Claims
- 1. A resin for use as a binder in a non-aqueous printing ink which comprises a salt-free modified hydrocarbon resin based on monomers of unsaturated hydrocarbon fractions having a boiling range between 20.degree. and 230.degree. C. and containing at least 70% by weight of monoolefins including between 15 and 30% by weight of indenes and up to 30% by weight of diolefins said percentages being based on the total of the polymerisable monomers, and said hydrocarbon resin containing adducted thereto at most dibasic carboxylic acid units with 3 to 15 carbon atoms, the carboxylic groups of which are partially esterified with a polyhydric alcohol having 2 to 20 carbon atoms in such an amount that the modified hydrocarbon resin product contains from 0.01 to 0.7 ester groups of polyhydric alcohol based on each acid group originally present and said compositions has a melting point of at least about 130.degree. C.
- 2. A resin as claimed in claim 1 which contains up to 80%, referred to the ester groups of the polyhydric alcohol as defined in claim 1, of ester groups of monohydric alcohols having from 1 to 30 carbon atoms, the total of the ester groups being at most 90%, based on the acid groups originally present.
- 3. A resin as claimed in claim 1 wherein the polyhydric alcohol component contains between two alcoholic OH-groups a radical selected from the group consisting of (a) an unsubstituted straight chain alkylene having from 2 to 10 carbon atoms, (b) a straight chain alkylene having from 2 to 10 carbon atoms and also having one ro more substituents and (c) and alicyclic ring, wherein the substituents of (b) are selected from the group consisting of (1) alkyl having 1 to 3 carbon atoms, (2) alkylol having 1 to 3 carbon atoms (3) a combination of (1) and (2) and (4) an aryl having 6 to 10 carbon atoms and one or more OH-groups.
- 4. A resin as claimed in claim 1 wherein the modified hydrocarbon resin contains one or more polyhydric alcohols as an esterifying component in which at least one methylol group is bound to a tertiary carbon atom.
- 5. A resin as claimed in claim 1 wherein the alcohol component contains aliphatic straight-chained diols in such an amount that they contribute up to 20% of the total number of alcoholic hydroxyl groups.
- 6. A composition as claimed in claim 1 wherein the starting hydrocarbon resin is derived from a mixture of unsaturated hydrocarbon monomers from hydrocarbon fractions having a boiling point from 20.degree. to 230.degree. C. containing at least 70% by weight of aromatic monoolefinic units and at most 30% by weight of diolefin units, the percentages being based on the total of the polymerisable monomers.
- 7. A resin as claimed in claim 1 wherein the starting hydrocarbon resin is based on a mixture of unsaturated monomers containing at least 15% and at most 30% by weight of indenses, referred to the total weight of all polymerisable monomers, and has a molecular weight up to 2000, wherein the final resin contains from 0.1 to 7% by weight of the polyhydric alcohol component and wherein the carboxylic units are derived from a monoolefinically unsaturated mono- or dibasic carboxylic acid having 3 to 15 carbon atoms.
- 8. A resin as claimed in claim 1 wherein the amount of the carboxylic units as defined in claim 1 in the unesterified starting hydrocarbon resin as defined in claim 1 is from 0.5 to 40% by weight.
- 9. A composition comprising, in addition to the resin of claim 1, additional resins selected from the group consisting of modified or unmodified hydrocarbon resins, modified colophony, cumarone resins, indene resins, ester resins, unmodified phenol formaldehyde resins and phenol formaldehyde resins being colophony modified as binders.
- 10. A process for the preparation of a modified hydrocarbon resin as defined in claim 1 which comprises polymerising a mixture of unsaturated monomeric hydrocarbons having a boiling range between 20.degree. C. and 230.degree. C. and containing at least 70% by weight of monoolefins including between 15 and 30% by weight of indenes and up to 30% by weight of diolefins, said percentages being based on the total of the polymerisable monomers, whereafter the product is subjected to an addition reaction with a reactant selected from the group consisting of
- (a) olefinically unsaturated at most dibasic carboxylic acid units containing 3 to 15 carbon atoms followed by esterification with a polyhydric alcohol having 2 to 20 carbon atoms,
- (b) olefinically unsaturated esters of at most dibasic carboxylic acids containing 3 to 15 carbon atoms with polyhydric alcohols having 2 to 20 carbon atoms. wherein the carboxylic groups of said at most dicarboxylic acids are partially esterified with said polyhydric alcohol in such an amount that the modified hydrocarbon resin contains from 0.01 to 0.7 ester groups.
- 11. A process as claimed in claim 10 wherein the mixture of monomers as defined in claim 1, contains a substance selected from the group consisting of
- (a) up to 10% by weight, referred to the total weight of polymerizable monomers, of dienes.
- 12. A process as claimed in claim 10, wherein in embodiment (b) the ester is a monomeric ester of a compound selected from the group consisting of acrylic acid, methacrylic acid and maleic acid on one hand and trimethylolethane, trimethylolpropane, 1,3-dimethylpropanediol and pentaerythritol on the other hand.
Parent Case Info
This application is a continuation-in-part of U.S. application Ser. No. 483,418 filed June 26, 1974.
US Referenced Citations (12)
Continuation in Parts (1)
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Number |
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483418 |
Jun 1974 |
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