Patent Application
20160185923
This application is a continuation of International Application No. PCT/CN2014/095866, with an international filing date of Dec. 24, 2014.
This present invention, which discloses a modified thermoplastic polyurethane (TPU) rolling film and a preparation method thereof, belongs to the field of resin film manufacturing.
Thermoplastic polyurethane (TPU) film has been widely used in automotive electronics, medical equipment, daily necessities, and other areas due to its superior characteristics of excellent toughness, high strength, non-toxic, tasteless, and thermal processing performance. Tape casting is currently a widely used method for the manufacture of TPU films. The method suffers from low productivity, non-uniform thickness, and high production cost because all of the modified additives must be granulated before being added. As such, application of the thermoplastic polyurethane (TPU) film is limited.
This present invention has optimized the recipe and the preparation method, overcome the process issues of uneven plasticizing and easily stuck to the roller and so on. The modified thermoplastic polyurethane (TPU) rolling film disclosed herein offers better economic and social advantages due to its properties of high productivity, uniform thickness, high surface gloss, and excellent resistance to yellowing, abrasion, flame, and low temperature.
The present invention aims at developing a modified TPU rolling film and a preparation method thereof to overcome the shortcomings of the prior art. The modified TPU rolling film disclosed herein offers the features of high productivity, uniform thickness, high surface gloss, yellowing resistant (48 hours, UVB, reach to 4 grade), abrasion resistant, flame retardant (the thickness is 2.0 mm, reach to V0 grade), low temperature resistant (−30° C.) and excellent folding capability (Folding 150000 times to 200000 times).
The modified TPU rolling film comprises:
The grade of said TPU resin is TPU DP6386A, which was purchased from Bayer AG.
The grade of said TPO resin is CMW402, which was purchased from Exxon Mobil.
The said Thermoplastic Silicone Vulcanizate (TPSiV) resin is 3011 series, which was purchased from Dow Coming.
The said TPU color masterbatch is prepared through an extruding and granulating process with TPU resin (DP6386A) used as carrier and toner.
The said antioxidant is prepared by mixing β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid octadecanol ester with N, N′-hexamethylene bis (3,5-di-tert-butyl-4-hydroxyphenyl propionamide) at a mass ratio of 1:1.5.
The said light stabilizer is prepared by mixing 2-(2′-hydroxy-3′,5′-cumylphenyl) benzotriazole with 2-(2′-hydroxy-3′,5′-di-tert-amyl-phenyl) benzotriazole at a mass ratio of 1:2.
The flame retardant is prepared by mixing the organophosphate flame retardants with talcum powder of 5000 mesh at a mass ratio of 3:1.
The compound lubricant is prepared by mixing erucamide with oleic acid amide and stearic acid, at a mass ratio of 1:1:1.
The TPSiV resin, developed by the Dow Corning, is a kind of thermoplastic silicone elastomer that is composed by thermoplastic substrates and vulcanization silicone rubber particles.
The process for preparing the modified TPU rolling film comprises the following steps:
In the present invention, TPO resin controls the hardness of TPU films and improve TPU workability. TPSiV resin makes TPU film surface clean and dry, yet still maintains high mechanical properties after air aging. The modified TPU rolling film has the properties of both TPU and organosilicon material, has excellent aging resistance, scratch resistance, and oil resistance, and can be used at low temperature. More importantly, TPSiV resin has good compatibility with TPU resin. The antioxidant is compounded by antioxidants of different melting points and molecular weights. The light stabilizer is compounded by light stabilizers of different melting points and molecular weights. Every component acts synergistically with each other, which improves the yellowing resistance of TPU films. The flame retardant is a blend of the organophosphate flame retardants and talcum powder, which form synergies, decrease the fire resistance of melt drip of TPU material, and improve the flame retardance. The compound lubricant is a blend of erucamide, oleic acid amide and stearic acid with different primary effect and termination effect in machining Erucamide, oleic acid amide, and stearic acid complement each other seamlessly, which ensures that the compound lubricant has excellent properties during the processing, and can avoid the phenomenon of uneven plasticizing and sticking.
The modified TPU rolling film disclosed herein offers high productivity, uniform thickness, high surface gloss, excellent resistance to yellowing (48 hours, UVB, reach to grade 4), abrasion, flame (the thickness is 2.0 mm, reach to grade V0), and low temperature (−30° C.), and excellent folding capability (folding 150000 times to 200000 times), and free from the phenomenon of uneven plasticizing and sticking.
Not Applicable
The present invention is further described in the following three exemplified preferred embodiments to illustrate the application of the principles of the invention. It is understood that the invention may be embodied otherwise without departing from such principles. The scope of the claims of the present invention expressly should not be limited to such exemplary or preferred embodiments.
In this embodiment, the present application provides a modified TPU rolling film comprising:
The grade of said TPU resin is TPU DP6386A, which was purchased from Bayer Company.
The grade of said TPO resin is CMW402, which was purchased from Exxon Mobil.
The said TPSiV resin is 3011 series, which was purchased from Dow Coming.
The said TPU color masterbatch is prepared through the extruding and granulating process with TPU resin (DP6386A) used as carrier and toner.
The said antioxidant is prepared by mixing β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid octadecanol ester (antioxidant 1076) with N, N′-hexamethylene bis (3,5-di-tert-butyl-4-hydroxyphenyl propionamide) (antioxidant 1098) at a mass ratio of 1:1.5.
The said light stabilizer is prepared by mixing 2-(2′-hydroxy-3′,5′-cumylphenyl) benzotriazole (UV234) with 2-(2′-hydroxy-3′,5′-di-tert-amyl-phenyl) benzotriazole (UV328) at a mass ratio of 1:2.
The flame retardant is prepared by mixing the organophosphate flame retardants (grade OP1320) with talcum powder of 5000 mesh at a mass ratio of 3:1.
The compound lubricant is prepared by mixing erucamide with oleic acid amide and stearic acid, at a mass ratio of 1:1:1.
The TPSiV resin, developed by the Dow Corning, is a kind of thermoplastic silicone elastomer that is composed of thermoplastic substrates and vulcanization silicone rubber particles.
The present application further provides a process for preparing the modified thermoplastic polyurethane (TPU) rolling film, comprising the following steps:
In the second embodiment, the present application provides a modified TPU rolling film comprising:
The grade of said TPU resin is TPU DP6386A, which was purchased from Bayer Company.
The grade of said TPO resin is CMW402, which was purchased from Exxon Mobil.
The said TPSiV resin is 3011 series, which was purchased from Dow Coming.
The said TPU color masterbatch is prepared through the extruding and granulating process with TPU resin (DP6386A) used as carrier and toner.
The said antioxidant is prepared by mixing β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid octadecanol ester (antioxidant 1076) with N, N′-hexamethylene bis (3,5-di-tert-butyl-4-hydroxyphenyl propionamide) (antioxidant 1098) at a mass ratio of 1:1.5, respectively.
The said light stabilizer is prepared by mixing 2-(2′-hydroxy-3′,5′-cumylphenyl) benzotriazole (UV234) with 2-(2′-hydroxy-3′,5′-di-tert-amyl-phenyl) benzotriazole (UV328) at a mass ratio of 1:2.
The flame retardant is prepared by mixing the organophosphate flame retardants (grade OP1320) with talcum powder of 5000 mesh at a mass ratio of 3:1.
The compound lubricant is prepared by mixing erucamide with oleic acid amide and stearic acid, at a mass ratio of 1:1:1.
The TPSiV resin, developed by the Dow Corning, is a kind of thermoplastic silicone elastomer that is composed of thermoplastic substrates and vulcanization silicone rubber particles.
The present application further provides a process for preparing the modified thermoplastic polyurethane (TPU) rolling film, comprising the following steps:
In the third embodiment, the present application provides a modified TPU rolling film comprising:
The grade of said TPU resin is TPU DP6386A, which was purchased from Bayer Company.
The grade of said TPO resin is CMW402, which was purchased from Exxon Mobil.
The said TPSiV resin is 3011 series, which was purchased from Dow Coming.
The said TPU color masterbatch is prepared through the extruding and granulating process with TPU resin (DP6386A) used as carrier and toner.
The said antioxidant is prepared by mixing β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid octadecanol ester (antioxidant 1076) with N, N′-hexamethylene bis (3,5-di-tert-butyl-4-hydroxyphenyl propionamide) (antioxidant 1098) at a mass ratio of 1:1.5, respectively.
The said light stabilizer is prepared by mixing 2-(2′-hydroxy-3′,5′-cumylphenyl) benzotriazole (UV234) with 2-(2′-hydroxy-3′,5′-di-tert-amyl-phenyl) benzotriazole (UV328) at a mass ratio of 1:2.
The flame retardant is prepared by mixing the organophosphate flame retardants (grade OP1320) with talcum powder of 5000 mesh at a mass ratio of 3:1.
The compound lubricant is prepared by mixing Erucamide with Oleic acid amide and Stearic acid, at a mass ratio of 1:1:1.
The TPSiV resin, developed by the Dow Corning, is a kind of thermoplastic silicone elastomer that is composed of thermoplastic substrates and vulcanization silicone rubber particles.
The present application further provides a process for preparing the modified thermoplastic polyurethane (TPU) rolling film, comprising the following steps:
| Number | Date | Country | Kind |
|---|---|---|---|
| PCT/CN2014/095866 | Dec 2014 | CN | national |
