This invention relates to molding apparatus and related methods.
Early male touch fastener products were generally woven materials, with hooks formed by cutting filament loops. More recently, arrays of small fastener elements have been formed by molding the fastener elements, or at least the stems of the elements, of resin, forming an interconnected sheet of material. Generally, molded plastic hook tape has displaced traditional woven fabric fasteners for many applications, primarily because of lower production costs.
Molded plastic hook tape is often attached to substrates by employing an adhesive, or by sewing when the substrate is a made from sewable material. Often, adhesive-backed hook tape is utilized to attach the hook tape at desired locations on the substrate. Unfortunately, the process of applying adhesive-backed hook tape can be slow, and adhesion of the adhesive-backed hook tape to the substrate can be poor.
Generally, the invention relates to molding apparatus and related methods.
In one aspect, the invention features a method of molding projections on a substrate. The method includes introducing a substrate having an outer surface into a gap formed between a peripheral surface of a rotating mold roll that defines a plurality of discrete cavities that extend inwardly from the peripheral surface, and a supporting surface. Resin is delivered to a nip formed between the outer surface of the substrate and the peripheral surface of the rotating mold roll. The outer surface of the substrate and the peripheral surface of the rotating mold roll are arranged to generate sufficient pressure to at least partially fill the cavities in the mold roll as the substrate is moved through the gap to mold an array of discrete projections including stems that extend integrally from a layer of the resin bonded to the substrate. The molded projections are then withdrawn from their respective cavities by separation of the peripheral surface of the mold roll from the outer surface of the substrate by continued rotation of the mold roll. The substrate has a beam stiffness, measured as a product of an overall moment of inertia of a nominal transverse cross-section and an effective modulus of elasticity of a material from which the substrate is formed, that is greater than about 200 lb-in2 (0.574 N-m2).
In some embodiments, the beam stiffness is greater than 1,000 lb-in2 (2.87 N-m2), e.g., 4,000 lb-in2 (11.48 N-m2) or more, e.g., 8,000 lb-in2 (22.96 N-m2).
In some instances, the effective modulus of elasticity of the material from which the substrate is formed is greater than 100,000 psi (6.89×108 N/m2), e.g., 250,000 psi (1.72×109 N/m2), 750,000 psi (5.17×109 N/m2), 1,000,000 psi (6.89×109 N/m2) or more, e.g., 5,000,000 psi (3.45×1010 N/m2), 15,000,000 psi (1.03×1011 N/m2) or more, e.g., 30,000,000 psi (2.07×1011 N/m2).
In some implementations, the supporting surface is a peripheral surface of a counter-rotating pressure roll or a fixed pressure platen.
In some embodiments, the cavities of the mold roll are shaped to mold hooks so as to be engageable with loops. In other embodiments, the cavities of the mold roll are shaped to mold hooks, and the hooks are reformed after molding.
In some instances, each projection defines a tip portion, and the method further includes deforming the tip portion of a plurality of projections to form engaging heads shaped to be engageable with loops, or other projections, e.g., of a complementary substrate.
In some embodiments, the resin is delivered directly to the nip. In some implementations, the resin is delivered first to the outer surface of the substrate upstream of the nip, and then the resin is transferred to the nip, e.g., by rotation of the mold roll.
The substrates can have a variety of shapes, e.g., the substrate can have an “L” shape, “T” shape or “U” shape in transverse cross-section.
In some embodiments, the method further includes introducing another resin beneath the resin such that the other resin becomes bonded to the outer surface of the substrate and the resin becomes bonded to an outer surface of the other resin.
The substrate can have, e.g., an average surface roughness of greater than 1 micron, e.g., 2 micron, 4 micron, 8 micron, 12 micron or more, e.g., 25 micron.
In some implementations, the substrate is formed from more than a single material.
In some instances, the projections have a density of greater than 300 projections/in2 (46.5 projections/cm2).
In some embodiments, the method further comprises pre-heating the substrate prior to introducing the substrate into the gap, or priming the substrate prior to introducing the substrate into the gap.
In another aspect, the invention features a method of molding projections on a substrate. The method includes introducing a substrate, e.g., a linear substrate, having an outer surface into a gap formed between a peripheral surface of a rotating mold roll that defines a plurality of discrete cavities that extend inwardly from the peripheral surface, and a supporting surface. The resin is delivered to a nip formed between the outer surface of the substrate and the peripheral surface of the rotating mold roll. The outer surface of the substrate and the peripheral surface of the rotating mold roll are arranged to generate sufficient pressure to at least partially fill the cavities in the mold roll as the substrate is moved through the gap to mold an array of discrete projections including stems extending integrally from a layer of the resin bonded to the substrate. The molded projections are withdrawn from their respective cavities by separation of the peripheral surface of the mold roll from the outer surface of the substrate by continued rotation of the mold roll. The substrate has a beam stiffness sufficiently great that during withdrawal of the molded projections from their respective cavities, the substrate remains substantially linear.
In some embodiments, the beam stiffness of the substrate, measured as a product of an overall moment of inertia of a nominal transverse cross-section and an effective modulus of elasticity of material of the substrate, is greater than about 200 lb-in2 (0.574 N-m2).
In another aspect, the invention features an article having molded fastening projections. The article includes a substrate and an array of discrete molded projections including stems extending outwardly from and integrally with a molded layer of resin solidified about surface features of the substrate, and thereby securing the projections directly to the substrate. The substrate has a beam stiffness, measured as a product of an overall moment of inertia of a nominal transverse cross-section and an effective modulus of elasticity of a material from which the substrate is made, that is greater than about 200 lb-in2 (0.574 N-m2).
In some embodiments, the beam stiffness is greater than about 1,000 lb-in2 (2.87 N-m2), e.g., 4,000 lb-in2 (11.48 N-m2).
Embodiments may have one or more of the following advantages. Projections can be integrally molded onto substrates, e.g., substrates useful in construction, e.g., wallboard, window frames, panels, or tiles, without the need for using an adhesive, often reducing manufacturing costs, e.g., by reducing labor costs and increasing throughput. Integrally molding projections often improves adhesion of the molded projections to the substrate and reduces the likelihood of delamination of the molded projections from the substrate during the application of a force, e.g., a peeling force, or a shear force.
In situ lamination of hook, bands or islands on rigid materials held in a planar orientation or presenting a planar surface, extend in rigid flexible materials is also featured.
All publications, patent applications, patents, and other references mentioned herein are incorporated by reference herein in their entirety.
Other features and advantages of the invention will be apparent from the following detailed description, and from the claims.
Like reference symbols in the various drawings indicate like elements.
Rigid or elastically stretchable substrates having molded fastener projections, and methods of making the same are described herein. Generally, rigid substrates have a beam stiffness that is sufficiently great such that during withdrawal of the molded projections from their respective cavities, the substrate remains substantially straight, and does not bend away from its support. In other cases, elastically stretchable substrates have flexibility in only one orthogonal direction. The elastic material is arranged with the stretchable direction lying in the cross machine direction.
Referring collectively to FIGS. 1 and 1A-1C, a process 10 for integrally molding projections, e.g., hooks 12, onto a substrate 14, e.g., a T-shaped substrate, includes introducing the substrate 14 that has an outer surface 16 into a gap 18 formed between a peripheral surface 20 of a rotating mold roll 22 and a fixed pressure platen 24 that has a supporting surface 27. The mold roll 22 defines a plurality of discrete cavities, e.g., cavities 26 in the shape of hooks, that extend inwardly from peripheral surface 20 of the rotating mold roll 22. An extruder (not shown) pumps resin 30, e.g., molten thermoplastic resin, through a die 31 where it is delivered to a nip N formed between outer surface 16 of the substrate and peripheral surface 20 of the rotating mold roll 22. The outer surface 16 of the substrate 14 and peripheral surface 20 of rotating mold roll 22 are arranged to generate sufficient pressure to fill the cavities in the mold roll 22 as substrate 14 is moved through gap 18 to integrally mold an array of discrete hooks 12, including stems 34, which extend outwardly from and are integral with a layer 40 that is bonded to outer surface 16. The molded hooks 12 are withdrawn from their respective cavities 26 by separation of the peripheral surface 20 of the mold roll 22 from outer surface 16 of substrate 14 by continued rotation of mold roll 22. Substrate 14 has a beam stiffness sufficiently great such that during withdrawal of hooks 12 from their respective cavities, the substrate 14 remains substantially linear, and is not bent away from the supporting surface 27 of fixed pressure platen 24 toward moll roll 22 (indicated by arrow 29). For example, substrate 14 has a beam stiffness, measured as a product of an overall moment of inertia of a nominal transverse cross-section and an effective modulus of elasticity (Young's modulus) of a material from which the substrate is formed, that is, e.g., greater than 1,000 lb-in2 (2.87 N-m2), e.g., 4,000 lb-in2 (11.48 N-in2) or greater, e.g., 8,000 lb-in2 (22.96 N-m2). The effective modulus of elasticity of the material from which the substrate is formed is measured using ASTM E111-04 at 25° C. at fifty percent relative humidity, allowing sufficient time for moisture and temperature equilibration.
In some implementations, the outer surface 16 of substrate 14, the peripheral surface 20 of the rotating mold roll 22 and the resin 30 are arranged to generate sufficient friction such that the substrate 14 is pulled into and moved through gap 18, in a direction indicated by arrow 41, by continued rotation of mold roll 22.
In some embodiments, mold roll 22 includes a face-to-face assembly of thin, circular plates or rings (not shown) that are, e.g., about 0.003 inch to about 0.250 inch (0.0762 mm-6.35 mm) thick, some rings having cutouts in their periphery that define mold cavities, and other rings having solid circumferences, serving to close the open sides of the mold cavities and to serve as spacers, defining the spacing between adjacent projections. In some embodiments, adjacent rings are configured to mold hooks 12 such that alternate rows 50, 52 (
Referring to
Referring particularly to
In some embodiments, the process shown in
Referring now to
Referring to
Referring particularly to
It is often desirable to chill the conformation roll, e.g., by running cold water through a channel 115 in the center of roll 114, to counteract heating of conformation roll 114 by the heat of the resin. Process 100 can be performed in line with the process shown in
Referring now to
In any of the above embodiments, suitable materials for forming projections, e.g., hooks 12 or stems 82, are resins, e.g., thermoplastic resins, that provide the mechanical properties that are desired for a particular application. Suitable thermoplastic resins include polypropylene, polyethylene, acrylonitrile-butadiene-styrene copolymer (ABS), polyamide, e.g., nylon 6 or nylon 66, polyesters, e.g., polyethylene terephthalate (PET) or polybutylene terephthalate (PBT), and blends of these materials. The resin may include additives, e.g., lubricating agents, e.g., silicones or fluoropolymers, solid fillers, e.g., inorganic fillers, e.g., silica or pigments, e.g., titanium dioxide. In some embodiments, lubricating agents are employed to reduce the force required to remove molded hooks from their respective cavities. In some embodiments, an additive is used to improve adhesion of the resin 30 to substrate 14, e.g., an anhydride-modified linear low-density polyethylene, e.g., Plexar® PX114 available from Quantum.
In any of the above embodiments, the overall moment of inertia of the nominal transverse cross-section of the substrate can be greater than 0.00020 in4 (0.00832 cm4). Examples of substrate inertial moments include 0.00065 in4 (0.0271 cm4), 0.0050 in4 (0.208 cm4), 0.040 in4 (1.67 cm4) and 0.5 in4 (20.8 cm4).
In any of the above embodiments, the effective modulus of elasticity of the material from which the substrate can be greater than 100,000 psi (6.89×108 N/m2), e.g., 250,000 psi (1.72×109 N/m2), 750,000 psi (5.17×109 N/m2), 1,000,000 psi (6.89×109 N/m2) or more, e.g., 5,000,000 psi (3.45×1010 N/m2), 15,000,000 psi (1.03×1011 N/m2) or more, e.g., 30,000,000 psi (2.07×1011 N/m2). The effective modulus of elasticity of the material from which the substrate is formed is measured using ASTM E111-04 at 25° C. at fifty percent relative humidity, allowing sufficient time for moisture and temperature equilibration.
In any of the above embodiments, the substrate can be, e.g., a construction material, such as wallboard, window frame, wall panel, floor tile, or ceiling tile.
In any of the above embodiments, in order to improve adhesion of resin to the substrate, it is often advantageous to mold onto a substrate with an average surface roughness of greater than 1 micron, e.g., 2, 3, 4, 5 micron or more, e.g., 10 micron, as measured using ISO 4288:1996(E).
In any of the above embodiments, the projections, e.g., hooks 12 or stems 82, preferably have a density of greater than 300 projections/in2 (46.5 projections/cm2), e.g., 500 (77.5 projections/cm2), 1,000 (155.0 projections/cm2), 2000 (310.0 projections/cm2) or more, e.g., 3,500 projections/in2 (542.5 projections/cm2).
In any of the above embodiments, the substrate can be pre-heated prior to introducing substrate 14 into the gap 18. Pre-heating is sometimes advantageously used to improve adhesion of the resin 30 (or other resin 152) to substrate 14. It can also be used, when a thermoplastic resin is employed, to prevent over cooling of the thermoplastic resin before entering the nip N.
In any of the above embodiments, substrate 14 can be primed, e.g., to improve the adhesion of resin 30 (or 152) to substrate 14. In some embodiments, the priming is performed just prior to introduction of substrate 14 into the gap 18. Suitable primers include acetone, isobutane, isopropyl alcohol, 2-mercaptobenzothiazole, N,N-dialkanol toluidine, and mixtures of these materials. Commercial primers are available from Loctite® Corporation, e.g., Loctite® T7471 primer.
While certain embodiments have been described, other embodiments are envisioned.
While various locations of an extruder head are specifically shown in
As another example, while embodiments have been described in which substrates are formed from a single material, in other embodiments, substrates are formed from multiple materials. For example, the substrates can be formed of wood, metal, e.g., steel, brass, aluminum, aluminum alloys, or iron, plastic, e.g., polyimide, polysulfone, or composites, e.g., composites of fiber and resin, e.g., fiberglass and resin.
As an additional example, while embodiments have been described in which the base of the fastener is formed of a single layer, in other embodiments, such bases are formed of more than a single layer of material. Referring to
As a further example, while substrates have been described that are T-shaped and planar in transverse cross-section, other transverse shapes are possible. Referring to
While the embodiments of
While projections 82 of
Referring to
Where the band or bands of fastener stems or fully formed hooks are to be applied near the edge of substrate 14, the required nip forces are sufficiently low that rolls 46a and 48a may be supported from one end using suitably spaced bearings of a cantilever mounting. That arrangement is suggested in the solid line diagram of the mounting of mold roll 46a in
Referring to
The amount of molten thermoplastic resin delivered to the mold roll determines whether the hooks will form an integral array of thermoplastic resin joined together by a thin base layer which is adhered to the surface of the preformed carrier sheet or substrate 14 or whether the hooks will be separate from one anther, individually adhered to the carrier. For example, as shown in
However, by reducing the amount of thermoplastic resin delivered to the mold roll, joining base layer 122a can be eliminated so that the base of each molded fastener stem is in situ bounded substrate 14 without thermoplastic resin joining hooks 124c together.
Referring now to
It will be realized that the apparatus of
There are other ways to form e.g. separated parallel linear bands or discrete, disconnected islands of hooks on the above-described substrates within certain broad aspects of the present invention. For example, at dispersed, selected locations across the width of a traveling preformed substrate, e.g. a material defining hook-engageable loops, discrete separate molten resin deposits of the desired form, e.g. of x, y-isolated islands, or in spaced apart parallel bands, may be deposited upon the surface structure of the substrate. Following this, upper portions of the resin deposits, while still molten, or after being reheated by an intense localized flame line, are molded into fastener stems by mold cavities that are pressed against the resin deposits. For instance, at selected widthwise separated locations along a deposit line, as the substrate transits the line, discrete island-form deposits are made at selected locations. Immediately, with the resin still molten, or after heat activation, the substrate is introduced into a molding nip, formed by a mold roll and a pressure roll. The mold roll, for instance, defines tiny fixed hook fastener cavities as described above, or smaller fastener features, e.g. of less than 0.005 inch height, or similarly shallow cavities for tiny stem preforms, that are aligned to press down upon the resin deposits under conditions in which nip pressure causes the molten resin to enter the cavities at the base of the stem portion of the cavities, and fill the molds, and be molded into a localized dense array of stem preforms or into a localized dense array of fully formed loop-engageable molded hooks. With appropriate amounts of resin in the deposits, a base layer common to all of the molded stems of a discrete island deposit can be formed by the mold roll surface, as may be desired. The mold pressure, simultaneously with the molding, causes the resin to bond firmly to the surface structure of the preformed carrier, effecting in situ lamination. Where the preformed substrate has a fibrous or porous makeup, as with hook-engageable loop material, the nip pressure causes the resin to commingle with the top fibers or other structure that define the surface structure of the substrate, without penetrating the full depth of the substrate. Thus the opposite side of the substrate can remain pristine, free of the molding resin, and, if the opposite surface of the preformed web defines a uniform surface of hook-engageable loops across the full width of the article, the effectiveness of those loops can be preserved while the molded stems or fully molded hooks are molded and in situ bonding occurs.
With such arrangements it will be understood that the regions of the substrate between the separated islands remain free of the resin from which the hooks or stem preforms are molded. Thus, in the case of elastically stretchy substrate webs or carrier sheet preforms, whether of plain preformed elastomer sheet, or of stretchy hook-engageable loop material, the resin-free regions enable the web to be elastically stretchy, while flexibility of the article in both orthogonal (X,Y) directions in the plane of the web is achieved. Where the preformed carrier web is a non-stretchy, but flexible material, such as a bi-directionally stabilized knit loop product having hook-engageable loops on both sides, the regions between the separated islands enable the finished article to be simply flexible in both X and Y directions in the plane of the fabric.
In certain embodiments, rather than locating discrete regions of hook cavities on the mold roll, in positions to register with a pre-arranged pattern of resin deposits, the mold roll may simply have an array of mold cavities entirely occupying the mold surface of the roll, or may have such mold cavities in narrow bands separated by enlarged spacer rings or cross-wise extending ridges, as described above.
Still other embodiments are within the scope of the claims that follow.
This application is a continuation of U.S. Ser. No. 11/748,427, filed May 14, 2007, which is a continuation-in-part of U.S. Ser. No. 11/005,185, filed Dec. 6, 2004, which is a divisional of Ser. No. 10/163,169, filed Jun. 4, 2002, now U.S. Pat. No. 6,991,843, which is a continuation-in-part of U.S. Ser. No. 09/808,395, filed Mar. 14, 2001, now U.S. Pat. No. 7,048,818, which claims the benefit of U.S. Ser. No. 60/242,877, filed Oct. 24, 2000. The entire contents of each of the foregoing are hereby incorporated by reference.
Number | Name | Date | Kind |
---|---|---|---|
822536 | Mills | Jun 1906 | A |
2820277 | Forster | Oct 1955 | A |
2760230 | Van Riper | Aug 1956 | A |
2893056 | Henning | Jul 1959 | A |
3312583 | Rochlis | Apr 1967 | A |
3399425 | Lemelson | Sep 1968 | A |
3547776 | Curtis | Dec 1970 | A |
3557407 | Lemelson | Jan 1971 | A |
3718725 | Hamano | Feb 1973 | A |
3752619 | Menzin et al. | Aug 1973 | A |
3758657 | Menzin et al. | Sep 1973 | A |
3762000 | Menzin et al. | Oct 1973 | A |
3857397 | Brosseau | Dec 1974 | A |
3945781 | Doleman | Mar 1976 | A |
4097634 | Bergh | Jun 1978 | A |
4164008 | Miller et al. | Aug 1979 | A |
4173444 | Alfio | Nov 1979 | A |
4234300 | Yamagisi et al. | Nov 1980 | A |
4234531 | Jocteur | Nov 1980 | A |
4281211 | Tatum | Jul 1981 | A |
4285648 | Jocteur | Aug 1981 | A |
4468435 | Shimba et al. | Aug 1984 | A |
4602191 | Davila | Jul 1986 | A |
4732800 | Groshens | Mar 1988 | A |
4734229 | Johnson et al. | Mar 1988 | A |
4775310 | Fischer | Oct 1988 | A |
4794028 | Fischer | Dec 1988 | A |
4803872 | Crawford et al. | Feb 1989 | A |
4863541 | Katz et al. | Sep 1989 | A |
4872243 | Fischer | Oct 1989 | A |
4880589 | Shigemoto et al. | Nov 1989 | A |
4887339 | Bellanger | Dec 1989 | A |
4999067 | Erb et al. | Mar 1991 | A |
5077870 | Melbye et al. | Jan 1992 | A |
5226992 | Morman | Jul 1993 | A |
5260015 | Kennedy et al. | Nov 1993 | A |
5310964 | Roberts et al. | May 1994 | A |
5312570 | Halter | May 1994 | A |
5324188 | Santoh et al. | Jun 1994 | A |
5326415 | Thomas et al. | Jul 1994 | A |
5441687 | Murasaki et al. | Aug 1995 | A |
5455749 | Ferber | Oct 1995 | A |
5499912 | Mezei | Mar 1996 | A |
5503792 | Kawamura et al. | Apr 1996 | A |
5505747 | Chesley et al. | Apr 1996 | A |
5518795 | Kennedy et al. | May 1996 | A |
5537723 | Yoshida et al. | Jul 1996 | A |
5569549 | Redford | Oct 1996 | A |
5607635 | Melbye et al. | Mar 1997 | A |
5620015 | Gribble et al. | Apr 1997 | A |
5620769 | Wessels et al. | Apr 1997 | A |
5643651 | Murasaki | Jul 1997 | A |
5669120 | Wessels et al. | Sep 1997 | A |
5679302 | Miller et al. | Oct 1997 | A |
5716574 | Kawasaki | Feb 1998 | A |
5749129 | Murasaki et al. | May 1998 | A |
5755015 | Akeno et al. | May 1998 | A |
5763112 | Redford | Jun 1998 | A |
5781969 | Akeno et al. | Jul 1998 | A |
5792408 | Akeno et al. | Aug 1998 | A |
5800760 | Takizawa et al. | Sep 1998 | A |
5800845 | Akeno et al. | Sep 1998 | A |
5807516 | Wolstenholme et al. | Sep 1998 | A |
5845375 | Miller et al. | Dec 1998 | A |
5857245 | Sakakibara et al. | Jan 1999 | A |
5863566 | Wood et al. | Jan 1999 | A |
5868987 | Kampfer et al. | Feb 1999 | A |
5879604 | Melbye et al. | Mar 1999 | A |
5908680 | Moren et al. | Jun 1999 | A |
5933927 | Miller et al. | Aug 1999 | A |
5938997 | Sakakibara et al. | Aug 1999 | A |
5945131 | Harvey et al. | Aug 1999 | A |
5945193 | Pollard et al. | Aug 1999 | A |
5948337 | Sakakibara et al. | Sep 1999 | A |
5953797 | Provost et al. | Sep 1999 | A |
5981027 | Parellada | Nov 1999 | A |
6000106 | Kampfer et al. | Dec 1999 | A |
6036259 | Hertel et al. | Mar 2000 | A |
6039911 | Miller et al. | Mar 2000 | A |
6054091 | Miller et al. | Apr 2000 | A |
6060009 | Welygan et al. | May 2000 | A |
6115891 | Suenaga et al. | Sep 2000 | A |
6210771 | Post et al. | Apr 2001 | B1 |
6248276 | Parellada et al. | Jun 2001 | B1 |
6248419 | Kennedy et al. | Jun 2001 | B1 |
6254304 | Takizawa et al. | Jul 2001 | B1 |
6258311 | Jens et al. | Jul 2001 | B1 |
6280670 | Buzzell et al. | Aug 2001 | B1 |
6287665 | Hammer | Sep 2001 | B1 |
6406467 | Dilnik et al. | Jun 2002 | B1 |
6481063 | Shepard et al. | Nov 2002 | B2 |
6540863 | Kenney et al. | Apr 2003 | B2 |
6592800 | Levitt et al. | Jul 2003 | B1 |
6604264 | Naohara et al. | Aug 2003 | B1 |
6610231 | Takizawa et al. | Aug 2003 | B2 |
6627133 | Tuma | Sep 2003 | B1 |
6668380 | Marmaropoulos et al. | Dec 2003 | B2 |
6697262 | Adams et al. | Feb 2004 | B2 |
6991843 | Armela et al. | Jan 2006 | B2 |
7048818 | Krantz et al. | May 2006 | B2 |
20010016245 | Tuman et al. | Aug 2001 | A1 |
20010018110 | Tuman et al. | Aug 2001 | A1 |
20020022108 | Krantz et al. | Feb 2002 | A1 |
20020044356 | Arakawa et al. | Apr 2002 | A1 |
20020069495 | Murasaki | Jun 2002 | A1 |
20020125605 | Lacey et al. | Sep 2002 | A1 |
20030085492 | Schulte | May 2003 | A1 |
20030135964 | Provost et al. | Jul 2003 | A1 |
20040008835 | Knox et al. | Jan 2004 | A1 |
20040088835 | Tachauer et al. | May 2004 | A1 |
20040131823 | Rodgers et al. | Jul 2004 | A1 |
20040201124 | Harvey et al. | Oct 2004 | A2 |
20040222551 | Provost et al. | Nov 2004 | A1 |
20050091805 | Armela et al. | May 2005 | A1 |
20060210762 | Tachauer | Sep 2006 | A1 |
20070264482 | Banker et al. | Nov 2007 | A1 |
Number | Date | Country |
---|---|---|
2213686 | Oct 1972 | DE |
0341993 | May 1989 | EP |
0482749 | Sep 1991 | EP |
0766934 | Sep 1996 | EP |
0811332 | Oct 1996 | EP |
0 813 277 | Dec 1997 | EP |
0826354 | Apr 1998 | EP |
2 256 977 | Dec 1992 | GB |
2 275 373 | Aug 1994 | GB |
2290052 | Jun 1995 | GB |
2349354 | Nov 2000 | GB |
59196214 | Nov 1984 | JP |
2000 333709 | May 2000 | JP |
2001 291433 | Oct 2003 | JP |
2003 299506 | Oct 2003 | JP |
WO 8202480 | Aug 1982 | WO |
WO 9201401 | Feb 1992 | WO |
WO 9204839 | Apr 1992 | WO |
WO 9423610 | Oct 1994 | WO |
WO 9505140 | Feb 1995 | WO |
WO 9533390 | Dec 1995 | WO |
WO 9814086 | Apr 1998 | WO |
WO 9830381 | Jul 1998 | WO |
WO 9833410 | Aug 1998 | WO |
WO 9857564 | Dec 1998 | WO |
WO 9857565 | Dec 1998 | WO |
WO 9910161 | Mar 1999 | WO |
WO 9911452 | Mar 1999 | WO |
WO 9948455 | Sep 1999 | WO |
WO 0000053 | Jan 2000 | WO |
WO 0124654 | Apr 2001 | WO |
WO 03028499 | Apr 2003 | WO |
WO2004018796 | Mar 2004 | WO |
WO 2005090045 | Sep 2005 | WO |
WO2005090045 | Sep 2005 | WO |
Number | Date | Country | |
---|---|---|---|
20100239699 A1 | Sep 2010 | US |
Number | Date | Country | |
---|---|---|---|
60242877 | Oct 2000 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 10163169 | Jun 2002 | US |
Child | 11005185 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 11748427 | May 2007 | US |
Child | 12777750 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 11005185 | Dec 2004 | US |
Child | 11748427 | US | |
Parent | 09808395 | Mar 2001 | US |
Child | 10163169 | US |