1. Field of the Invention
The present invention relates to plasma generators, and more particularly to devices having a nozzle that discharges a plasma plume which can be generated using microwaves.
2. Discussion of the Related Art
In recent years, the progress on producing plasma has been increasing. Typically, plasma consists of positive charged ions, neutral species and electrons. In general, plasmas may be subdivided into two categories: thermal equilibrium and thermal non-equilibrium plasmas. Thermal equilibrium implies that the temperature of all species including positive charged ions, neutral species, and electrons, is the same.
Plasmas may also be classified into local thermal equilibrium (LTE) and non-LTE plasmas, where this subdivision is typically related to the pressure of the plasmas. The term “local thermal equilibrium (LTE)” refers to a thermodynamic state where the temperatures of all of the plasma species are the same in the localized areas in the plasma.
A high plasma pressure induces a large number of collisions per unit time interval in the plasma, leading to sufficient energy exchange between the species comprising the plasma, and this leads to an equal temperature for the plasma species. A low plasma pressure, on the other hand, may yield one or more temperatures for the plasma species due to insufficient collisions between the species of the plasma.
In non-LTE, or simply non-thermal plasmas, the temperature of the ions and the neutral species is usually less than 100° C., while the temperature of electrons can be up to several tens of thousand degrees in Celsius. Therefore, non-LTE plasma may serve as highly reactive tools for powerful and also gentle applications without consuming a large amount of energy. This “hot coolness” allows a variety of processing possibilities and economic opportunities for various applications. Powerful applications include metal deposition system and plasma cutters, and gentle applications include plasma surface cleaning systems and plasma displays.
One of these applications is plasma sterilization, which uses plasma to destroy microbial life, including highly resistant bacterial endospores. Sterilization is a critical step in ensuring the safety of medical and dental devices, materials, and fabrics for final use. Existing sterilization methods used in hospitals and industries include autoclaving, ethylene oxide gas (EtO), dry heat, and irradiation by gamma rays or electron beams. These technologies have a number of problems that must be dealt with and overcome and these include issues as thermal sensitivity and destruction by heat, the formation of toxic byproducts, the high cost of operation, and the inefficiencies in the overall cycle duration. Consequently, healthcare agencies and industries have long needed a sterilizing technique that could function near room temperature and with much shorter times without inducing structural damage to a wide range of medical materials including various heat sensitive electronic components and equipment.
These changes to new medical materials and devices have made sterilization very challenging using traditional sterilization methods. One approach has been using a low pressure plasma (or equivalently, a below-atmospheric pressure plasma) generated from hydrogen peroxide. However, due to the complexity and the high operational costs of the batch process units needed for this process, hospitals use of this technique has been limited to very specific applications. Also, low pressure plasma systems generate plasmas having radicals that are mostly responsible for detoxification and partial sterilization, and this has negative effects on the operational efficiency of the process.
It is also possible to generate an atmospheric plasma such as for treating surfaces, such as pre-treatment of plastic surfaces. One method of generating an atmospheric plasma is taught by U.S. Pat. No. 6,677,550 (Förnsel et al.). Förnsel et al. disclose a plasma nozzle in
Another method of generating an atmospheric plasma is described in U.S. Pat. No. 3,353,060 (Yamamoto et al.). Yamamoto et al disclose a high frequency discharge plasma generator where high frequency power is supplied into an appropriate discharge gas stream to cause high-frequency discharge within this gas stream. This produces a plasma flame of ionized gas at an extremely high temperature. Yamamoto et al. uses a retractable conductor rod 30 and the associated components shown in
Using microwaves is one of the conventional methods for generating plasma. However, existing microwave techniques generate plasmas that are not suitable, or at best, highly inefficient for sterilization due to one or more of the following drawbacks: their high plasma temperature, a low energy field of the plasma, a high operational cost, a lengthy turnaround time for sterilization, a high initial cost for the device, or they use a low pressure (typically below atmospheric pressure) using vacuum systems. Thus, there is a need for a sterilization system that: 1) is cheaper than currently available sterilization systems, 2) uses nozzles that generate a relatively cool plasma and 3) operates at atmospheric pressure so no vacuum equipment is needed.
The present invention provides various systems and methods for generating a relatively cool microwave plasma using atmospheric pressure. These systems have a low per unit cost and operate at atmospheric pressure with lower operational costs, lower power consumption and a short turnaround time for sterilization. A relatively cool microwave plasma is produced by nozzles which operate, unlike existing plasma generating systems, at atmospheric pressure with an enhanced operational efficiency.
As opposed to low pressure plasmas associated with vacuum chambers, atmospheric pressure plasmas offer a number of distinct advantages to users. Atmospheric pressure plasma systems use compact packaging which makes the system easily configurable and it eliminates the need for highly priced vacuum chambers and pumping systems. Also, atmospheric pressure plasma systems can be installed in a variety of environments without needing additional facilities, and their operating costs and maintenance requirements are minimal. In fact, the main feature of an atmospheric plasma sterilization system is its ability to sterilize heat-sensitive objects in a simple-to-use manner with faster turnaround cycles. Atmospheric plasma sterilization can achieve a direct effect of reactive neutrals, including atomic oxygen and hydroxyl radicals, and plasma generated UV light, all of which can attack and inflict damage to bacteria cell membranes. Thus, applicants recognized the need for devices that can generate an atmospheric pressure plasma as an effective and low-cost sterilization device.
According to one aspect of the present invention, a microwave plasma nozzle for generating plasma from microwaves and a gas is disclosed. The microwave plasma nozzle includes a gas flow tube for having a gas flow therethrough, where the gas flow tube has an outlet portion including a material that is substantially transparent to microwaves. The outlet portion refers to a section including the edge and a portion of the gas flow tube in proximity to the edge. The nozzle also includes a rod-shaped conductor disposed in the gas flow tube. The rod-shaped conductor can include a tip disposed in proximity to the outlet portion of the gas flow tube. It is also possible to include a vortex guide disposed between the rod-shaped conductor and the gas flow tube. The vortex guide has at least one passage that is angled with respect to a longitudinal axis of the rod-shaped conductor for imparting a helical shaped flow direction around the rod-shaped conductor to a gas passing along the passage. It is possible to provide the passage or passages inside the vortex guide and/or the passage(s) can be a channel disposed on an outer surface of the vortex guide so that they are between the vortex guide and the gas flow tube.
According to another aspect of the present invention, a microwave plasma nozzle for generating plasma from microwaves and a gas comprises a gas flow tube for having a gas flow therethrough, a rod-shaped conductor disposed in the gas flow tube and a vortex guide disposed between the rod-shaped conductor and the gas flow tube. The rod-shaped conductor has a tip disposed in proximity to the outlet portion of the gas flow tube. The vortex guide has at least one passage angled with respect to a longitudinal axis of the rod-shaped conductor for imparting a helical shaped flow direction around the rod-shaped conductor to a gas passing along the passage.
According to still another aspect of the present invention, a microwave plasma nozzle for generating plasma from microwaves and a gas comprises a gas flow tube for having a gas flow therethrough, a rod-shaped conductor disposed in the gas flow tube, a grounded shield for reducing microwave power loss through the gas flow tube, and a position holder disposed between the rod-shaped conductor and the grounded shield for securely holding the rod-shaped conductor relative to the grounded shield. The rod-shaped conductor has a tip disposed in proximity to the outlet portion of the gas flow tube. The grounded shield has a hole for receiving a gas flow therethrough and is fitted into the exterior surface of the gas flow tube.
According to yet another aspect of the present invention, an apparatus for generating plasma is provided. The apparatus comprises a microwave cavity having a wall forming a portion of a gas flow passage; a gas flow tube for having a gas flow therethrough, the gas flow tube having an inlet portion connected to the microwave cavity and the gas flow tube has an outlet portion including a dielectric material. The nozzle also includes a rod-shaped conductor disposed in the gas flow tube. The rod-shaped conductor has a tip disposed in proximity to the outlet portion of the gas flow tube. A portion of the rod-shaped conductor is disposed in the microwave cavity and can receive microwaves passing therethrough. The microwave plasma nozzle can also include a means for reducing a microwave power loss through the gas flow tube. The means for reducing a microwave power loss can include a shield that is disposed adjacent to a portion of the gas flow tube. The shield can be supplied to the exterior and/or interior of the gas flow tube. The nozzle can also be provided with a grounded shield disposed adjacent to a portion of the gas flow tube. A shielding mechanism for reducing microwave loss through the gas flow tube can also be provided. The shielding mechanism may be an inner shield tube disposed within the gas flow tube or a grounded shield covering a portion of the gas flow tube.
According to another aspect of the present invention, a plasma generating system comprises a microwave cavity and a nozzle operatively connected to the microwave cavity. The nozzle includes a gas flow tube that has an outlet portion made of a dielectric material, a rod-shaped conductor disposed in the gas flow tube, a grounded shield connected to the microwave cavity and disposed on an exterior surface of the gas flow tube, and a position holder disposed between the rod-shaped conductor and the grounded shield for securely holding the rod-shaped conductor relative to the grounded shield. The rod-shaped conductor has a tip disposed in proximity to the outlet portion of the gas flow tube and a portion disposed in the microwave cavity to collect microwave. The grounded shield reduces microwave power loss through the gas flow tube and has a hole for receiving a gas flow therethrough.
According to another aspect of the present invention, a plasma generating system is disclosed. The plasma generating system comprises a microwave generator for generating microwave; a power supply connected to the microwave generator for providing power thereto; a microwave cavity having a wall forming a portion of a gas flow passage; a waveguide operatively connected to the microwave cavity for transmitting microwaves thereto; an isolator for dissipating microwaves reflected from the microwave cavity; a gas flow tube for having a gas flow therethrough, the gas flow tube having an outlet portion including a dielectric material, the gas flow tube also having an inlet portion connected to the microwave cavity; and a rod-shaped conductor disposed in the gas flow tube. The rod-shaped conductor has a tip disposed in proximity to the outlet portion of the gas flow tube. A portion of the rod-shaped conductor is disposed in the microwave cavity for receiving or collecting microwaves. A vortex guide can also be disposed between the rod-shaped conductor and the gas flow tube. The vortex guide has at least one passage that is angled with respect to a longitudinal axis of the rod-shaped conductor for imparting a helical shaped flow direction around the rod-shaped conductor to a gas passing along the passage.
According to another aspect of the present invention, a plasma generating system is disclosed. The plasma generating system comprises: a microwave generator for generating microwave; a power supply connected to the microwave generator for providing power thereto; a microwave cavity; a waveguide operatively connected to the microwave cavity for transmitting microwaves to the microwave cavity; an isolator for dissipating microwaves reflected from the microwave cavity; a gas flow tube for having a gas flow therethrough, the gas flow tube having an outlet portion including a dielectric material; a rod-shaped conductor disposed in the gas flow tube; a grounded shield connected to the microwave cavity and configured to reduce a microwave power loss through the gas flow tube; and a position holder disposed between the rod-shaped conductor and the grounded shield for securely holding the rod-shaped conductor relative to the grounded shield. The rod-shaped conductor has a tip disposed in proximity to the outlet portion of the gas flow tube. A portion of the rod-shaped conductor is disposed in the microwave cavity for receiving or collecting microwaves. The ground shield has a hole for receiving a gas flow therethrough and is disposed on an exterior surface of the gas flow tube.
According to yet another aspect of the present invention, a method for generating plasma using microwaves is provided. The method comprises the steps of providing a microwave cavity; providing a gas flow tube and a rod-shaped conductor disposed in an axial direction of the gas flow tube; positioning a first portion of the rod-shaped conductor adjacent an outlet portion of the gas flow tube and disposing a second portion of the rod-shaped conductor in the microwave cavity; providing a gas to the gas flow tube; transmitting microwaves to the microwave cavity; receiving the transmitted microwaves using at least the second portion of the rod-shaped conductor; and generating plasma using the gas provided in the step of providing a gas to the gas flow tube and by using the microwaves received in the step of receiving.
These and other advantages and features of the invention will become apparent to those persons skilled in the art upon reading the details of the invention as more fully described below.
The microwave supply unit 11 provides microwaves to the microwave cavity 24 and may include: a microwave generator 12 for generating microwaves; a power supply for supplying power to the microwave generator 14; and an isolator 15 having a dummy load 16 for dissipating reflected microwaves that propagates toward the microwave generator 12 and a circulator 18 for directing the reflected microwaves to the dummy load 16.
In an alternative embodiment, the microwave supply unit 11 may further include a coupler 20 for measuring fluxes of the microwaves; and a tuner 22 for reducing the microwaves reflected from the microwave cavity 24. The components of the microwave supply unit 11 shown in
At least some parts of an outlet portion of the gas flow tube 40 can be made from conducting materials. The conducting materials used as part of the outer portion of the gas flow tube will act as a shield and it will improve plasma efficiencies. The part of the outlet portion using the conducting material can be disposed, for example, at the outlet edge of the gas flow tube.
The gas flow tube 40 provides mechanical support for the overall nozzle 26 and may be made of any material that microwaves can pass through with very low loss of energy (substantially transparent to microwaves). The material may be preferably quartz or other conventional dielectric material, but it is not limited thereto.
The vortex guide 36 has at least one passage or channel 38. The passage 38 (or passages) imparts a helical shaped flow direction around the rod-shaped conductor 34 to the gas flowing through the tube as shown in
In
Referring back to
In a second alternative embodiment, the portion 53 of the gas flow tube 54 may be made of a dielectric material, and the portion 55 may include two sub-portions: a sub-portion made of a dielectric material near the outlet portion of the gas flow tube 54 and a sub-portion made of a conducting material. In a third alternative embodiment, the portion 53 of the gas flow tube 54 may be made of a dielectric material, and the portion 55 may include two sub-portions: a sub-portion made of a conducting material near the outlet portion of the gas flow tube 54 and a sub-portion made of a dielectric material. As in the case of
As illustrated in
The main heating mechanism applied to the nozzles shown in FIGS. 2 and 4A-4C is the microwaves that are focused and discharged at the tip of the rod-shaped conductor, where the nozzles can produce non-LTE plasmas for sterilization. The temperature of the ions and the neutral species in non-LTE plasmas can be less than 100° C., while the temperature of electrons can be up to several tens of thousand degrees in Celsius. To enhance the electron temperature and increase the nozzle efficiency, the nozzles can include additional mechanisms that electronically excite the gas while the gas is within the gas flow tube, as illustrated in
Referring back to
As illustrated in
It is well known that some precious metals are good microwave conductors. Thus, to reduce the unit price of the device without compromising the performance of the rod-shaped conductor, the skin layer of the rod-shaped conductor can be made of precious metals that are good microwave conductors while cheaper conducting materials can be used for inside of the core.
As illustrated in
It is noted that the rod-shaped conductor 502 may be one of the various embodiments illustrated in
The gas flow tube of 508 (
While the present invention has been described with reference to the specific embodiments thereof, it should be understood that the foregoing relates to preferred embodiments of the invention and that modifications may be made without departing from the spirit and scope of the invention as set forth in the following claims.
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PCT/US2005/023886 | 7/7/2005 | WO | 00 | 1/4/2007 |
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WO2006/014455 | 2/9/2006 | WO | A |
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