Claims
- 1. A modified aluminum oxy compound, obtained by a process that comprises reacting:an aluminum oxy compound(a) having a ratio of an intensity at 30 ppm(H2) to an intensity at 10 ppm(H1)[H2/H1] in an 27Al-solid NMR spectrum of less than 0.35, water(b), and a compound(c) having a hydroxy group selected from the group consisting of tertiary alcohols and alcohols substituted with a halogen atom, the alcohols substituted with a halogen being selected from the group consisting of alcohols indicated by the formula CR1R2R3—OH (wherein each of R1, R2 and R3 independently represents a hydrogen atom or hydrocarbon group having 1 to 20 carbon atoms, which is optionally substituted with a halogen atom, and they may be mutually the same or different), halogenated phenol compounds and silanol compounds; wherein the modified aluminum oxy compound has a ratio of an intensity at 30 ppm(M2) to an intensity at 10 ppm(M1)[M2/M1] in an 27Al-solid NMR spectrum of 0.60 or more, the molar ratio[(a)/(b)] of the aluminum oxy compound(a) to water(b) is 1/3 to 1/0.01, and the molar ratio [(a)/(c)] of the aluminum oxy compound(a) to the compound(c) is 1/3 to 1/0.01.
- 2. The modified aluminum oxy compound according to claim 1, wherein said aluminum oxy compound (a) is an aluminum oxy compound that is soluble in an aromatic hydrocarbon or an aliphatic hydrocarbon represented by the general formula(1) or (2) below: in which R indicates a hydrocarbon group having 1 to 20 carbon atoms, wherein the R groups may be the same or different; and m represents a number of 1 to 50.
- 3. The modified aluminum oxy compound according to claim 1, wherein the compound(c) is a member selected from the group consisting of halogenated phenol compounds, halogenated alcohol compounds and silanol compounds.
- 4. The modified aluminum oxy compound according to claim 3, wherein the compound(c) is a member selected from the group consisting of halogenated phenol compounds and silanol compounds.
- 5. A modified aluminum oxy compound, obtained by a process that comprises reacting:an aluminum oxy compound(a′) having a ratio of an intensity at 30 ppm(L2) to an intensity at 10 ppm(L1)[L2/L1] in an 27Al-solid NMR spectrum of not less than 0.35, which is obtained by reacting an aluminum oxy compound(a) having a ratio of an intensity at 30 ppm(H2) to an intensity at 10 ppm(H1)[H2/H1] in an 27Al-solid NMR spectrum of less than 0.35 and water(b); and a compound(c) having a hydroxy group selected from the group consisting of tertiary alcohols and alcohols substituted with a halogen atom, the alcohols substiuted with a halogen being selected from alcohols indicated by the formula CR1R2R3—OH (wherein each of R1, R2 and R3 independently represents a hydrogen atom or hydrocarbon group having 1 to 20 carbon atoms, which is optionally substituted with a halogen atom, and they may be mutually the same or different), halogenated phenol compounds and silanol compounds, wherein the modified aluminum oxy compound has a ratio of an intensity at 30 ppm(M2) to an intensity at 10 ppm(ml)[M2/M1] in an 27Al-solid NMR spectrum of 0.60 or more, the molar ratio[(a)/(b)] of the aluminum oxy copound(a) to water(b) is 1/3 to 1/0.01, and the molar ratio[(a)/(c)]]of the aluminum oxy compound(a) to the compound(c) is 1/3 to 1/0.01.
- 6. The modified aluminum oxy compound according to claim 5, wherein the ratio L2/L1 is not less than 0.35 and less than 0.90.
- 7. The modified aluminum oxy compound according to claim 5, wherein said aluminum oxy compound (a) is an aluminum oxy compound that is soluble in an aromatic hydrocarbon or an aliphatic hydrocarbon represented by the general formula (1) or (2) below: in which R indicates a hydrocarbon group having 1 to 20 carbon atoms, wherein the R groups may be the same or different; and m represents a number of 1 to 50.
- 8. The modified aluminum oxy compound according to claim 5, wherein the compound(c) is a member selected from the group consisting of halogenated phenol compounds, halogenated alcohol compounds and silanol compounds.
- 9. The modified aluminum oxy compound according to claim 8, wherein the compound(c) is a member selected from the group consisting of halogenated phenol compounds and silanol compounds.
- 10. A modified aluminum oxy compound, obtained by a process that comprises reacting:an aluminum oxy compound(a″) having a ratio of an intensity at 30 ppm(N2) to an intensity at 10 ppm(N1)[N2/N1] in an 27Al-solid NMR spectrum of not less than 0.35 obtained by reacting an aluminum oxy compound(a) having a ratio of an intensity at 30 ppm(H2) to an intensity at 10 ppm H1[H2/H1] in its 27Al-solid NMR spectrum of less than 0.35 and a compound(c) having a hydroxy group selected from the group consisting of tertiary alcohols and alcohols substituted with a halogen atom, the alcohol being selected from alcohols indicated by the formula CR1R2R3—OH (wherein each of R1, R2 and R3 independently represents a hydrogen atom or hydrocarbon group having 1 to 20 carbon atoms, which is optionally substituted with a halogen atom, and they may be mutually the same or different), halogenated phenol compounds and silanol compounds, with water(b), wherein the modified aluminum oxy compound has a ratio of an intensity at 30 ppm(M2) to an intensity at 10 ppm(M1)[M2/M1] in an 27Al-solid NMR spectrum of 0.60 or more, the molar ratio[(a)/(b)] of the aluminum oxy compound(a) to water(b) is 1/3 to 1/0.01, and the molar ratio[(a)/(c)]] of the aluminum oxy compound(a) to the compound(c) is 1/3 to 1/0.01.
- 11. The modified aluminum oxy compound according to claim 10, wherein the ratio N2/N1 is not less than 0.35 and less than 0.60.
- 12. The modified aluminum oxy compound according to claim 10, wherein said aluminum oxy compound (a) is an aluminum oxy compound that is soluble in an aromatic hydrocarbon or an aliphatic hydrocarbon represented by the general formula (1) or (2) below: in which R indicates a hydrocarbon group having 1 to 20 carbon atoms, wherein the R groups may be the same or different; and m represents a number of 1 to 50.
- 13. The modified aluminum oxy compound according to claim 10, wherein the compound(c) is a member selected from the group consisting of halogenated phenol compounds, halogenated alcohol compounds and silanol compounds.
- 14. The modified aluminum oxy compound according to claim 13, wherein the compound(c) is a member selected from the group consisting of halogenated phenol compounds and silanol compounds.
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of U.S. application Ser. No. 09/391,662, filed Sep. 7, 1999, now pending.
US Referenced Citations (11)
Foreign Referenced Citations (18)
Number |
Date |
Country |
19711304 |
Oct 1997 |
DE |
0269002 |
Jun 1988 |
EP |
0452156 |
Oct 1991 |
EP |
0561476 |
Sep 1993 |
EP |
0726271 |
Aug 1996 |
EP |
0 726 271 |
Aug 1996 |
EP |
0906914 |
Apr 1999 |
EP |
1081167 |
Mar 2001 |
EP |
001217016 |
Jun 2002 |
EP |
5819309 |
Feb 1983 |
JP |
60130604 |
Jul 1985 |
JP |
60260602 |
Dec 1985 |
JP |
63130601 |
Jun 1988 |
JP |
6136053 |
May 1994 |
JP |
6329714 |
Nov 1994 |
JP |
2693538 |
Sep 1997 |
JP |
9410180 |
May 1994 |
WO |
9532095 |
Nov 1995 |
WO |
Non-Patent Literature Citations (2)
Entry |
European Search Report dated Apr. 25, 2001. |
E. Lindner, et al., “Poly(Alumosiloxanes) as Matrixes for the Immobilization of Catalytically Active Ruthenium (II) Complexes”, Chem. Mater., vol. 10, No. 1, 1998, pp. 217-225. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
09/391662 |
Sep 1999 |
US |
Child |
09/661626 |
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US |