surfaces 104 and 106 exhibits a substantially planar topography. However, in other embodiments, each of the first and second interfacial surfaces 104 and 106 may exhibit a nonplanar topography, and an interfacial surface of the first superabrasive cutting portion 108 and an interfacial surface of the second superabrasive cutting portion 110 may each exhibit a correspondingly configured nonplanar topography. Furthermore, although the superabrasive compact 100 is illustrated as being cylindrical, the superabrasive compacts disclosed herein may depart from being cylindrical and may exhibit any suitable geometry.
The first superabrasive cutting portion 108 includes at least one lateral surface 112 and a working, front surface 114. The second superabrasive cutting portion 110 includes at least one lateral surface 116 and a working, front surface 118 that faces generally away (e.g., generally opposing) from the front surface 114 of the superabrasive cutting portion 108. Although the front surfaces 112 and 114 are illustrated as being generally planar, the front surfaces 112 and 114 may be concave, convex, or another suitable geometry. Although not illustrated, each of the first and second superabrasive cutting portions 108 and 110 may include an edge chamfer or any desired edge geometry (e.g., a radius, multiple chamfers, etc.), if desired. It is noted that at least a portion of the at least one lateral surfaces 112 and 116 may also function as a working surface that contacts a subterranean formation during drilling operations. In fact, any surface of the first and second superabrasive portions 108 and 110 that, in operation, contacts an object to be worked may be considered a working surface.
It is noted that the superabrasive compact 100 may be free of superabrasive structures (e.g., a PCD structure) disposed on or in the at least one peripheral surface 107 of the cemented carbide substrate 102 that extends between the first and second interfacial surfaces 104 and 106. However, in some embodiments, a superabrasive structure (e.g., a PCD structure) may be disposed on or in the at least one peripheral surface 107 to further enhance the operational lifetime of the PDC 100.
The superabrasive cutting portions 108 and 110 may be made from a number of different superabrasive materials, such as PCD, polycrystalline cubic boron nitride, silicon carbide, diamond grains bonded together with silicon carbide, or combinations of the foregoing. In an embodiment, the first and second superabrasive cutting portions 108 and 110 each is a PCD table that includes a plurality of directly bonded-together diamond grains exhibiting diamond-to-diamond bonding therebetween (e.g., sp3 bonding), which define a plurality of interstitial regions. A portion of or substantially all of the interstitial regions of the first and second superabrasive cutting portions 108 and 110 may include a metal-solvent catalyst disposed therein that is infiltrated from the cemented carbide substrate 102 or another source. For example, the metal-solvent catalyst may be selected from iron, nickel, cobalt, and alloys of the foregoing metals.
In an embodiment, the first and second superabrasive cutting portions 108 and 110 may each be integrally formed with the cemented carbide substrate 102. For example, the first and second superabrasive cutting portions 108 and 110 may each be a PCD table that is integrally formed with the cemented carbide substrate 102. In such an embodiment, the infiltrated metal-solvent catalyst is used to catalyze formation of the first and second superabrasive cutting portions 108 and 110 from diamond powder during HPHT processing. In another embodiment, the first and second superabrasive cutting portions 108 and 110 may each be a pre-sintered superabrasive cutting portion that has been HPHT bonded to the cemented carbide substrate 102 in a second HPHT process after being initially formed in a first HPHT process. For example, the first and second superabrasive cutting portions 108 and 110 may each be a pre-sintered PCD cutting portion that has been HPHT bonded to the cemented carbide substrate 102. In yet another embodiment, one of the first and second superabrasive cutting portions 108 and 110 may be integrally formed with the cemented carbide substrate 102, while the other one of the first and second superabrasive cutting portions 108 and 110 may be a pre-sintered superabrasive cutting portion.
Referring specifically to
Referring to
A first superabrasive cutting portion 210 is bonded to and may extend laterally over substantially all of the first interfacial surface 204, and a second superabrasive cutting portion 212 is bonded to and may extend laterally over substantially all of the second interfacial surface 206. A superabrasive core 214 extends through the through hole 208 and interconnects the first and second PCD cutting portions 210 and 212 thermally and physically. The superabrasive core 214 may promote efficient heat transfer from the first superabrasive cutting portion 210 to the second superabrasive cutting portion 212 and vice versa to help prevent thermal degradation of, for example, diamond grains in the first and second superabrasive cutting portions 210 and 212 at high temperatures typically experienced when the superabrasive compact 200 is used as a cutting element for drilling a subterranean formation.
The first and second superabrasive cutting portions 210 and 212 may be spaced from each other to define a dimension 216 of the superabrasive compact 200, such as a maximum longitudinal dimension. The cemented carbide substrate 202 may also be dimensioned so that the first and second superabrasive cutting portions 210 and 212 are spaced from each other a dimension 218. For example, the dimension 218 may be at least about 5 mm, such as about 7 mm to about 15 mm or about 10 mm to about 14 mm.
In an embodiment, the first superabrasive cutting portion 210, the second superabrasive cutting portion 212, and the superabrasive core 214 may be PCD integrally formed with each other and include a metal-solvent catalyst disposed interstitially between directly bonded-together diamond grains thereof. For example, the metal-solvent catalyst may be infiltrated from the cemented carbide substrate 202 during HPHT processing to catalyze formation of the PCD that forms the first superabrasive cutting portion 210, the second superabrasive cutting portion 212, and the superabrasive core 214. In another embodiment, one or both of the first and second superabrasive cutting portions 210 and 212 may be a pre-sintered PCD cutting portion and the superabrasive core 214 may be separately formed PCD core that is bonded to the pre-sintered PCD cutting portions during HPHT bonding of the pre-sintered PCD cutting portions to the cemented carbide substrate 202.
The plurality of superabrasive particles of each of the first and second superabrasive masses 302 and 304 may exhibit one or more selected sizes. The one or more selected sizes may be determined, for example, by passing the superabrasive particles through one or more sizing sieves or by any other method. In an embodiment, the plurality of superabrasive particles of each of the first and second superabrasive masses 302 and 304 may include a relatively larger size and at least one relatively smaller size. As used herein, the phrases “relatively larger” and “relatively smaller” refer to particle sizes determined by any suitable method, which differ by at least a factor of two (e.g., 40 μm and 20 μm). More particularly, in various embodiments, the plurality of superabrasive particles of each of the first and second superabrasive masses 302 and 304 may include a portion exhibiting a relatively larger size (e.g., 100 μm, 90 μm, 80 μm, 70 μm, 60 μm, 50 μm, 40 μm, 30 μm, 20 μm, 15 μm, 12 μm, 10 μm, 8 μm) and another portion exhibiting at least one relatively smaller size (e.g., 30 μm, 20 μm, 10 μm, 15 μm, 12 μm, 10 μm, 8 μm, 4 μm, 2 μm, 1 μm, 0.5 μm, less than 0.5 μm, 0.1 μm, less than 0.1 μm). In an embodiment, the plurality of superabrasive particles of each of the first and second superabrasive masses 302 and 304 may include a portion exhibiting a relatively larger size between about 40 μm and about 15 μm and another portion exhibiting a relatively smaller size between about 12 μm and 2 μm. Of course, the plurality of superabrasive particles of each of the first and second superabrasive masses 302 and 304 may also include three or more different sizes (e.g., one relatively larger size and two or more relatively smaller sizes) without limitation.
The assembly 300 may be placed in a pressure transmitting medium, such as a refractory metal can embedded in pyrophyllite or other pressure transmitting medium. The pressure transmitting medium, including the cemented carbide substrate 102 and the first and second superabrasive masses 302 and 304 therein, may be subjected to a HPHT process using an ultra-high pressure press to create temperature and pressure conditions at which, for example, diamond is stable. The temperature of the HPHT process may be at least about 1000° C. (e.g., about 1200° C. to about 1600° C.) and the pressure of the HPHT process may be at least 4.0 GPa (e.g., about 5.0 GPa to about 8.0 GPa) for a time sufficient to, for example, sinter the superabrasive particles of the first and second superabrasive masses 302 and 304 to form the corresponding first and second superabrasive cutting portions 108 and 110 (
During the HPHT process, a metal-solvent catalyst from the cemented carbide substrate 102 or another source may liquefy and infiltrate into the superabrasive particles of the first and second superabrasive masses 302 and 304. When the superabrasive particles are diamond particles, the infiltrated metal-solvent catalyst may function as a catalyst that catalyzes formation of directly bonded-together diamond grains from the diamond particles to form the first and second superabrasive cutting portions 108 and 110 (
Referring to
The assembly 400 may be placed in a pressure transmitting medium, such as a refractory metal can embedded in pyrophyllite or other pressure transmitting medium. The pressure transmitting medium, including the assembly 400, may be subjected to a HPHT process using an ultra-high pressure press to create temperature and pressure conditions at which diamond is stable. The temperature of the HPHT process may be at least about 1000° C. (e.g., about 1200° C. to about 1600° C.) and the pressure of the HPHT process may be at least 4.0 GPa (e.g., about 5.0 GPa to about 8.0 GPa) so that the metal-solvent catalyst in the cemented carbide substrate 102 may be liquefied and infiltrate into the first and second at least partially leached PCD cutting portions 402 and 404. For example, the pressure of the HPHT process may be about 5 GPa to about 7 GPa and the temperature of the HPHT process may be about 1150° C. to about 1450° C. (e.g., about 1200° C. to about 1400° C.). Upon cooling from the HPHT process, in an embodiment, the infiltrated PCD cutting portions represented in an embodiment as the superabrasive cutting portions 108 and 110 in
In one embodiment, the HPHT process conditions may be accurately controlled so that the metal-solvent catalyst from the cemented carbide substrate 102 only partially infiltrates each of the first and second at least partially leached PCD cutting portions 402 and 408. For example, the interstitial regions of a region 414 of the first at least partially leached PCD cutting portion 402 and the interstitial regions of a region 416 of the second at least partially leached PCD cutting portion 408 may remain un-infiltrated by the metal-solvent catalyst, while the interstitial regions of a region 418 of the first at least partially leached PCD cutting portion 402 and the interstitial region of a region 420 of the second at least partially leached PCD cutting portion 408 may be filled with the metal-solvent catalyst. The region that the metal-solvent catalyst infiltrates into the first and second at least partially leached PCD cutting portions 402 and 408 may be controlled by selecting the pressure, temperature, and/or process time employed in the HPHT process. In one embodiment, the assembly 400 may be subjected to a temperature of about 1150° C. to about 1300° C. (e.g., about 1270° C. to about 1300° C.) and a corresponding pressure that is within the diamond stable region, such as about 5.0 GPa. Such temperature and pressure conditions are lower than temperature and pressure conditions typically used to fully infiltrate the first and second at least partially leached PCD cutting portions 402 and 408.
In other embodiments, the metal-solvent catalyst from the cemented carbide substrate 102 substantially infiltrates each of the first and second at least partially leached PCD cutting portions 402 and 408 so that the interstitial regions of the regions 414 and 416 are filled by the infiltrated metal-solvent catalyst. In such an embodiment, if desired, the infiltrated metal-solvent catalyst may be removed in a second leaching process from the regions 414 and 416 of the infiltrated first and second at least partially leached PCD cutting portions 402 and 408.
In another embodiment, the interstitial regions of the regions 414 and 416 may be infiltrated prior to, during, or after bonding the first and second at least partially leached PCD cutting portions 402 and 408 to the cemented carbide substrate 102. For example, respective layers of infiltrant (not shown) may be positioned adjacent to the front surfaces 404 and 410 of the first and second at least partially leached PCD cutting portions 402 and 408. Suitable infiltrants include a nonmetallic catalyst, silicon, a silicon-cobalt alloy, or another suitable infiltrant. For example, the nonmetallic catalyst may be selected from a carbonate (e.g., one or more carbonates of Li, Na, K, Be, Mg, Ca, Sr, and Ba), a sulfate (e.g., one or more sulfates of Be, Mg, Ca, Sr, and Ba), a hydroxide (e.g., one or more hydroxides of Be, Mg, Ca, Sr, and Ba), elemental phosphorous and/or a derivative thereof, a chloride (e.g., one or more chlorides of Li, Na, and K), elemental sulfur and/or a derivative thereof, a polycyclic aromatic hydrocarbon (e.g., naphthalene, anthracene, pentacene, perylene, coronene, or combinations of the foregoing) and/or a derivative thereof, a chlorinated hydrocarbon and/or a derivative thereof, a semiconductor material (e.g., germanium or a geranium alloy), and combinations of the foregoing. For example, one suitable carbonate catalyst is an alkali metal carbonate material including a mixture of sodium carbonate, lithium carbonate, and potassium carbonate that form a low-melting ternary eutectic system. This mixture and other suitable alkali metal carbonate materials are disclosed in U.S. patent application Ser. No. 12/185,457, which is incorporated herein, in its entirety, by this reference. The alkali metal carbonate material disposed in the interstitial regions of the regions 414 and 416 of the infiltrated first and second at least partially leached PCD cutting portions 402 and 408 may be partially or substantially completely converted to one or more corresponding alkali metal oxides by suitable heat treatment following infiltration.
As previously discussed, the infiltrant may be silicon or a silicon-cobalt alloy (e.g., cobalt silicide). In an embodiment, respective layers of infiltrant (not shown) each including silicon particles present in an amount of about 50 to about 60 wt % and cobalt particles present in an amount of about 40 to about 50 wt % may be positioned adjacent to the front surfaces 404 and 410 of the first and second at least partially leached PCD cutting portions 402 and 408. In a more specific embodiment, each infiltrant layer may include silicon particles and cobalt particles present in an amount of about equal to or near a eutectic composition of the silicon-cobalt chemical system. In some embodiments, the silicon particles and cobalt particles may be held together by an organic binder to form a green layer of cobalt and silicon particles. In another embodiment, each layer may comprise a thin sheet of a silicon-cobalt alloy or a green layer of silicon-cobalt alloy particles formed by mechanical alloying having a low-melting eutectic or near eutectic composition. The respective layers of infiltrant, the cemented carbide substrate 102, and the first and second at least partially leached PCD cutting portions 402 and 408 may be subjected to an HPHT process to infiltrate the regions 414 and 416 of the first and second at least partially leached PCD cutting portions 402 and 408 with material therefrom. After the HPHT process, the interstitial regions of the regions 414 and 416 may include silicon carbide, cobalt carbide, a mixed carbide of cobalt and silicon, or combinations of the foregoing disposed therein that are reaction products formed by the infiltrant reacting with the diamond grains. Also, substantially pure silicon, substantially pure cobalt, or a silicon-cobalt alloy (e.g., a cobalt silicide) may also be present in the interstitial regions of the regions 414 and 416 of the first and second at least partially leached PCD cutting portions 402 and 408.
Although not shown in
The first and second at least partially leached PCD cutting portions 402 and 408 may be fabricated by subjecting a plurality of diamond particles to an HPHT sintering process in the presence of a metal-solvent catalyst (e.g., cobalt, nickel, iron, or alloys thereof) to facilitate intergrowth between the diamond particles and form a PCD body comprised of bonded diamond grains that exhibit diamond-to-diamond bonding therebetween. For example, the metal-solvent catalyst may be mixed with the diamond particles having any of the diamond particle sizes or distributions disclosed herein, infiltrated from a metal-solvent catalyst foil or powder adjacent to the diamond particles, infiltrated from a metal-solvent catalyst present in a cemented carbide substrate, or combinations of the foregoing. The bonded diamond grains, so-formed by HPHT sintering the diamond particles, define interstitial regions with the metal-solvent catalyst disposed within the interstitial regions.
The as-sintered PCD body may be leached by immersion in an acid, such as aqua regia, nitric acid, hydrofluoric acid, or subjected to another suitable process to remove at least a portion of the metal-solvent catalyst from the interstitial regions of the PCD body and form the first or second at least partially leached PCD cutting portion 402 or 408. For example, the as-sintered PCD body may be immersed in the acid for about 2 to about 7 days (e.g., about 3, 5, or 7 days) or for a few weeks (e.g., about 4 weeks) depending on the process employed. It is noted that when the metal-solvent catalyst is infiltrated into the diamond particles from a cemented tungsten carbide substrate including tungsten carbide particles cemented with a metal-solvent catalyst (e.g., cobalt, nickel, iron, or alloys thereof), the infiltrated metal-solvent catalyst may carry tungsten and/or tungsten carbide therewith and the as-sintered PCD body may include such tungsten and/or tungsten carbide therein disposed interstitially between the bonded diamond grains. The tungsten and/or tungsten carbide may not be substantially removed by the leaching process and may enhance the wear resistance of the first and second at least partially leached PCD cutting portions 402 and 408 so-formed.
The first and second at least partially leached PCD cutting portions 402 and 408 may be subjected to a shaping process prior to or subsequent to bonding to the cemented carbide substrate 102, such as grinding or lapping, to tailor the geometry thereof, as desired, for a particular application. For example, each of the first and second at least partially leached PCD cutting portions 402 and 408 may be chamfered prior to or subsequent to being bonded to the cemented carbide substrate 102. The as-sintered PCD body may also be shaped prior to or subsequent to leaching or bonding to the cemented carbide substrate 102 by a machining process, such as electro-discharge machining or grinding.
The first and second cemented carbide substrates 504a and 504b may be joined together via a diffusion-bonding process, an HPHT bonding process, or another suitable joining process. For example, the first and second superabrasive compacts 502a and 502b may be stacked with the first and second cemented carbide substrates 504a and 504b abutting each other and subjected to a diffusion-bonding process under non-diamond-stable pressure/temperature conditions or an HPHT process under diamond-stable pressure/temperature conditions. Referring to
A first superabrasive cutting portion 608 may be disposed in the first recess 604. A front surface 610 of the first superabrasive cutting portion 608 may be substantially coplanar with a laterally adjacent surface 611 of the cemented carbide substrate 602. A second superabrasive cutting portion 612 may be disposed in the second recess 606. A front surface 614 of the second superabrasive cutting portion 612 may be substantially coplanar with a laterally adjacent surface 615 of the cemented carbide substrate 602. The exposed front surfaces 611 and 615 of the cemented carbide substrate 602 provide brazeable surfaces for brazing the superabrasive compact 600 into a recess of a drill-bit body. The first and second superabrasive cutting portions 608 and 612 may be spaced to define a dimension 616 of the superabrasive compact 600. The first and second superabrasive cutting portions 608 and 612 may each be a pre-sintered PCD cutting portion, PCD cutting portion integrally formed with the cemented carbide substrate 602 from un-bonded diamond particles (e.g., diamond powder), or another disclosed superabrasive cutting portion.
In another embodiment, the first and second recesses 604 and 606 may be generally centered about the axis A. Referring to
In an embodiment, the brazeable layers 700 and 702 may each be made from a binderless tungsten carbide material that is deposited by chemical vapor deposition (“CVD”) or physical vapor deposition (“PVD”). The binderless tungsten carbide material includes a plurality of bonded tungsten carbide grains and is substantially free of a cementing constituent (i.e., a binder), such as cobalt or other diamond-catalyzing material, that cements the tungsten carbide grains together. In an embodiment, the binderless tungsten carbide may be formed by CVD or variants thereof (e.g., plasma-enhanced CVD, etc.), without limitation. Specifically, one example of a commercially available CVD tungsten carbide layer (currently marketed under the trademark HARDIDE®) is currently available from Hardide Layers Inc. of Houston, Tex. In other embodiments, the binderless tungsten carbide may be formed by PVD, variants of PVD, high-velocity oxygen fuel (“HVOF”) thermal spray processes, or any other suitable process, without limitation.
In another embodiment, the brazeable layers 700 and 702 may be made from a metallic material (e.g., a metal or an alloy) that is deposited by, for example, sputtering or another suitable PVD, CVD, electroless, or electroplating process. For example, the metallic material may be a material, such as iron, nickel, copper, tungsten, alloys of the foregoing metals, or another suitable metal or alloy. In an embodiment, the metallic material may not be catalytic relative to diamond so that the thermal stability of the superabrasive cutting portions 108 and 110 is not substantially compromised.
The disclosed PDC embodiments that include dual superabrasive cutting portions may help prevent damage to a recess formed in a bit body in which a superabrasive compact is brazed. For example, referring to
The superabrasive compacts disclosed herein (e.g., superabrasive compact 100 of
Thus, the embodiments of superabrasive compacts disclosed herein may be used in any apparatus or structure in which at least one conventional superabrasive compact is typically used. In one embodiment, a rotor and a stator, assembled to form a thrust-bearing apparatus, may each include one or more superabrasive compacts (e.g., superabrasive compact 100 of
While various aspects and embodiments have been disclosed herein, other aspects and embodiments are contemplated. The various aspects and embodiments disclosed herein are for purposes of illustration and are not intended to be limiting. Additionally, the words “including,” “having,” and variants thereof (e.g., “includes” and “has”) as used herein, including the claims, shall have the same meaning as the word “comprising” and variants thereof (e.g., “comprise” and “comprises”).
This application is a continuation of U.S. application Ser. No. 12/425,053 filed on 16 Apr. 2009, the disclosure of which is incorporated herein, in its entirety, by this reference.
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Number | Date | Country | |
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Parent | 12425053 | Apr 2009 | US |
Child | 13413100 | US |