Oil and gas wells are drilled into Earth's surface or ocean bed to recover natural deposits of reservoir fluid (e.g., oil and gas) trapped within reservoirs in subterranean geological formations. After a wellbore is drilled, a plurality of casing strings (e.g., casing A, casing B, casing C, etc.) may be installed concentrically within the wellbore to protect the sidewall of the wellbore, isolate different subterranean formations, and maintain control of the reservoir fluid and well pressure during various subsequent downhole operations. The casing strings may be secured within the wellbore by cement. After the well is completed, various intervention operations may be performed to stimulate or otherwise optimize well productivity. Thereafter, additional metal tubular strings may be inserted within the wellbore to facilitate delivery of treatment fluid downhole and produce (or transfer) the reservoir fluid to the wellsite surface.
The annular space between the production tubing and casing A is known as annulus A. Similarly, the annular space between casing A and casing B is known as annulus B, and the annular space between casing B and casing C is known as annulus C. Pressure and/or temperature within annulus B are reliable indicators of the condition of well barriers formed by the casing strings and, thus, well safety. Thus, pressure and/or temperature sensors are installed within annulus B during well construction to facilitate real-time pressure and/or temperature monitoring of annulus B during subsequent production operations. For example, various sensors (e.g., pressure and/or temperature sensors) and communication devices (e.g., wireless transmitters and/or receivers) may be installed on or otherwise attached to the outside of casing A before or while casing A is being installed within the wellbore. Communication devices operable to communicate with the annulus B sensors and surface equipment may be subsequently deployed downhole with the production tubing to facilitate communication between the annulus B sensors and the surface equipment and, thus, facilitate real-time monitoring of pressure, temperature, and/or other parameters of annulus B.
However, such pressure and/or temperature monitoring of annulus B cannot be performed in existing wells that do not include pressure and/or temperature sensors installed within annulus B, because annulus B is sealed and not accessible for direct pressure and/or temperature measurements. Lack of pressure and/or temperature monitoring within annulus B prevents a robust assessment of the condition of the well barriers formed by the casing strings.
The present disclosure is best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
It is to be understood that the following disclosure provides many different embodiments, or examples, for implementing different features of various embodiments. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for simplicity and clarity, and does not in itself dictate a relationship between the various embodiments and/or configurations discussed. Moreover, the formation of a first feature over or on a second feature in the description that follows, may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the first and second features, such that the first and second features may not be in direct contact.
Furthermore, terms, such as upper, upward, above, lower, downward, and/or below are utilized herein to indicate relative positions and/or directions between apparatuses, tools, components, parts, portions, members and/or other elements described herein, as shown in the corresponding figures. Such terms do not necessarily indicate relative positions and/or directions when actually implemented. Such terms, however, may indicate relative positions and/or directions with respect to a wellbore when an apparatus according to one or more aspects of the present disclosure is utilized or otherwise disposed within the wellbore. For example, the terms upper and upward may mean in the uphole direction or uphole from, and the terms lower and downward may mean in the downhole direction or downhole from.
At least a portion of the wellbore 102 may be a cased wellbore 102 comprising a plurality of casings (or casing strings) installed concentrically within the wellbore 102 and secured by cement. For example, the casings may include an inner casing 112 comprising an upper portion (or upper casing string) and a lower portion (or lower casing string) collectively defining an internal space 103 of the wellbore 102. The casings may further comprise an intermediate casing 114 surrounding a portion of the inner casing 112. The casings may also comprise an outer casing 116 surrounding a portion of the intermediate casing 114. Each casing may be secured within the wellbore 102 by a corresponding layer of cement 118. A production tubing (or production tubing string) 120 may be installed within the internal space 103 of the wellbore 102 to facilitate the production of the reservoir fluid from the subterranean reservoir 107 to the surface equipment 110 at the wellsite surface 104. The production tubing 120 may define an internal space 121 through which the reservoir fluid may be transferred from the subterranean reservoir 107 to the wellsite surface 104. The inner casing 112 and the production tubing 120 may define an inner annular space 113 therebetween, the intermediate casing 114 and the inner casing 112 may define an intermediate annular space 115 therebetween, and the outer casing 116 and the intermediate casing 114 may define an outer annular space 117 therebetween. The casings 112, 114, 116 may be referred to in the oil and gas industry as casing A, casing B, and casing C, respectively, and the annular spaces 113, 115, 117 may be referred to in the oil and gas industry as annulus A, annulus B, and annulus C, respectively.
The surface equipment 110 may comprise a surface termination of the wellbore 102, known as a wellhead 122, comprising various spools, valves, and adapters that provide pressure control of the wellbore 102 and facilitate access to the internal space 103 of the wellbore 102, including the annular space 113 and the internal space 121 of the production tubing 120. The wellhead 122 may support each casing 112, 114, 116 in a predetermined position within the wellbore 102 during well construction operations. For example, each casing 112, 114, 116 may be connected to the wellhead 122 via a corresponding casing hanger 124, each maintaining a corresponding casing 112, 114, 116 in the predetermined position and fluidly isolating (or scaling) a corresponding annular space 113, 115 from the internal space 103 of the wellbore 102 and other portions of the wellhead 122. The wellhead 122 may support the production tubing 120 suspended within the internal space 103 of the wellbore 102 via a production tubing hanger 125.
A downhole intervention and/or sensor assembly, referred to as a tool string 130, may be conveyed within the internal space 103 of the wellbore 102 when the production tubing 120 is not installed within the internal space 103 or within the internal space 121 of the production tubing 120 when the production tubing 120 is installed within the internal space 103 of the wellbore 102. The tool string 130 may be conveyed within the wellbore 102 via a conveyance line 132 operably coupled with one or more pieces of the surface equipment 110. For example, the conveyance line 132 may be operably connected with a conveyance device 140 operable to apply an adjustable downward- and/or upward-directed force to the tool string 130 via the conveyance line 132 to convey the tool string 130 within the wellbore 102. The conveyance line 132 may be or comprise coiled tubing, a cable, a wireline, a slickline, a multiline, or an e-line, among other examples also within the scope of the present disclosure. The conveyance device 140 may be, comprise, or form at least a portion of a sheave or pulley, a winch, a drawworks, an injector head, and/or another device coupled to the tool string 130 via the conveyance line 132. The conveyance device 140 may be supported above the wellbore 102 via a mast, a derrick, a crane, and/or other support structure, which are collectively depicted in
The conveyance line 132 may comprise tubing, support wires, and/or cables configured to support the weight of the downhole tool string 130. The conveyance line 132 may also comprise one or more insulated electrical and/or optical conductors 134 operable to transmit electrical energy (i.e., electrical power) and electrical and/or optical signals (e.g., sensor data, control data, etc.) between the tool string 130 and one or more components of the surface equipment 110, such as a power and control system 150. The conveyance line 132 may comprise and/or be operable in conjunction with a means for communication between the tool string 130, the conveyance device 140, the winch conveyance device 144, and/or one or more other portions of the surface equipment 110, including the power and control system 150.
The wellbore 102 may be capped by a plurality (e.g., a stack) of fluid control devices 126, such as fluid control valves, spools, and fittings (e.g., a Christmas tree) individually and/or collectively operable to direct and control the flow of fluid out of the wellbore 102. The fluid control devices 126 may also or instead comprise a blowout preventer (BOP) stack operable to prevent the flow of fluid out of the wellbore 102. The fluid control devices 132 may be mounted on top of the wellhead 122.
The surface equipment 140 may further comprise a sealing and alignment assembly 128 mounted on the fluid control devices 126 and operable to seal the conveyance line 132 during deployment, conveyance, intervention, and other wellsite operations. The sealing and alignment assembly 128 may comprise a lock chamber (e.g., a lubricator, an airlock, a riser, etc.) mounted on the fluid control devices 126, a stuffing box operable to seal around the conveyance line 132 at the top of the lock chamber, and return pulleys operable to guide the conveyance line 132 between the stuffing box and the drum 146, although such details are not shown in
The power and control system 150 (e.g., a control center) may be utilized to monitor and control various portions of the wellsite system 100. The power and control system 150 may be located at the wellsite surface 104 or on a structure located at the wellsite surface 104. However, the power and control system 150 may instead be located at a location remote from the wellsite surface 104. The power and control system 150 may include a source of electrical power 152, a control workstation 154 (i.e., a human machine interface (HMI)), and a surface controller 156 (e.g., a processing device or computer). The surface controller 156 may be communicatively connected with various equipment of the wellsite system 100, such as may permit the surface controller 156 to monitor operations of one or more portions of the wellsite system 100 and/or to provide control of one or more portions of the wellsite system 100, including the tool string 130, the conveyance device 140, and/or the winch conveyance device 144. The control workstation 154 may be communicatively connected with the surface controller 156 and may include input devices for receiving the control data from human wellsite personnel and output devices for displaying sensor data and other information to the human wellsite personnel. The surface controller 156 may be operable to receive and process sensor data or information from the tool string 130 and/or control data (i.e., control commands) entered to the surface controller 156 by the human wellsite personnel via the control workstation 154. The surface controller 156 may store executable computer programs and/or instructions and may be operable to implement or otherwise cause one or more aspects of methods, processes, and operations described herein based on the executable computer programs, the received sensor data, and the received control data.
The tool string 130 may be conveyed within the wellbore 102 to perform various downhole sampling, testing, intervention, and other downhole operations. The tool string 130 may further comprise one or more downhole tools 136 (e.g., devices, modules, etc.) operable to perform such downhole operations. The downhole tools 136 of the tool string 130 may each be or comprise an acoustic tool, a cable head, a casing collar locator (CCL), a cutting tool, a density tool, a depth correlation tool, a directional tool, an electrical power module, an electromagnetic (EM) tool, a formation testing tool, a fluid sampling tool, a gamma ray (GR) tool, a gravity tool, a formation logging tool, a hydraulic power module, a magnetic resonance tool, a formation measurement tool, a jarring tool, a mechanical interface tool, a monitoring tool, a neutron tool, a nuclear tool, a packer, a photoelectric factor tool, a plug, a plug setting tool, a porosity tool, a power module, a ram, a reservoir characterization tool, a resistivity tool, a seismic tool, a straddle packer, a stroker tool, a surveying tool, and/or a telemetry tool, among other examples also within the scope of the present disclosure. The downhole tools 136 of the tool string 130 (or another tool string, not shown) may comprise a perforating tool operable to form perforations 105 through the casing 112, the cement 118, and the formation 106 comprising the subterranean reservoir 107 to facilitate flow of the reservoir fluid into the wellbore 102.
The present disclosure is further directed to a downhole sensor system 160 for measuring properties of or within the intermediate annular space (or annulus B) 115. The sensor system 160 may be installed in the inner annular space 113 and in fluid communication with the intermediate annular space 115 via a hole (or opening) 119 in the inner casing 112 and extending between the inner annular space 113 and the intermediate annular space 115. The hole 119 may be formed by a downhole tool 136 (e.g., a hole puncher, a drill, etc.) conveyed downhole within the internal space 103 of the wellbore 102 as part of the tool string 130 before the production tubing 120 is installed. After the hole 119 is formed in the inner casing 112, at least a portion of the sensor system 160 may be installed in association with the hole 119 via the conveyance line 132 as part of the tool string 130 before the production tubing 120 is installed. The hole 119 may instead be formed after a first portion of the sensor system 160 is conveyed downhole via the conveyance line 132 and installed along the inner casing 112. For example, the hole 119 may be formed or otherwise facilitated by the first portion of the sensor system 160 installed along the inner casing 112 before the production tubing 120 is installed. Thereafter, a second portion of the sensor system 160 may be installed in association with the first portion of the sensor system 160 previously installed along the inner casing 112. For example, the second portion of the sensor system 160 may be installed in association with the first portion of the sensor system 160 via the production tubing 120 as the production tubing 120 is installed within the internal space 103 of the wellbore 102. The sensor system 160 may then be used to measure properties (e.g., pressure, temperature, etc.) of or within the intermediate annular space 115 and transmit sensor data indicative of such properties to the surface equipment 110 (e.g., the surface controller 156) via a downhole communication (or telemetry) means (e.g., wireless communication means and/or wired communication means). Wireless communication means may include an acoustic transmitter implemented as part of the sensor system 160 and operable to transmit acoustic signals via the production tubing 120 to a corresponding acoustic receiver located at the wellsite surface 104 and communicatively connected with the surface equipment. Wired communication means may include a communication conductor extending along the production tubing 120 between the sensor system 160 and the surface equipment 110.
The tool string 202 may comprise a downhole tool 204 (e.g., a hole puncher, a drill, a laser emitter, etc.) operable to form a hole (or opening) 119 through a wall of a tubular within which the tool string 202 is conveyed. For example, the tool string 202 may be conveyed downhole within the internal space 103 of the wellbore 102 and form the hole 119 in the inner casing 112 and extending into the intermediate annular space 115.
After the hole 119 in the inner casing 112 and extending into the intermediate annular space 115 is formed by the downhole tool 204, a straddle packer 212 of the downhole sensor system 210 may be conveyed downhole and installed within the internal space 103 of the wellbore 102 in association with the hole 119. The straddle packer 212 may be conveyed downhole via the conveyance line 132 or other conveyance means. For example, the straddle packer 212 may be conveyed downhole as part of the tool string 202 and installed after the hole 119 is formed by the downhole tool 204. The straddle packer 212 may instead be conveyed downhole as part of another tool string and installed after the downhole tool 204 forms the hole 119 and the tool string 202 is retrieved to the wellsite surface 104.
The straddle packer 212 may comprise a packer body 214 comprising a first bore (or pathway) 216 and a second bore (or pathway) 218. The packer body 214 may comprise a tubular geometry, having an outer circumferential (or cylindrical) surface and an inner circumferential (or cylindrical) surface defining the first bore 216 extending along a central longitudinal axis 215 of the packer body 214. The second bore 218 may extend radially with respect to the central longitudinal axis 215 between the outer surface and the inner surface of the packer body 214. The straddle packer 212 may further comprise a first sealing element 222 carried by the packer body 214 and operable to expand in a radially outward direction to seal against an inner surface of the inner casing 112, and a second sealing element 224 carried by the packer body 214 and operable to expand in a radially outward direction to seal against the inner surface of the inner casing 112. The first sealing element 222 and the second sealing element 224 may be operable to isolate an interval of an annular space 225 defined between the inner surface of the inner casing 112 and the outer surface of the packer body 214 when the first sealing element 222 and the second sealing element 224 are sealed against the inner surface of the inner casing 112. The straddle packer 212 may also comprise an obstruction (e.g., an obstructing member, an obstruction system, etc.) selectively movable, reversible, or otherwise operable between a first position (shown in
During installation operations of the straddle packer 212, the straddle packer 212 may be conveyed within the inner casing 112 until the hole 119 is located between the first sealing element 222 and the second sealing element 224. The first sealing element 222 and the second sealing element 224 may then be set against the inner casing 112 such that the first sealing element 222 and the second sealing element 224 are located on opposing sides of the hole 119. The straddle packer 212 may further comprise one or more fluid seals 230 between the packer body 214 and the obstruction 226 to prevent or inhibit fluid communication therebetween.
After the straddle packer 212 is installed in association with the hole 119 and the tool string used for installing the straddle packer 212 is retrieved to the wellsite surface 104, a sensor sub 232 of the downhole sensor system 210 may be conveyed downhole within the internal space 103 of the wellbore 102 and installed in association with the straddle packer 212. The sensor sub 232 may be conveyed downhole via or as part of the production tubing 120 installed within the internal space 103 of the wellbore 102 for producing the reservoir fluid containing the oil and/or gas from the subterranean reservoir 107.
The sensor sub 232 may therefore be configured to engage the straddle packer 212 and for connection within the production tubing 120 or another downhole pipe string. For example, the sensor sub 232 may comprise a sub body 234 comprising a first connector 236 (e.g., a male or female threaded coupler) configured for connection with a first (e.g., upper) portion of the production tubing 120 and a second connector 238 (e.g., a male or female threaded coupler) configured for connection with a second (e.g., lower) portion of the production tubing 120. The sensor sub 232 may further comprise a sensor 240 connected to or otherwise carried by the sub body 234. The sensor 240 may be operable to output sensor data indicative of properties within the inner annular space 115. The sensor 240 may be or comprise a pressure sensor operable to output pressure data indicative of pressure within the inner annular space 115. The sensor 240 may also or instead be or comprise a temperature sensor operable to output temperature data indicative of temperature within the inner annular space 115. The sensor data output by the sensor 240 may be transmitted to the surface equipment 110 via a communication conductor 241 (e.g., a cable) extending along the production tubing 120 between the sensor 240 and the surface equipment 110.
The sub body 234 may further comprise a first bore (or pathway) 242 extending between the first connector 234 and the second connector 236, and configured to fluidly connect the first portion of the production tubing 120 and the second portion of the production tubing 120 to permit the reservoir fluid to flow through the sub body 234. The sub body 234 may comprise a tubular geometry, having an outer circumferential (or cylindrical) surface and an inner circumferential (or cylindrical) surface defining the first bore 242 extending along a central longitudinal axis 235 of the sub body 234. The sub body 234 may also comprise a second bore (or pathway) 244 extending between the outer surface of the sub body 234 and the sensor 240. The sub body 234 may further comprise an upper surface, a lower surface, and one or more third bores 246 extending between the upper surface and the lower surface, wherein the upper surface and the lower surface are on opposing sides of the outer surface of the sub body 234. The third bores 246 may be open to the inner annular space 113 thereby fluidly connecting the inner annular space 113 on opposing sides of the sensor system 210. The sub body 234 may comprise a smaller diameter section 250 comprising or containing the first connector 236, the second connector 238, and the first bore 242, and a larger diameter section 252 comprising or containing the outer surface, the second bore 244, and the third bores 246. The third bores 246 may be distributed circumferentially around the smaller diameter section 250 and the first bore 242.
The sensor sub 232 may be installed (or inserted) within or otherwise in association with the straddle packer 212 to assemble or otherwise form the sensor assembly 210. For example, the inner surface (or the bore 216) of the packer body 214 may be configured to accommodate the sensor sub 232 such that the outer surface of the sub body 234 is disposed against the inner surface of the packer body 214 and the bore 218 of the straddle packer 212 and the bore 244 of the sensor sub 232 are operatively connected (e.g., fluidly connected, in fluid communication, etc.). The sensor sub 232 may therefore comprise one or more fluid seals 254 along or carried by the outer surface of the sub body 234 to prevent or inhibit fluid communication between the inner surface of the packer body 214 and the outer surface of the sub body 234. Furthermore, the sensor sub 232 may be slidably movable within the straddle packer 212 such that when the sensor sub 232 is slidably moved within the straddle packer 212, the sub body 234 contacts the obstruction 226 and moves the obstruction 226 from the first position to the second position. For example, the sub body 234 may comprise a shoulder 258 facing downward and extending in a radially outward direction. The shoulder 258 may be configured to contact the obstruction 226 and move the obstruction 226 from the first position to the second position when the sensor sub 232 is slidably moved within the straddle packer 212.
When the sensor sub 232 is installed (or inserted) within or otherwise in association with the straddle packer 212 to assemble or otherwise form the sensor assembly 210, the sensor 240 may be operatively connected (e.g., fluidly connected, in fluid communication, etc.) with inner annular space 115 via the bores 218, 244, the interval of annular space 225, and the hole 119 in the inner casing 112. Accordingly, the sensor 240 may be in contact with or otherwise exposed to the fluid within the inner annular space 115 and, thus, operable to measure properties (e.g., temperature, pressure, etc.) of or within the inner annular space 115.
As described above with reference to
The sensor system 310 may comprise various features described above in association with the sensor system 210 shown in
As shown in
As shown in
The method 600 may comprise conveying 602 a straddle packer 212 within a wellbore 102 lined with a casing 112 (e.g., casing B) such that the straddle packer 212 is disposed adjacent a hole 119 extending through the casing 112 into an annular space 115 (e.g., annulus B) behind the casing 112. The straddle packer 212 may comprise a packer body 214 having a longitudinal bore 216 and a radial bore 218 connected with the longitudinal bore 216. The method 600 may further comprise setting 604 the straddle packer 212 such that a first scaling element 222 of the straddle packer 212 seals against the casing 112 above the hole 119 and a second sealing element 224 of the straddle packer 212 seals against the casing 112 below the hole 119. The method 600 may further comprise installing 606 a production tubing string 120 comprising a sensor sub 232 within the wellbore 102. The sensor sub 232 may comprise a pressure sensor 240 and a sub body 234. Installing the production tubing string 120 within the wellbore 102 may comprise conveying the production tubing string 120 within the wellbore 102 until the sub body 234 is within the longitudinal bore 216 of the packer body 214 such that the sensor 240 is in fluid communication with the annular space 115 behind the casing 112 via the hole 119 through the casing 112 and the radial bore 218 through the packer body 214. The method 600 may also comprise monitoring 608 pressure within the annular space 115 in real time via the pressure sensor 240.
The pressure sensor 240 may be connected to the sub body 234 and the sub body 234 may comprise a bore 244 extending between an outer surface of the sub body 234 and the pressure sensor 240. Installing the production tubing string 120 within the wellbore 102 may therefore comprise conveying the production tubing string 120 within the wellbore 120 until the sub body 234 is within the longitudinal bore 216 of the packer body 214 such that the bore 244 through the sub body 234 and the radial bore 218 through the packer body 214 are in fluid communication.
The method 700 may comprise conveying 702 a straddle packer 312 within a wellbore 102 lined with a casing 112. The straddle packer 312 may comprise a hole making device 314 and a packer body 214 having a longitudinal bore 216 and a radial bore 218 connected with the longitudinal bore 216. The method 700 may further comprise setting 704 the straddle packer 312 such that a first sealing element 222 of the straddle packer 312 seals against the casing 112 and a second sealing element 224 of the straddle packer 312 seals against the casing 112. The method 700 may further comprise operating 706 the hole making device 314 to cause the hole making device 314 to form a hole 119 in the casing 112 between the first sealing element 222 and the second sealing element 224. The hole 119 may extend through the casing 112 into an annular space 115 behind the casing 112. The method 700 may further comprise installing 708 a production tubing string 120 comprising a sensor sub 232 within the wellbore 102. The sensor sub 232 may therefore comprise a pressure sensor 240 and a sub body 234. Installing the production tubing string 120 within the wellbore 102 may comprise conveying the production tubing string 120 within the wellbore 102 until the sub body 234 is within the longitudinal bore 216 of the packer body 214 such that the sensor 240 is in fluid communication with the annular space 115 behind the casing 112 via the hole 119 through the casing 112 and the radial bore 218 through the packer body 214. The method 700 may also comprise monitoring 710 pressure within the annular space 115 in real time via the pressure sensor 240.
If the hole making device 314 is or comprises a pin 416 supported by the packer body 214 between the first sealing element 222 and the second sealing element 224, the method may further comprise: conveying an actuator tool 418 within the wellbore 102 until the actuator tool 418 is adjacent the hole making device 314; operating the actuator tool 418 to cause the actuator tool 418 to operate the hole making device 314 by causing the actuator tool 418 to move the pin 416 through the casing 112 to form the hole 119 in the casing 112 between the first sealing element 222 and the second sealing element 224; and retrieving the actuator tool 418 to the wellsite surface 104 from within the wellbore 102.
If the hole making device 314 is or comprises is or comprises an explosive device 514 having a projectile 516 and an explosive charge 518, the method may further comprise operating the explosive device 514 by detonating the explosive charge 518 to propel the projectile 516 toward the casing 112 to form the hole 119 in the casing 112 between the first sealing element 222 and the second sealing element 222.
The foregoing outlines features of several embodiments so that a person having ordinary skill in the art may better understand the aspects of the present disclosure. A person having ordinary skill in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. A person having ordinary skill in the art should also realize that such equivalent constructions do not depart from the scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the scope of the present disclosure.
This application is the National Stage Entry of International Application No. PCT/US2023/020313, filed Apr. 28, 2023, which claims the benefit of U.S. Provisional Application No. 63/363,719, entitled “MONITORING CASING ANNULUS,” filed Apr. 28, 2022, the disclosure of which is hereby incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/US2023/020313 | 4/28/2023 | WO |
Publishing Document | Publishing Date | Country | Kind |
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WO2023/212270 | 11/2/2023 | WO | A |
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Entry |
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Search Report and Written Opinion of International Patent Application No. PCT/US2023/020313 dated Aug. 10, 2023, 12 pages. |
Number | Date | Country | |
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63363719 | Apr 2022 | US |