Patent Application
20240002729
Pyrolysis is the process of heating waste in an inert environment to induce thermal decomposition of the waste. This thermal decomposition changes the chemical composition of the waste, resulting in by-products with a host of industrial and commercial uses. When the waste contains organic matter, any resulting solid residue is typically high in carbon, taking the form of char. However, pyrolysis may also generate gaseous and liquid by-products, depending on the composition of the waste. Applications of pyrolysis include the conversion of biowaste to syngas and biochar, the production of coke from coal, the production of charcoal from wood, the conversion of ethane to ethylene (i.e., “cracking”), and waste management.
Pyrolysis has been investigated as a feasible approach to processing municipal solid waste. However, such waste typically has a high moisture content (often in excess of 70%), which slows the heating of the waste. One way to improve the heating rate of pyrolysis is to use microwaves (i.e., electromagnetic waves in the microwave region of the electromagnetic spectrum). Water is an excellent absorber of microwaves, converting the absorbed microwaves into heat. This same principle is used in microwave ovens to heat food (through its water content) much more rapidly than through conventional ovens. Some waste materials (e.g., plastic) are fairly transparent to microwaves, allowing the microwave energy to penetrate the waste and heat it from within. Other waste materials (e.g., food) are not as transparent to microwaves, yet may become increasingly transparent as they are heated and broken down.
In the military, current methods for waste management depend on the type of waste and platform. For example, the United States Navy is permitted to throw certain materials overboard ships (e.g., paper rags, glass, metal, food when further than twelve nautical miles from land, ground-up food waste when further than three nautical miles from shore). An incinerator using JP-5 jet fuel is used for paper, rags and wood, wasting weight and cost related to burning jet fuel to dispose of garbage. In the case of US Navy submarines, all possible waste is eliminated prior to deployment, while on-board waste is pumped or blown out. Other solutions include storing waste in frozen food lockers, burial in the field, and pyrolysis.
Thermochemical processes, pyrolysis, incineration, gasification, etc., have been used for waste management. Unlike incineration and gasification, pyrolysis does not directly process the waste for energy production, but converts it into intermediary compounds that can be used for up-conversion, fuel, or environmentally safe products that can be used for fertilization. Another process for upconverting waste materials is hydrothermal carbonization. Near-supercritical and supercritical fluid have been successfully used for carbonization, gasification, liquefaction, and upgrading of hydrocarbon resources including crude oils, microalgae, lignocellulosic biomasses, food wastes, and plastics. Combined hydrocarbon and nitrogen compounds can be successfully recovered from human biowaste.
Most of the work in the waste sector uses convection-based heating methods. However, microwave heating offers improved thermal efficiency and reaction speed. Microwave heating uses Joule losses of the electric field, combined with electrical conductivity of the waste material at GHz frequencies, to increase waste temperature. Because of the high penetration depth of electromagnetic waves in the radio-frequency spectrum, this type of heating may be confined within a volume possibly without damage or overheating of the surface, which is difficult to achieve with convection heating. This localized heating also improves system efficiency by directly producing heat inside the intended material, and therefore the heating rate is not limited due to thermal conductivity to an external heat source and the heat capacity of the material.
The present embodiments feature pyrolysis reactors that use microwaves to rapidly heat waste materials. At the heart of these pyrolysis reactors are microwave cavities within which the waste materials are located. Electromagnetic modes of the cavities are excited by electromagnetic fields that are coupled into the cavity by one or more microwave probes (or launchers) driven by an external microwave source. The present embodiments advantageously use a number of techniques to ensure appropriate distribution of the electromagnetic energy throughout the cavity, thereby ensuring that the waste materials are rapidly and more uniformly heated (as compared to operation without these techniques). As described in more detail below, these techniques include overmoding of the cavity, outphasing, amplitude modulation, and frequency modulation. Unlike many prior-art pyrolysis reactors, the present embodiments are not adversely affected by the moisture content of the waste, and may even perform better when water is intentionally added to the waste.
The pyrolysis reactors of the present embodiments feature spatial power combining, within the cavity, of electromagnetic power from several solid-state sources. By comparison, magnetron sources (e.g., as typically used in conventional microwave ovens) are usually not power combined since it is difficult to control the relative frequency and phase. Solid-state sources do not achieve as high power as magnetrons, but with spatial power combining, high microwave power levels (e.g., up to tens of kilowatts) can be achieved inside the cavity using solid-state amplifiers. To increase efficiency, the amplifiers can be operated nonlinearly. The microwave cavity can be excited using multiple probes that are all driven by solid-state power amplifiers, which are excited by one or more microwave oscillators. Dynamic relative phase shifting of the power amplifier outputs can be used to improve heating efficiency of the waste in the cavity.
In some embodiments, a radio frequency (RF) applicator delivers electromagnetic energy to a treatment volume containing an emulsion of a hydrocarbon and a substrate, which facilitates separation of the hydrocarbon and substrate molecules into layers. Hydrocarbons and other products can then be recovered from their respective layers (e.g., see U.S. Pat. No. 7,486,248). Microwave heating has also been shown to be much faster than conventional resistance heating in hydrothermal treatments.
The present embodiments can be used to process both large and small quantities of waste mass, and are therefore scalable while maintaining high energy conversion efficiency. This scaling can be implemented via (1) selection of the cavity size and frequency, (2) microwave power density by power combining the outputs of multiple solid-state amplifiers, (3) overall power using solid-state amplifiers, (4) time-domain profile when the power is on, and (5) mode-mixing through one or more of mechanical means, frequency modulation, and varying the cavity boundary conditions.
Pyrolysis reactor 100 includes a microwave cavity 110 formed by electrically conductive walls 114 that surround inner volume 112. Electrically conductive walls 114 may be made of metal (e.g., copper, silver, gold, aluminum, etc.). Microwave cavity 110 supports a plurality of electromagnetic modes that store electromagnetic energy when excited. In
Microwaves are coupled into the microwave cavity 110 through one or more probes 122, each driven by a corresponding amplifier 120. In the example of
Probes 122 are driven with an electrical microwave signal 131 that is generated by a frequency source 130 and split with a power splitter 132. Microwave signal 131 may have a single frequency selected to resonate with one of the modes of microwave cavity 110. For example, the frequency may be selected to coincide with the lowest-frequency fundamental resonance of microwave cavity 110 (when the cavity is empty, i.e., not loaded). However, to increase the spatial uniformity of the electric field within microwave cavity 110, microwave cavity 110 may be overmoded, i.e., driven at a frequency higher than that of the fundamental resonance to excite several modes. In some embodiments, microwave signal 131 contains a plurality of frequencies.
Since amplifier linearity is not a relevant specification for microwave-based pyrolysis, each amplifier 120(1), 120(2) may be a high-efficiency solid-state amplifier based on GaN or LDMOS power transistors. Each amplifier 120(1), 120(2) may output several watts of power, or more, depending on the volume and contents of waste mass 102.
The frequency of microwave signal 131 may be selected near 2.45 GHz or 900 MHz, where the electromagnetic energy has sufficient penetration depth given the electrical conductivity of most waste materials. Therefore, the use of these frequencies may help ensure uniform heating and even thermal breakdown throughout all of waste mass 102. In some embodiments, the frequency of microwave signal 131 lies within the Industrial, Scientific, and Medical (ISM) band between 2.4 and 2.5 GHz. In these embodiments, each amplifier 120(1), 120(2) may be based on GaN power transistors. In other embodiments, the frequency of microwave signal 131 lies within the ISM band between 915 and 928 MHz. In these embodiments, each amplifier 120(1), 120(2) may be based on either GaN power transistors or LDMOS power transistors However, in general, the frequency of microwave signal 131 is not limited to only these bands, provided that the cavity is shielded.
Given that pyrolysis reactor 100 may operate with powers up to tens of kilowatts, or more, operation at frequencies within ISM bands advantageously minimizes the likelihood of generating interference that can disrupt telecommunications. In some embodiments, pyrolysis reactor 100 operates at multiple frequencies simultaneously. For example, first probe 122(1) may be driven near the ISM band at 915 MHz, while second probe 122(2) is driven near the ISM band at 2.45 GHz. The use of multiple frequencies can help ensure uniform heating given the different absorption properties of materials within waste mass 102, and how these absorption properties change as the waste mass 102 breaks down. Additional ISM bands are centered at 5.8 GHz, 24.125 GHz, 61.25 GHz, 433.92 MHz, 40.68 MHz, etc. Additional probes 122 may be driven at frequencies within these additional ISM bands to further increase the frequency diversity of the electric field within microwave cavity 110. Since the number of transverse-electric (TE) and transverse-magnetic (TM) modes within the microwave cavity 110 scales as f3, where f is the frequency of the microwave signal 131, operating microwave cavity 110 at higher frequencies can advantageously facilitate overmoding. However, a higher frequency usually results in a lower efficiency of solid-state amplifiers 120, and less penetration of the waste due to a smaller skin depth. Thus, there is a trade-off between overmoding and efficiency that can be evaluated based on the design requirements.
To determine the relative phase Δϕ, signal processing module 210 monitors waste mass 102 to determine how microwave properties (e.g., real and imaginary components of the permittivity) change as waste mass 102 heats and breaks down. Thus, waste mass 102 may be thought of as a microwave load that varies spatially and temporally. To determine changes in the microwave load, signal processing module 210 may use a plurality of thermocouples 212 to record temperatures of waste mass 102 at various positions, both at the surface of waste mass 102 and inside waste mass 102. Signal processing module 210 may additionally or alternatively use one or more infrared cameras (e.g., infrared camera 207 as shown) to record a temperature distribution of waste mass 102. Infrared camera 207 may view waste mass 102 via a viewport 204. Signal processing module 210 processes this temperature data to determine the optimum phase shift AO, and then outputs corresponding phase-control signal 208. Signal processing module 210 may operate as part of a feedback loop.
In one embodiment, pyrolysis reactor 200 uses radiometry at microwave frequencies to measure the properties of waste mass 102 at depths of several centimeters. This embodiment advantageously overcomes limitations of infrared camera 207, which can only detect the temperature of waste mass 102 to within a few millimeters of its surface. Radiometry may also provide a greater density of spatial temperature measurements than can be implemented with the plurality of thermocouples 212. In this embodiment, pyrolysis reactor 200 additionally includes a radiometer 209 for receiving the emitted black-body radiation in the microwave region of the spectrum where the skin depth in waste is comparable to the waste dimensions.
Although
As shown in
To improve electric field uniformity inside microwave cavity 110, some embodiments use frequency modulation to implement mode mixing in microwave cavity 110. When microwave cavity 110 is overmoded, a small change in the microwave frequency can greatly change the electric field distribution within the microwave cavity 110.
In some embodiments, spindle 424 is made of metal and paddles 426 are made of a non-electrically conductive material, such as ceramic, that can withstand the high temperatures achieved within pyrolysis reactor 400. Therefore, in these embodiments, only spindle 424, and not paddles 426, serves as the center conductor of coaxial microwave cavity 410. In other embodiments, paddles 426 are also made of metal and are in electrical contact with spindle 424. In these embodiments, both spindle 424 and paddles 426 serve as the center conductor of coaxial microwave cavity 410. While
Frequency-selective surface 502 is shown in
Frequency-selective surface 502 may be configured differently than shown in
In
In some embodiments, multiple frequency-selective panels 502 are placed in front of walls 514 of microwave cavity 510. In some embodiments, frequency-selective panels 502 with different electrical properties are used in different regions of microwave cavity 510 to account for spatial variations of waste mass 102. For example, a first frequency-selective panel 502 may be used at the top of microwave cavity 510 (in the +z direction) to create a first electric field distribution that is matched to that portion of waste mass 102 at the top of the inner volume 512. Similar, a second frequency-selective panel 502 may be used at the middle of microwave cavity 510 to create a second electric field distribution that is matched to that portion of waste mass 102 at the middle of the inner volume 512. Finally, a third frequency-selective panel 502 may be used at the bottom of microwave cavity 510 to create a third electric field distribution that is matched to that portion of waste mass 102 at the bottom of inner volume 512. As an example of how these embodiments may be used, consider waste mass 102 as it undergoes chemical changes: the resulting char and ash may fall to the bottom of inner volume 512 (i.e., in the −z direction), where it accumulates. In this case, the third frequency-selective panel 502 may be designed to optimally heat the char and ash, while the first and/or second frequency-selective panels 502 may be designed to optimally heat that portion of waste mass 102 that has not yet been converted to char and ash.
In any of the above embodiments, water may be added to waste mass 102 within the inner volume 112, 512 to facilitate thermal conduction of heat within waste mass 102. The water may be salt water. Alternatively or additionally, small metallic particles (e.g., nanoparticles) may be added to waste mass 102 (either with or without additional water added) to enhance scattering of the electromagnetic fields throughout waste mass 102, thereby improving the uniformity with which the electromagnetic energy is absorbed by waste mass 102.
In any of the above embodiments, the microwave cavity 110, 510 may be externally surrounded with thermal shielding, for example in space 553, to reduce heat loss, thereby improving the energy efficiency of the pyrolysis reactor. For example, this thermal shielding may be made of a material having low thermal conductivity (e.g., fiberglass, ceramic, Styrofoam, plastic, etc.) to minimize convective heat loss from the microwave cavity to the surrounding environment. For similar purposes, a heat shield (e.g., aluminum foil, steel panels, ceramic thermal barriers) may be placed around the microwave cavity to reduce radiative heat loss. In some embodiments, the microwave cavity is placed within a larger vacuum system that may be evacuated to reduce convective heat loss from the microwave cavity. For example, wall 551 confines vacuum space 553, in which microwave cavity 510 is placed. Wall 551 of the larger vacuum system may be made of metal to act as heat shield.
The features described above with respect to the pyrolysis reactors 100, 200, 400, and 500 may be combined in any way without departing from the scope hereof. Specifically, the present embodiments include all combinations of: the outphasing shown in
In step 710, a microwave signal is generated with an oscillator. In one example of step 710, probes 122 of
Step 730 includes amplifying the plurality of drive signals into a corresponding one of a plurality of amplified signals. This amplification is for example achieved using a solid-state power amplifier for each probe. In step 740, the amplified drive signals are coupled into the microwave cavity to excite a plurality of cavity modes. In one example of step 740, one or more probes 122, each driven by a corresponding amplifier 120, excites microwave modes in microwave cavity 110 (see
Step 750 includes measuring one or more temperatures of the waste mass. Step 750 is, for example, performed with thermocouples 212 in
Step 750 may also include recording a thermal image stream of the waste mixture using an infrared camera. For example, infrared camera 207 records a temperature distribution of waste mass 102 through viewport 204. Infrared camera, however, penetrates only a few millimeters into the water volume due to the limited skin depth. For this reason, the image stream from the infrared camera may be used in conjunction with thermocouples 212 placed at various locations and depth of waste mass 102.
In certain embodiments, step 750 includes, instead of or in addition to the infrared camera, a microwave radiometer (e.g., radiometer 209 in
In step 760, at least one phase-control signal is determined based on the measured temperatures. By way of example, to determine the phase-control signal, or relative phase Δϕ, processing module 210 monitors the measured temperatures at various locations including at the surface and inside of waste mass 102, to determine how its microwave properties (e.g., real and imaginary components of the permittivity) change as waste mass 102 heats and breaks down. As waste mass 102 undergoes changes, the thermal load changes as a function of space and time. As a result, the relative phase is continuously updated to maintain thermal efficiency and uniformity. This process requires accurate measurements of temperature at as many locations in the cavity as possible. In certain embodiments, one or both of an infrared camera (e.g., infrared camera 207) and a microwave radiometer (e.g., radiometer 209) may be used in conjunction with the plurality of thermocouples to provide better spatial and temporal resolution of the measured temperature profile.
Additionally, in step 760, the one or more phase-control signals are outputted to a one or more corresponding variable phase-shifters. In one example of step 760, after having determined the relative phase between two probes 120(1) and 120(2) needed to maintain thermal uniformity and efficiency in cavity 110 in step 740, signal processing module 210 outputs the relative phase 208 to variable phase shifter 214 for probe 122(2). For reactors having more than two probes, only the relative phase differences among the plurality of probes are determined. Accordingly, the number of variable phase shifters, and therefore the number of phase-control signals, may be one less than the number of probes. However, a different number of phase shifters (and corresponding phase control signals) may be used without departing from the scope hereof.
From step 760, the phase-adjusted drive signal from each phase-shifter is fed into a corresponding power amplifier of step 730. Accordingly, steps 730, 740, 750 and 760 may be iterated until the waste is fully converted into one or more intermediary compounds that can be used for up-conversion, fuel, or environmentally safe products that can be used for, for example, fertilization.
Method 700 may include additional steps without departing from the scope hereof. As part of maintaining thermal uniformity of the waste mass throughout the thermochemical process, method 700 may include, for example, stirring the waste mixture with an auger located at least partially within the internal space of the microwave cavity. For example, mixing auger 422 may be rotated by motor 412 to mix waste mass 110, thereby improving thermal uniformity of waste mass 110.
Method 700 may also include additional or alternate steps to maintain an optimal level of power transfer, or heating efficiency, for efficient breakdown of waste. One such step includes improving electric field uniformity inside the microwave cavity by implementing mode mixing using frequency modulation. When the microwave cavity is overmoded, a small change in the frequency of the microwave signal can greatly change the electric field distribution within the microwave cavity. For example, in
Additionally, to achieve and maintain a high level of field efficiency and therefore the power transfer, the steps in method 700 may be modified to accommodate design choices in hardware. For example, the cavity design may include frequency selective surfaces, as shown in
The pyrolysis reactor and methods described herein may be used in a system that can be scaled to process waste of any size including, for example, municipal solid waste. In such a system, any microwave pyrolysis reactor, including magnetron-based microwave reactor, has advantages over a conventional convection-based reactor, with those advantages being (1) improved thermal efficiency, leading to more rapid thermochemical process to take place and (2) improved thermal uniformity (e.g., not overheating certain parts, such as the surface of waste mass) due to high penetration depth of electromagnetic waves in the radio-frequency spectrum. However, solid-state-based microwave pyrolysis reactor disclosed herein has additional advantages over a conventional magnetron-based microwave reactor with the most important advantage being that the solid-state-based microwave pyrolysis reactor can be scaled in terms of (1) waste mass by cavity size and frequency choice, (2) microwave power density by power combining a plurality of solid-state amplifiers, and (3) overall power by mode-mixing through mechanical, frequency and/or cavity boundary condition design. Additionally, in such a system, byproducts of the pyrolysis process can be further processed to produce liquid fuel, which in turn may at least partially power pyrolysis reactor.
More specifically, in waste processing system 800 a waste mass 802 is placed in the microwave cavity of pyrolysis reactor 810 and is processed following method 700. Dirty bio-oil 870 from the pyrolysis process has characteristics that vary according to the initial composition of waste mass 802. However, there are some contaminants that negatively influence the quality of the final product of the system. For example, liquid fuel 890, as the final product in system 800, may contain contaminants including nitrogen, sulfur, and metal-containing compounds. In some embodiments, waste processing system 800 includes a co-product recovery module 874 that analyzes dirty bio-oil 870 for these contaminants, and removes any such contaminants that are found. Some of the analysis techniques that may be used in co-product recovery module 874 include gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (LC-MS) for compound identification and quantitation. Removal of the contaminants from dirty bio-oil 870 may involve one of more compound separation techniques, such as counter current chromatography.
In addition, depending on the biosolids pyrolyzed, dirty bio-oil can harm industrial equipment, produce hazardous emissions upon combustion, or both. Accordingly, some embodiments of the waste processing system 800 includes a microbial upgrading module 872 that uses a sequence of one or more microbial bioreactors to remove these harmful compounds, especially sulfur and nitrogen. An example bioreactor may have an established mixed culture dominated by strains of Pseudomonas, Klebsiella, or other genera that metabolize contaminating nitrogen compounds. In certain embodiments, the sequence of bioreactors is optimized, such that the broadest and the highest toxic compounds in dirty bio-oil 870 are removed first. This type of optimization may prolong and enhance the stability of the biological treatment processes.
After the removal of harmful contaminants, the product of system 800 is clean biofuel. For example, dirty bio-oil 870, after having toxic and harmful contaminants removed by co-product recovery module 874 and microbial upgrading module 872, becomes the final product of system 800, i.e., liquid fuel 890. Liquid fuel 890 may be sold as clean biofuel 886.
Additionally, system 800 may recycle all or a portion of the final product to at least partially power the pyrolysis reactor. More specifically, in some embodiments, system 800 includes an electric generator 892. Electric generator 892 may use all or portion of liquid fuel 890 to generate electricity 884 that can be combined with external power source 882 and supply electricity to pyrolysis reactor 810. Accordingly, pyrolysis reactor 810 can be powered fully or partially by an external power source 882, by electric generator 892 using liquid fuel 890 or by a combination of both sources.
Commercial ashing machines typically use approximately 1200 W of power in a small cavity (e.g., 22 cm×23 cm×10 cm), giving about 0.24 W/cm3 of volume power density compared to a standard microwave oven (which results in approximately 0.01 W/cm3). A full calculation requires many assumptions since waste content varies and results in varied heating. For example, carbon content is converted to coke (highly caloric fuel), and waste with more carbon results in more coke mass. By-products include particulate matter, volatile organic compounds, polynuclear aromatic hydrocarbons, methane, ammonia, carbon monoxide, hydrogen sulfide, hydrogen cyanide, and sulfur oxides that can be either pumped out or used to continue the coking process. Generally, a reasonable approximation for the temperature change dT/dt is given by
where P is the power in watts, C the specific heat in cal/g, and ρ is the volume mass density in g/cm3.
The efficiency of incineration methods is informally quantified by the amount of diesel energy required to produce carbon-rich products from waste. In the case of microwave breakdown, the input is electrical power and the total efficiency will depend on (1) the primary electrical power source efficiency, (2) the microwave generation chain efficiency, and (3) the efficiency of power delivery to the waste mass over time. For the purposes of waste breakdown, a rate efficiency can be defined as:
where V is the volume of the mixed waste (making it difficult to define mass), P is the power in watts required to heat the waste, and τ is the time required to reach an average temperature T. We control power and time separately, but one can also quantify it in terms of energy (e.g., joules). This definition of rate efficiency scales in volume.
The input power in the rate efficiency η is the electrical power delivered to the microwave source. The heat energy dissipated in the waste mass can be expressed as:
where σ(x,y,z,t,T) is the non-uniform waste conductivity, which is a function of temperature and therefore time. The total electric field magnitude is also a function of position within the waste volume and changes with time, since the waste mass electrical properties change, therefore modifying the loading of the microwave cavity. Some relevant values that can be used in initial simulations for possible non-metallic waste are given in Table 1.
An example of the approach for predicting the thermal power is shown next. The thermal power produced in the cavity depends on the filling material properties, relative permittivity (εr), conductivity (σ), geometry of the cavity and type of excitation, and is calculated from:
P
Th
=∫∫∫|E(x,y,z)|2σ(x,y,z)dV
It is desirable to keep the power density of Joule losses uniform through the heating process because that will usually result in the best time-average efficiency. Several rectangular and cylindrical cavities with volumes ranging from 0.0008 to 0.15 m3 were compared using a full-wave eigenmode solver (Ansys HFSS) to determine the modal content around the operating frequency of 2.4 GHz. With a single waveguide port excitation used for the simulation there is a tradeoff between large volumes which can have a high level of field uniformity and small volumes which are effectively heated with a single feed. The cavity has the shape of an actual trash-can, cylindrical in shape and with one basis larger, as shown in
The equation above for thermal power can be simplified if the waste volume is assumed to consist of sub-volumes that have uniform conductivities, where the integral becomes a sum:
The fields can be found using a full-wave electromagnetic (EM) solver given a specific geometry, electrical properties, and excitation. It is worth noting that the magnetic component of the electromagnetic field has a small effect on heating since the magnetic properties/loss of the waste load are usually negligible compared to the dielectric ones/loss.
Hydrothermal carbonization (HTC) is carried out mainly to produce a solid product similar to coal starting from wet biomass feedstock. Though it is most effective with wet biomass, HTC has been successfully applied to municipal solid waste and plastics. Removing carboxyl and hydroxy (—OH) groups reduces the oxygen-to-carbon ratio significantly to make the final product more energy dense. The solid yield from this process roughly varies between 35% and 65% of the initial dry feedstock with a higher heating value (HHV) around 13-30 MJ/kg depending on the initial energy content of the feedstock. A feedstock with 75-90% moisture content is considered ideal for this process. HTC consists of three processes, namely, dehydration, decarboxylation, and decarbonylation, for which pretreatment or drying of the feedstock waste is not needed.
The idea remains the same, while process conditions (temperatures of 180-220° C. and pressures of 20-25 bar) are intensified to speed up the process. The reaction time can vary from 1 to 72 hours based on the feedstock and desired output products. This is one of the most promising processes for waste treatment as it can handle large amount of water content. Notice how the pressure requirement is rather moderate for this process that keeps the material cost low.
To maximize efficiency, thermal insulation may be used, in certain embodiments. The electrical and chemical processes that occur when there is an electromagnetic field inside a material are linked through the heating rate caused by Joule losses as:
where ρ is the mass density of the filling material, c is the specific heat of the material, T is the temperature at a specific point within the material, and K is the thermal conductivity. An analytical solution for the heating rate is complicated since the temperature and electric field are functions of position. Therefore, multi-physics simulations were used to determine the temperature increase due to Joule losses and account for the anticipated energy leakage through the cavity walls with specific thermal insulation as shown in
The RF power is first generated using an efficient oscillator, then amplified through efficient saturated gain stages and delivered to the output power stage. Since linearity is not a specification for the heating application, solid-state GaN circuits can be designed with efficiencies exceeding 80% at the lower power levels. Multiple-level power combining is investigated as a means to increase overall efficiency. Circuit-level combining is limited by combiner loss for a larger number of devices. To maximize efficiency in the present embodiments, power may be combined at the circuit level and via spatial combining within the cavity. Spatial combining has been demonstrated to maintain combining efficiency in plane-wave combiners and over-moded waveguide horn combiners. At the cavity level, the waste mass heating will result in a variable load to the probe, and thus the output-state power amplifiers (PA), which can result in reduced efficiency and instabilities.
The standard approach to dealing with load mismatch is to use isolators or impedance tuners at the output of the power amplifier. These devices can also be controlled adaptively in a closed loop. The performance of the tuners, such as insertion loss and adaptation speed, typically degrades as the range of load reflection coefficient increases. The type of tuning device has been limited to lossy p-i-n diodes at higher power levels. For a larger tuning range, the number of tuning elements increases, therefore increasing insertion loss. In the present embodiments, out-phasing of two or more PAs is used. Outphasing is traditionally used to maintain efficiency for high peak-to-average power ratio (PAPR) signals by feeding two amplifiers with a constant-envelope signal, varying their relative phase to change the combined amplitude at the output. In the case of a non-isolated Chireix combiner, the reactive impedances presented to the two PAs are complex conjugates. A tunable Chireix-type combiner can be designed to address load impedance variations instead of signal amplitude variations (PAPR). This architecture requires a very simple tuner with only two tunable elements which handle half of the output power with a small required tuning range.
In addition to varying the phase for load-modulation, the DC supply to the PA transistor can be varied to produce RF power variation, which is not possibly with, for example, magnetron sources. This method is referred to as “supply modulation” and is used effectively for efficiency enhancement when communication signals are amplified. In this case, however, the supply modulation does not need to be fast (e.g., 100 MHz in communications systems), but can be on the order of the heating time constants, and therefore the dynamic supply (supply modulator) can be extremely efficient and not degrade the overall system efficiency while providing a means to vary the power level. Variation of the power level is crucial as waste changes properties during breakdown, and from one loading to another where materials might have dramatically different electrical properties.
The key to efficient waste heating is maintaining the electric field uniformity inside the cavity. The present embodiments combine several approaches to ensure field homogeneity for scalable pyrolysis. First, the temperature of the waste mixture may be measured throughout the volume, such as with an infrared (IR) camera and several thermocouples (see
Other approaches to maintain electric field uniformity include: (a) the use of multiple probes and variable/adaptive probe excitation phasing, which has been shown to improve field uniformity, especially as the cavity loading changes with heating; (b) various types of mode mixing such as frequency modulation (FM) and load stirring; (c) cavity design with modified wall boundary conditions through frequency selective surfaces (FSS), which can also be electrically or mechanically variable; and (d) time-domain pulse shaping can enable superposition of modes over time thus improving overall uniformity averaged over time. These approaches may be used in any combination without departing from the scope hereof.
Frequency modulation can be done at the low-power voltage controlled oscillator.
Load stirring is another effective means of mode mixing. The statistics are different and therefore combining different methods will give improved uniformity. A statistical approach to modeling this type of problem also showed agreement with simulation.
For cavity design and modified boundary conditions, metallic walls are fixed boundary conditions which enforce the tangential electric field to be zero on the walls, limiting the type of modes that exist. It has been shown that varying boundary conditions with periodic structures can improve uniformity of the B-field in high-field travelling-wave magnetic resonance imaging (MRI) bores (e.g., at 16 T and 10.5 T). This can also be applied to the electric field for volume power density uniformity, through frequency selective surfaces (FSS). In fact, these can also be electrically or mechanically variable for adaptive boundary conditions.
For time-domain pulse shaping, this concept is borrowed from MRI time-interleaved acquisition of modes method, which enables superposition of modes over time thus improving overall uniformity. With supply modulation, combined with FM, time-domain pulse shaping is straightforward.
Changes may be made in the above methods and systems without departing from the scope hereof. It should thus be noted that the matter contained in the above description or shown in the accompanying drawings should be interpreted as illustrative and not in a limiting sense. The following claims are intended to cover all generic and specific features described herein, as well as all statements of the scope of the present method and system, which, as a matter of language, might be said to fall therebetween.
Combination of Features
Features described above as well as those claimed below may be combined in various ways without departing from the scope hereof. The following examples illustrate possible, non-limiting combinations of features and embodiments described above. It should be clear that other changes and modifications may be made to the present embodiments without departing from the spirit and scope of this invention:
(A) A pyrolysis reactor includes a microwave cavity configured to contain a waste mixture within an internal space and a plurality of probes that couple a corresponding plurality of drive signals into the microwave cavity to excite a plurality of cavity modes and heat the waste mixture.
(B) In the pyrolysis reactor denoted (A), the microwave cavity has walls shaped as a cylindrical shell surrounding the internal space.
(C) In the pyrolysis reactor denoted (B), the pyrolysis reactor further includes a linear electrical conductor surrounded by the cylindrical shell.
(D) In the pyrolysis reactor denoted (C), the linear electrical conductor is a spindle for an auger located at least partially within the internal space, to stir the waste mixture.
(E) In any one of the pyrolysis reactors denoted (A) to (D), the pyrolysis reactor further includes thermal insulation surrounding the microwave cavity.
(F) In the pyrolysis reactor denoted (E), the pyrolysis reactor further includes a heat shield between the microwave cavity and the thermal insulation.
(G) In any one of the pyrolysis reactors denoted (A) to (F), the pyrolysis reactor further includes at least one frequency selective surface disposed in front of at least a part of the microwave cavity and in the internal space, to surround the waste mixture.
(H) In any one of the pyrolysis reactors denoted (A) to (G), the pyrolysis reactor further includes an oscillator for generating a microwave signal, a plurality of solid-state power amplifiers for amplifying the microwave signal into the plurality of drive signals, and one or more variable phase shifters electrically connected to the oscillator, each of the variable phase shifters being configured to phase-shift one of the microwave signals prior to amplification in a corresponding one of the plurality of solid-state power amplifiers.
(I) In the pyrolysis reactor denoted (H), the pyrolysis reactor further includes a plurality of sensors for measuring temperatures of the waste mixture, and a processing unit configured to (i) determine, based on measured temperatures, one or more phase-control signals and (ii) output the phase-control signals to the one or more phase-shifters to maximize power transfer to the waste mixture.
(J) In the pyrolysis reactor denoted (I), the plurality of sensors includes a plurality of thermocouples and an infrared camera for recording a thermal image stream of the waste mixture.
(K) In the pyrolysis reactor denoted (I), the plurality of sensors includes one or more microwave radiometers for measuring thermally-emitted electromagnetic radiation from the waste mixture.
(L) A method for processing a waste mixture includes coupling a plurality of drive signals into a microwave cavity to excite a plurality of cavity modes, the microwave cavity containing the waste mixture. The method further includes phase-shifting, based on a temperature of the waste mixture, one or more of the plurality of drive signals.
(M) In the method denoted (L), the method further includes generating a microwave signal with an oscillator, splitting the microwave signal into the plurality of drive signals, and amplifying each of the plurality of drive signals into a corresponding one of a plurality of amplified signals. Said coupling includes coupling the plurality of amplified signals into the microwave cavity, and said phase-shifting occurs prior to said amplifying.
(N) In either one of the methods denoted (L) and (M), the method further includes measuring the temperature of the waste mixture with a thermocouple.
(O) In any one of the methods denoted (L) to (N), the method further includes recording a thermal image stream of the waste mixture using an infrared camera.
(P) In any one of the methods denoted (L) to (O), the method further includes measuring thermally-emitted electromagnetic radiation from the waste mixture using a microwave radiometer.
(Q) In any of the methods for processing a waste mixture denoted (L)-(P), the method further includes stirring the waste mixture with an auger.
(R) In any of the methods for processing a waste mixture denoted (L)-(Q), the method further includes adding one or more additives to the waste mixture to increase thermal conductivity of the waste mixture.
(S) A system for processing a waste mixture includes a microwave power generator, a pyrolysis reactor having a plurality of microwave probes connected to the microwave power generator and configured to drive electromagnetic energy that heats the waste mixture inside the pyrolysis reactor and produce bio-oil. The system also includes a bio-oil upgrade element for producing a liquid fuel from the bio-oil.
(T) In the system denoted (S), the system further includes an electric generator for at least partially powering the microwave power generator using the liquid fuel.
This application claims priority to U.S. Provisional Patent Application No. 63/090,460, filed Oct. 12, 2020, the entirety of which is incorporated herein by reference.
This invention was made with government support under grant number W911NF-18-1-0203 awarded by ARMY/ARO. The government has certain rights in the invention.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US2021/054597 | 10/12/2021 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 63090460 | Oct 2020 | US |
