Claims
- 1. A method for catalyzing an anionic displacement reaction by means of a silacrown ether of the structure: ##STR7## in which n is an integer from 4 to 10 inclusive and R.sup.1 and R.sup.2 are selected from the group consisting of organic radicals and hydrogen, wherein the silacrown ether solvates metal ions by forming stable molecular complexes with the cation of a salt selected from the group consisting of alkaline salts and alkaline earth salts thereby leaving the anions unencumbered to act as potent bases and nucleophiles, and wherein the displacing anion is selected from the group consisting of halogens, nitrite, pseudohalogens and organic anions.
- 2. A method according to claim 1 wherein said displacing anion is selected from the group consisting of cyanide, acetate, fluoride and iodide.
- 3. A method according to claim 1 wherein the silacrown ether catalyzes the reaction of said salt with an organic salt in which the organic moiety is selected from group consisting of octyl, hexyl, benzyl and allyl.
- 4. A method according the claim 1 wherein said reaction is a solid/liquid phase transfer reaction.
- 5. A method according to claim 1 wherein said silacrown ethers are immobilized.
- 6. A method according to claim 1 wherein said reactions are liquid/liquid phase transfer reactions.
- 7. A method according to claim 1 wherein vinylmethyl-14-crown-5 catalyzes the reaction of benzyl bromide and sodium cyanide.
- 8. A method according to claim 1 wherein sila-17-crown-6 catalyzes the reaction of potassium cyanide and RBr where R is selected from the group consisting of octyl, hexyl, benzyl and allyl.
- 9. A method according to claim 1 wherein sila-17-crown-6 catalyzes the reaction of potassium cyanide and benzyl chloride.
- 10. A method according to claim 1 wherein sila-17-crown-6 catalyzes the reaction of potassium cyanide and hexylbromide.
- 11. A method according to claim 1 wherein a sila-crown ether catalyzes the reaction of benzyl bromide and KX, where X is selected from the group consisting of cyanide, acetate and fluoride.
- 12. A method according to claim 11 wherein the silacrown ether catalyst is sila-17-crown-6.
- 13. A method according to claim 11 wherein sila-17-crown-6 catalyzes the reaction of benzyl bromide and potassium cyanide.
- 14. A method according to claim 11 wherein vinylmethylsila-14-crown-5 catalyzes the reaction of benzyl bromide and potassium cyanide.
- 15. A method according to claim 11 wherein vinylmethylsila-17-crown-6 catalyzes the reaction of benzyl bromide and potassium cyanide.
- 16. A method according to claim 8 wherein said sila-17-crown-6 is immobilized.
- 17. A method according to claim 8 wherein said reaction is a liquid/liquid phase transfer reaction.
- 18. A method according to claim 9 wherein said sila-17-crown-6 is immobilized.
- 19. A method according to claim 9 wherein said reaction is a liquid/liquid phase transfer reaction.
Parent Case Info
This application is a division of my co-pending application Ser. No. 323,629 filed Nov. 23, 1981, now U.S. Pat. No. 4,362,884.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
4056509 |
Werbrugge et al. |
Nov 1977 |
|
Non-Patent Literature Citations (3)
Entry |
Walter E. Keller, "Compendium of Phase-Transfer Reactions and Related Synthetic Methods, Listed According to Type of Compound Formed", 1979, Fluka AG, Switzerland, pp. I-XXV. |
C. J. Pederson, J. Am. Chem. Soc., 89, 7017 (1967). |
R. Kieble, C. Burkhard, J. Am. Chem. Soc. 69, 2689 (1947). |
Divisions (1)
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Number |
Date |
Country |
Parent |
323629 |
Nov 1981 |
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