Certain articles of manufacture are constructed from multiple workpiece assemblies. Each of the individual workpiece assemblies may include two or more prefabricated workpiece substrates that need to be joined together. One of the prefabricated workpiece substrates may be formed of a composite material having a thermoplastic or thermoset polymer matrix along with a reinforcement phase, such as certain reinforcing fibers or filler particles, distributed throughout the polymer matrix. The joining of one composite material workpiece substrate to another workpiece substrate—whether the other workpiece substrate is also formed from a composite material or a metal—has typically required the use of mechanical fasteners such as solid rivets, flow drill screws, blind rivets, etc. But puncturing the workpiece substrates with mechanical fasteners exposes and locally damages the polymer matrix and the reinforcement phase of the workpiece substrate(s). This may result in the fatigue strength of one or both of the workpiece substrates being adversely impacted. Other joining techniques including the use of ultrasonic welding and the application of adhesives are available but tend to be inefficient on a mass production scale and, in the case of adhesives, may emit VOCs into the surrounding environment. New and effective ways for joining prefabricated workpiece substrates when at least one of those substrates is formed of a composite material are therefore needed.
A method of joining workpiece substrates to form a workpiece assembly according to one implementation of the present disclosure includes several steps. In one step, a local mold tool is positioned into contact with a first workpiece substrate and a second workpiece substrate. The local mold tool defines a mold cavity in conjunction with the first and second workpiece substrates and further encloses an edge portion of the first workpiece substrate and an edge portion of the second workpiece substrate such that the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate are contained within the mold cavity. In another step, a liquid polymer molding compound is injected into the mold cavity. The liquid polymer molding compound flows through and fills the mold cavity and, further, contacts each of the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate. In yet another step, the liquid polymer molding compound is hardened into a polymer joint that adheres the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate together.
The method according to the aforementioned implementation may include additional steps or be further defined. For example, in one variation, the liquid polymer molding compound may fill a gap between the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate when injected into the mold cavity. As another example, at least one of the first workpiece substrate or the second workpiece substrate may be composed of a composite material that comprises a polymer matrix and a reinforcement phase embedded within and dispersed throughout the polymer matrix. In yet another example, each of the first workpiece substrate and the second workpiece substrate is separately composed of the composite material, and the composite material of the first workpiece substrate and the composite material of the second workpiece substrate may be the same or different.
The edge portions of the first workpiece substrate and the second workpiece substrate may be oriented in various arrangements within the context of the method according to the aforementioned implementation. In one configuration, the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate may be oriented in a butt joint arrangement in which the edge portions are opposed but do not overlap. In another configuration, the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate may be oriented in a lap joint arrangement in which the edge portions overlap. In still another configuration, which is a modification of the lap joint arrangement, one of the edge portion of the first workpiece substrate or the edge portion of the second workpiece substrate defines a series of holes that traverse a thickness of the workpiece substrate in which the series of holes are defined.
The liquid polymer molding compound injected into the mold cavity may encompass a variety of formulations within the context of the method according to the aforementioned implementation. For example, the hardening of the liquid polymer molding compound may result in the polymer joint comprising a solid structural engineering plastic selected from the group consisting of a polyamide, a polyurethane, a polyurea, and an epoxy. In one version, the liquid polymer molding compound may be a polymer composition that comprises a molten thermoplastic polymer heated to a temperature above its melting temperature. The hardening of such a polymer composition into the polymer joint may involve allowing the molten thermoplastic polymer to cool to a temperature below its melting temperature within the mold cavity. In another version, the liquid polymer molding compound may be a polymerizable composition that includes reactive polymerizable molecules that are polymerizable into a thermoplastic or thermoset polymer. The hardening of such a polymerizable composition may involve allowing the reactive polymerizable molecules to polymerize within the mold cavity and, if a thermoset polymer is being formed, to also cure. And, regardless of the formulation of the liquid polymer molding compound, the polymer joint may further mechanically interlock the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate.
A method of joining workpiece substrates to form a workpiece assembly according to another implementation of the present disclosure includes several steps. In one step, a first mold plate and a second mold plate are closed to enclose an edge portion of a first workpiece substrate and an edge portion of a second workpiece substrate. The first mold plate and the second mold plate, when closed, define a mold cavity in conjunction with the first and second workpiece substrates. The edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate are contained within the mold cavity. In another step, a liquid polymer molding compound is injected into the mold cavity. The liquid polymer molding compound flows through and fills the mold cavity and, further, contacts each of the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate. The liquid polymer molding compound comprises (i) a polymer composition that includes a molten thermoplastic polymer or (2) a polymerizable composition that includes reactive polymerizable molecules that are polymerizable into a thermoplastic or a thermoset polymer. In yet another step, the liquid polymer molding compound is hardened into a polymer joint that adheres the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate together. The polymer joint comprises a solid structural engineering plastic selected from the group consisting of a polyamide, a polyurethane, a polyurea, and an epoxy.
The method according to the aforementioned implementation may include additional steps or be further defined. For example, each of the first workpiece substrate and the second workpiece substrate may be separately composed of the composite material, and the composite material of the first workpiece substrate and the composite material of the second workpiece substrate may be the same or different. As another example, the liquid polymer molding compound may fill a gap between the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate when injected into the mold cavity. Consequently, the polymer joint may occupy the same gap when the liquid polymer molding compound is hardened into the polymer joint. In still another example, the polymer joint may further mechanically interlock the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate.
The present disclosure is directed to a method of joining first and second workpiece substrates into a workpiece assembly when at least one, and preferably both, of the workpiece substrates is formed of a composite material. The method involves positioning a local mold tool around adjacent end portions of the first and second workpiece substrates. The mold tool encloses the end portions of the first and second workpiece substrates and, together with the workpiece substrates, defines a mold cavity. A polymer molding compound is then injected into the mold cavity and hardened into a polymer joint that adheres the edge portion of the first workpiece substrate and the edge portion of the second workpiece substrate together. The local mold tool is subsequently removed from the now-joined workpiece substrates. The joining method is quick, reliable, and can be used with a variety of stacking arrangements of the end portions of the first and second workpiece substrates including a butt arrangement, a lap arrangement, and a modified lap arrangement referred to as a stitch arrangement. Additionally, the disclosed joining method creates a solid, non-dissolvable polymer joint that obviates the need to use mechanical fasteners to join the workpiece substrates and does not release byproduct VOCs.
Referring now to
Each of the first workpiece substrate 12 and the second workpiece substrate 14 may be composed of a composite material 18, 20 as shown in
A wide variety of thermoplastic and thermoset polymers may constitute the polymer matrix 22 of the composite materials 18, 20. For example, the polymer matrix 22 may be comprised of any of the following thermoplastics: polyvinyl chloride, polyvinylidene chloride, polyvinyl acetate, polyvinyl alcohol, polystyrene, acrylonitrile-styrene polymer, acrylonitrile-butadiene-styrene, polyacrylates, polymethacrylate, polyethylene including medium-density polyethylene (HDPE) and low-density polyethylene (LDPE), polypropylene, thermoplastic olefin resins, aliphatic polyamides (PA46, PA6, PA66, PA6/66, PA11, PA12, PA610), fully or partially aromatic polyamides, polyacetals, polybenzimidazole, polycarbonate, polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polyphenyl ethers, polyphenylene oxides, polyphenylene sulfide, polyethersulfones, polyetherether ketones, polyether ketones, polyetherimides, polylactides, polyoxymethylenes, thermoplastic polyurethanes, or any combination or heteropolymer of any two or more of these materials. The polymer matrix 22 may also be comprised of any of the following thermosets: benzoxazine, bis-maleimide, cyanate ester polymers, an epoxy, a phenolic, polyacrylate (acrylic), polyimide, an unsaturated polyester, a polyurethane, vinyl ester, siloxane, polydicyclopentadiene, or any combination or heteropolymer of any two or more of these materials.
The fibers and/or particles that may be included within the polymer matrix 22 as the reinforcement phase 24 may also vary. Some examples of suitable reinforcement fibers that may be employed include carbon fibers, glass fibers (e.g., fiber glass, quartz), basalt fibers, aramid fibers (e.g., KEVLAR®, polyphenylene benzobisoxazole (PBO), and TWARON™ para-aramid synthetic fibers), polyethylene fibers (e.g., ultra-high molecular weight polyethylene (UHMWPE)), polypropylene fibers (e.g., high-strength polypropylene), boron fibers, ceramic fibers, polyester fibers, natural fibers (e.g., cellulose, cotton, flax, hemp, spider silk, etc), and combinations of any two or more of such fibers. Some examples of suitable reinforcement particles that may be employed include mineral particles such as calcium carbonate, talc, silica, wollstonite, clay (varieties of which include any of kaolin, smectite, hectorite, montmorillonite, bentonite, beidelite, saponite, stevensite, sauconite, nontronite, illite, and halloysites), calcium sulfate, carbon black, mica, glass platelets, hollow glass spheres, alumina trihydrate, magnesium hydroxide, titanium dioxide, and combinations of any two or more of such particles.
While a number of combinations of the polymer matrix 22 and the reinforcement phase 24 are possible, certain combinations may be more common or more preferred than others. Notably, in certain preferred embodiments, the polymer matrix 22 of either or both composite materials 18, 20 may include polyethylene, polypropylene, a thermoplastic olefin rein, an aliphatic polyamide (PA46, PA6, PA66, PA6/66, PA11, PA12, PA610), a fully or partially aromatic polyamide, a polyphenyl ethers or a polyphenylene oxide, if a thermoplastic is desired, or it may include an epoxy, a phenolic, an unsaturated polyester, or a vinyl ester, if a thermoset is desired. Additionally, the reinforcement phase 24 of each composite material 18, 20, if present, may preferably include fibers such as carbon fibers, glass fibers, basalt fibers and/or hemp, may preferably include particles such as calcium carbonate, talc, silica, wollastonite, carbon black, and/or hollow glass spheres, or some combination of the aforementioned fibers and particles. In one particular embodiment, the composite material 18, 20 of either or both of the first and second workpiece substrates 12, 14 may be sheet molding compound (SMC), which is a fiber-reinforced thermoset resin in which the fibers are typically glass or carbon and the thermoset resin is typically a polyester, vinyl ester, or epoxy resin.
Each of the first workpiece substrate 12 and the second workpiece substrate 14 is prefabricated prior to being joined. That is, each of the first and second workpiece substrates 12, 14 has undergone some type of forming procedure to introduce a specified three-dimensional shape to the workpieces 12, 14. For example, if composed of the composite material 18, 20, the first workpiece substrate 12 and/or the second workpiece substrate 14 may be compression molded or plastic injection molded into a particular shape, although other molding techniques are certainly possible. And, if composed of a metal, the first workpiece substrate 12 or the second workpiece substrate 14, whichever is not composed of a composite material, may be stamped, drawn, additively manufactured, formed via quick plastic forming, or otherwise deformed into a particular shape. The prefabrication of the first and second workpiece substrates 12, 14 may involve trimming or further processing of the workpiece substrates 12, 14 after their initial shaping.
The method for joining the first and second workpiece substrates 12, 14 to obtain the workpiece assembly 10 is illustrated generically in
Once the first and second workpiece substrates 12, 14 are located relative to each other, a local mold tool 42 is positioned into contact with the first and second workpiece substrates 12, 14. The local mold tool 42 encloses an edge portion 44 of the first workpiece substrate 12 and an edge portion 46 of the second workpiece substrate 14 and defines, in combination with the first and second workpiece substrates 12, 14, a mold cavity 48. The edge portions 44, 46 are terminal portions of their respective workpiece substrates 12, 14 that include the edge surfaces 30, 36 as well as the cutouts 38, 40 in this particular embodiment of a butt joint arrangement of the workpiece substrates 12, 14. In that regard, the edge portion 44 of the first workpiece substrate 12 and the edge portion 46 the second workpiece substrate 14 are contained within the mold cavity 48, and a gap 50 exists between and separates the edge portions 44, 46 and, more specifically, exists between and separates the opposed edge surfaces 30, 36 of the workpiece substrates 12, 14. The local mold tool 42 may be sealed against the front surfaces 26, 32 and the back surfaces 28, 34 of the workpiece substrates 12, 14 or it may permeably engage the front surfaces 26, 32 and the back surfaces 28, 34 to allow for venting. Interior portions 12′, 14′ of the first and second workpiece substrates 12, 14 situated inboard of the edge portions 44, 46 are not covered by the local mold tool 42.
The local mold tool 42 has a first mold plate 52 and a second mold plate 54 that are closeable (as indicated by the arrows in
When the mold plates 52, 54 are closed around the edge portions 44, 46 of the first and second workpiece substrates 12, 14 and the local mold tool 42 is established and positioned, a liquid polymer molding compound 66 is injected into the mold cavity 48, as depicted in
The liquid molding compound 66 may be a polymer composition that comprises a thermoplastic polymer, which may optionally include dispersed fibers, particles, or fibers and particles. The polymer composition may be heated to a temperature above the melting temperature of the thermoplastic polymer when injected into the mold cavity 48. In this case, the thermoplastic polymer may be a polyamide such as polycaprolactam, also known as nylon 6 and PA6, poly(hexamethylene adipamide), also known as nylon 66 and PA66, or poly(caprolactam-co-hexamethylene adipamide), also known as nylon 6/66 and PA6/66, and the selection of the particular thermoplastic polymer may be based on compatibility with the polymer matrix 22 of the composite material(s) 18, 20 of the first and/or second workpiece substrates 12, 14. If fibers and/or particles are dispersed within the thermoplastic polymer, the fibers and the particles may be any of the fibers and particles disclosed above in connection with the composite materials 18, 20. When the polymer molding compound 66 includes a polymer composition that comprises a thermoplastic polymer, the first engagement surface 56 of the first mold plate 52, the second engagement surface 58 of the second mold plate 54, or both engagement surfaces 56, 58 may be compliant to non-sealingly engage its respective front and back surfaces 26, 32, 28, 34 of the first and second workpiece substrates 12, 14 and allow for venting.
The liquid polymer molding compound 66 may also be a polymerizable composition that polymerizes into a polymer within the mold cavity 48, which may optionally include the same types of dispersed fibers and/or particles mentioned above for the polymer composition. The polymerizable composition may include reactive polymerizable molecules—e.g., monomers, oligomers, and/or prepolymers—that are polymerizable into a thermoplastic polymer with or without the aid of a catalyst. For instance, the polymerizable composition may include caprolactam and an amount of water acting as a catalyst, which undergoes ring-opening polymerization to produce polycaprolactam when heated to a temperature of 250° C. to 260° C. When the polymer molding compound 64 includes a polymerizable composition—whether the composition polymerizes into a thermoplastic as disclosed above or polymerizes and cures into a thermoset as disclosed below—the first engagement surface 56 of the first mold plate 52 and the second engagement surface 58 of the second mold plate 54 may be sealed against their respective front and back surfaces 26, 32, 28, 34 of the first and second workpiece substrates 12, 14.
The polymerizable compound may include reactive polymerizable molecules that are polymerizable and curable into a thermoset polymer, and may additionally include a catalyst, a curing agent (hardener, chain extender, cross-linker, etc.), a diluent, and any other additives that may be needed to complete the polymerization and curing processes. For example, the polymerizable composition may include (i) a diisocyanate, such as hexamethylene diisocyanate (HDI) or isophorone diisocyanate (IPDI) or hydrogenated methylene diphenyl diisocyanate (HMDI), and (ii) a polyol, such as a hydroxyl-terminated polyether or polyester, along with (iii) a catalyst such as a ternary amine (e.g., 1,4-diazabicyclo[2.2.2]octane), which undergoes condensation polymerization and crosslinking when mixed together to form a polyurethane. In another example, the polymerizable composition may include (i) a diisocyanate, such as IPDI, and (ii) a polyamine, such as an amine-terminated ethylene or propylene oxide, along with low molecular weight chain extenders such as diethylenetriamine (DETA) or triethylene tetraamine (TETA) or a polyetheramine, which undergoes condensation polymerization and crosslinking when mixed together to form a polyurea. In yet another example, the polymerizable composition may include (i) a diepoxide such as epichlorohydrin, (ii) a diol or polyol such as bisphenol A or bisphenol F, and (iii) a polyfunctional amine, such as diethylenetriamine or triethylenetetramine, which undergo polyaddition (to form a polyepoxide such as diglycidyl ether of bisphenol A or bisphenol F) and crosslinking when mixed together to form an epoxy.
The liquid polymer molding compound 66 may be heated to its applicable temperature, if needed, prior to being delivered to the injection head 72 and injected into the mold cavity 48. Any mixing required of the liquid polymer molding compound 66 may also be performed in the injection head 72 under impingement mixing conditions. The heating of the liquid polymer molding compound 66 may entail heating the liquid polymer molding compound 66 or its individual components in a heat exchanger upstream of the injection head 72. The first and second mold plates 52, 54 may even be heated or cooled if desired to help manage the temperature of the liquid polymer molding compound 66 once received in the mold cavity 48. Since the liquid polymer molding compound 66 is typically heated only to moderate temperatures of 260° or less, and often 140° C. or less, a wide variety of materials are available for the construction of the first and second mold plates 52, 54, which can further help manage the temperature of the liquid polymer molding compound 66 once received in the mold cavity 48. For instance, the mold plates 52, 54 may be constructed from a thermally conductive rapid tooling material, such as zinc, aluminum, steel, or kirksite, so that heat can be expeditiously removed from the liquid polymer molding compound 66 to increase the speed at which it hardens within the mold, as described below. Other materials including a variety of composite materials may also be used to construct the mold plates 52, 54.
The liquid polymer molding compound 66 hardens within the mold cavity 48 to form the polymer joint 16, which is illustrated in
When the polymer joint 16 is fully hardened, the local mold tool 42 is opened by separating the first mold plate 52 and the second mold plate 54 from their respective front and back surfaces 26, 32, 28, 34 of the first and second workpiece substrates 12, 14, as shown in
The disclosed joining method may be applied to different joint arrangements of the first and second workpiece substrates in addition to the butt joint arrangement described above without detracting from the spirit and objectives of the present disclosure. In the following discussion of alternate embodiments, reference numerals that correspond to the reference numerals used in the description of the previous embodiment will be used to identify the same or similar elements having the same or similar functionality. To that end, the description of aspects of the previously-described embodiment shown in
In this embodiment, and similar to before, the local mold tool 142 is positioned into contact with the first and second workpiece substrates 112, 114 and encloses the edge portions 144, 146. The local mold tool 142 defines, in combination with the first and second workpiece substrates 112, 114, the mold cavity 148 in which the edge portions 144, 146 of the first and second workpiece substrates 112, 114 are contained. And again, as before, interior portions 112′, 114′ of the first and second workpiece substrates 112, 114 are not covered by the local mold tool 142. The local mold tool 142 may include a first mold plate 152 and a second mold plate 154 that have first and second engagement surfaces 156, 158, respectively, that make contact with the front and back surfaces 126, 132, 128, 134 (either sealingly or non-sealingly) of the workpiece substrates 112, 114. The front surfaces 126, 132 of the workpiece substrates 112, 114 do not necessarily have to include cutouts here since the edge portions 144, 146 overlap and the polymer joint 116 interleaves through the gap 150 established between the edge portions 144, 146. While the mold cavity 148 can be shaped in any number of ways, the engagement surfaces 156, 158 may be contoured so that the liquid polymer molding compound 166 injected into the mold cavity 148 contacts only the edge surface 130 and the back surface 132 of the first workpiece substrate 112 and only the edge surface 136 and the front surface of the second workpiece substrate 114.
The polymer joint 116 that adheres the edge portions 144, 146 of the first and second workpiece substrates 112, 114 together is formed from the liquid polymer molding compound 166 in the same way as before. Both the liquid polymer molding compound 166 and the polymer joint 116 are shown in
Additional interlocking may be provided by defining a cutout 138, 140 in either or both of the workpiece substrates 112, 114 similar to before. The cutout 138 defined in the first workpiece substrate 112 may be the same as in the previous embodiment while the cutout 140 defined in the second workpiece substrate 114 involves a step down in the back surface 134 to an intermediate surface 134″ that extends out to the edge surface 136 of the edge portion 146. These cutout portions 138, 140 may be occupied by laterally extending wings of the lip portions 186, 188 of the body 174 such that the body 174 wraps around the edge portions 144, 146 of the workpiece substrate 112, 114. In a similar but slightly different variation, and as described above in connection with
In another alternate embodiment, and referring now to
The local mold tool 242 may include a first mold plate 252 and a second mold plate 254 that have first and second engagement surfaces 256, 258, respectively, that make contact with the front and back surfaces 226, 232, 228, 234 (either sealingly or non-sealingly) of the workpiece substrates 212, 214. Moreover, if the series of holes 290 are defined in the first workpiece surface 212, as illustrated here in
The polymer joint 216 thus adherently joins the edge portions 244, 246 of the first and second workpiece substrates 212, 214 together while also mechanically interlocking the edge portions 244, 246 between the first and second lip portions 286, 288 of the body 274 of the polymer joint 216, as in the previous embodiment, with additional mechanical interlocking being provided by the plugs 292, especially the flange 298 of the plugs 292. Indeed, in a slight alteration, and owing to the ability of the plugs 292 to provide mechanical interlocking, the engagement surfaces 256, 258 of the first and second mold plates 252, 254 may be contoured so that liquid polymer molding compound 266 injected into the mold cavity 248 contacts only the back surface 228 of the first workpiece substrate 212 and the front surface of the second workpiece substrate 214, thereby resulting in the body 274 of the polymer joint 216 having the central portion 284 and the plugs 292, but not the lip portions 286, 288.
The above description of preferred exemplary embodiments and specific examples are merely descriptive in nature; they are not intended to limit the scope of the claims that follow. Each of the terms used in the appended claims should be given its ordinary and customary meaning unless specifically and unambiguously stated otherwise in the specification.