The object of the invention relates to a microbubble generating nozzle, introducing water at low pressure (1.5 bar-6 bar), without requiring air saturators or compressors, entailing a low energy cost in water treatment stations.
Energy efficiency and sustainability are becoming increasingly important in water treatment operations.
Surface, marine and waste waters contain suspended solids, dissolved and suspended pollutants, which must be separated so that drinking or dumped water strictly complies with government regulations.
Technologies aimed at improving the final quality of waste water and drinking water have been the subject of continuous research, an example of which is flotation, an operation used to separate solids and immiscible liquids suspended in a liquid phase.
One of these technologies is based on the use of facilities that use Dissolved Air Flotation or DAF technology as a step in the water treatment process. Dissolved Air Flotation or DAF technology is an effective method for removing low-density solids or oils and greases that cannot be removed by sedimentation in applications such as drinking water, process water and waste water treatment.
The flotation of solids is obtained by introducing fine bubbles, generally air bubbles, into the liquid phase, through microbubble generating nozzles. The microbubbles are created by cavitation of the air that has previously been dissolved in a water stream treated by the DAF and recirculated (8 to 15%) in a saturator.
The pressurized air/water mixture is sent through a series of rows of nozzles or special injectors, depending on the type of DAF technology. For some applications, nitrogen is used as the flotation gas instead of air.
The sudden pressure difference on either side of the nozzle precipitates the air of the solution and creates microbubbles, which adhere to the solids and float them to the surface of the flotation area. Solid-free water is collected at the bottom of the DAF.
The thrust force generated causes the particles to rise to the surface where they can be easily removed.
As fine bubbles collide and adhere to the particles, the effective density of the resulting agglomerate decreases and the effective diameter thereof increases. The net result is that the particles rise rapidly to the surface of the fluid. As for particles, this phenomenon also applies to water-immiscible fluid droplets that are suspended in the fluid.
The sludge formed by the solids in the upper portion of the tank is hydraulically removed over a stationary weir by raising the water level on a predetermined interval, or mechanically removed with a scraper.
Flotation consists of several steps for the process to be carried out, these steps being as follows:
Dissolved Air Flotation or DAF is produced with a dispersion of fine air bubbles by dramatically lowering the pressure of an air saturated stream. The content of suspended solids is low and the concentrations of flocs between 5 and 50 mg/l, such as, for example, in the production of drinking water, for pre-treatment in seawater desalination or for treatments for reusing purified waters.
The installations that carry out this process require a compressor and a saturator, which is a pressurised chamber with a recirculation system to force the air that is going to dissolve until it saturates the aqueous phase.
The stream, rich in dissolved air, is taken to the DAF, wherein a controlled decrease in pressure is caused so that the released air generates microbubbles.
In a dissolved air flotation or DAF process, the typical values of the bubble size generated range between 10 and 100 micrometres, the process being quite expensive as it requires the use of a compressor that generates a pressure in the air the values of which are between 5 and 8 bars.
In addition, a pressurised chamber with recirculation and a system to control the pressure when releasing the stream of saturated water is required, which entails an increase in the cost of the water treatment installation.
The generating nozzles that are included in this type of DAF installation exhibit problems in terms of the size of the microbubbles and the relationship between said size and the working pressure of both the water column and the operating water pressure itself.
Moreover, conventional generating nozzles are not scalable to withstand different working conditions, establishing a specific type of generating nozzle for certain working conditions.
Additionally, some of the microbubble generating nozzles exhibit obstruction problems due to the fact that the air current is introduced into the nozzle through capillaries that can be obstructed by water or particles entrained in the system. This type of obstruction completely prevents the operation of the microbubble generating nozzles.
In addition, some of the microbubble generating nozzles based on the introduction of air through capillaries cannot supply different air flows without varying the operating conditions or consumption and, therefore, exhibit less flexibility to adapt to the operating conditions required by each type of water.
These types of nozzles based on the introduction of air through capillaries are currently not applicable to industrial plants with high treatment flows due to the limited water and air flows with which they operate.
Document DE19950600A1 discloses A device for gassing liquids and suspensions comprises a feed pipe (1) of constant cross-section for the liquid to be gassed opening out into vertical flat intermediate chamber (3) which forms parallel plates (2); and a pneumatic connection with the outer air formed in the region of the opening of the feed pipe so that openings (7) are provided in the plates through which gassing air is sucked via a connection (8), the air being distributed in fine bubbles of required size. Preferred Features: The feed pipe is locked with the lower edge of the upper plate forming the intermediate chamber. The plates have a circular shape.
The microbubble generating nozzle, object of the invention, enables elements such as the compressor and the saturator to be removed from a water treatment installation that uses Dissolved Air Flotation or DAF techniques, reducing the installation, operation and maintenance costs of the process.
Said nozzle is intended to be located immersed inside a water tank of a DAF installation, but also in other water treatment processes that require the generation of bubbles or microbubbles, such as degreasers, floats or bioreactors, and is used for producing microbubbles that will help separate solid particles and pollutants from the water to be treated.
The microbubble generating nozzle comprises a main body with a first inlet in the upper surface; and with a second inlet in the lateral wall, both inlets being able to be threaded holes.
The first inlet is intended to receive a first connection linked to a duct through which a water stream circulates and the second inlet is intended to receive a second connection which, additionally, is linked to a duct through which an air or gas stream circulates. Both streams, the water stream and the air or gas stream, come from the installation of which the microbubble generating nozzle is a part.
Likewise, the second inlet is located in a lateral recess made in the main body, so that the air or gas inlet inside the main body is as airtight as possible and on a flat surface, without loss of air quantity or pressure variation, since, if the second inlet were directly located on the lateral wall of the main body, due to the curvature of the surface of said wall, there would be gaps through which there could be losses of quantity or pressure of the air stream that is introduced into the nozzle.
The amount of air received by the microbubble generating nozzle is adjustable by using an air adjustment valve that can be located at any point in the installation, before the generating nozzle.
The microbubble generating nozzle functions without the presence of capillaries, avoiding obstructions due to the same, and being able to work in a very wide range of operating conditions, keeping the performance thereof and being able to adapt to different types of water to be treated.
Additionally, the generating nozzle comprises a gauge located in the lower portion of the main body and attached thereto by means of fixing elements, creating a separation between the gauge and the main body, said separation ranging from 0.3 millimetres to 5 millimetres and enabling the nozzle to be scaled to variable operating conditions of pressure and speed of the air and water stream.
The separation formed by the attachment between the gauge and the main body is called the “air-water contact area” wherein the air and water that circulate through the inside of the main body and that is intended after that contact for producing microbubbles come into contact.
The microbubble generating nozzle in turn comprises a first duct that is located inside the main body, which starts from the first inlet and communicates with the air-water contact area, intended to lead the incoming water stream inside the main body to the air-water contact area, into which said first duct opens.
Moreover, inside the main body there is a second duct that starts from the second inlet and is intended to circulate the air through the inside of said main body.
Inside the main body, in addition, a hollow internal ring with a diameter cross section is placed surrounding the first duct and receiving the second duct. Said ring is intended to proportionally distribute the amount of air it receives from the second duct and comprises third ducts that open into the air-water contact area, intended to lead the air that circulates through the mentioned internal ring towards the contact area in a distributed way, producing the microbubbles in that air-water contact area, distributing themselves in the tank wherein the nozzle is immersed.
Finally, the microbubble generating nozzle generates bubbles with a size of up to 50 micrometers without using a saturator or a compressor in the DAF water treatment facility, only introducing water at a pressure ranging from 1.5 bar to 6 bar, optimising the process of separating solids from water using flotation by removing elements of the installation that can cause failures during the process.
As a complement to the description provided herein, and for the purpose of helping to make the features of the invention more readily understandable, in accordance with a preferred practical exemplary embodiment thereof, said description is accompanied by a set of drawings constituting an integral part of the same, which by way of illustration and not limitation, represent the following:
A preferred embodiment of the microbubble generating nozzle is described below with the help of
Moreover, the hollow ring (6) is located surrounding the first duct (4) and transversely receiving the second duct (5); said hollow ring (6) additionally comprising third ducts (7) through which the air that has been proportionally distributed inside the hollow ring (6) circulates.
The microbubble generating nozzle additionally comprises a gauge (8) that is located in the lower portion of the main body (1), attached to said main body (1) by means of fixing elements creating a separation (9) into which the first duct (4) and the third ducts (7) open; and that said separation (9) is intended to produce the microbubbles due to the contact between the water and the air coming from the ducts (4, 7) and to expel the aforementioned microbubbles inside a water tank of the water treatment facility, wherein the nozzle is immersed to achieve the separation of solids using flotation.
Finally,
Number | Date | Country | Kind |
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P202130638 | Jul 2021 | ES | national |
Filing Document | Filing Date | Country | Kind |
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PCT/ES2022/070028 | 1/20/2022 | WO |