This disclosure claims priority to Chinese Patent Application No. 201910149242.X filed with the China Patent Office on Feb. 28, 2019, the disclosure of which is incorporated herein by reference in its entirety.
This application relates to a technology in the microelectronics field, for example, to a micro-nano wire manufacturing device and a micro-nano structure.
Micro-nano patterns or micro-nano wires manufactured on a specific substrate by using liquid-phase nanomaterials have great research prospects in integrated circuits, optical microelectronic devices, biosensors, and biodetectors. The performance of devices in these fields depends largely on one-dimensional micro-nano patterns or micro-nano wires. For example, micro-nano patterns or micro-nano wires made of organic materials can improve the balance of electron and hole transfer, thereby improving the performance of the integrated circuits and the optical microelectronic devices.
In recent decades, there are many methods for manufacturing one-dimensional micro-nano patterns or micro-nano wires, such as photolithography, micro-contact printing, inkjet printing, etc., However, these methods are costly and have a complex process. Moreover, micro-nano patterns that can be manufactured by using these methods are limited. Usually only some designed patterns can be transferred to the substrate. In addition, it is difficult to manufacture nanoscale patterns by using these methods. In the related art, the drip method is generally used to manufacture nanoscale patterns. However, the drip method has a low success rate and a small area in manufacturing micro-nano wires, and the shapes, directions, and positions of the micro-nano wires are random and uncontrollable in the drip method.
This application proposes a micro-nano wire manufacturing device and a micro-nano structure in view of the preceding deficiencies in the related art.
This application is achieved through the technical solution below.
This application relates to a micro-nano wire manufacturing device. The device includes a liquid-phase nanomaterial storage device and a micro-nano wire applying mechanism. The liquid-phase nanomaterial storage device is provided with a liquid outlet, and the micro-nano wire applying mechanism is provided in one-to-one correspondence with the liquid outlet. The micro-nano wire applying mechanism includes at least two flexible wires. The roots of the flexible wires are secured to the liquid-phase nanomaterial storage device. One ends of the two flexible wires hang down to a substrate and abut against each other. The range of the angle between the projections of the two flexible wires on the substrate is 1° to 5°.
This application relates to a micro-nano structure. The micro-nano structure includes a one-dimensional pattern composed of micro-nano wires. The micro-nano structure is disposed on a substrate and manufactured by the preceding micro-nano wire manufacturing device.
Hereinafter this application will be described in detail in conjunction with drawings and embodiments.
As shown in
It is to be noted that as shown in
It is to be understood that as shown in
In some embodiments, the micro-nano wire applying mechanism optionally includes multiple groups of flexible wires (such as animal hairs 600), and each group includes two flexible wires.
In the same group of flexible wires, one ends of two flexible wires hang down to the substrate and abut against each other.
In some embodiments, the liquid-phase nanomaterial storage device 500 is connected to a motion actuator through a bracket, and the motion actuator is configured to drive the liquid-phase nanomaterial storage device 500 to move. In some embodiments, the surface of each flexible wire has regularly distributed microstructures.
In some embodiments, the liquid-phase nanomaterial storage device 500 is securely connected to the Z-axis linear displacement mechanism 300 through the bracket 400 and can move stably on the Z-axis linear displacement mechanism 300, the Z-axis linear displacement mechanism 300 is connected to the Y-axis linear displacement mechanism 200 and can move stably on the Y-axis linear displacement mechanism 200, the Y-axis linear displacement mechanism 200 is connected to the X-axis linear displacement mechanism 100 and can move stably on the X-axis linear displacement mechanism 100, and the X-axis linear displacement mechanism 100 is secured to a stable platform.
As shown in
It is to be understood that the X axis, the Y axis, and the Z axis are three coordinate axes perpendicular to each other.
In some embodiments, the X-axis linear displacement mechanisms 100, the Y-axis linear displacement mechanism 200, and the Z-axis linear displacement mechanism 300 are all programmable linear displacement mechanisms, such as linear motor modules, which can accurately control the movement direction and movement speed of the animal hairs 600 and the pressure of the animal hairs 600 relative to the substrate.
In some embodiments, the distance between the roots of the two animal hairs 600 is 1-3 mm.
The angle and distance between the animal hairs 600 and the substrate 800 can be adjusted through rotation of the liquid-phase nanomaterial storage device 500 relative to the bracket 400. In some embodiments, the angle between the tangent of the roots of the animal hairs 600 and the substrate 800 is 20°-70°, and the vertical distance from the roots to the substrate is less than 7 cm.
The operating principle of the embodiment of this application is as described below.
The liquid-phase nanomaterial flows into the gap between the two animal hairs 600 through the liquid outlet 501 under the action of gravity.
When the animal hair 600 contacts the substrate 800, the liquid-phase nanomaterial in the gap is continuously and controllably transferred to the substrate 800 under the action of gravity, the Laplace pressure difference and the asymmetric retention force, so that a micro-nano wire 700 with a uniform width is formed. The micro-nano wire 700 has the same functional properties as the liquid-phase nanomaterial.
The shape of the micro-nano wire 700 varies with the motion track of the animal hairs 600. The width and thickness of the micro-nano wire 700 can be both under nanoscale control. The thickness of the micro-nano wire 700 depends on the movement speed, the length of the hairs and the surface tension of the liquid. In some embodiments, the micro-nano wire 700 has a width of 50-1000 nm and a thickness of 40-150 nm.
In some embodiments, each flexible wire may be made of animal hair.
In some embodiments, the liquid-phase nanomaterial storage device stores a liquid-phase nanomaterial which includes at least one of a quantum dot material, a fluorescent material, or a conductive and high-molecular-weight polymer material.
In some embodiments, the substrate is any one of a silicon-based material or a flexible material. Optionally, the flexible material may be a planar structure or a curved structure.
In some embodiments, the liquid-phase nanomaterial storage device is connected to the motion actuator through a bracket. Optionally, the liquid-phase nanomaterial storage device is rotatable up and down on the bracket, and the natural hanging angle of each flexible wire can be adjusted by the rotation. Optionally, a hinge structure with a controllable rotation angle is adopted.
In some embodiments, the motion actuator includes a pair of X-axis linear displacement mechanisms, a Y-axis linear displacement mechanism erected on the pair of X-axis linear displacement mechanisms, and a Z-axis linear displacement mechanism erected on the Y-axis linear displacement mechanism. The Z-axis linear displacement mechanism is used to control the pressure of each flexible wire relative to the substrate, thereby controllingso that the width of the micro-nano wire is controlled.
In some embodiments, the motion actuator may be a robot, such as a parallel robot or a serial robot.
Compared with the related art, this application has the advantages below.
Number | Date | Country | Kind |
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201910149242.X | Feb 2019 | CN | national |
Filing Document | Filing Date | Country | Kind |
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PCT/CN2020/074811 | 2/12/2020 | WO |
Publishing Document | Publishing Date | Country | Kind |
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WO2020/173301 | 9/3/2020 | WO | A |
Number | Name | Date | Kind |
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20050066890 | Wetzel | Mar 2005 | A1 |
Number | Date | Country |
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102344115 | Feb 2012 | CN |
103612391 | Mar 2014 | CN |
103660540 | Mar 2014 | CN |
105185910 | Dec 2015 | CN |
107399713 | Nov 2017 | CN |
108264017 | Jul 2018 | CN |
109807907 | May 2019 | CN |
209850936 | Dec 2019 | CN |
2012222019 | Nov 2012 | JP |
20130036550 | Apr 2013 | KR |
Entry |
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Liu et al “Bio-Inspired Direct Patterning Functional Nanothin Microlines: Controllable Liquid Transfer” (ACS Nano 2015, vol. 9(4), pp. 4362-4370). |
Jiang et al Chinese Brushes: Controllable Liquid Transfer in Ratchet Conical Hairs (Adv. Mater. 26, 4889-4894 (2014)) as applied to claim 4 above, and in further view of Wetzel (US 20050066890). |
Office Action and Search Report in CN 201910149242X (Oct. 28, 2023). |
ISR for PCT/CN2020/074811 (May 9, 2020). |
Number | Date | Country | |
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20210257130 A1 | Aug 2021 | US |