The present invention relates to a mold having a heat-insulating layer formed therein, and a method for manufacturing the mold.
A thermoplastic resin has been used in various fields such as electrical components and electronic components used for a car and the like; office equipment; containers for food and drink; and the like since it weighs less than other materials such as metal, and can be easily molded into desired forms by the injection-molding method and the like.
In a case in which a mold is filled with a molten thermoplastic resin as in the injection-molding method to obtain a resin molded article in a desired shape, a pattern and shape to be formed in the resin molded article are formed on a cavity surface of the mold.
In order to improve transferability of the pattern and shape on the cavity surface to the resin molded article, methods have been known such as those in which improvement is made in a thermoplastic resin, those in which a specific additive is added to a thermoplastic resin, and those in which a mold temperature is increased.
In particular, a method in which a mold temperature is increased is effective in that improvement of materials is not required. However, when a mold temperature is increased, more time is required for cooling and solidifying a plasticized thermoplastic resin, which generally decreases the forming efficiency.
In this regard, Patent Literature 1 and others disclose a mold having an inner wall surface coated with a heat-insulating layer having small heat conductivity, i.e., a heat-insulating mold.
In addition to the improvement of transferability as described above, the heat-insulating mold described above in Patent Literature 1 and others is also suitable for a case in which a mold temperature needs to be increased (for example, a case in which moldability or the like is improved).
[Patent Document 1] Japanese Unexamined Patent Application, Publication No. H09-155876
Meanwhile, in order to easily remove a resin molded article from a mold after molding, an ejector pin is used which is to be inserted through a through-hole provided in the mold such that the pin can move back and forth. When an ejector pin is used for a mold having a heat-insulating layer formed therein, friction between the heat-insulating layer and the ejector pin occurs at the rim of a through-hole in the inside of the mold. This friction causes a problem such as chipping of a heat-insulating layer.
Further, for the purpose of monitoring the conditions of a resin in a mold during molding, sensors such as a thermometer and a pressure gage is placed in a through-hole provided in the mold. In a case where a sensor is installed in a mold having a heat-insulating layer formed therein, friction between the heat-insulating layer and the sensor occurs at the rim of the through-hole when inserting the sensor because a clearance between the through-hole and the sensor is very small. This friction causes a problem such as chipping of a heat-insulating layer.
The present invention has been made in order to solve the above problems. An object of the present invention is to provide a technology for suppressing, in a mold having a heat-insulating layer formed therein, a problem of chipping of the heat-insulating layer and the like even when a penetrating member is inserted through a through-hole provided in the mold.
The present inventors found that in a mold having heat-insulating layer formed therein, a problem of chipping of the heat-insulating layer and the like occurs when a penetrating member is inserted through a through-hole provided in the mold. Accordingly the present inventors have conducted extensive studies to solve the above problem. As a result, the present inventors have found that the above problem can be solved by providing a mold comprising: a mold body having a convex part on an inner wall surface of the mold body, a heat-insulating layer arranged on the inner wall surface, and a through-hole which penetrates the convex part in a thickness direction of the mold body and through which the penetrating member can be inserted, wherein an outer periphery of the through-hole is inside an outer periphery of a top surface of the convex part. Then the present inventors have completed the present invention. More specifically, the present invention provides the following.
(1) A mold having a heat-insulating layer formed on an inner wall surface of the mold, comprising a through-hole extending from the inner wall surface in a thickness direction, wherein, with a penetrating member being inserted through the through-hole, the heat-insulating layer does not make a contact with the penetrating member, and an end surface of the penetrating member at the side of a cavity coincides with a surface of the cavity.
(2) The mold according to (1), comprising: a mold body having a convex part on an inner wall surface of the mold body; a through-hole penetrating the convex part in a thickness direction of the mold body; and a penetrating member inserted through the through-hole, wherein an outer periphery of the through-hole is present inside an outer periphery of a top surface of the convex part.
(3) The mold according to (2), wherein a spacing between the outer periphery of the through-hole on the top surface of the convex part and the outer periphery of the top surface of the convex part is 0.5 mm or less.
(4) The mold according to (2) or (3), wherein a side of the convex part is a sloped surface extending downward from the top surface to the inner wall surface, and the heat-insulating layer is a heat-insulating layer formed by a spraying method.
(5) The mold according to (2) or (3), wherein a side of the convex part comprises a perpendicular surface perpendicularly extending downward from the top surface to the inner wall surface and a sloped surface extending downward to the inner wall surface from a lower end of the perpendicular surface when a line of intersection between the top surface and the perpendicular surface is taken as an upper end of the perpendicular surface, and the heat-insulating layer is a heat-insulating layer formed by a spraying method.
(6) The mold according to (4) or (5), wherein an exterior angle between the top surface of the convex part and the sloped surface is 45° or less.
(7) A method for manufacturing a mold comprising: a heat-insulating layer forming step of forming a heat-insulating layer on an inner wall surface of a mold body having a convex part provided on the inner wall surface; a removal step of removing a portion of the heat-insulating layer or a portion of the heat-insulating layer and a portion of the convex part from a surface of the heat-insulating layer; and a through-hole forming step of forming a through-hole penetrating from a top surface of the convex part in a thickness direction of the mold body, wherein the removal step is a step of removing the portion of the heat-insulating layer or the portion of heat-insulating layer and the portion of the convex part so that an outer periphery of an opening of the through-hole on the top surface is present inside relative to an outer periphery of the top surface.
(8) A method for manufacturing a mold comprising: a second through-hole forming step of forming a through-hole from a top surface of a convex part of a mold body having the convex part, in a height direction of the convex part, the convex part being provided on an inner wall surface of the mold body; a second heat-insulating layer forming step of forming a heat-insulating layer on the inner wall surface, with a mask covering the through-hole and an outer periphery of the through-hole being placed on the top surface; and a removal step of removing the mask after forming the heat-insulating layer; wherein the second through-hole forming step is a step of forming the through-hole so that an outer periphery of an opening of the through-hole on the top surface is present inside relative to an outer periphery of the top surface.
A mold according to the present invention or a mold manufactured by the manufacturing method according to the present invention can suppress, in a mold having a heat-insulating layer formed therein, a problem of chipping of the heat-insulating layer and the like even when a penetrating member is inserted through a through-hole provided in the mold.
1, 1A, 1B: Mold
10, 10A, 10B: Mold body
101, 101B: Convex part
11: Through-hole
12: Heat-insulating layer
2: Mask
Hereinafter, embodiments of the present invention will be described. It should be understood that the present invention is not limited to the following embodiments.
As shown in
As shown in
There is a space inside the mold body 10 which serves as a cavity. The mold body 10 has an inner wall surface F1 (hereinafter may be referred to as the surface F1) and a surface F2 which forms the outer surface of the mold 1. As described below, most of the cavity surface forms the surface of the heat-insulating layer 12. When forming the heat-insulating layer 12, a shape of a resin molded article may be formed on the heat-insulating layer 12, but the shape which will be transferred to the resin molded article is preferably pre-formed on the surface F1. Further, in this embodiment, a mold in which the through-hole 11 is formed in the dual-divided mold 1 has a flange portion extending out from the edge of an inner wall surface of the mold. A portion of a surface of this flange portion forms a portion of a mold parting surface. Further, in a case where a heat-insulating layer described below is formed by the spraying method, on the surface of the flange portion, an angle between the surface to be a portion of the mold parting surface and the surface at the side of the inner wall surface is preferably 45° or more.
Moreover, there is no particular limitation on the shape of the other surface F2. It may be appropriately selected in view of easiness of mold-clamping and the like.
The convex part 101 extends toward the inside of the mold 1 from the surface F1. According to this embodiment, the convex part 101 is in a trapezoidal shape, and has a top surface F3. In addition, according to this embodiment, the exterior angle e between the side of the trapezoidal convex part 101 and the top surface F3 is 45° or less. Note that there is no particular limitation on the number, size and the like of the convex parts 101, and they may be adjusted as desired. Further, according to this embodiment, the convex part 101 is located at the side of the inner wall surface of the mold 1, but there is no particular limitation on the position of the convex part 101, and the convex part 101 may be provided at a desired position.
The through-hole 11 is a through-hole penetrating in the thickness direction of the mold body 10. According to this embodiment, the through-hole 11 is formed linearly extending from the top surface F3 of the convex part 101 in the thickness direction of the mold body 10.
A penetrating member can be inserted through the through-hole 11. Penetrating members can include an ejector pin and sensors such as a thermometer and a pressure gage. The end surface of a penetrating member at the side of the cavity is present within the same surface as the cavity surface when inserted through the through-hole 11. Note that a penetrating member is omitted and not shown in
The heat-insulating layer 12 is arranged on the surface F1 as shown in
Further, according to the present invention, the heat-insulating layer 12 described below is not formed at an outer periphery R1 of the through-hole 11. Therefore, the outer periphery of the through-hole 11 is present inside the outer periphery of the top surface F3. That is, a certain spacing is present between the outer periphery R1 of the through-hole 11 and the heat-insulating layer 12. According to this embodiment, the heat-insulating layer 12 is not formed on the top surface F3 of the convex part 101, and the outer periphery R1 of an opening of the through-hole 11 on the top surface F3 is present within the top surface F3 as shown in
There is no particular limitation on the thickness of the heat-insulating layer 12, but it is appropriately selected in view of the heat-insulating effect and the like of a material which constitutes the heat-insulating layer 12. Further, the thickness of the heat-insulating layer may not be constant. Moreover, according to this embodiment, the heat-insulating layer 12 forms the cavity surface.
The thermal conductivity required for the heat-insulating layer 12 is particularly preferred to be 2 W/m·K or less although it may differ depending on applications and the like.
There is no particular limitation on the material which constitutes the heat-insulating layer 12 as long as it has low thermal conductivity and thermal resistance good enough not to produce a fault even when contacted with a hot resin composition.
Examples of the material which satisfies the thermal resistance and thermal conductivity required for the heat-insulating layer 12 can include resins having low thermal conductivity and high thermal resistance such as a polyimide resin, and porous ceramics such as porous zirconia. Hereinafter, these materials will be described.
Specific examples of the polyimide resin include pyromellitic acid (PMDA) based polyimide, biphenyltetracarboxylic acid based polyimide, polyamidoimide in which trimellitic acid is used, bismaleimide based resin (bismaleimide/triazine based and the like), benzophenonetetracarboxylic acid based polyimide, acetylene-terminated polyimide, and thermoplastic polyimide. Note that a heat-insulating layer constituted of a polyimide resin is particularly preferred. Preferred materials other than polyimide resins include a tetrafluoroethylene resin and the like. Further, the heat-insulating layer may contain a resin other than a polyimide resin and a tetrafluoroethylene resin, an additive and the like in a range where the effect of the present invention is not compromised.
Zirconia contained in porous zirconia is not particularly limited, and may be any of stabilized zirconia, partially stabilized zirconia and unstabilized zirconia. Stabilized zirconia, which is zirconia in which cubic zirconia is stabilized even at room temperature, is excellent in mechanical properties such as strength and toughness and wear resistance. Partially stabilized zirconia, which refers to a state in which tetragonal zirconia partially remains even at room temperature, undergoes martensitic transformation from the tetragonal system to the monoclinic system, inhibits growth of cracks spread due to tensile stress in particular, and has high rupture toughness. Unstabilized zirconia refers to zirconia which is not stabilized by a stabilizer. At least two selected from stabilized zirconia, partially stabilized zirconia, and unstabilized zirconia may be used in combination.
As a stabilizer contained in stabilized zirconia and partially stabilized zirconia, a conventionally known stabilizer can be employed. Examples thereof include yttria, ceria and magnesia. The amount of the stabilizer used is not particularly limited, and can be appropriately set according to the use, the material to be used, and the like.
Note that porous ceramics other than porous zirconia can also be used, but porous zirconia has higher durability as compared with other porous ceramics. For this reason, when the mold 1 having the heat-insulating layer 12 constituted of porous zirconia formed therein is used, faults such as deformation of the heat-insulating layer 12 do not easily occur. Therefore, more molded articles can be continuously molded, leading to the significantly increased productivity of molded articles.
A raw material to form the heat-insulating layer 12 may further contain conventionally known additives and the like in addition to the above-described zirconia and stabilizer within a range of not hindering the effect of the present invention.
In the present invention, there is no particular limitation on the method for manufacturing the above mold 1, but the mold according to the present invention is preferably manufactured using the manufacturing method according to the present invention. Hereinafter, the method for manufacturing the mold according to the present invention will be described with reference to the manufacturing method according to the present invention as an example.
The manufacturing method according to the present invention comprises a heat-insulating layer forming step, a removal step and a through-hole forming step.
In the heat-insulating layer forming step, the heat-insulating layer 12 is formed on an inner wall surface of the mold body 10. There is no particular limitation on the method for forming the heat-insulating layer 12. Preferred conditions may be appropriately used depending on a material which constitutes the heat-insulating layer 12 or the like.
The heat-insulating layer forming step according to this embodiment corresponds to a step of transforming a state shown in
For example, in a case where the material which constitutes the heat-insulating layer 12 is a resin having high thermal resistance and low thermal conductivity such as a polyimide resin, the following methods may be used: a method for forming a heat-insulating layer of polyimide film and the like, the method comprising: applying a solution of a polymer precursor capable of forming a polymeric heat-insulating layer such as a polyimide precursor to the surface F1 and the surface of the convex part 101 (also referred to as “a heat-insulating layer-formed surface” herein), applying heat to evaporate a solvent and further applying heat for polymerization; a method in which a monomer of a thermally stable polymer, for example, pyromellitic acid anhydride and the 4,4-diaminodiphenyl ether is vapor deposited and polymerized; or in the case of a planar mold, a method for forming the heat-insulating layer 12, the method comprising attaching a polymeric heat-insulating film on a heat-insulating layer-formed surface of the mold body 10 using an appropriate adhesion method or a polymeric insulating film in a form of an adhesive tape. In addition, a polyimide film may be formed, and then on that surface, a chromium (Cr) film or a titanium nitride (TiN) film as a metal based hard film may be further formed.
Further, in a case where a material which constitutes the heat-insulating layer 12 is porous ceramics such as porous zirconia, the spraying method is preferably used. By employing the spraying method, the thermal conductivity of porous zirconia and the like is easily adjusted to fall within a desired range. In addition, there is not a problem that the mechanical strength of the heat-insulating layer 12 is considerably decreased due to formation of excessive bubbles in the inner part of porous zirconia and the like. By forming the heat-insulating layer 12 by spraying as described above, the structure of the heat-insulating layer 12 becomes suitable for the use of the present invention.
For example, formation of the heat-insulating layer 12 by spraying can be performed in the following manner. First, a raw material is melted into a liquid. The liquid is accelerated to collide against the heat-insulating layer-formed surface. Lastly, the raw material, which collides against the heat-insulating layer-formed surface and is deposited thereon, is solidified. In this way, a very thin heat-insulating layer 12 is formed on the inner surface of a mold. By further causing a molten raw material to collide onto the very thin heat-insulating layer 12 and to be solidified, the thickness of the heat-insulating layer 12 can be adjusted. For the method for solidifying a raw material, conventionally known cooling means may be used, or the raw material may be merely left standing and thereby solidified. The spraying method is not particularly limited, and a preferred method can be appropriately selected from arc spraying, plasma spraying, flame spraying and the like.
The removal step refers to a step of removing a portion of the heat-insulating layer 12 (in some cases, a portion of the heat-insulating layer 12 and a portion of the convex part) from the surface of the heat-insulating layer 12 formed in the heat-insulating layer forming step. The heat-insulating layer removal step corresponds to a step of transforming a state shown in
In this step, first, the heat-insulating layer 12 is removed from the surface of the heat-insulating layer 12 in the thickness direction of the heat-insulating layer 12. Continued removal will expose the top surface F3. In this step, it is sufficient to remove the heat-insulating layer 12 present on the top surface F3. Then, as the removal step is continued, the convex part 101 is being removed from the top surface F3 such that it becomes thin in the height direction of the convex part 101 (which is the same direction as the thickness direction of the heat-insulating layer in this embodiment). In the removal step, after the top surface F3 is reached, how far the removal step is continued in the thickness direction of the heat-insulating layer 12 is determined, for example, depending on the size of the opening of the through-hole 11 and the like. According to this embodiment, the outer periphery R1 of the opening of the through-hole 11 is present inside the outer periphery R2 of the top surface F3. Therefore, in a case where the outer periphery R1 of the opening of the through-hole 11 may not be surrounded by the outer periphery R2 of the top surface F3 before removal, the removal step is performed to an extent that the outer periphery R1 may be surrounded by the outer periphery R2.
There is no particular limitation on the method for performing the removal step, but a preferred method is appropriately selected depending on a material which constitutes the heat-insulating layer 12, a material which constitutes the convex part 101 and the like. Examples of the method include grinding with diamond paste.
Note that in the description of this embodiment, an example is described in which the heat-insulating layer 12 and the convex part 101 are removed so that the surface of the heat-insulating layer 12 coincides with the top surface F3 of the convex part 101. But the removal step may be performed without leveling the height of the heat-insulating layer 12 with that of the convex part 101, or the removal step may be performed so that a portion having a different thickness within the heat-insulating layer 12 may appear.
The through-hole forming step refers to a step of forming the through-hole 11 which penetrates in the thickness direction of the convex part 101 (in the height direction of the convex part 101), and through which a penetrating member can be inserted. Further, the through-hole forming step is a step of transforming a state shown in
The through-hole 11 is formed so that it penetrates the convex part 101 in the height direction of the convex part 101. In this step of this embodiment, the through-hole 11 is formed so that, on the top surface F3, a certain spacing is provided between the outer periphery R2 of the top surface F3 and the outer periphery R1 of the through-hole 11. There is no particular limitation on the specific method for forming the through-hole 11, and any common method such as machining may be used.
After forming the through-hole 11, a penetrating member is inserted through the through-hole 11, thereby completing the mold according to this embodiment.
In addition to the mold manufacturing methods described above, the mold according to the present invention can also be manufactured by the following method.
The manufacturing method according to the second embodiment comprises a second through-hole forming step of forming the through-hole 11 from the top surface F3 of the convex part 101 of the mold body 10 in the height direction of the convex part 101, a second heat-insulating layer forming step of forming a heat-insulating layer on an inner wall surface, with a mask covering the through-hole 11 and the outer periphery of the through-hole 11 being placed on the top surface F3, and a mask removal step of removing the mask after forming the heat-insulating layer.
The second through-hole forming step is a step of transforming a state shown in
The second heat-insulating layer forming step is a step of transforming a state shown in
Subsequently, the heat-insulating layer 12 is formed on an inner wall surface of the mold body 10 including the surface of the mask 2. A method for forming the heat-insulating layer 12 is similar to that in the manufacturing method according to the first embodiment as described above.
The mask removal step is a step of transforming a state shown in
According to the mold according to the present embodiment and the method for manufacturing the mold, the following effects can be achieved.
The convex part 101 and the heat-insulating layer 12 are present on the surface F1, and the through-hole 11 is provided in the convex part 101. By forming the through-hole 11 in the convex part 101, a state where the heat-insulating layer 12 is not formed at the outer periphery R1 of the through-hole 11 can be easily obtained. If the heat-insulating layer 12 is not formed at the outer periphery R1 of the through-hole 11, problems such as abrasion of the heat-insulating layer 12 by a penetrating member will not arise even when the penetrating member is inserted through the through-hole 11.
According to the mold of the present embodiment, the spacing between the outer periphery R1 of the through-hole 11 at the top surface F3 of the convex part 101 and the outer periphery R2 of the top surface F3 of the convex part 101 is 0.5 mm or less. In a case where the spacing is about 0.5 mm or less, adjustment of the spacing is not difficult, and even in a mold for manufacturing a small molded article, a problem caused by the heat-insulating layer 12 not being formed on a portion of the top surface F3 of the convex part 101 will not easily arise.
In the mold 1 according to the present embodiment, the side of the convex part 101 is a sloped surface extending downward from the top surface F3 to an inner wall surface of the mold. By forming the aforementioned sloped surface, even in a case where the heat-insulating layer 12 is formed by the spraying method, problems such as a non-uniform thickness of the heat-insulating layer 12 can be suppressed. In view of easiness of forming the heat-insulating layer 12, the exterior angle 0 between the top surface F3 of the convex part 101 and the sloped surface is preferably 45° or less.
According to the method for manufacturing the mold 1 according to the embodiment, in the step of removing a portion of the heat-insulating layer 12 or a portion of the heat-insulating layer 12 and a portion of the convex part 101 from the surface of the heat-insulating layer 12 in the thickness direction of the heat-insulating layer 12, the spacing between the outer periphery R1 and the outer periphery R2 can be adjusted. Therefore, a state in which the heat-insulating layer 12 is not formed at the outer periphery R1 of the through-hole 11 can be easily formed.
The preferred embodiments of the mold according to the present invention are described above, but the present invention is not limited to the aforementioned embodiments, but can be performed in various forms.
Further, the bottom of the mold body 10 in the aforementioned embodiments has an angle of 90° as shown in
Further, preferred embodiments of the mold according to the present invention also include an embodiment shown in
As shown in
The convex part 101B extends toward the inside of the mold 1B from the surface F1. According to this embodiment, the convex part 101B has the top surface F3, and the side of the convex part 101B comprises a perpendicular surface perpendicularly extending downward from the top surface F3 to the surface F1, and a sloped surface extending downward to the surface F1 from a lower end of the perpendicular surface when the line of intersection between the top surface F3 and the perpendicular surface is taken as an upper end of the perpendicular surface. The exterior angle e between the sloped surface which constitutes the side of the convex part 101B and the top surface F3 is 45° or less. More specifically, it is as shown in
In the present invention, there is no particular limitation on the method for manufacturing the mold 1B, but the mold 1B can be manufactured by substituting the convex part 101B for the convex part 101 in the method for manufacturing the mold 1 as described in
According to the mold 1B of this embodiment and the method for manufacturing the mold 1B, the following effects can be achieved.
In the mold 1B, the side of the convex part 101B not only has a sloped surface but also has a perpendicular surface. Therefore, a portion in which a thickness of the heat-insulating layer 12 is thin becomes small as compared with the case of the mold 1. Therefore, in the mold 1B, a higher heat-insulating effect can be obtained near the convex part 101B.
In a case where the mold 1B is manufactured according to
Note that other effects are similar to those from the mold 1 and the method for manufacturing the mold 1.
Further, the mold body 10 at the side in which the through-hole 11 is not formed in the dual-divided mold 1 as shown in
A mold in which the through-hole 11 is not formed can be manufactured according to the manufacturing method as shown in
Number | Date | Country | Kind |
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2011-188347 | Aug 2011 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2012/072040 | 8/30/2012 | WO | 00 | 2/27/2014 |