Aspects relate to three dimensional printing by molten metal jetting.
“Three dimensional printing” as an art includes various methods for producing solid metal parts.
Although some researchers have prototyped metal jetting techniques for additive manufacturing, there is no commercially reliable and affordable method for additive manufacturing by molten metal jetting.
According to one aspect of an embodiment of a method of molten metal jetting for additive manufacturing, a wire of solid metal is fed along a material feed path. The metal material is melted to a molten metal in a melt reservoir. The melt reservoir is pressurized to a predetermined pressure insufficient to eject droplets, and a pressure oscillation is generated in the molten metal in the reservoir to force one or both of jetting of the molten metal through a nozzle and/or formation of molten metal droplets by surface tension at the nozzle. The nozzle is driven to relatively move with respect to a build plate in at least three degrees of freedom. Successive layers of solidified metal are formed by accumulation of the molten metal droplets impacting a previously deposited layer of solidified metal and cooling thereon. Each successive layer may be traversed with a normalizing or leveling device, such as grinding wheel, ablating laser beam or electron beam, or reflowing laser beam or electron beam, to level each successive layer.
Optionally, the normalizing grinding wheel is driven to traverse with its rotating axis, or the laser or electron beam is swept, entirely within a plane parallel to a plane in which the layer is formed. Further optionally, the normalizing grinding wheel, laser, or electron beam generator is connected to and moved with the nozzle. Further optionally, the normalizing grinding wheel, laser beam, or electron beam removes sufficient material to shave both peaks and valleys in irregular surface. Further optionally, the normalizing grinding wheel, laser beam, or electron beam removes 10-80% of the deposited solidified metal height. Further optionally, a contact surface consisting of a line along the width of the grinding wheel or a swept laser beam or electron beam is traversed over an area of no more than 125% of the area of the previously deposited solidified metal layer.
Additionally, or in the alternative, one of an inert gas supply and an inert gas generator supplies an inert gas or an anoxic gas to shield the molten metal from oxidation. In this case, the supply of inert gas may be shared among at least two of an inert gas feed to maintain an oxidation-free environment in the melt reservoir; an inert gas feed to maintain an oxidation-free environment in the print chamber, and/or an inert gas feed to maintain an oxidation shield extending between the nozzle and the print bed and about the molten droplets as they are jetted.
According to another aspect of the embodiments, a method of molten metal jetting for additive manufacturing includes, or an apparatus performs, feeding a wire of solid metal along a material feed path. The metal material is melted to a molten metal in a melt reservoir, and the molten metal is pressurized in the melt reservoir to a predetermined pressure insufficient to eject droplets. Inert gas (or anoxic gas) is supplied to shield the molten metal from oxidation from one of an inert gas supply and an inert gas generator. A pressure oscillation is generated in the molten metal reservoir to force at least one of jetting of molten metal through a nozzle and formation of molten metal droplets by surface tension at the nozzle. The nozzle is driven to relatively move with respect to a build plate in at least three degrees of freedom. Successive layers of solidified metal are formed by accumulation of the molten metal droplets impacting a previously deposited layer of solidified metal and cooling thereon.
Optionally, the melt reservoir is loaded by introducing an initial charge of unmelted material to the melt reservoir. Inert gas may be fed into the print head, and/or an oxide removal agent may be introduced into the print head. The print head may be heated to activate the oxide removal agent. Metal and oxidized metal may be purged from the print head. Further optionally, metal and oxidized metal may be purged from the print head by feeding additional oxide removal agent, metal, and inert gas into the nozzle.
Alternatively, or in addition, before removing a part, associated with a locked/unlocked state of an electronic interlock on a sealed door, the anoxic chamber may be purged by at least one of removing oxygen from and flowing inert gas into the anoxic chamber; or, associated with a locked/unlocked state of an electronic interlock on a sealed door, the melt reservoir may be purged by at least one of removing oxygen from and flowing inert gas into the melt reservoir.
Alternatively, or in addition, before beginning printing, associated with a locked/unlocked state of an electronic interlock on a sealed door, the anoxic chamber may be purged by at least one of removing oxygen from and flowing inert gas into the anoxic chamber; or, associated with a locked/unlocked state of an electronic interlock on a sealed door, the melt reservoir may be purged by at least one of removing oxygen from and flowing inert gas into the melt reservoir.
Alternatively, or in addition, before beginning printing, associated with a locked/unlocked state of an electronic interlock on a sealed door, the melt reservoir may be purged by flowing anoxic gas through the melt reservoir in a gaseous volume in excess of the melt reservoir volume.
Various aspects of at least one embodiment are discussed below with reference to the accompanying figures, which are not intended to be drawn to scale. The figures are included to provide illustration and a further understanding of the various aspects and embodiments, and are incorporated in and constitute a part of this specification, but are not intended as a definition of the limits of the invention. In the figures, each identical or nearly identical component that is illustrated in various figures is represented by a like numeral. For purposes of clarity, not every component may be labeled in every figure. In the figures:
This patent application incorporates the following disclosures by reference in their entireties: U.S. patent application Ser. Nos. 61/804,235; 61/815,531; 61/831,600; 61/847,113; 61/878,029; 61/880,129; 61/881,946; 61/883,440; 61/902,256; 61/907,431; and 62/080,890; 14/222,318; 14/297,437; and 14/333,881, which may be referred to herein as “Composite Filament Fabrication patent applications” or “CFF patent applications”. Although the present disclosure discusses various molten metal jetting 3D printing systems, at least the mechanical and electrical motion, control, and sensor systems of the CFF patent applications may be used as discussed herein. In addition, U.S. Pat. Nos. 6,202,734; 5,337,961; 5,257,657; 5,598,200; 8,523,331; 8,721,032, and U.S. Patent Publication No. 20150273577, are incorporated herein by reference in their entireties.
The printer(s) of
The feed rate (the tangential or linear speed of the drive 40) and/or printing rate (e.g., the relative linear speed of the platen/part via the Z drive 120 and print head drives 116, 118) may be monitored or controlled to maintain compression, neutral tension, or positive tension within an unsupported zone. As shown in
With reference to
A 3D printing method or apparatus by molten metal jetting includes at least one printhead 10 including at least one molten metal jet 10a, a material supply 40, 10b connected to the print head 10 and/or molten metal jet 10a for providing material that is jetted by the print head 10, a build plate 16 upon which a metal part 18 is additively formed, a set of at least 3 actuators 116, 118, 120 connected to the print head 10 and/or to the build plate 16 to relatively move them in at least 3 degrees of freedom (in many cases, X, Y, and Z Cartesian directions). A controller 20 regulates the relative positions of the print head 10 and build plate 16.
As discussed herein, the molten metal jet 10a may be constructed with different melting and jetting mechanisms. In one exemplary system, after leaving a jetting orifice tip or nozzle 202, a molten metal droplet 206 driven by a kinetic driver 106 may pass through a charging electrode system 102 and acquire a uniform charge, permitting the charged droplets 206 to be steered to X-Y locations on the build plate 16 with electrostatic members/plates. The charged droplets 206 can then be steered to specific positions on the target substrate 180 using electrostatic plates 208, 210. In another example, e.g., with a magnetohydrodynamic (MHD) kinetic driver, the MHD kinetic driver 106 converts modulated current into pressure pulses to dispense high temperature molten metal droplets 206. The shape and size of the jetting orifice 202, the surface tension and viscosity of the metal in the droplets 206, the wetting interaction between the metal and the orifice 202 material, and the configuration and timing of the modulation signal from the controller 20 may be tuned.
As noted, the molten metal jet may by magnetohydrodynamically driven. Molten metal may be supplied to a reservoir or crucible 10a, or melted therein, and maintained in a fluid state. A magnetic field may be applied to the fluid reservoir 10a, the field having a direction aligned with the print head 10 jetting direction. Electric current may be driven in a drive chamber (which may also act as the reservoir or crucible 10a) through the molten metal to exert a jetting direction force and subsequently in the opposite direction to form a droplet 206. The electric current may be an alternating electric current burst from a pulse generator. A temperature differential of the molten metal from the reservoir 10a to the jetter orifice 202 may be very small (a few degrees). The magnetic force may be provided by an electromagnet or any very strong rare earth (e.g., samarium-cobalt) permanent magnet. The kinetic driver 106 in this case may be formed from the molten metal itself, the magnetic field throughout, and the AC pulse current (and resulting Lorenz force).
The kinetic driver 106 may be any form of vibrating volume change in a molten fluid system. For example, pressurized molten metal may be ejected from an ejection orifice 202 of about 0.5 mm, driven by a kinetic driver 106 in the form of a vibrating plunger 205 vibrated by an audio speaker a powered by an amplifier and voltage pulse generator to eject droplets at a rate of 30 droplets per second at 350° C. An argon atmosphere in the build volume may prevent oxidation. In several of the molten metal jetting processes discussed herein, the reservoir 10a is kept at a pressure below that sufficient to eject droplets (e.g., by back pressure in a molten metal fluid path, by added inert gas pressure, by gravity, as some examples). The kinetic driver 106 tends to generate a pressure oscillation in the molten metal reservoir 10a to force at least one of jetting of molten metal through a nozzle and/or formation of molten metal droplets by surface tension at the nozzle. A kinetic driver 106 as discussed herein may do either or both (create a jet, or transform the jet otherwise generated into droplets, or create a jet of droplets).
With reference to
Each section of description herein may use reference numbers appearing in
Following an induced pressure wave, as inertia in the system damps out, residual motion in the molten metal, e.g., a residual pressure wave, may generate a residual current which may be used as a feedback signal for control. The electrodes 102a, 102b creating the Lorenz force in the molten metal may be switched provide actuation current and permit detection of residual current. The acoustic behavior of the molten metal and the reservoir 10a may also be monitored as a feedback signal for control (e.g., acoustic behavior, frequency and amplitude and presence, are different between an operative and failing process).
As another example of a molten metal jet, as shown in
In an additional example, as shown in
As noted, droplet size may be a function of molten metal jet and/or orifice diameter and/or molten metal jet velocity and/or waveform frequency, amplitude, duration, or modulation. As shown in
Alternatively, or in addition, as shown in
As another example of types of kinetic drivers 106 that may be used (in each case, a surrounding, embedded, or integrated heat source maintains the molten metal in a high temperature, molten metal state).
Alternatively, a spooled aluminum filament 10b may be pre-heated and melted in a reservoir or crucible upstream from a printhead/nozzle 10 to form a reservoir 10a of molten metal. A pulsed magnetic field may induce a transient current within the molten metal 10a, the field and current coupling to create a Lorentz force that ejects a molten metal droplet 206 whose velocity may depend on the applied Lorentz force pressure. Alternatively, or in addition, an actuator may include a molten metal reservoir 203, temperature control (e.g., via a heater 204), and a pneumatic connection 200a (for inert gas used with the kinetic driver).
Nozzles or orifices 202 may be straight tubes, tapered, or otherwise internally shaped. One additional variety is a star-shaped silicon nozzle 202 (e.g., with a channel formed as a multipointed star prism), which may include microfluidic channels. A droplet 206 may be formed and suspended on points of the star-shaped nozzle 202. A droplet 206 may be is centered if the repellent capillary pressure of the nozzle grooves is too high for the molten metal to move into the grooves. In one example, thirteen or a higher number of nozzle grooves create a contact angle of about 120 degrees toward the nozzle material. Using inert gas as an actuator or kinetic driver, when pressure in the molten metal column at the nozzle entrance is higher than the applied actuation on the top of the molten metal, gas shear flow may pull a molten metal plug toward the nozzle outlet 202, the molten metal column may become constricted, and the droplet 206 may finally break off.
Alternatively or in addition, in the above systems, one or more heaters such as induction coil(s) 204 about, or within, the melt chamber 203 may be used in a heating mode to melt metal (e.g., high frequency, low amplitude) and also, or in the alternative, in a kinetic driver mode to create physical oscillations on a driver plate 205 or coupled with a magnetic field, directly within molten metal (e.g., low frequency, high amplitude) and coupled with an appropriate nozzle 202 as described, propel molten metal.
In between successive additive layers jetted by the molten metal jet, and/or in between successive steps for forming such layers, the control system (including the controller 20), an optional sensor array 600 and an optional mechanical leveling mechanism may perform operations to level or compensate for imperfections in a layer, via selective jetting on the previous layer, current layer, or a successive layer, or via successive material removal on the previous layer, current layer, or a successive layer.
For example, a stochastic droplet size and landing position can result in uneven piling up of printed material. It may be advantageous to integrate a skimming or doctor blade method or system to eliminate vertically protruding peaks in a layer or layers, and level the part in a repeated, or as-needed fashion.
In one preferred embodiment, as shown in
A further advantage of the inclusion of the grinding wheel 502 is the ability to automatically level the printing bed 16 (e.g., the controller 20 controls the grinding wheel motor and at least some of actuators 116, 118, and 120 to grind a layer from the print bed 16 itself). Dressing the bed to ensure flatness may eliminate major failure modes of 3D printing, wherein the surface tolerance of the part 180 is compromised by the lack of flatness of the bed 16. Further, using the grinding wheel 502 to flatten the printing surface 16 ensures a consistent active gap between the printhead 10 and the first layers of the part 180. This is useful for ensuring dimensional accuracy of the part 180, as well as for ensuring good adhesion of the part 180 to the printing surface 16.
In one embodiment, the print bed 16 is a reusable surface wherein the part 180 is knocked off, or scraped off, after printing. In another version, a disposable, sacrificial layer 16b is used covering the print bed 16. Such a layer 16b may be a thin sheet of the material that is the same, or similar to the material of the part 180 to be printed (stainless steel, titanium, aluminum or the like) that is held down to the print bed 16 by means of an vacuum chuck 16a integrated in the print bed 16. If desired, the flatness of the vacuum chuck 16a, and the squareness to the print head 16, can be ensured by using the grinding wheel 502 to square the print bed 16. Additionally, or alternatively, the sacrificial print surface can be attached to the print bed 16, and then made flat and parallel to the print head 10 by dressing the surface with the grinding wheel 502.
In another embodiment, as seen in 2D printing, the flatness of the deposited layer can be ensured by means of optical inspection, feedback, and compensation using an optical array 600 (e.g., such as a laser scanner, camera, RGBD camera, or the like). In 2D printing, for example, a print nozzle 10 can clog, which may present as a blank streak in the printed image. Inline inspection systems 600 may catch the clogged nozzle, and the controller 20 may, e.g., in response, increase a drop size of neighboring nozzles 10-1, 10-2, 10-3 (in the case of a multi-nozzle or parallel print head, e.g., as shown in
Another aspect of the disclosed invention is to build in fault tolerance to clogs in the print head 10 or nozzle/orifice 202. For example, if one of the print nozzles 202 is clogged, the droplet 206 size of the neighboring print nozzles 202 of neighboring print heads 10-1, 10-2, 10-3, 10-n can be increased to compensate for the clog. At the same time, the frequency of the pulses or other distribution force provided by the kinetic driver(s) 106 of the neighboring nozzles 202 may be reduced to effectively reduce the over-stuffing of the part 180. Unlike 2D printing, however, the droplets 206 will not simply “bleed” into the neighboring areas of the printed part 180. Instead, oversized or additional droplets 206 will pile up and create ridge that may be leveled by the grinding wheel 502.
In an alternative embodiment, when one print nozzle 202 of a parallel or parallelized array of printheads 10-1, 10-2, 10-3, 10-n is deemed to stop working, the immediate neighboring nozzles 202 can be increased in drop size, while the two-over or second neighbors can be reduced in drop size, as to prevent the excessive buildup of material (e.g., in a profile like the letters “oOxOo”, where “x” is the clogged printhead, “O” are the larger immediate neighbors, and “o” are the two-over neighbors). In order to achieve the maximal packing density, the second neighbors can be shot out of phase from the immediate neighbors in order to substantially, approximately match the packing density.
Optionally, in the case of soft metal printing, such as aluminum, the leveling system may be achieved by a rotating end mill instead of a grinding wheel 502 (but arranged in an interchangeable manner), a sanding apparatus, or any of a plurality of methods to remove minute amount of material.
In another embodiment, a laser cutter/smoother 1302 may be alternatively (or additionally) used to level high peaks in the system. The laser cutter 1302 is designed to operate by sweeping an arc through the top surface plane. This 1-D arc simplifies the required optics, and sweeps across the top of the printed part area 180, effectively shaving any peaks down. Two exemplary methods of peak shaving may be employed. The first method, ablation, acts like a laser cutter, removing the metal. An alternative process, laser smoothing, melts and reflows the top surface, using surface tension to smooth the surface. In another embodiment, the laser 1302 is mounted to the print head 10 (and travels relative to the print bed in three degrees of freedom), and is able to selectively smooth, or ablate high spots in the part 180. Additionally, the smoothing function allows said laser 1302 to fill in low spots.
In another embodiment, as shown in
In order to supply the molten metal jet 10a and/or the support material jet 18a with a predictable, reliable, and/or steady supply or pressure of unoxidized materials to be melted and/or jetted, as well as to maintain the melted materials in an unoxidized condition, the control system 20, an optional sensor set, e.g., 600, and an optional set of actuators, e.g., 502, 1302 may perform operations within a gas and/gas conduit system to feed, supply, meter gases to or from a build plate 16, build chamber 306, feed management system (e.g., as shown in
For example, an inert gas may be used in a plurality of ways to shield both the part 180 being made, and the metal droplets 206 that are en route to the part while printing. A first method of shielding is to surround the print nozzle 10 with an, e.g., ceramic collet 1304 that serves to direct and flow shielding gas over the ejected droplets 206 and the printed part 180. This embodiment may be suitable for large build areas that cannot fit within a chamber 306.
Another embodiment encloses the entire printing area 306 in an anoxic environment. The anoxic environment can be achieved by purging the chamber with inert gas, such as argon, nitrogen, or the like. Argon is readily available in pressurized bottles. However, a preferred embodiment reduces dependence upon large industrial containers, with the possibility of an office-friendly 3D printer.
One embodiment creates an anoxic environment through the inclusion of an inert gas generator 200 into the printer 1000, which may be connected to either or both of the print head (via, e.g., line 200a) and the printer anoxic chamber (e.g., vial line 200b). A suitable candidate may be a Pressure Swing Adsorption nitrogen generator, including the motorized gas pump 200d connected to and controlled by the controller 20. In one embodiment, the print chamber 306 may be a pressure sealed environment similar to a commercially available vacuum chamber. In this configuration, the anoxic environment may be achieved by vacuum pumping the print chamber down with a motorized vacuum pump 200e connected to and controlled by the controller 20. Alternatively, or in conjunction, nitrogen gas may be pumped into the chamber, diluting out the concentration of oxygen. A pre-purge routine may involve flowing inert gas into the chamber 306 for a sufficiently long time to dilute the chamber oxygen content to an acceptable level for the given material to be printed.
In another preferred embodiment, the anoxic environment may be accelerated through the use of a Solid Electrolyte Oxygen Separation pump employed as the inert gas generator 200. These solid state electrode devices may be 100% selective for oxygen, thereby accelerating the creation of the anoxic environment, and may drive the lowest possible level of oxygen in the system. The chamber gas (feed air) may be pumped over a ceramic separator, which extracts oxygen, and exhausts the gas (which includes only air components) external to the printer 100.
Under normal usage, in order to minimize the warm up time for the printer, the anoxic environment may be maintained. After a print job is completed, the chamber 306 may be opened to remove the part 180, which will contaminate the chamber with oxygen. As shown in
In order to provide the molten metal jet 10 with a soluble or removable support material deposition such that overhangs, cantilevers, bridges, and/or flyers can be printed onto an underlying support or base, the control system 20, an optional sensor set, e.g., 500, and an optional set of actuators may perform operations within a material feed and/or support material jetting system to form soluble and other supports.
For example, as shown in
An additional utility of soluble supports may be provided in the first few layers of a model printed on top of them. Depending on the combination of model material (metal) and support material used, different anchor strategies may be employed. A first anchor strategy is to embed the first layer droplets 206 into the part. Printing in PVA plastic or the other support materials discussed may enable a molten droplet 206 to both stick to, and partially submerge into, a soluble support layer 190 (e.g., as shown in
A second anchor strategy is to “double tap”, as shown in
Another method for anchoring supports, as shown in
As shown in
In order to provide a plurality of molten metal jets 10 which may print at a higher speed or other performance improvement, the control system 20, an optional sensor set, e.g., 600, and an optional set of support members and actuators may perform operations within a material feed and/or support material jetting system to jet molten material in one or more parallel deposition systems. For example, as shown in
In order to supply the molten metal jet 10a and/or the support material jet 18a with a predictable, reliable, and/or steady supply or pressure of materials to be melted and/or jetted, the control system 20, an optional sensor set e.g., 600, and an optional set of actuators, e.g., 502, 1302 may perform operations within a material supply and feed management system to feed or supply solidified metal to a melt zone, crucible, pre-melt, reservoir 10a or the like upstream of the molten metal jet. The feed management system may be integrated within or to the melt zone 10a.
As shown in
As another example, a wire feed system 1702 may feed wire 1701 that is substantially similar to welding wire, into the crucible 10a that is in fluid communication with the print head 10. As shown in
In one embodiment, the control system 20 of the feed wire 1701 is designed to dip the feed wire 1701 into the crucible 10a to control and promote the feeding of the material 1701 (10b) into the crucible. Another aspect of the embodiment is to orient the feed wire 1701 in a substantially vertical manner such that gravity aids in the dropping of the molten feed wire 1701 into the crucible 10a (along with surface tension and other attractive forces). Although the jetting or metal jetting nozzle/orifice 10 not shown in
In one embodiment, as shown in
In one embodiment, as shown in
In another embodiment, as shown in
In another embodiment as shown in
The sharp thermal gradient of the system may be further enhanced by cooling fluid, such as inert gas purge, that is optimally introduced near the heat break 10j, and flows upward through the wire guide tube 1702, cooling the feed wire 1701. A plurality of locations for the inert gas purge may be used, such that the cooling gas can both shield the molten metal at the top of the crucible 10a, and cool the incoming feed wire 1701. The inert gas purge may further serve as a pressurizing agent for the crucible 10a. An optional gas-tight seal 1703 can be positioned in the feed tube 1702 that creates a seal between the feed tube wall, and a diameter controlled incoming feed wire 1701. The seal 1703 may be also used to maintain pressure, while a diverter valve is used to flow a portion of air upstream to cool the incoming feed wire 1701. Using a valve to control the pressure in this way would help maintain constant pressure in the crucible 10a, while making use of the bleed purge air to flow up the wire guide 1702 and cool the incoming feed wire 1701. Alternatively, a tightly fitting (slip fit) and heat conductive collet may be used to locate and heat sink the material.
In the present disclosure, “3D printer” is inclusive of both discrete printers and/or toolhead accessories to manufacturing machinery which carry out an additive manufacturing sub-process within a larger process. A 3D printer is controlled by a motion controller 20 which interprets dedicated G-code and drives various actuators of the 3D printer in accordance with the G-code.
“Fill material” includes material that may be deposited in substantially homogenous form as extrudate, fluid, or powder material, and is solidified, e.g., by hardening, crystallizing, or curing. “Substantially homogenous” includes powders, fluids, blends, dispersions, colloids, suspensions and mixtures.
“Filament” generally may refer to the entire cross-sectional area of an (e.g., spooled) build material.
Having thus described several aspects of at least one embodiment of this invention, it is to be appreciated various alterations, modifications, and improvements will readily occur to those skilled in the art. Such alterations, modifications, and improvements are intended to be part of this disclosure, and are intended to be within the spirit and scope of the invention. Accordingly, the foregoing description and drawings are by way of example only.
This application is a continuation of U.S. patent application Ser. No. 15/275,849, filed on Sep. 26, 2016 [now U.S. Pat. No. 10,315,247], which claims the benefit under 35 U.S.C. § 119(e) of U.S. Provisional Application Ser. No. 62/232,352, filed Sep. 24, 2015, both of which are herein incorporated by references in their entirety.
Number | Date | Country | |
---|---|---|---|
62232352 | Sep 2015 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 15275849 | Sep 2016 | US |
Child | 16427448 | US |