The present invention relates to a reciprocating internal combustion engine which sequesters ambient CO.sub.2 into a carbonate salt, thereby helping to reduce a primary cause of global warming.
Global warming is expected to become an increasingly important issue for a significant fraction of the world's population. Global temperatures are expected to rise several degrees in the coming decades, leading to extreme weather events, ozone depletion, animal and plant extinctions and more pronounced spread of diseases. Driving much of this warming are hydrocarbon emissions from automobile sources. It is thus natural to assert that since automobiles have brought to our present global warming crisis, they should be the conduit to reverse present CO.sub.2 buildup.
We assert that this reversal can be best accomplished via the construction of an automobile motor that burns a carbon-free fuel while at the same time reduces the ambient levels of carbon dioxide in the atmosphere. This is accomplished in the present invention by the reaction of incoming CO.sub.2 with aqueous base in the motor system. The aqueous base is produced in situ by electrochemical oxidation of water in the presence of a metal salt. The energy for the electrolysis derives in part from a turbo-generator connected to exhaust end of an internal combustion engine. The reaction of CO.sub.2 with hydroxide base is illustrated as follows for hydroxide salts possessing group I cations M.sup.+:
CO.sub.2+2M.sup.+(OH.sup.−).fwdarw.M.sub.2CO.sub.3+H.sub.20
It is understood that cations from groups I (for example Li.sup.+, Na.sup.+, K.sup.+), group II (for example Ca.sup.+2 or Sr.sup.+2) or group III (e.g Al.sup.+3), as well as transition metals, may be used. M may also represent ammonia containing cations, such as NH.sub.4.sup.+. The resulting carbonate salt can be collected in a suitable receptacle in the automobile and later disposed in solid form. In this manner we have a net reversal of CO.sub.2 emissions. The reaction vessel may be in the form of a grill having hydroxide-containing channels that are exposed to incoming air/CO.sub.2. The reaction vessel containing aqueous base may be located in the path to the intake manifold of the engine or it may be located in the path after combustion. The present invention can be also be used in an automobile that burns hydrocarbons, for a diminution of CO2 emissions. Typical reaction temperatures would be from −25.degree. C. to 100.degree. C.
The hydroxide in the present invention is made in situ via the electrolysis of an aqueous salt solution as shown in the following reaction:
2M.sup.++2H.sub.2O+2e.sup.−.fwdarw.H.sub.2+2MOH
where M is again a metal.
We hereby provide an illustration in
As shown in the
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