Mixtures composed of monocarboxy-functionalized dialkylphosphinic acid salts, their use und a process for their preparation

Abstract

The invention relates to mixtures composed of monocarboxy-functionalized dialkylphosphinic salts and of further components, which comprise A) from 98 to 100% by weight of monocarboxy-functionalized dialkylphosphinic salts of the formula (I)

Description

Claims

1. A mixture comprising: A) from 98 to 100% by weight of at least one monocarboxy-functionalized dialkylphosphinic salt of the formula (I)

2. The mixture as claimed in claim 1, comprising from 99.9995 to 100% by weight of the at least one monocarboxy-functionalized dialkylphosphinic salt of the formula (I) and from 0 to 0.0005% by weight of the at least one halogen.

3. The mixture as claimed in claim 1, wherein the at least one monocarboxy-functionalized dialkylphosphinic salt is aluminum(III) 3-(ethylhydroxyphosphinyl)propionate, calcium(II) 3-(ethylhydroxyphosphinyl)propionate, cerium(III) 3-(ethyl-hydroxyphosphinyl)propionate, zinc(II) 3-(ethylhydroxyphosphinyl)propionate, aluminum(III) 3-(ethylhydroxyphosphinyl)-2-methylpropionate, the methyl ester of aluminum(III) 3-(propylhydroxyphosphinyl)propionate, aluminum(III) 3-(propyl-hydroxyphosphinyl)propionate, zinc(II) 3-(propylhydroxyphosphinyl)propionate, aluminum(III) 3-(ethylhydroxyphosphinyl)butyrate, zinc(II) 3-(ethylhydroxy-phosphinyl)butyrate, aluminum(III) 3-(butylhydroxyphosphinyl)propionate, aluminum(III) 3-(propylhydroxyphosphinyl)butyrate, aluminum(III) 3-(ethylhydroxy-phosphinyl)pentanoate, aluminum(III) 3-(propylhydroxyphosphinyl)-2-methylpropionate, aluminum(III) 3-(butylhydroxyphosphinyl)-2-methylpropionate, aluminum(III) 3-(ethylhydroxyphosphinyl)-2-methylbutyrate, the methyl ester of aluminum(III) 3-(ethylhydroxyphosphinyl)propionate, the 2-hydroxyethyl ester of aluminum(III) 3-(ethylhydroxyphosphinyl)propionate, the 2-hydroxyethyl ester of zinc(II) 3-(ethylhydroxyphosphinyl)propionate, the 2,3-dihydroxypropyl ester of aluminum(III) 3-(ethylhydroxyphosphinyl)propionate, the allyl ester of aluminum(III) 3-(ethylhydroxyphosphinyl)-2-methylpropionate or a mixture thereof.

4. A process for preparation of a mixture as claimed in claim 1 comprising the steps of reacting, in a stage 1, hypophosphorous acid or a salt thereof (component C) of the formula II

5. The process as claimed in claim 4, wherein X is H and Z is H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, hydroxyethyl, or hydroxypropyl.

6. The process as claimed in claim 4, wherein, in stage 1, in a step 1, component C is reacted in the presence of at least one free-radical initiator with component E to give an alkylphosphonous acid in a resultant reaction solution and, in step 2, the resultant reaction solution is esterified with an alcohol to produce phosphonous ester in the resultant reaction solution and phosphonous ester is removed by distillation and, in a step 3, the resultant reaction solution is reacted in the presence of the at least one free-radical initiator or of a basic initiator with component D, and then stage 2 of the process is carried out.

7. The process as claimed in claim 6, wherein, in step 2, the alkylphosphonous acid is directly esterified with a linear or branched alcohol of the formula M-OH, where M is a linear or branched alkyl radical having from 1 to 10 carbon atoms.

8. The process as claimed in claim 7, wherein the alcohol is n-butanol, isobutanol, or ethylhexanol.

9. The process as claimed in claim 6, wherein component C is the ammonium or sodium salt of hypophosphorous acid.

10. The process as claimed in claim 4, wherein the at least one free radical initiator is a free-radical, anionic, cationic, or photochemical initiator.

11. The process as claimed in claim 4, wherein the at least one free radical initiator is a peroxide-forming compound, a peroxo compound, an azo compound or a mixture thereof.

12. The process as claimed in claim 4, wherein the at least one α,β-unsaturated carboxylic acid and at least one α,β-unsaturated carboxylic acid derivatives derivative are acrylic acid, methyl acrylate, ethyl acrylate, methacrylic acid, hydroxyethyl acrylate, crotonic acid, ethyl crotonate, tiglic acid (trans-2,3-dimethylacrylic acid), (trans-)2-pentenoic acid, furan-2-carboxylic acid, thiophene-2-carboxylic acid or a mixture thereof.

13. The process as claimed in claim 4, wherein the at least one olefin (component E) is ethylene, propylene, n-butene, isobutene, 1-hexene, 1-heptene, 1-octene, allyl alcohol, allylamine, allylbenzene, allylanisole, styrene, α-methylstyrene, 4-methylstyrene, vinyl acetate or a mixture thereof.

14. The process as claimed in claim 4, wherein the reaction of component C with component D, E or both takes place at a temperature of from 50 to 150° C.

15. A process for preparation of a mixture as claimed in claim 1, comprising the steps of m in stage 1 of the process, reacting component C, in a step 1, with a ketone to give 1-hydroxy-1-dialkylphosphinate, reacting the 1-hydroxy-1-dialkylphosphinate, in a step 2, in the presence of at least one free-radical initiator with component D, in a step 3, removing the ketone, and reacting the resultant reaction mixture, in a step 4, in the presence of the at least one free-radical initiator with component E, and then carrying out stage 2 of the process.

16. A process for preparation of a mixture as claimed in claim 1, comprising the steps of, in stage 1 of the process, reacting component C, in a step 1, with a ketone to give 1-hydroxy-1-dialkylphosphinate, reacting the 1-hydroxy-1-dialkylphosphinate, in a step 2, in the presence of at least one free-radical initiator with component E, in a step 3, removing the ketone, and reacting the resultant reaction mixture, in a step 4, in the presence of the at least one free-radical initiator with component D, and then carrying out stage 2 of the process.

17. The process as claimed in claim 4, wherein the metal compounds of stage 2 of are aluminum hydroxide, aluminum sulfates, zinc sulfate heptahydrate, magnesium chloride hexahydrate, calcium chloride dihydrate or a mixture thereof.

18. The process as claimed in claim 1, wherein the reaction in stage 2 takes place at a temperature of from 20 to 150° C.

19. A process of making a flame retardant or a flame retardant article comprising the step of adding a mixture as claimed in claim 1 to the flame retardant or flame retardant article during the manufacture of the flame retardant or the flame retardant article, wherein the flame retardant article is selected from the group consisting of flame-retardant molding compositions, flame-retardant moldings, flame-retardant films, flame-retardant filaments, and flame-retardant fibers.

20. The process as claimed in claim 19, wherein the flame retardant article comprises from 1 to 50% by weight of the mixture, from 1 to 99% by weight of a polymer or a mixture of the same, from 0 to 60% by weight of additives, and from 0 to 60% by weight of filler, where the entirety of the components always amounts to 100% by weight.

21. The process as claimed in claim 4, wherein the at least free radical initiator is selected from the group consisting of hydrogen peroxide, sodium peroxide, lithium peroxide, potassium persulfate, sodium persulfate, ammonium persulfate, sodium peroxodisulfate, potassium peroxoborate, peracetic acid, benzoyl peroxide, di-tert-butyl peroxide, peroxodisulfuric acid, azodiisobutyronitrile, 2,2′-azobis(2-amidinopropane) dihydrochloride, 2,2′-azobis(N,N′-dimethyleneisobutyramidine) dihydrochloride and mixtures thereof.

22. A flame retardant or flame retardant article made in accordance with the process of claim 20.