The present disclosure is directed to a microfluidic cartridge, and, more particularly, is directed to a microfluidic cartridge comprising a silicone pressure-sensitive adhesive.
Microfluidic cartridges exist for delivering compositions, including fluid compositions comprising perfume mixtures, either onto a surface or into the air using a microfluidic die. Microfluidic cartridges may contain a fluid composition and a microfluidic die having one or more nozzles for dispensing the fluid composition. The microfluidic cartridges may be releasably connectable with a housing of a microfluidic delivery device. In microfluidic cartridges, particularly as they have been used with fluid compositions that are free of perfume compositions, adhesive may be used to attach certain components to the microfluidic cartridge, including the electric circuit. However, fluid compositions comprising perfume mixtures can react with materials such as adhesive, which can potentially lead to electrical, mechanical, and chemical issues.
Thus, it would be beneficial to provide a microfluidic cartridge that is chemically compatible with a fluid composition comprising a perfume mixture.
“Combinations:”
A. A microfluidic cartridge comprising:
B. The microfluidic cartridge of Paragraph A, wherein the first end portion of the electric circuit is disposed on a first face of the exterior and the second end portion of the electric circuit is disposed on a second face of the exterior, and wherein the microfluidic die is disposed on the second face.
C. The microfluidic cartridge of Paragraph B further comprising a sticker, wherein the sticker comprises a silicone pressure-sensitive adhesive.
D. The microfluidic cartridge of Paragraph C, wherein the sticker covers the microfluidic die.
E. The microfluidic cartridge of any of Paragraphs A through D, wherein the microfluidic die comprises a semiconductor substrate comprising a plurality of thermal resistors, a fluid flow substrate comprising a fluid supply channel and one or more fluid chambers, wherein each fluid chamber is associated with one of the plurality of thermal resistors, and a nozzle plate comprising one or more nozzles, wherein each nozzle is in fluid communication with a fluid chamber.
F. The microfluidic cartridge of any of Paragraphs A through E, wherein the fluid composition comprises at least 70 wt. % of a perfume mixture, based on the total weight of the fluid composition.
G. A microfluidic cartridge comprising:
H. The microfluidic cartridge of Paragraph G, wherein the first end portion of the electric circuit is disposed on a first face of the exterior and the second end portion of the electric circuit is disposed on a second face of the exterior, and wherein the microfluidic die is disposed on the second face.
I. The microfluidic cartridge of Paragraph G or Paragraph H further comprising a sticker, wherein the sticker comprises a silicone pressure-sensitive adhesive.
J. The microfluidic cartridge of Paragraph I, wherein the sticker covers the microfluidic die.
K. The microfluidic cartridge of any of Paragraphs G through J, wherein the microfluidic die comprises a semiconductor substrate comprising a plurality of thermal resistors, a fluid flow substrate comprising a fluid supply channel and one or more fluid chambers, wherein each fluid chamber is associated with one of the plurality of thermal resistors, and a nozzle plate comprising one or more nozzles, wherein each nozzle is in fluid communication with a fluid chamber.
L. The microfluidic cartridge of any of Paragraphs G through J, wherein the fluid composition comprises at least 70 wt. % of a perfume mixture, based on the total weight of the fluid composition.
While the below description describes a microfluidic cartridge and a microfluidic delivery device, both having various components, it is to be understood that the microfluidic cartridge and microfluidic delivery device are not limited to the construction and arrangement set forth in the following description or illustrated in the drawings. The microfluidic cartridge, sticker, and method of installing the microfluidic cartridge into a housing of a microfluidic delivery device are applicable to other configurations or may be practiced or carried out in various ways. For example, the sticker may be used with various microfluidic cartridges or other housing configurations for delivering a fluid composition into the air or onto a surface.
Throughout the present disclosure, reference is made to cartesian coordinate system including an X-axis, Y-axis, and a Z-axis that extend from a common origin and that are mutually orthogonal. Reference may also be made to an X-direction, a Y-direction, and a Z-direction that run parallel with the respective axis. The microfluidic cartridge is configured to be connected with a microfluidic delivery device in a Z-direction.
The present disclosure is directed to a microfluidic cartridge. The microfluidic cartridge is configured to be releasably connectable with a housing of a microfluidic delivery device. The microfluidic cartridge may include an interior and an exterior. The interior of the microfluidic cartridge may comprise a reservoir for containing a liquid composition. The reservoir may include a fluid channel extending from reservoir and terminating at a fluid opening that is in fluid communication with a microfluidic die disposed on the exterior of the microfluidic cartridge. The microfluidic cartridge may include an electric circuit that electrically connects the microfluidic die with a power source and a controller. The electric circuit may be joined with the exterior of the microfluidic cartridge using a silicone pressure-sensitive adhesive. It has been found that a silicone pressure-sensitive adhesive, unlike other common adhesives, is chemically compatible with a fluid composition comprising a perfume mixture, while also providing the adhesion strength to join the electric circuit with the exterior of the microfluidic cartridge.
The microfluidic delivery device may comprise a housing and a power source. The housing may include a receptacle having an opening for receiving the microfluidic cartridge. The receptacle may receive a portion of the microfluidic cartridge or the microfluidic cartridge may be completely disposed within the receptacle. The receptacle of the housing may include electrical contacts that are in electrical connect with a power source and are configured to electrically connect with the electrical contacts of the microfluidic cartridge. The receptacle may include one or more housing connectors that are configured to connect with the cartridge connectors to enable a robust electrical connection between the housing and the microfluidic cartridge.
Microfluidic Cartridge
With reference to
With reference to
The reservoir 16 of the microfluidic cartridge 10 may contain from about 5 mL to about 50 mL of fluid composition, alternatively from about 10 mL to about 30 mL of fluid composition, alternatively from about 15 mL to about 20 mL of fluid composition. The reservoir 16 can be made of any suitable material for containing a fluid composition. Suitable materials for the containers include, but are not limited to, plastic, metal, ceramic, composite, and the like. A microfluidic cartridge may be configured to have multiple reservoirs, each containing the same or a different composition. The microfluidic delivery device may utilize one or more microfluidic cartridges, each containing a separate reservoir.
The reservoir 16 may also contain a porous material 19 such as a sponge that creates a back pressure to prevent the fluid composition from leaking from the microfluidic die when the microfluidic die is not in operation. The fluid composition may travel through the porous material and to the microfluidic die through gravity force and/or capillary force acting on the fluid composition. The porous material may comprise a metal or fabric mesh, open-cell polymer foam, or fibrous polyethylene terephthalate, polypropylene, or bi-components of fibers or porous wick, that contain multiple interconnected open cells that form fluid passages. The sponge may include a polyurethane foam. The reservoir 16 may also include a back pressure device, such as a spring or bladder, in addition to or in place of a porous material.
With reference to
The microfluidic cartridge 10 may comprise at least a first face 26 and a second face 28 joined along an edge 30. For example, the first face 26 may be a bottom face and the second face 28 may be a side face.
In a microfluidic cartridge 10 that is substantially cube-shaped, the microfluidic cartridge 10 may include a top face, a bottom face that opposes the top face, and four side faces extending between the top and bottom faces. Each joining face may be connected along an edge. In a cylindrical-shaped microfluidic cartridge, for example, the microfluidic cartridge may include a top face, a bottom face opposing the top face, and a single curved side face extending between the top and bottom faces.
With reference to
The primary components of a microfluidic die are a semiconductor substrate, a flow feature layer, and a nozzle plate layer. The flow feature layer and the nozzle plate layer may be formed from two separate layers or one continuous layer. The semiconductor substrate is preferably made of silicon and contains various passivation layers, conductive metal layers, resistive layers, insulative layers and protective layers deposited on a device surface thereof. Fluid ejection actuators in the semiconductor substrate generate rapid pressure impulses to eject the fluid composition from the nozzles. The rapid pressure impulses may be generated by piezoelectric device that vibrates at a high frequency (e.g., micro mechanical actuation) or by a heater resistor that cause volatilization of a portion of a fluid composition within the fluid composition through rapid heating cycles (e.g., micro thermal nucleation). For thermal actuators, individual heater resistors are defined in the resistive layers and each heater resistor corresponds to a nozzle in the nozzle plate for heating and ejecting the fluid composition from the nozzle.
With reference to
The nozzle plate 128 may include about 4-200 nozzles 126, or about 6-120 nozzles, or about 8-64 nozzles. Each nozzle 126 may deliver about 0.5 to about 35 picoliters, or about 1 to about 20 picoliters, or about 2 to about 10 picoliters of a fluid composition per electrical firing pulse. Individual nozzles 126 may have of a diameter typically about 0.0024 inches (5-50 microns). The flow rate of fluid composition released from the microfluidic die 51 could be in the range of about 5 to about 70 mg/hour or any other suitable rate or range.
With reference to
In the case of a flexible or semi-flexible electric circuit 52, the electric circuit 52 may be disposed on and span two faces of the microfluidic cartridge 10. For example, with reference to
In the case of a rigid electric circuit 52, the electric circuit 52 may be disposed on a single face of the microfluidic cartridge 52 such that the microfluidic die 51 and the electrical contacts 60 are disposed on the same face.
With reference to
With reference to
Exemplary silicone pressure-sensitive adhesives include RT130GS silicone adhesive tape, available from Fastelmask.
With reference to
With reference to
As shown in
The sticker 32 may be sized and/or shaped in various ways in order to cover the microfluidic die and at least one cartridge connector.
The sticker 32 may be disposed on the first and second surfaces to cover at least the microfluidic die and at least the one or more cartridge connectors 36. The sticker may have various different shapes and sizes, so long as the microfluidic die and the at least one cartridge connector 36 are covered.
The sticker 32 covers the microfluidic die to ensure that the fluid composition remains sealed in the microfluidic cartridge 10 until the microfluidic cartridge is to be installed in the housing. The sticker also covers at least one of the cartridge connectors 36 to prevent the microfluidic cartridge from making electrical connection with the housing unless the sticker has been removed by the user.
The sticker 32 and/or lid sticker 63 may comprise a carrier material and an adhesive disposed on the side of the carrier material that will contact the microfluidic cartridge 10. The carrier material may be selected from a variety of materials, including plastic films such as polypropylene film, paper, cardboard, etc. The sticker 32 and lid sticker 63 may both be in contact with the fluid composition, and, thus, may both need to be designed to be chemically compatible with the fluid composition.
When a sticker is intended to be removed during normal use of the microfluidic cartridge 10, the adhesive may be selected to provide a high enough interfacial adhesion strength to remain securely joined with the microfluidic cartridge to seal the microfluidic die and to prevent fluid composition from prematurely leaking from the nozzles of the microfluidic die. However, in such stickers, the interfacial adhesion strength should not be too high so as to cause the cohesive bonds in the adhesive to break as the sticker is being removed from the microfluidic cartridge, which could cause some of the adhesive to leave a residue on the microfluidic die. The adhesive should also have a high enough cohesion strength such that the adhesive does not migrate into the nozzles of the microfluidic die. A relatively high cohesion strength may be attributed to a relatively high molecular weight and cross-linked density adhesive. Lower molecular weight and low cross-linked density result in a lower cohesion strength. The adhesive may be selected from a pressure-sensitive adhesive (“PSA”); hot melt films; B-stage epoxies; B-stage phenolics; thermoplastic bonding films; and combinations thereof. The adhesive may preferably be a silicone pressure-sensitive adhesive.
Like the adhesive used to join the electric circuit 52 with the microfluidic cartridge 10, it has also been found that the adhesive used for stickers 32 or portions of the stickers 32 that may come into contact with the fluid composition are also subject chemical compatibility issues with perfume mixtures. As such, for stickers 32 that are intended to cover the microfluidic die 51 or stickers placed adjacent to the electric circuit 52 or the microfluidic die 51 where fluid composition may be present, the adhesive may preferably be a silicone pressure-sensitive adhesive.
As shown in
The sticker 32 may be comprised of one or more carrier materials and/or one or more adhesives. For example, with reference to
The sticker 32 may have various different shapes, so long as the sticker covers the cartridge connectors and the microfluidic die of the microfluidic cartridge.
The sticker may be configured to not cover the electrical contacts of the electric circuit of the microfluidic cartridge. If the sticker contacted the electrical contacts, the sticker could leave behind adhesive that could negatively impact the electrical connections between the microfluidic cartridge and the housing.
The sticker may be designed in various ways to draw attention the user's attention to the sticker and the need to remove the sticker before inserting the microfluidic cartridge into the housing. Aspects of the sticker that may be designed to draw attention to the user include the shape, size, color(s), words, graphics, symbols, tabs, the like, and combinations thereof.
The sticker may have a tab that the user is able to grasp and pull to remove the sticker. The tab may be free of adhesive. The tab may be an extension of the carrier material that is free of adhesive. Or the tab may be a separate portion that is connected with the carrier material comprising adhesive.
Microfluidic Delivery Device
With reference to
The receptacle 64 may include one or more housing connectors 38 configured to be received by the one or more cartridge connectors 36 of the microfluidic cartridge 10. The housing connectors 38 may be in the form of male connectors or female connectors. For example, if the cartridge connectors 36 are configured as female connectors, the housing connectors 38 may be configured as male connectors, or vice versa. The housing connectors 38 and cartridge connectors 36 may be sized and shaped to mate with each other for a sufficient mechanical and electrical connection to occur.
The housing 46 may include a faceplate 47 disposed on a front side of the housing 46. The housing 46 may also include a fluid outlet 74 for releasing the fluid composition from the microfluidic cartridge 10 into the air. The housing 46 may include an air outlet 76 for directing air toward the dispensed fluid composition upward and/or outward into the surrounding space. The fluid outlet 74 and the air outlet 76 may be disposed in the faceplate 47.
With reference to
With reference to
The receptacle 64 may include one or more guiderails for directing the microfluidic cartridge 10 into the receptacle 64.
The microfluidic delivery device may be configured to be compact and easily portable. In such case, the microfluidic delivery device may be battery operated. The microfluidic delivery device may be capable for use with electrical sources as 9-volt batteries, conventional dry cells such as “A”, “AA”, “AAA”, “C”, and “D” cells, button cells, watch batteries, solar cells, as well as rechargeable batteries with recharging base.
The microfluidic delivery device may include a fan for generating air flow to assist with delivering the fluid composition into the air. Any fan may be used that provides the desired air flow velocity, size, and power requirements for the microfluidic delivery device. The fan may be used to push the fluid composition further into the air and/or may be used to direct the fluid composition in a different direction than the fluid composition is dispensed from the microfluidic die. The fan may be disposed in the interior of the housing or at least partially in the interior of the housing, or at the exterior of the housing. The fan may also be used to direct air over the microfluidic die 51 to minimize the amount of fluid composition that is deposited back onto the microfluidic die 51.
Fluid Composition
To operate satisfactorily in a microfluidic delivery device, many characteristics of a fluid composition are taken into consideration. Some factors include formulating fluid compositions with viscosities that are optimal to emit from the microfluidic delivery member, formulating fluid compositions with limited amounts or no suspended solids that would clog the microfluidic delivery member, formulating fluid compositions to be sufficiently stable to not dry and clog the microfluidic delivery member, formulating fluid compositions that are not flammable, etc. For adequate dispensing from a microfluidic die, proper atomization and effective delivery of an air freshening or malodor reducing composition may be considered in designing a fluid composition.
The fluid composition may comprise a perfume mixture comprising one or more perfume raw materials. Perfume raw materials deliver a hedonic, fragrance benefit. The fluid composition may contain a perfume mixture present in an amount greater than about 50%, by weight of the fluid composition, alternatively greater than about 60%, alternatively greater than about 70%, alternatively greater than about 75%, alternatively greater than about 80%, alternatively from about 50% to about 100%, alternatively from about 60% to about 100%, alternatively from about 70% to about 100%, alternatively from about 80% to about 100%, alternatively from about 90% to about 100%. The fluid composition may consist entirely of the perfume mixture (i.e. 100 wt. %).
The fluid composition may be substantially free of suspended solids or solid particles existing in a mixture wherein particulate matter is dispersed within a liquid matrix. The fluid composition may have less than 5 wt. % of suspended solids, alternatively less than 4 wt. % of suspended solids, alternatively less than 3 wt. % of suspends, alternatively less than 2 wt. % of suspended solids, alternatively less than 1 wt. % of suspended solids, alternatively less than 0.5 wt. % of suspended solids, or free of suspended solids. Suspended solids are distinguishable from dissolved solids that are characteristic of some perfume materials.
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
It should be understood that every maximum numerical limitation given throughout this specification will include every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.
Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
It should be understood that every maximum numerical limitation given throughout this specification will include every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.
Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
Number | Date | Country | |
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62875112 | Jul 2019 | US |