Claims
- 1. An adduct of a polyfunctional acrylate and an amine terminated polyolefin having the formula: wherein:R is hydrogen or methyl; R1 is a polyolefin; R2 and R3 are independently H or substituted or unsubstituted C1-C25 alkyl; R4 is an organic group derived from a polyfinctional acrylate and optionally includes side groups formed by the reaction of vinyl groups and amine terminated polyolefins; and m is from 1 to 30.
- 2. The adduct according to claim 1, wherein R4 is —C(O)—Q, wherein Q is an organic group comprising at least one moiety selected from the group consisting of polyethers, urethanes, epoxies, polyesters, and isocyanates.
- 3. The adduct according to claim 1, wherein the polyfunctional acrylate is a polyoxyalkylene acrylate.
- 4. The adduct according to claim 1, wherein R1 is derived from an amine terminated polyolefin in which at least about 70% of the unsaturated carbon-carbon double bonds are hydrogenated.
- 5. The adduct according to claim 1, wherein R1 is a hydrogenated polybutadiene or a hydrogenated polyisoprene.
- 6. The adduct according to claim 1, wherein R2 and R3 are both hydrogen.
- 7. The adduct according to claim 1, wherein the adduct is the reaction product of a polyfunctional acrylate and an amine terminated polymer having the formula III: wherein R1 is a polyolefin, and R2, R3, R5, and R6, are each independently H or substituted or unsubstituted C1-C25 alkyl.
- 8. The adduct according to claim 7, wherein R2 and R5 are not both hydrogen and R3 and R6 are not both hydrogen.
- 9. The adduct according to claim 7, wherein R5 and R6 are H.
- 10. The adduct according to claim 1, wherein the adduct is the reaction product of an amine terminated polymer and a polyfunctional acrylate selected from the group consisting of 1,6-hexanediol diacrylate, 1,4-butanediol diacrylate, ethylene glycol diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, tetraethylene glycol diacrylate, tripropylene glycol diacrylate, neopentyl glycol diacrylate, polyethylene glycol diacrylate, 1,3-butylene glycol diacrylate, trilsopropylene glycol diacrylate, trimethylolpropane triacrylate, pentaerythritrol monohydroxy triacrylate, trimethylolpropane triethoxy triacrylate, pentaerythritol tetraacrylate, di-trimethylol propane tetraacrylate, dipentaerythritol (monohydroxy) pentaacrylate, ethoxylated neopentyl glycol diacrylate, propoxylated neopentyl glycol diacrylate, ethoxylated bisphenol A diacrylate, bisphenol A epoxy diacrylate, hexafiunctional aromatic urethane acrylate, aliphatic urethane diacrylate, tetrafuinctional polyester acrylate, tris (2-hydroxy-ethyl)isocyanurate triacrylate, and polyether diacrylates.
- 11. The adduct according to claim 10, wherein the polyfunctional acrylate is a polyoxyalkylenediacrylate.
- 12. A quaternized adduct of a polyfunctional acrylate and an amine terminated polyolefin wherein said adduct before quaternization has the formula wherein:R is hydrogen or methyl; R1 is a polyolefin; R2 and R3 are independently H or substituted or unsubstituted C1-C25 alkyl; R4 is an organic group derived from a polyfunctional acrylate and optionally includes side groups formed by the reaction of vinyl groups and amine terminated polyolefins; and m is from 1 to 30.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is related to copending provisional Application Serial No. 60/218,911 filed Jul. 18, 2000, the entire disclosure of which is hereby incorporated by reference, and claims the benefit of its earlier filing date under 35 USC 119(e).
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|
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