Claims
- 1. A composition resistant to moisture permeation, comprising:
- a blend having,
- about 100 parts by weight of an aliphatic mercaptain compound having at least two thio terminal groups,
- from about 20 parts to about 300 parts by weight of an epoxy resin, and
- from about 0.1 to about 4.0 parts by weight of an amino-titanate compound.
- 2. A composition resistant to moisture permeation according to claim 1, wherein said amino-titanate compound has the formula ##STR11## where x is 1,2 or 3, where y is 0,1 or 2, where x+y=3; where R.sup.1 is alkyl having from 1 to 7 carbon atoms; where X is C.dbd.O, O.dbd.S.dbd.O, or nothing; where R.sup.11 is an aromatic having 6 or 12 carbon atoms, an alkyl substituted aromatic having from 6 to 12 carbon atoms, an alkyl having from 1 to 8 carbon atoms, or R.sup.2 --NH--R.sup.21 where R.sup.2 and R.sup.21 can be the same or different and where R.sup.2 or R.sup.21 is an alkyl having from 1 to 10 carbon atoms; or where --R.sup.11 --NH.sub.2 is tetra ethylene triamine; and where R.sup.3 is an alkyl having from 1 to 25 carbon atoms or an alkyl substituted aromatic having from 10 to 25 carbon atoms.
- 3. A composition according to claim 2, wherein said mercaptan compound has the formula ##STR12## where R is an aliphatic group having from 1 to 18 carbon atoms, where n is 1 or 2, and where x is 2 or 3, wherein the amount of the epoxy is from about 25 to about 250 parts and wherein the amount of said titanate compound ranges from about 0.2 to about 2 parts by weight.
- 4. A composition according to claim 3 wherein said R in said mercaptan is a alkyl having from 1 to 11 carbon atoms and x is 3, wherein R.sup.1 in said titanate is propyl, R.sup.11 is said aromatic, or said R.sup.2 --NH--R.sup.21 where R is 1 to 3 carbon atoms, or wherein R.sup.11 --NH.sup.2 is tetra ethylene triamine, and wherein in said amino formulation R.sup.3 is an alkyl having from 15 to 20 carbon atoms.
- 5. A composition according to claim 4 wherein said mercaptan formula R is propyl, and wherein the amount of epoxy is from about 25 parts to about 200 parts by weight and wherein the amount of said titanate compound is from about 0.3 to about 0.7 parts by weight.
- 6. A composition according to claim 2 wherein a protonic acid is utilized in preparing said composition, the amount of said protonic acid ranging from about 0.01 to about 0.5 parts by weight per 100 parts of said mercaptan.
- 7. A composition according to claim 4, wherein a carboxylic acid is utilized in preparing said composition, wherein the amount of said carboxylic acid is from about 0.01 to about 0.2 parts by weight per 100 parts by weight of said mercaptan and wherein said carboxylic acid is selected from the group consisting of lactic acid, butyric acid and acetic acid.
- 8. A laminate wherein the blend of claim 1 forms an outer layer on a transparent material or forms an interlayer between transparent materials.
- 9. A laminate according to claim 8, wherein said transparent material is selected from the group consisting of acrylic, polycarbonate, polyurethane, glass, polyvinyl butyral, and combinations thereof.
- 10. A laminate wherein the blend of claim 1 is transparent and forms an outer layer or an inner layer contiguous with at least one heat-resistant transparent material,
- said heat-resistant transparent material comprising about 100 parts by weight of an epoxy resin, from about 5 to about 30 parts by weight of a boroxine, and from about 1 to about 10 parts by weight of a phenyl substituted alkyl alcohol, said alkyl alcohol having from 1 to 20 carbon atoms, said boroxine having the formula ##STR13## where R is a compound having from 1 to 18 carbon atoms.
- 11. A laminate according to claim 10, including in said heat-resistant transparent layer containing said epoxy resin and said boroxine from about 1 to about 40 parts by weight of a phosphorus compound having the formula ##STR14## wherein R.sub.3 is selected from the group consisting of hydrocarbon radicals having from 1 to 24 carbon atoms, halo-substituted organic radicals having from 1 to 24 carbon atoms, and multihalo-substituted organic radicals having from 1 to 24 carbon atoms, and wherein R.sub.3 may be the same or different radicals; and
- R.sub.4 is selected from the group consisting of all the radicals of R.sub.3, oxygen, and radicals of the formula: O--R.sub.6, where R.sub.6 is selected from the group consisting of all the radicals of R.sub.3, organo-phosphorus polymeric radicals, and organo-phosphorus esters; where R.sub.5 is selected from the group consisting of hydrogen, hydroxyl, oxygen, sulfur, halogens or no radical at all; and where Z is selected from the group consisting of oxygen, sulfur, or no radical at all.
- 12. A laminate according to claim 11, wherein said phosphorus compound is selected from the group consisting of a phosphite, and a phosphate, wherein said phosphite is selected from the group consisting of diphenyl phosphite, trisnonylphenyl phosphite, triphenyl phosphite, diphenylisodecyl phosphite, diphenylisooctyl phosphite and phenyldiisodecyl phosphite, and wherein said phosphate compound is selected from the group consisting of tri(beta, beta' dichloroisopropyl) phosphate, tri(beta chloroethyl) phosphate, bis-chloroethyl phosphate ester, and a phosphate polymer of the formula ##STR15## where n is a number from 1 to 20.
- 13. A laminate according to claim 12, wherein said R of said boroxine is an alkyl having 1 to 2 carbon atoms, wherein the amount of said boroxine ranges from about 8 to about 15 parts by weight, wherein the amount of said alcohol ranges from about 1 to about 5 parts.
- 14. A laminate wherein the blend of claim 4 forms an outer layer on a transparent material or forms an interlayer between transparent materials.
- 15. A laminate according to claim 14, wherein said transparent material is selected from the group consisting of acrylic, polycarbonate, polyurethane, glass, polyvinyl butyral, and combinations thereof.
- 16. A laminate wherein the blend of claim 15, is transparent and forms an outer layer or an inner layer contiguous with at least one heat-resistant transparent material,
- said heat-resistant transparent material having about 100 parts by weight of an epoxy resin, from about 5 to about 30 parts by weight of a boroxine, and from about 1 to about 10 parts by weight of a phenyl substituted alkyl alcohol, said alkyl alcohol having from 1 to 20 carbon atoms, said boroxine having the formula ##STR16## where R is a compound having from 1 to 18 carbon atoms.
- 17. A laminate according to claim 16, including from about 1 to about 40 parts by weight of a phosphorus compound having the formula ##STR17## where R.sub.3 is selected from the group consisting of hydrocarbon radicals having from 1 to 24 carbon atoms, halo-substituted organic radicals having from 1 to 24 carbon atoms, and multihalo-substituted organic radicals having from 1 to 24 carbon atoms; and wherein R.sub.3 may be the same or different radicals; and
- R.sub.4 is selected from the group consisting of all the radicals of R.sub.3, oxygen, and radicals of the formula: --O--R.sub.6, where R.sub.6 is selected from the group consisting of all the radicals of R.sub.3, organophosphorus polymeric radicals, and organo-phosphorus esters; where R.sub.5 is selected from the group consisting of hydrogen, hydroxyl, oxygen, sulfur, halogens or no radical at all; and where Z is selected from the group consisting of oxygen, sulfur, or no radical at all.
- 18. A laminate according to claim 17, wherein said phosphorus compound is selected from the group consisting of a phosphite, and a phosphate, wherein said phosphite is selected from the group consisting of diphenyl phosphite, trisnonylphenyl phosphite, triphenyl phosphite, diphenylisodecyl phosphite, diphenylisooctyl phosphite and phenyldiisodecyl phosphite, and wherein said phosphate compound is selected from the group consisting of tri(beta, beta' dichloroisopropyl) phosphate, tri(beta chloroethyl) phosphate, bis-chloroethyl phosphate ester, and a phosphate polymer of the formula ##STR18## where n is a number from 1 to 20.
- 19. A laminate according to claim 18, wherein said R of said boroxine is an alkyl having 1 to 2 carbon atoms, wherein the amount of said boroxine ranges from about 8 to about 15 parts by weight, and wherein the amount of said alcohol ranges from about 1 to about 5 parts.
CROSS-REFERENCE
This application is a continuation-in-part of U.S. Ser. Nos. 394,204, now U.S. Pat. No. 4,454,201, and Ser. No. 394,205, now U.S. Pat. No. 4,450,202, both filed July 1, 1982. Application Ser. Nos. 394,204 and 394,205 are divisions of Ser. No. 232,054, filed Feb. 5, 1981, now U.S. Pat. No. 4,343,928. Application Ser. No. 232,054 is a continuation-in-part of Ser. No. 204,424, filed Nov. 6, 1980, now U.S. Pat. No. 4,352,848, which in turn is a continuation-in-part of U.S. Ser. No. 70,390, filed Aug. 28, 1979, now U.S. Pat. No. 4,294,886.
US Referenced Citations (4)
Non-Patent Literature Citations (1)
Entry |
Kirk-Othmer, Encyclopedia of Chemical Technology, vol. 1, pp. 213-219, 2nd Ed., 1963, Wiley, N.Y. |
Divisions (1)
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Number |
Date |
Country |
Parent |
232054 |
Feb 1981 |
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Continuation in Parts (3)
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Number |
Date |
Country |
Parent |
394204 |
Jul 1982 |
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Parent |
204424 |
Nov 1980 |
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Parent |
70390 |
Aug 1979 |
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