Patent Application
20130343147
The present invention relates to a mixing device. The present invention further relates to a method for mixing. In particular, the present invention relates to a mixing device for mixing two or more gases. The mixing device may be part of a large apparatus, such as a production apparatus.
When mixing gases wherein at least one gas is corrosive to the mixing device, there is a need for protecting the mixing device. This may be achieved using specific corrosion resistant metallic materials or by applying lining or coating to the interior of the mixing device. In some applications the temperature is to high for the safe use of metallic materials or polymeric materials. The present invention provides a device that reduces at least these problems.
In a first aspect, the present invention relates to a mixing device for mixing a first gas with a second gas wherein at least one of the first or the second gas is corrosive, the mixing device comprising a first inlet section, a second inlet section, an outlet section, a first duct sheet, a second duct sheet, a distribution chamber, at least two injection ducts arranged in said first duct sheet and at least two mixing ducts arranged in said second duct sheet. The space between the first duct sheet and the second duct sheet forms the distribution chamber and each of the at least two injection ducts corresponds to one of said at least two mixing ducts. This means that each injection duct is in flow relation to a mixing duct, such that each pair of ducts will perform mixing of the two gasses when the gasses stream through the mixing ducts.
The arrangement of the mixing device is contemplated to allow the gases to mix by means of the injection principle, and in the case where the two gasses have different temperatures, the temperature of the relative colder gas will increase during the injection mixing process in each mixing duct. This is advantageous if the colder gas is a wet corrosive gas, as it can raise the temperature of the corrosive gas above its dew-point, whereby the need for corrosion resistant materials on the inner surface of the equipment downstream of the mixing duct is reduced or removed. In an embodiment of the invention, the mixing device itself is however at least partly made of ceramic materials in order to withstand corrosion from at least one corrosive gas of the two gasses to be mixed.
In an embodiment of the invention, the first and the second duct sheets, the distribution chamber and the at least two injection ducts and corresponding mixing ducts are at least partly made of ceramic materials, to protect the equipment against corrosion induced by one or both the gasses.
In a further embodiment of the invention, the circumference of the outlet of each of the at least two injection ducts is equal to or smaller than the circumference of the corresponding mixing duct and each injection duct outlet centre-line is arranged in an angle of 0° to 90° to the corresponding mixing duct inlet centre-line. These restrictions to the size of corresponding duct pairs and of their centre-lines according to this embodiment of the invention, provides that substantially all the gas flow leaving an injection duct further on streams through its corresponding mixing duct and when doing so it draws the other gas stream through the mixing duct, thereby performing an injection.
In an embodiment, the centre line relationship is further restricted so that each injection duct outlet centre-line is arranged substantially parallel to the corresponding mixing duct inlet centre-line and said circumference of the outlet of each of the at least two injection ducts is arranged within the circumference of the inlet of the corresponding mixing duct in cross sectional view. Thus, the gas flow from the injection duct is not forced to change direction when entering the corresponding mixing duct, and possible deflection of the injection gas flow by the mixing duct edges is minimized. These restrictions enables a further embodiment where the at least two injection ducts are arranged partly within the corresponding mixing ducts, whereby each of the at least two mixing ducts overlaps the corresponding injection ducts. This ensures that there is no risk of deflection of the injection gas flow stream when leaving the injection duct and entering the mixing duct, but still the injection gas flow stream can draw the other gas into the mixing duct as there is a gap between the injection duct outlet circumference and the mixing duct inlet circumference.
Instead of tubes, the injection ducts as well as the mixing ducts can be formed as bores in the first and the second duct sheets in further embodiments. However, if the injection ducts are to be arranged partly within the mixing ducts, the injection ducts off course have to be formed at least partly as tubes.
In an embodiment of the invention, the two inlet sections and the outlet section are arranged such that the flow direction of the first gas in the first inlet section is substantially perpendicular to the flow direction of the second gas. This embodiment allows for a relative simple construction of the mixing device.
In a further embodiment either the first or the second gas is a relative cold gas (in this context relative means one of the two gasses relative to the other of the two gasses), with a temperature below its dew point and the other gas is a relative hot gas with a temperature above its dew point, and the condensate of either or both the first and the second gas is corrosive. In a further embodiment of the invention, the mixing zone is formed within each of said at least two mixing ducts and the gas leaving said at least two mixing ducts has an average temperature above the dew point of the perfectly mixed gas. This embodiment ensures that even though one of the two gasses to be mixed has a temperature below its dew point, which means that it may be corrosive, the mix of the two gasses has a temperature above the dew point of the perfectly mixed gas which minimizes the corrosive properties. Mixing of the two gas streams starts just before the inlet of the mixing ducts, or in the mixing ducts, but a perfect mix which ensures that all droplets have vaporised may not have taken place until a distance after the mixing duct outlets. Therefore the gas stream leaving the mixing ducts may be corrosive when passing this distance and the mixing ducts as well as the duct or channel material in contact with the gas stream a distance after the mixing ducts may be made of corrosion resistant materials. These corrosion resistant materials can be ceramic materials.
In an embodiment of the invention, the corrosion resistant materials can comprise at least one of: silicon carbide based materials, including reaction sintered, nitride bonded oxide bonded and oxynitride bonded types; oxide based materials, including types based on silica or alumina; or silicate and borosilicate based materials, including glass, wherein said materials can be either impermeable or permeable to gas and liquid.
In a further embodiment of the invention, at least one of the first or the second inlet section comprises a circumferential crevice adapted to pass a purge gas into said first or second inlet section. As this purge gas enters circumferential, it can contribute to a corrosion protection of the equipment as it can wrap a non-corrosive purge gas around a corrosive process gas, such that the corrosive process gas is not in contact with the surrounding duct or channel material, hence the corrosion protection by means of for instance ceramic material can be reduced or omitted in the area where the purge gas isolates the material from the corrosive gas.
In a second aspect, the present invention is a method for mixing a first gas and a second gas, the method comprises the steps of providing a mixing device for mixing the first gas with the second gas, the mixing device comprises: A first inlet section, a second inlet section and an outlet section; a first duct sheet a second duct sheet and a distribution chamber; at least two injection ducts arranged in said first duct sheet and at least two mixing ducts arranged in said second duct sheet, wherein the space between the first duct sheet and the second duct sheet forms the distribution chamber. In a following step a first flow comprising the first gas is provided at the first inlet section and a second flow comprising the second gas is provided at the second inlet section and in a following step the first gas and the second gas is mixed in a mixing zone formed within each of the at least two mixing ducts. One of the two gasses (the first and the second gas) is a relative cold corrosive gas with a temperature below its dew point and the other gas is a relative hot corrosive gas with a temperature above its dew point. Therefor the mixing device is at least partly made of ceramic materials which are able to withstand the corrosion of the gas.
In an embodiment of this second aspect of the invention, the first and the second duct sheets, the distribution chamber, the at least two injection ducts and their corresponding mixing ducts are made of corrosion resistant ceramic materials.
In a further embodiment, the first gas is a relative cold corrosive gas with a temperature below its dew point and the second gas is a relative hot corrosive gas with a temperature above its dew point. Yet a further embodiment specifies that the temperature of the first gas in the first inlet section is in the range of 0° C.-200° C., preferably in the range of 145° C.-180° C. and the second gas has a temperature in the second inlet section in the range of 300° C.-600° C., preferably in the range of 360° C.-450° C.
In an embodiment of the invention, the first gas and the second gas are mixed by means of injection.
In yet a further embodiment of the invention, the temperature of the mixed gas after the outlet section is above the dew point of the perfectly mixed gas. In this context, perfectly mixed gas means the gas mixed of the first and the second gas where the temperature and the content of the gas is homogenous. The mixture of the first and the second gas is not necessarily entirely homogenous right after leaving the mixing zone, the temperature and the content of the mixture may vary slightly in different areas of the duct right after the mixing zone. Therefore it can be necessary to have corrosion resistant material in the duct in a distance after the mixing zone, the distance can vary depending of the process parameters.
In a further specific embodiment of the invention, the first gas comprises SO3 and H2O and has a temperature below the H2SO4 dew point, and said gas thus comprises droplets or mist of the liquid phase of the gas.
In a further embodiment of the invention, the mixing device is used in a plant for production of sulphuric acid.
The features and advantages mentioned in relation to the first and second aspect may apply equally to the other aspects of the present invention.
The present invention will be discussed in more detail with reference to the embodiments in the drawings in which:
A first gas 02 enters the mixing device via the first inlet section and flows into the distribution chamber. A second gas 03 enters the mixing device via the second inlet section and flows into the injection ducts. Mixing of the first and the second gas takes place inside the mixing ducts as the second gas flows from each of the injection ducts into the corresponding mixing ducts and by means of the injection effect the first gas is drawn along into each mixing duct. From the mixing ducts, the fully or partly mixed gas 04 flows to the outlet section.
The mixing device may be partly or fully lined with or constructed by a corrosion and temperature resistant material such as a ceramic material. The embodiment according to
In an other embodiment of the invention, only the injection ducts 27 are in the form of tubes, whereas the mixing ducts 28 are formed as bores in the second duct sheet 26. This embodiment is simpler than the embodiment according to
On
On
In cases (not shown on the figures) where the hot gas entering the mixing device has a composition which results in a dew point for any kind of corrosive species (e.g. mineral- or organic acids), the hot gas inlet to the mixing device can be constructed accordingly. In one embodiment the steel duct carrying the hot gas to the mixing device is overlapping a distance into the brick lined inlet section. A circumferential crevice is present between the steel duct and the inside surface of the brick lining. A purge gas is passed through this circumferential crevice. The purge gas ensures that hot gas cannot enter the area around the transition from brick lining to unprotected steel duct. The temperature of the purge gas shall be above the given dew point temperature of the hot gas. In another embodiment, the steel duct for the hot gas is overlapping a distance into the brick lined inlet section, leading to the first tube sheet. A circumferential crevice is present between the steel duct and the inside surface of the brick lining. The crevice is filled with insulation material which is attached to the outside surface of the steel duct. The steel duct is connected to the brick lined duct by a flange ring. This ring is positioned a distance from the end of the steel duct.
As described, to resist corrosion from condensate in the gas, the mixing device is constructed and/or lined with corrosion and temperature resistant ceramic materials in those sections of the device in contact with wet gas and where the temperature is at the same time too high for the use of metallic and polymeric materials. Applicable ceramic material types includes, but are not limited to:
Ceramic materials which are either impermeable or permeable to gas and liquid can be used.
In one embodiment, the mixing device works in two stages, in the first stage the device creates a distribution of hot gas and wet gas, which minimizes the influence of entrance effects (e.g. upstream bends, constraints etc.) and at the same time ensures a homogeneous gas distribution in the distribution chamber. The gasses are initially kept separate as the hot gas enters through the injection ducts and the wet gas distributes in the distribution chamber. The chamber is designed in such a manner that the cold wet gas distributes evenly in the entire chamber. In the second stage, a local mixing of the two gasses takes place inside each of the individual mixing ducts. These ducts are designed for optimization of mixing and minimization of wet gas pressure drop. The minimization of wet gas pressure drop is achieved by an injector design of the mixing ducts inlet region. This principle works for the described embodiments irrespective of whether the injection ducts are overlapping inside the mixing ducts or not.
1. A mixing device for mixing a first gas with a second gas wherein at least one of the first or the second gas is corrosive, the mixing device comprising:
2. A mixing device according to feature 1, wherein the first and the second duct sheets, the distribution chamber and the at least two injection ducts and corresponding mixing ducts are at least partly made of ceramic materials.
3. A mixing device according to any of the preceding features, wherein the circumference of the outlet of each of said at least two injection ducts is equal to or smaller than the circumference of the corresponding said mixing duct, each injection duct outlet centre-line is arranged in an angle of 0° to 90° to the corresponding mixing duct inlet centre-line.
4. A mixing device according to any of the preceding features, wherein each injection duct outlet centre-line is arranged substantially parallel to the corresponding mixing duct inlet centre-line and said circumference of the outlet of each of the at least two injection ducts is arranged within said circumference of the corresponding mixing duct in cross sectional view.
5. A mixing device according to any of the preceding features, wherein each of said at least two injection ducts are formed by an injection tube arranged in the first duct sheet.
6. A mixing device according to any of the preceding features, wherein each of said at least two mixing ducts are formed by a mixing tube arranged in the second duct sheet and the circumference of the outlet of each of said at least two injection ducts is equal to or smaller than the circumference of the corresponding said mixing tube.
7. A mixing device according to any of the features 1-4 or 6, wherein each of said at least two injection ducts are formed by a bore in the first duct sheet.
8. A mixing device according to any of the features 1-5 or 7, wherein each of said at least two mixing ducts are formed by a bore in the second duct sheet.
9. A mixing device according to any of the features 1-6 or 8, wherein the circumference of the outlet of each said at least two injection tubes is smaller than the circumference of the inlet of the corresponding mixing duct and each of the at least two injection tubes are arranged partly within the corresponding mixing duct, whereby each of the at least two mixing ducts partly overlaps the corresponding injection tube in an axial direction.
10. A mixing device according to any of the preceding features, wherein said first inlet section, said second inlet section and said outlet section is arranged such that the flow direction of the first gas in the first inlet section is substantially perpendicular to the flow direction of the second gas in the second inlet section.
11. A mixing device according to any of the preceding features, wherein either the first or the second gas is a relative cold gas with at temperature below its dew point and the other gas is a relative hot gas with a temperature above its dew point, and the condensate of either or both the first and the second gas is corrosive.
12. A mixing device according to any of the preceding features, wherein a mixing zone is formed within each of said at least two mixing ducts and the gas leaving said at least two mixing ducts has an average temperature above the dew point of the perfectly mixed gas.
13. A mixing device according to any of the preceding features, wherein said corrosion resistant ceramic materials comprises at least one of
14. A mixing device according to any of the preceding features, wherein at least one of the first or the second inlet section comprises a circumferential crevice adapted to pass a purge gas into said first or second inlet section.
15. A method for mixing a first gas and a second gas, the method comprising the steps of:
16. The method according to feature 15, wherein the first and the second duct sheets, the distribution chamber and the at least two injection ducts and corresponding mixing duct are made of corrosion resistant ceramic materials.
17. The method according to feature 15 or 16, wherein the first gas is a relative cold corrosive gas with at temperature below its dew point and the second gas is a relative hot corrosive gas with a temperature above its dew point.
18. The method according to feature 17, wherein the first gas has a temperature in the first inlet section in the range of 0° C.-200° C., preferably in the range of 145° C.-180° C. and the second gas has a temperature in the second inlet section in the range of 300° C.-600° C., preferably in the range of 360° C.-450° C.
19. The method according to any of the features 15-18, wherein the first gas and the second gas are mixed in the mixing zones by means of injection.
20. The method according to any of the features 15-19, wherein the temperature of the mixed gas after the outlet section is above the dew point of the perfectly mixed gas.
21. The method according to any of the features 15-20, wherein the first gas comprises SO3 and H2O and has a temperature below the H2SO4 dew point, and said gas thus comprises droplets of the liquid phase of the gas.
22. Use of a mixing device according to any of the features 1-14 for a Sulphuric-Acid plant.
The mixing device can be used for sulphuric acid producing plants, in which SO3 and H2O containing process gas may comprise sulphuric acid mist or droplets in certain sections of the process. This may be the case when the temperature is below the sulphuric acid dew point for a given gas composition. Handling such corrosive gasses most often requires use of expensive materials such as high alloyed steels or alloys, fluoropolymers or acid resistant refractory.
As preparation for certain unit operations in these plants, it is therefore desirable to dry op the wet corrosive gas. This makes the gas suitable for processing in e.g. unprotected carbon/low alloy steel equipment and ducting, which most often represents a much cheaper construction.
In cases where the dew point temperature is very high, traditional heat exchangers, constructed in acid resistant alloys or polymeric materials cannot sustain the conditions or have a limited operation window. In those cases the proposed mixing device according to the invention can be used safely and with much more flexibility for heating and drying the wet process gas.
The dried and heated process gas exits the mixing device at a temperature somewhat above the dew point temperature. The gas is then heated further to approx. 390° C. in a regular heat exchanger made in carbon steel or low alloy steel.
Downstream of this heat exchanger about ⅓ of the hot gas volume is recycled back into the mixing device. In this example the hot gas is let in through the inlet tube sheet and into the distribution chamber. An air blower is used to drag the recycle from the main stream and force it into the mixing device.
| Number | Date | Country | Kind |
|---|---|---|---|
| PCT EP2011/001545 | Mar 2011 | EP | regional |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2012/001279 | 3/23/2012 | WO | 00 | 9/9/2013 |
