The present invention relates to a refrigeration system with a low temperature portion and a medium temperature portion. The present invention relates more particularly to a refrigeration system where the low temperature portion may receive condenser cooling from refrigerant in the medium temperature portion in a cascade arrangement, or may share condenser cooling directly with the medium temperature system. The present invention relates more particularly to use of carbon dioxide (CO2) as both a low temperature refrigerant and a medium temperature coolant.
Refrigeration systems typically include a refrigerant that circulates through a series of components in a closed system to maintain a cold region (e.g., a region with a temperature below the temperature of the surroundings). One exemplary refrigeration system is a vapor refrigeration system including a compressor. Such a refrigeration system may be used, for example, to maintain a desired temperature within a temperature controlled storage device, such as a refrigerated display case, coolers, freezers, etc. The refrigeration systems may have a first portion with equipment intended to maintain a first temperature (such as a low temperature) and a second temperature (such as a medium temperature). The refrigerant in the low temperature portion and the refrigerant in the medium temperature portion are condensed in condensers which require a source of a coolant.
Different refrigerants maybe be used in different vapor compression refrigeration systems to maintain cases at several different temperatures. However, using different refrigerants typically requires separate closed loop systems and additional piping and equipment.
Further, with a traditional refrigeration system, if the amount of space needing for cooling is increased, for instance, by adding additional chilled display cases, equipment such as compressors may have to be replaced to accommodate the additional cooling load.
Accordingly, it would be desirable to provide a modular refrigeration system capable of using CO2 as a refrigerant for cooling refrigeration devices operating at different temperatures.
One embodiment of the invention relates to a cascade CO2 refrigeration system, comprising a medium temperature loop for circulating a medium temperature refrigerant and a low temperature loop for circulating a CO2 refrigerant. The medium temperature loop including a compressor; a discharge header; a condenser; a subcooler; an expansion device; and a heat exchanger having a first side and a second side. The first side of the heat exchanger is configured to evaporate the medium temperature refrigerant. The medium temperature loop further includes a suction header configured to direct medium temperature refrigerant to the compressor. The low temperature loop includes a compressor, a discharge header configured to circulate the CO2 refrigerant through the second side of the heat exchanger to condense the CO2 refrigerant; a liquid-vapor separator configured to collect liquid CO2 refrigerant and to direct vapor CO2 refrigerant to the second side of the heat exchanger; a pump; a subcooler; a liquid CO2 refrigerant supply header; a plurality of medium temperature loads configured to receive liquid CO2 refrigerant from the liquid CO2 refrigerant supply header for use as a liquid coolant in the medium temperature loads; a plurality of low temperature loads; and a low temperature expansion device configured to expand the liquid CO2 refrigerant from the liquid CO2 refrigerant supply header into liquid-vapor CO2 for use as a refrigerant by the low temperature loads.
Another embodiment relates to a cascade refrigeration system having a common subcooled liquid supply for both low temperature refrigerated cases and medium temperature refrigerated cases. The system includes an upper cascade portion for circulating a first refrigerant; lower cascade portion for circulating a second refrigerant; a plurality of medium temperature refrigerated cases configured to receive liquid second refrigerant from the common subcooled liquid supply for use as a coolant in the medium temperature refrigerated cases, and an expansion device configured to expand the liquid second refrigerant from the common subcooled liquid supply into liquid-vapor second refrigerant for use as a refrigerant by the low temperature refrigerated cases. The upper cascade portion includes a compressor, a condenser, an expansion device, and a heat exchanger having a first side and a second side, the first side configured to evaporate the first refrigerant. The lower cascade portion includes a compressor configured to direct the second refrigerant to the second side of the heat exchanger, the second side of the heat exchanger configured to condense the second refrigerant, a liquid-vapor separator configured to direct liquid second refrigerant to the common subcooled liquid supply and to direct vapor second refrigerant to the second side of the heat exchanger.
Yet another embodiment relates to a cascade refrigeration system having a common liquid supply for both low temperature refrigeration loads and medium temperature refrigeration loads. The system includes an upper cascade portion for circulating a first refrigerant, a lower cascade portion for circulating a second refrigerant, and a liquid-vapor separator. The upper cascade portion including a compressor, a condenser, an expansion device, and a heat exchanger having a first side and a second side, the first side configured to evaporate the first refrigerant. The lower cascade portion including a compressor configured to direct the second refrigerant to the second side of the heat exchanger, the second side of the heat exchanger configured to condense the second refrigerant. The liquid-vapor separator configured to receive the liquid second refrigerant from the second side of the heat exchanger and to provide a source of liquid second refrigerant for the common liquid supply. The medium temperature refrigeration loads are configured to receive liquid second refrigerant from the common liquid supply for use as a coolant. Expansion devices are configured to expand the liquid second refrigerant from the common liquid supply into a liquid-vapor mixture for use as a second refrigerant in the low temperature refrigeration loads.
Still another embodiment relates to a refrigeration system comprising a plurality of modular medium temperature compact chiller, a plurality of modular low temperature compact condenser units, a liquid-vapor separator communicating with the modular low temperature compact condenser units, and a pump. The modular medium temperature compact chiller units have a first heat exchanger and a second heat exchanger. The modular medium temperature compact chiller units are arranged in parallel and configured to circulate a medium temperature refrigerant through the first and second heat exchangers to cool a medium temperature liquid coolant for circulation to a plurality of medium temperature refrigeration loads. The modular low temperature compact condenser units have a first heat exchanger and a second heat exchanger. The modular low temperature compact condenser units are arranged in parallel, with the first heat exchanger configured to receive the medium temperature liquid coolant to condense a low temperature refrigerant for circulation to the first heat exchanger to condense a vapor CO2 refrigerant to a liquid CO2 refrigerant. The liquid-vapor separator communicates with the modular low temperature compact condenser units to direct vapor CO2 refrigerant to the first heat exchanger and to receive liquid CO2 refrigerant from the first heat exchanger. The pump is configured to direct the liquid CO2 refrigerant from the liquid-vapor separator to a plurality of low temperature refrigeration loads.
Referring to
The terms “low temperature” and “medium temperature” are used herein for convenience to differentiate between two subsystems of refrigeration system 10. Medium temperature loop 20 maintains one or more cases 24 such as refrigerator cases or other cooled areas at a temperature lower than the ambient temperature but higher than low temperature cases 34. Low temperature loop 30 maintains one or more cases 34 such as freezer display cases or other cooled areas at a temperature lower than the medium temperature. According to one exemplary embodiment, medium temperature cases 24 may be maintained at a temperature of approximately 20° F. and low temperature cases 34 may be maintained at a temperature of approximately minus (−) 20° F. Although only two subsystems are shown in the exemplary embodiments described herein, according to other exemplary refrigeration system 10 may include more subsystems that may be selectively cooled in a cascade arrangement or other cooling arrangement.
A first or medium temperature loop 20 (e.g., the upper cascade portion) includes a medium temperature chiller 22 (e.g. modular medium temperature compact chiller unit), one or more medium temperature cases 24 (e.g., refrigerated display cases), and a pump 26. Pump 26 circulates a medium temperature liquid coolant (e.g., propylene glycol, water, etc.) between chiller 22 and cases 24 to maintain cases 24 at a relatively constant medium temperature. Medium temperature chiller 22 removes heat energy from medium temperature cases 24 and, in turn, gives the heat energy up to a heat exchanger, such as an outdoor fluid cooler 60 or outdoor cooling tower to be dissipated to the exterior or outside environment. Outdoor fluid cooler 60 cools a third coolant (e.g., water, etc.) that is circulated with a pump 62.
Medium temperature chiller 22 is further coupled to a low-temperature chiller 32 (e.g. modular low temperature compact condenser units) to absorb (e.g. remove, etc.) heat from a low temperature loop 30. The second or low temperature loop 30 (e.g., the lower cascade portion) includes a low temperature chiller 32, one or more low temperature cases 34 (e.g., refrigerated display cases, freezers, etc.), and a pump 36. Pump 36 circulates a low temperature coolant (e.g., carbon dioxide) between chiller 32 and refrigerated cases 34 to maintain cases 34 at a relatively constant low temperature. The carbon dioxide (CO2) coolant is separated into liquid and gaseous portions in a receiver or liquid-vapor separator 38. Liquid CO2 exits the liquid-vapor separator 38 and is pumped by pump 36 to valve 39 (which may be an expansion valve for expanding liquid CO2 into a low temperature saturated vapor for removing heat from low temperature cases 34, and would be returned to the suction of a compressor, such as shown in
One exemplary chiller unit 40 is shown in
Another exemplary chiller unit 50 is shown in
Intermediate heat exchanger 61 allows refrigerant exiting second heat exchanger 56 (e.g., as a saturated liquid) to be subcooled further by low temperature refrigerant exiting first heat exchanger 52. By subcooling the refrigerant with heat exchanger 61, the efficiency of the system is increased by reducing premature vaporization or flash off of the refrigerant before it reaches the heat exchanger 52. Further, the subcooled refrigerant is then expanded through expansion valve 58 at a lower enthalpy than it would be if it were not first subcooled. The lower enthalpy vapor refrigerant is then able to absorb more heat as it passes through first heat exchanger 52.
According to one exemplary embodiment, chiller unit 40 is a compact modular chiller unit. System 10 may include a multitude of chiller units 40 or 50 arranged in parallel as low temperature chillers (e.g. condensing units) 32 and medium temperature chillers 22. The number of chiller units 40 or 50 may be varied to accommodate various cooling loads associated with a particular system. Likewise, the number of medium temperature cases 24 and low temperature cases 34 may be varied.
Referring now to
Low temperature loop 130 (e.g., lower cascade portion) includes a CO2 refrigerant that is circulated through a refrigeration cycle including a receiver or liquid-vapor separator 132, a pump 134, a subcooler 136, a common liquid supply header 138, low temperature cases 140 with associated expansion devices 142, medium temperature cases 150 with associated control valves 152, and one or more compressors 146.
Liquid CO2 refrigerant from liquid-vapor separator 132 is circulated by pump 134 to supply header 138 through one side of subcooler 136. Pump 134 pressurizes the CO2 liquid refrigerant. Subcooler 136 allows liquid CO2 refrigerant exiting separator 132 to be subcooled further by low temperature vapor CO2 refrigerant exiting low temperature cases 140. By subcooling the refrigerant with pump 134 and subcooler 136, the efficiency of the system is increased by reducing premature vaporization or flash off of the refrigerant before it reaches the cooling loads. Further, the subcooled refrigerant is expanded through expansion valve 142 at a lower enthalpy than it would be if it were not first subcooled. The lower enthalpy liquid refrigerant is then able to absorb more heat as it passes through low temperature cases 140 and medium temperature cases 150.
Supply header 138 allows liquid CO2 refrigerant to flow to both low temperature cases 140 and medium temperature cases 150. Liquid refrigerant flowing to low temperature cases 140 passes through expansion devices 142 (e.g., expansion valves) expanding to a liquid-vapor mixture. In this way, the CO2 refrigerant is provided as an expansion type refrigerant at a relatively low temperature (e.g. approximately minus (−) 20° F. or other suitable “low” temperature) to cool the low temperature cases 140 (e.g. cooling loads). Liquid refrigerant flowing to medium temperature cases 150, on the other hand, passes through valves 152 and is provided as a liquid refrigerant or coolant at a “medium” temperature (e.g. approximately 20° F. or other suitable “medium” temperature) to cool the medium temperature cases 150 cooling loads. By using a common supply header 138, and passing the refrigerant using different components 142 and 152 before they pass through low temperature cooling cases 140 and medium temperature cooling cases 150, the overall system 10 may be simplified by supplying a common refrigerant through a common header for use in refrigeration loads (e.g. display cases, etc.) having different operating temperature requirements. For instance, in a system with interspersed medium temperature cases 150 and low temperature cases 140 (such as shown in
After the CO2 refrigerant has absorbed heat from low temperature cases 140, a suction header 144 coupled to the low temperature cases 140 directs the CO2 vapor refrigerant through subcooler 136 and to compressor 146. The refrigerant is superheated in subcooler 136 by the warmer CO2 liquid refrigerant from separator 132. By superheating the CO2 vapor refrigerant before it reaches compressor 146, the chances of any damaging moisture or liquids entering compressor 146 are reduced. The CO2 vapor refrigerant is compressed to a high-pressure super-heated vapor in compressor 146 and directed to a heat exchanger 182 (e.g. de-superheater, etc.) shown as located upstream of heat exchanger 162 and intended to pre-cool the compressed CO2 vapor prior to entering heat exchanger 162, in order to reduce the cooling demand or load required by heat exchanger 162. According to one embodiment, heat exchanger 182 is an air-cooled heat exchanger (operating in a manner similar to an air-cooled condenser) that takes advantage of available ambient air cooling to reduce the demand on medium temperature loop 120. According to an alternative embodiment, the de-superheating heat exchanger may also be arranged to selectively “reclaim” the heat from the compressed CO2 vapor for use in other applications (e.g. heating water or air for other uses in a facility, etc.) and as such may be air or liquid cooled as appropriate. According to one exemplary embodiment, the temperature of the compressed vapor discharged from compressor(s) 146 is within a range of approximately 150-165° F., and the medium temperature cooling loop 120 is required to reduce the temperature of the compressed vapor to about 25° F. and then condense the CO2 into liquid form. The applicants believe that use of the de-superheater as described would be effective in reducing the temperature of the compressed vapor to about 110° F. (or lower depending on ambient conditions) prior to entering the heat exchanger 162, resulting in an energy savings of approximately 10% or more. After being cooled by the de-superheating heat exchanger 182, the CO2 refrigerant is directed through valve 155 to heat exchanger 162 in the medium temperature loop. After passing through heat exchanger 162, the refrigerant returns to liquid-vapor separator 132.
Referring further to
The medium temperature loop 120 (e.g., the upper cascade portion) is similar to chiller unit 50 shown in
Subcooler 170 allows refrigerant exiting second heat exchanger 166 (e.g., as a saturated or subcooled liquid) to be subcooled further by low temperature refrigerant exiting first heat exchanger 162. By subcooling the medium temperature refrigerant with subcooler 170, the efficiency of the system is increased by reducing premature vaporization or flash off of the refrigerant before it reaches the first heat exchanger 162. Further, the subcooled medium temperature refrigerant is then expanded through expansion valve 168 at a lower enthalpy than it would be if it were not first subcooled. The lower enthalpy refrigerant is then able to absorb more heat as it passes through first heat exchanger 162.
One or more components of medium temperature loop 120 may be packaged together as a modular chiller unit 122. According to one exemplary embodiment, modular unit 122 includes first heat exchanger 162, compressor 164, second heat exchanger 166, and expansion valve 168 (in a manner similar to that shown in
Referring now to
Refrigeration system 110 may include a portion 190 (shown in more detail in
If the power for refrigeration system 110 is lost or otherwise interrupted, the cooling cycle keeping the CO2 refrigerant cooled may be halted and the temperature of the CO2 may rise, causing it to expand and threaten to damage components of refrigeration system 110, such as piping and components on low pressure side of low temperature loop 130 (e.g., suction header 144, individual circuits feeding suction header 144, evaporators in low temperature cases 150, etc) upstream of solenoid valves 192. Upon loss of power, solenoid valves 192 are configured to close and isolate compressors 146. When closed, solenoid valves 192 prevent possible damage to compressors 146 by isolating them from CO2 pressure built up in low temperature case 150 evaporators and suction distribution piping.
Expansion devices 142 may be electronically controlled and configured to close automatically upon loss of power. However, some refrigerant may continue to leak through closed expansion devices 142 from the high-pressure side to the low pressure side of low temperature loop 130. If the pressure on the low pressure side of low temperature loop 130 exceeds the pressure on the high pressure side, refrigerant may pass through check valves 194 from the low pressure side to the high pressure side. If the pressure in the high pressure side exceeds a predetermined threshold, it escapes (e.g. vents, etc.) from refrigeration system 110 through high-side relief valve 198.
According to any exemplary embodiment, the pressure relief devices are intended to minimize potential pressure related damage to the system in the event of a power loss. In the event that CO2 refrigerant leaks-by (e.g. bleeds-past, etc.) the expansion valves 142, the CO2 will remain in the evaporators of the low temperature loads (e.g. refrigerated cases or freezers, etc.) and will be cooled by the thermal inertia of the low temperature objects (e.g. food, etc.) stored therein. In this manner, the pressure of the CO2 refrigerant in the refrigeration loads can go to a higher pressure than the pressure relief setting of relief valve 196, and bypass check valves 194 are intended to ensure that under any condition, the pressure of CO2 refrigerant within the refrigeration loads does not exceed the pressure relief setpoint of the relief valve 198.
Referring to
While the refrigerant for low temperature loop 130 has been described above as CO2, it should be realized that the arrangement of low temperature loop 130 allows various refrigerants to be used in both a liquid state and a vapor state to cool medium temperature cases 150 and low temperature cases 140. For example, according to anther exemplary embodiment, the low temperature refrigerant may be propane, ammonia or any other suitable refrigerant.
It is important to note that the construction and arrangement of the elements of the refrigeration system provided herein are illustrative only. Although only a few exemplary embodiments of the present invention(s) have been described in detail in this disclosure, those skilled in the art who review this disclosure will readily appreciate that many modifications are possible in these embodiments (such as variations in features such as connecting structure, components, materials, sequences, capacities, shapes, dimensions, proportions and configurations of the modular elements of the system, without materially departing from the novel teachings and advantages of the invention(s). For example, any number of chiller units may be provided in parallel to cool the low temperature and medium temperature cases, or more subsystems may be included in the refrigeration system (e.g., a very cold subsystem or additional cold or medium subsystems). Further, it is readily apparent that variations and modifications of the refrigeration system and its components and elements may be provided in a wide variety of materials, types, shapes, sizes and performance characteristics. Accordingly, all such variations and modifications are intended to be within the scope of the invention(s).
Number | Name | Date | Kind |
---|---|---|---|
2797068 | McFarlan | Jun 1957 | A |
4014182 | Granryd | Mar 1977 | A |
4122686 | Lindahl et al. | Oct 1978 | A |
4429547 | Granryd | Feb 1984 | A |
4441872 | Seale | Apr 1984 | A |
4484449 | Muench | Nov 1984 | A |
4750335 | Wallace et al. | Jun 1988 | A |
4984435 | Seino et al. | Jan 1991 | A |
RE33620 | Persem | Jun 1991 | E |
5042262 | Gyger et al. | Aug 1991 | A |
5046320 | Loose et al. | Sep 1991 | A |
5048303 | Campbell et al. | Sep 1991 | A |
5170639 | Datta | Dec 1992 | A |
5212965 | Datta | May 1993 | A |
5217064 | Kellow et al. | Jun 1993 | A |
5228581 | Palladino et al. | Jul 1993 | A |
5335508 | Tippmann | Aug 1994 | A |
5351498 | Takahashi et al. | Oct 1994 | A |
5386709 | Aaron | Feb 1995 | A |
5431547 | Boyko | Jul 1995 | A |
D361226 | Jones et al. | Aug 1995 | S |
D361227 | Jones et al. | Aug 1995 | S |
5438846 | Datta | Aug 1995 | A |
5475987 | McGovern | Dec 1995 | A |
5544496 | Stoll et al. | Aug 1996 | A |
5596878 | Hanson et al. | Jan 1997 | A |
5683229 | Stoll et al. | Nov 1997 | A |
5743110 | Laude-Bousquet | Apr 1998 | A |
6067814 | Imeland | May 2000 | A |
6089033 | Dube | Jul 2000 | A |
6094925 | Arshansky et al. | Aug 2000 | A |
6112532 | Bakken | Sep 2000 | A |
6148634 | Sherwood | Nov 2000 | A |
6170270 | Arshansky et al. | Jan 2001 | B1 |
RE37054 | Sherwood | Feb 2001 | E |
6185951 | Lane et al. | Feb 2001 | B1 |
6202425 | Arshansky et al. | Mar 2001 | B1 |
6205795 | Backman et al. | Mar 2001 | B1 |
6212898 | Ueno et al. | Apr 2001 | B1 |
6286322 | Vogel et al. | Sep 2001 | B1 |
6385980 | Sienel | May 2002 | B1 |
6393858 | Mezaki et al. | May 2002 | B1 |
6405558 | Sheehan | Jun 2002 | B1 |
6418735 | Sienel | Jul 2002 | B1 |
6449967 | Dube | Sep 2002 | B1 |
6467279 | Backman et al. | Oct 2002 | B1 |
6481231 | Vogel et al. | Nov 2002 | B2 |
6494054 | Wong et al. | Dec 2002 | B1 |
6502412 | Dubé | Jan 2003 | B1 |
6574978 | Flynn et al. | Jun 2003 | B2 |
6631621 | Vander Woude et al. | Oct 2003 | B2 |
6658867 | Taras et al. | Dec 2003 | B1 |
6672087 | Taras et al. | Jan 2004 | B1 |
6708511 | Martin | Mar 2004 | B2 |
6722145 | Podtchereniaev et al. | Apr 2004 | B2 |
6745588 | Kahler | Jun 2004 | B2 |
6775993 | Dube | Aug 2004 | B2 |
6843065 | Flynn | Jan 2005 | B2 |
6883343 | Lane et al. | Apr 2005 | B2 |
6889514 | Lane et al. | May 2005 | B2 |
6889518 | Lane et al. | May 2005 | B2 |
6915652 | Lane et al. | Jul 2005 | B2 |
6968708 | Gopalnarayanan et al. | Nov 2005 | B2 |
6981385 | Arshansky et al. | Jan 2006 | B2 |
6983613 | Dube | Jan 2006 | B2 |
6993918 | Cowans | Feb 2006 | B1 |
7000413 | Chen et al. | Feb 2006 | B2 |
7065979 | Arshansky et al. | Jun 2006 | B2 |
7121104 | Howington et al. | Oct 2006 | B2 |
7159413 | Dail | Jan 2007 | B2 |
7275376 | Swofford et al. | Oct 2007 | B2 |
RE39924 | Dube | Nov 2007 | E |
7357000 | Schwichtenberg et al. | Apr 2008 | B2 |
7374186 | Mason et al. | May 2008 | B2 |
7424807 | Sienel | Sep 2008 | B2 |
7610766 | Dube | Nov 2009 | B2 |
7628027 | Shapiro | Dec 2009 | B2 |
7878023 | Heinbokel | Feb 2011 | B2 |
7913506 | Bittner et al. | Mar 2011 | B2 |
8113008 | Heinbokel et al. | Feb 2012 | B2 |
20010023594 | Ives | Sep 2001 | A1 |
20010027663 | Zeigler et al. | Oct 2001 | A1 |
20020066286 | Alsenz | Jun 2002 | A1 |
20030019219 | Viegas et al. | Jan 2003 | A1 |
20030029179 | Vander Woude et al. | Feb 2003 | A1 |
20070089453 | Shapiro | Apr 2007 | A1 |
20080289350 | Shapiro | Nov 2008 | A1 |
20090000321 | Hall | Jan 2009 | A1 |
20090019878 | Gupte | Jan 2009 | A1 |
20090025404 | Allen | Jan 2009 | A1 |
20090120108 | Heinbokel et al. | May 2009 | A1 |
20090120117 | Martin et al. | May 2009 | A1 |
20090158612 | Thilly et al. | Jun 2009 | A1 |
20090260389 | Dube | Oct 2009 | A1 |
20090272128 | Ali | Nov 2009 | A1 |
20100023171 | Bittner et al. | Jan 2010 | A1 |
20100071391 | Lifson et al. | Mar 2010 | A1 |
20100077777 | Lifson et al. | Apr 2010 | A1 |
20100115975 | Mitra et al. | May 2010 | A1 |
20100132399 | Mitra et al. | Jun 2010 | A1 |
20100199707 | Pearson | Aug 2010 | A1 |
20100199715 | Lifson et al. | Aug 2010 | A1 |
20100205984 | Gu et al. | Aug 2010 | A1 |
20100212350 | Gu et al. | Aug 2010 | A1 |
20100314843 | Beck | Dec 2010 | A1 |
20100314846 | Zeng | Dec 2010 | A1 |
Number | Date | Country |
---|---|---|
0 602 911 | Jun 1994 | EP |
0 675 331 | Oct 1995 | EP |
1 134 514 | Sep 2001 | EP |
1 139 041 | Oct 2001 | EP |
WO 2009158612 | Dec 2009 | WO |
WO-2010045743 | Apr 2010 | WO |
Entry |
---|
“Experiences from CO2 Installations,” York Refrigeration, May 24, 2001, 1 pp. |
“Margaux Cascade Refrigeration System with Hot Gas Defrost Drawing” having a date indication of Sep. 27, 1989, 1 page. |
U.S. Appl. No. 12/948,442, filed Nov. 17, 2010, Hinde et al. |
Annex to Form PCT/ISA/206 Communication Relating to the Results of the Partial International Search, relating to International Application No. PCT/US 03/34606 (2 pgs.). |
Number | Date | Country | |
---|---|---|---|
20100031697 A1 | Feb 2010 | US |