Claims
- 1. A polyurethane liquid polymer composition comprising a polyurethane oligomer and a heat activated free radical generating catalyst, said polyurethane oligomer having an equivalent ratio of NCO to active hydrogen from about 0.5/1 to about 2/1 and being prepared by reacting
- (a) an isocyanate-terminated prepolymer having a final free NCO content ranging from about 0.5% to about 30% which is the product of reacting
- (1) an organic polyisocyanate with
- (2) an isocyanate reactive group-containing unsaturated monomer selected from the group consisting of hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxyethyl acrylamide, hydroxypropyl acrylamide, hydroxyethyl methacrylamide, and mixtures thereof, with
- (b) a polyol reactant comprising
- (1) a high functionality polyol having an average equivalent weight of from about 75 to about 500 and an average functionality of at least about 3, said high functionality polyol being prepared by reacting an alkylene oxide, or a mixture of alkylene oxides, with a polyhydric initiator comprising a carbohydrate or a carbohydrate derivative, and
- (2) a chain extender having an average equivalent weight from about 31 to about 4,000 and an average functionality of about 2, said chain extender being employed in an amount ranging from about 20 to about 1,500 parts by weight per 100 parts by weight of said high functionality polyol.
- 2. The composition of claim 1, including at least one additional component selected from the group consisting of a reinforcing agent and a filler.
- 3. The composition of claim 2, wherein said filler is added in an amount ranging from about 20 to about 400 parts by weight per 100 parts by weight of said polyurethane oligomer.
- 4. The composition of claim 2, wherein said reinforcing agent is added in an amount ranging from about 10 to about 150 parts by weight per 100 parts by weight of said polyurethane oligomer.
- 5. The composition of claim 1, including a copolymerizable solvent in said polyurethane liquid polymer composition.
- 6. The composition of claim 5, wherein said copolymerizable solvent is styrene.
- 7. The composition of claim 1, wherein said polyurethane oligomer has an equivalent ratio of NCO to active hydrogen from about 0.7/1 to about 1.5/1.
- 8. The composition of claim 7, wherein said isocyanate-terminated prepolymer has a final free NCO content ranging from about 10% to about 20%, and said polyurethane oligomer has an equivalent ratio of NCO to active hydrogen from about 0.8/1 to about 1.2/1.
- 9. The composition of claim 1, wherein said unsaturated monomer is selected from the group consisting of hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, and mixtures thereof.
- 10. The composition of claim 1, wherein said heat activated free radical generating catalyst is a peroxide catalyst.
- 11. The composition of claim 11, wherein said peroxide catalyst is selected from the group consisting of t-butyl perbenzoate, t-butyl peroctoate, and mixtures thereof.
- 12. The composition of claim 1, wherein said high functionality polyol has an average equivalent weight of about 100 to about 200 and an average functionality of from about 3.3 to about 6 and is prepared by condensing an alkylene oxide selected from the group consisting of propylene oxide and mixtures of propylene oxide and ethylene oxide with a polyhydric initiator selected from the group consisting of a mixture of sucrose and an aliphatic triol, a mixture of dextrose and an aliphatic triol, and a mixture of a methyl glucoside with an aliphatic triol.
- 13. The composition of claim 1, wherein said chain extending agent is selected from the group consisting of dipropylene glycol, tripropylene glycol, and 2-ethyl-1,3-hexane diol.
- 14. The composition of claim 1, including a filler and wherein:
- (a) about 20 to about 400 parts by weight of said filler are employed,
- (b) said polyurethane oligomer has an equivalent ratio of NCO to active hydrogen from about 0.8/1 to about 1.2/1,
- (c) said isocyanate-terminated prepolymer has a final free NCO content ranging from about 10% to about 20%, and
- (d) said unsaturated monomer is selected from the group consisting of hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, and mixtures thereof.
- 15. The composition of claim 1, wherein said isocyanate-terminated prepolymer is prepared by employing toluene diisocyanate as said organic polyisocyanate.
- 16. The composition of claim 15, wherein said isocyanate-terminated prepolymer has a final free NCO content ranging from about 10% to about 20%, and said polyurethane oligomer has an equivalent ratio of NCO to active hydrogen from about 0.8/1 to about 1.2/1.
- 17. The composition of claim 16, wherein said heat activated free radical generating catalyst is a peroxide catalyst.
- 18. The composition of claim 17, wherein said high functionality polyol has an average equivalent weight of about 100 to about 200 and an average functionality of from about 3.3 to about 6 and is prepared by condensing an alkylene oxide selected from the group consisting of propylene oxide and mixtures of propylene oxide and ethylene oxide with a polyhydric initiator selected from the group consisting of a mixture of sucrose and an aliphatic triol, a mixture of dextrose and an aliphatic triol, and a mixture of a methyl glucoside with an aliphatic triol.
- 19. The composition of claim 18, including at least one additional component selected from the group consisting reinforcing agent and a filler.
Parent Case Info
This application is a continuation-in-part of copending application Ser. No. 203,213, filed Nov. 3, 1980, abandoned.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3368988 |
Sekmakas |
Feb 1968 |
|
4246391 |
Watson, Jr. |
Jan 1981 |
|
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
203213 |
Nov 1980 |
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